散文網(wǎng) » 科技 »自然 » 【標(biāo)題速讀】【JACS】【2022年】【10月】

【標(biāo)題速讀】【JACS】【2022年】【10月】

2023-06-12 17:19 作者:Rt_Cola 0人讀過 | 我要投稿

聲明：本專欄主要對生命科學(xué)領(lǐng)域的一些期刊文章標(biāo)題進行翻譯，所有內(nèi)容均由本人手工整理翻譯。由于本人專業(yè)為生物分析相關(guān)，其他領(lǐng)域如果出現(xiàn)翻譯錯誤請諒解。

Liang and co-workers report a simple yet versatile and effective strategy to optimize biocatalytic activity by using a metal-organic framework to rapidly “l(fā)ock” the ultrasound-activated but more fragile conformation of metalloenzymes. This novel strategy gives rise to new possibilities for the exploitation of highly efficient biocatalysts for diverse applications.

Liang 及其同事報告了一種簡單但通用且有效的策略，通過使用金屬有機骨架快速“鎖定”超聲波激活但更脆弱的金屬酶構(gòu)象來優(yōu)化生物催化活性。這種新穎的策略為開發(fā)用于各種應(yīng)用的高效生物催化劑帶來了新的可能性。

Some inorganic solids undergo phase transitions that result in the formation of “molecules” in their crystalline frameworks, which are frequently accompanied by dramatic changes in physical properties. We have discovered the creation of a linear ruthenium trimer with atypical three-center–four-electron bonding in RuP at its metal–insulator transition.

一些無機固體經(jīng)歷相變，導(dǎo)致在其結(jié)晶框架中形成“分子”，這通常伴隨著物理性質(zhì)的顯著變化。我們發(fā)現(xiàn)在 RuP 的金屬 - 絕緣體轉(zhuǎn)變中產(chǎn)生了具有非典型三中心 - 四電子鍵合的線性釕三聚體。

Folded π molecules tend to form well-aligned 1D molecular columns of patterns (“box”, “braid”, or “stair”) with high packing energy, which is mainly contributed by numerous weak π interactions. As a result of effective suppression of molecular motion, all of the compounds show very high exciton utilization in solids.

折疊的 π 分子傾向于形成排列良好的一維分子柱模式（“盒子”、“辮子”或“階梯”），具有高堆積能，這主要是由許多弱 π 相互作用造成的。由于有效抑制分子運動，所有化合物在固體中都顯示出非常高的激子利用率。

Photoreactive surfaces for anchoring heterogenous cells have been developed using a photoactivatable dibenzocyclooctyne precursor. On the surface, a variety of cells can be selectively anchored onto the light-irradiated areas where various cell-anchoring molecules are conjugated through the click reaction. This surface has achieved single-cell pair arrays for intercellular communication analysis.

已經(jīng)使用可光活化的二苯并環(huán)辛炔前體開發(fā)了用于錨定異質(zhì)細胞的光反應(yīng)表面。在表面上，各種細胞可以選擇性地錨定在光照射區(qū)域上，各種細胞錨定分子通過點擊反應(yīng)結(jié)合在一起。該表面已經(jīng)實現(xiàn)了用于細胞間通訊分析的單細胞對陣列。

Nuclear spin hyperpolarization of water at room temperature is essential for high-sensitivity NMR/MRI applications but has been a challenging task. Using organic nanocrystals doped with a photoexcited triplet polarizing agent, the polarization transfer from nanocrystals to liquid water is demonstrated for the first time.

室溫下水的核自旋超極化對于高靈敏度 NMR/MRI 應(yīng)用至關(guān)重要，但一直是一項具有挑戰(zhàn)性的任務(wù)。使用摻雜有光激發(fā)三線態(tài)偏振劑的有機納米晶體，首次證明了從納米晶體到液態(tài)水的偏振轉(zhuǎn)移。

We report a multicomponent synthesis of a crystalline two-dimensional covalent organic framework (COF) by connecting acetaldehyde with aromatic aldehyde and acetonitrile building blocks to form cyano-substituted buta-1,3-diene linkages. Our multicomponent synthesis strategy may provide new insights for synthesizing COFs with structural diversity and functional variability.

我們通過將乙醛與芳香醛和乙腈結(jié)構(gòu)單元連接起來形成氰基取代的丁-1,3-二烯鍵，報告了結(jié)晶二維共價有機骨架 (COF) 的多組分合成。我們的多組分合成策略可能為合成具有結(jié)構(gòu)多樣性和功能可變性的 COF 提供新的見解。

Suspensions of colloidal particles experience spontaneous phase separation into particle-rich and particle-depleted domains in the presence of depletant when the enthalpy gain overwhelms entropic loss. The particle-rich solid phase has either crystalline or amorphous arrays depending on the rate of assembly.

當(dāng)焓增益超過熵損失時，膠體顆粒的懸浮液在存在耗盡劑的情況下會自發(fā)相分離成富含顆粒和耗盡顆粒的區(qū)域。富含顆粒的固相具有結(jié)晶或非晶陣列，具體取決于組裝速率。

The Pd1–Cu1 dual-atom catalyst is highly active/selective in the acetylene semi-hydrogenation reaction. Compared to the single-atom catalyst, it offers sterically favorable sites for the simultaneous adsorption of reactants and changes the reaction path to render high reactivity at low temperature.

Pd1-Cu1雙原子催化劑在乙炔半加氫反應(yīng)中具有高活性/選擇性。與單原子催化劑相比，它為反應(yīng)物的同時吸附提供了空間上有利的位點，并改變了反應(yīng)路徑以在低溫下提供高反應(yīng)性。

Functional-unit-based material design is an efficient approach for identifying high-performance functional materials. The discovery process includes the identification of useful functional units relevant to the desired properties (such as linear triatomic resonant bonds for thermoelectrics) and screening for desired materials within the space of compounds containing these units.

基于功能單元的材料設(shè)計是識別高性能功能材料的有效方法。發(fā)現(xiàn)過程包括識別與所需特性相關(guān)的有用功能單元（例如熱電的線性三原子共振鍵），以及在包含這些單元的化合物空間內(nèi)篩選所需材料。

Non-oxidative coupling of methane on Pt surfaces has been thoroughly investigated from an orbital perspective. Based on the analysis, a single atom alloy catalyst with a single Pt atom embedded in the Au surface was rationally proposed.

已從軌道角度對甲烷在 Pt 表面的非氧化偶聯(lián)進行了徹底研究。在此基礎(chǔ)上，合理地提出了在Au表面嵌入單個Pt原子的單原子合金催化劑。

Chemotherapy is almost exclusively administered via the intravenous route, which results in severe limitations. Therefore, the development of effective and less expensive chemotherapy that improves patients' quality of life could be a game changer in medical oncology. While subcutaneous (SC) administration has the potential to meet these criteria, it is extremely restrictive as it cannot be applied to most anticancer drugs, such as irritant or vesicant ones, due to prohibitive local toxicity. In this article, Bordat and co-workers reported an easy, safe, and robust approach for the SC administration of irritant/vesicant anticancer drugs through the design of well-defined hydrophilic polymer prodrugs by the “drug-initiated” method. The cover illustrates the SC administration of water-soluble polymer prodrugs.

化療幾乎完全通過靜脈內(nèi)途徑給藥，這導(dǎo)致嚴(yán)重的局限性。因此，開發(fā)有效且成本較低的化學(xué)療法來改善患者的生活質(zhì)量可能會改變腫瘤內(nèi)科的游戲規(guī)則。雖然皮下 (SC) 給藥有可能滿足這些標(biāo)準(zhǔn)，但由于局部毒性過高，它不能應(yīng)用于大多數(shù)抗癌藥物，例如刺激性或發(fā)泡性藥物，因此它受到了極大的限制。在這篇文章中，Bordat 及其同事報告了一種簡單、安全和穩(wěn)健的方法，通過“藥物引發(fā)”方法設(shè)計定義明確的親水性聚合物前體藥物，通過 SC 給藥刺激性/發(fā)泡性抗癌藥物。封面說明了水溶性聚合物前藥的 SC 給藥。

A π-conjugated nickel coordination complex containing thieno[3,2-b]thiophene units was designed and synthesized. Composite films of the resulting nickel complex and PVDF, which can be fabricated via a simple solution process under atmospheric conditions, exhibit remarkably high n-type conductivity (>200 S cm?1) with excellent stability against atmospheric oxidation.

設(shè)計并合成了含有噻吩并[3,2-b]噻吩單元的π-共軛鎳配位絡(luò)合物。由此產(chǎn)生的鎳絡(luò)合物和 PVDF 的復(fù)合膜可以在大氣條件下通過簡單的溶液工藝制造，具有非常高的 n 型電導(dǎo)率（>200 S cm-1）和出色的抗大氣氧化穩(wěn)定性。

Under high pressure, two-dimensional (2D) van der Waals hydrogenated germanene (GeH) exhibits structural and superconducting transitions. A superconducting transition with the critical temperature (Tc) of 5.41 K at 8.39 GPa is demonstrated in GeH, accompanied by the dehydrogenation process. Pressure-induced irreversible transition from the 2D crystalline phase to the 2D amorphous phase is achieved under compression above 16.80 GPa and decompression while superconductivity remains.

在高壓下，二維 (2D) 范德瓦爾斯氫化鍺烯 (GeH) 表現(xiàn)出結(jié)構(gòu)和超導(dǎo)轉(zhuǎn)變。在 GeH 中證明了在 8.39 GPa 下臨界溫度 (Tc) 為 5.41 K 的超導(dǎo)轉(zhuǎn)變，并伴隨著脫氫過程。在超過 16.80 GPa 的壓縮和減壓下實現(xiàn)從 2D 晶相到 2D 非晶相的壓力誘導(dǎo)不可逆轉(zhuǎn)變，同時保持超導(dǎo)性。

Organosulfides are promising cathodes for rechargeable lithium batteries. In this work, thiuram monosulfide without any active sites becomes electrochemically active via an in situ electrochemical oxidation strategy. As visually illustrated in the cover art, it is converted into an active material for rechargeable lithium batteries after electrochemical oxidation.

有機硫化物是可充電鋰電池的有前途的陰極。在這項工作中，沒有任何活性位點的秋蘭姆單硫化物通過原位電化學(xué)氧化策略變得具有電化學(xué)活性。如封面藝術(shù)所示，它在電化學(xué)氧化后轉(zhuǎn)化為可充電鋰電池的活性材料。

Spinel structured Co3O4 consisting of tetrahedral (Co2+-O)Td and octahedral (Co3+-O)Oh geometric configurations. This work has determined the superiority and dominant role of the (Co3+-O)Oh configuration in alkaline water reduction compared with (Co2+-O)Td.

尖晶石結(jié)構(gòu)的 Co3O4 由四面體 (Co2+-O)Td 和八面體 (Co3+-O)Oh 幾何構(gòu)型組成。與 (Co2+-O)Td 相比，這項工作確定了 (Co3+-O)Oh 構(gòu)型在堿性水還原中的優(yōu)勢和主導(dǎo)作用。

Amorphous palladium sulfide enables selective electrocatalytic semihydrogenation of terminal alkynes in water with excellent tolerance to easily reducible groups and deactivating skeletons because of specific σ-alkynyl adsorption on isolated palladium sites.

無定形硫化鈀能夠在水中對末端炔烴進行選擇性電催化半氫化，對易于還原的基團和失活骨架具有出色的耐受性，因為在孤立的鈀位點上具有特異性 σ-炔基吸附。

We present a successful application of a blind approach to reaction discovery, which revealed a plethora of competing thermal pathways affecting the multistep switching mechanism of donor–acceptor Stenhouse adducts (DASAs). Our approach bridges the gap between short fs/ps relaxation dynamics and long ns/ms reaction regimes.

我們展示了盲法在反應(yīng)發(fā)現(xiàn)中的成功應(yīng)用，揭示了影響供體-受體 Stenhouse 加合物 (DASA) 多步轉(zhuǎn)換機制的過多競爭性熱通路。我們的方法彌合了短 fs/ps 弛豫動力學(xué)和長 ns/ms 反應(yīng)機制之間的差距。

Thin, cross-linked zwitterionic polymer coatings with an in-built gradient of super-hydrophilic sulfobetaine molecules lower the activity of water at electrodes and protect aqueous electrolytes from electrochemical reduction in batteries.

薄的、交聯(lián)的兩性離子聚合物涂層具有內(nèi)置的超親水性磺基甜菜堿分子梯度，可降低電極處水的活性，并保護含水電解質(zhì)免受電池中的電化學(xué)還原。

Extreme ultraviolet (EUV) radiation ejects secondary electrons from the photoacid generator (PAG)-tethered cyclic polyphthalaldehyde resist matrix. The PAG accepts the ejected secondary electrons and generates the corresponding acid, which in turn causes the resist matrix to depolymerize, allowing fine features to be printed by EUV radiation.

極紫外 (EUV) 輻射從光致產(chǎn)酸劑 (PAG) 束縛的環(huán)狀聚苯二甲醛抗蝕劑基質(zhì)中射出二次電子。 PAG 接受射出的二次電子并產(chǎn)生相應(yīng)的酸，這反過來會導(dǎo)致抗蝕劑基質(zhì)解聚，從而允許通過 EUV 輻射印刷精細特征。

1.A Potential Roadmap to Integrated Metal Organic Framework Artificial Photosynthetic Arrays.

集成金屬有機框架人工光合陣列的潛在路線圖。

2.Cyanurate-Linked Covalent Organic Frameworks Enabled by Dynamic Nucleophilic Aromatic Substitution.

由動態(tài)親核芳香取代實現(xiàn)的氰尿酸酯連接的共價有機框架。

3.A High-Performance Single-Molecule Magnet Utilizing Dianionic Aminoborolide Ligands.

利用雙陰離子氨基硼化物配體的高性能單分子磁體。

4.Identifying Metal-Oxo/Peroxo Intermediates in Catalytic Water Oxidation by In Situ Electrochemical Mass Spectrometry.

通過原位電化學(xué)質(zhì)譜法鑒定催化水氧化中的金屬-氧/過氧中間體。

5.Maximizing Vanadium Deployment in Redox Flow Batteries Through Chelation.

通過螯合作用最大化釩在氧化還原液流電池中的部署。

6.Optically Switchable NIR Photoluminescence of PbS Semiconducting Nanocrystals using Diarylethene Photoswitches.

使用二芳基乙烯光開關(guān)的 PbS 半導(dǎo)體納米晶體的光可切換 NIR 光致發(fā)光。

7.Asymmetric Hydrogenation of Oximes Synergistically Assisted by Lewis and Br?nsted Acids.

Lewis 和 Br?nsted 酸協(xié)同輔助肟的不對稱氫化。

8.Syntheses of Bufospirostenin A and Ophiopogonol A by a Conformation-Controlled Transannular Prins Cyclization.

通過構(gòu)象控制的跨環(huán) Prins 環(huán)化合成蟾蜍螺菌素 A 和麥冬酚 A。

9.Remote and Proximal Hydroaminoalkylation of Alkenes Enabled by Photoredox/Nickel Dual Catalysis.

通過光氧化還原/鎳雙催化實現(xiàn)烯烴的遠程和近端加氫氨基烷基化。

10.Intercepting Hydrogen Evolution with Hydrogen-Atom Transfer: Electron-Initiated Hydrofunctionalization of Alkenes.

用氫原子轉(zhuǎn)移攔截氫的析出：電子引發(fā)的烯烴加氫官能化。

11.Total Synthesis of Ginkgolide C and Formal Syntheses of Ginkgolides A and B.

銀杏內(nèi)酯C的全合成和銀杏內(nèi)酯A、B的形式合成。

12.Conversion of Aryl Azides to Aminopyridines.

芳基疊氮化物轉(zhuǎn)化為氨基吡啶。

13.Gram-Scale Enantioselective Synthesis of (+)-Lucidumone.

(+)-Lucidumone 的克級對映選擇性合成。

14.Catalytic Enantioselective Sulfur Alkylation of Sulfenamides for the Asymmetric Synthesis of Sulfoximines.

次磺酰胺的催化對映選擇性硫烷基化用于亞砜亞胺的不對稱合成。

15.Copper-Catalyzed Coupling of Alkyl Vicinal Bis(boronic Esters) to an Array of Electrophiles.

銅催化偶聯(lián)烷基鄰位雙（硼酸酯）與一系列親電子試劑。

16.A Spectroscopically Observed Iron Nitrosyl Intermediate in the Reduction of Nitrate by a Surface-Conjugated Electrocatalyst.

表面共軛電催化劑還原硝酸鹽過程中的光譜觀察亞硝酰鐵中間體。

17.Investigation of Water Evaporation Process at Air/Water Interface using Hofmeister Ions.

使用霍夫邁斯特離子研究空氣/水界面的水蒸發(fā)過程。

18.Domain-Specific Phase Transitions in a Supramolecular Nanostructure.

超分子納米結(jié)構(gòu)中的域特定相變。

19.The Growth Dynamics of Organic–Inorganic Metal Halide Perovskite Films.

有機-無機金屬鹵化物鈣鈦礦薄膜的生長動力學(xué)。

20.Linear Trimer Molecule Formation by Three-Center–Four-Electron Bonding in a Crystalline Solid RuP.

在結(jié)晶固體 RuP 中通過三中心-四電子鍵合形成線性三聚體分子。

21.Locking the Ultrasound-Induced Active Conformation of Metalloenzymes in Metal–Organic Frameworks.

鎖定金屬有機框架中金屬酶的超聲誘導(dǎo)活性構(gòu)象。

22.Bioinformatic Atlas of Radical SAM Enzyme-Modified RiPP Natural Products Reveals an Isoleucine–Tryptophan Crosslink.

自由基 SAM 酶修飾的 RiPP 天然產(chǎn)物的生物信息學(xué)圖譜揭示了異亮氨酸-色氨酸交聯(lián)。

23.High-Resolution Cryo-Electron Microscopy Reveals the Unique Striated Hollow Structure of Photocatalytic Macrocyclic Polydiacetylene Nanotubes.

高分辨率冷凍電子顯微鏡揭示了光催化大環(huán)聚二乙炔納米管的獨特條紋空心結(jié)構(gòu)。

24.High Exciton Utilization of 1D Molecular Column with High Packing Energy Formed by Folded π-Molecules.

由折疊 π 分子形成的具有高堆積能的一維分子柱的高激子利用。

25.Multidimensional Control of Repeating Unit/Sequence/Topology for One-Step Synthesis of Block Polymers from Monomer Mixtures.

從單體混合物一步合成嵌段聚合物的重復(fù)單元/序列/拓撲的多維控制。

26.π-Extended Ligands in Two-Coordinate Coinage Metal Complexes.

π - 雙配位造幣金屬配合物中的擴展配體。

27.Insights into the Mechanism of Carbon Dioxide and Propylene Oxide Ring-Opening Copolymerization Using a Co(III)/K(I) Heterodinuclear Catalyst.

使用 Co(III)/K(I) 雜雙核催化劑深入了解二氧化碳和環(huán)氧丙烷開環(huán)共聚的機理。

28.Correlating Thermodynamic and Kinetic Hydricities of Rhenium Hydrides.

相關(guān)的熱力學(xué)和動力學(xué)氫化錸。

29.Ni-Centered Coordination-Induced Spin-State Switching Triggered by Electrical Stimulation.

由電刺激觸發(fā)的以鎳為中心的配位誘導(dǎo)自旋狀態(tài)切換。

30.Atomistic Insights into Activation and Degradation of La0.6Sr0.4CoO3?δ Electrocatalysts under Oxygen Evolution Conditions.

La0.6Sr0.4CoO3?δ 電催化劑在析氧條件下的活化和降解的原子洞察。

31.Bioorthogonal Photoreactive Surfaces for Single-Cell Analysis of Intercellular Communications.

用于細胞間通訊單細胞分析的生物正交光反應(yīng)表面。

32.Directed, Remote Dirhodium C(sp3)-H Functionalization, Desaturative Annulation, and Desaturation.

定向、遠程二銠 C(sp3)-H 功能化、去飽和環(huán)化和去飽和。

33.Scalable Synthesis and Characterization of Multilayer γ-Graphyne, New Carbon Crystals with a Small Direct Band Gap.

多層 γ-石墨烯、具有小直接帶隙的新型碳晶體的可擴展合成和表征。

34.Thermodynamics and Kinetics of the Cathode–Electrolyte Interface in All-Solid-State Li–S Batteries.

全固態(tài)鋰硫電池中陰極-電解質(zhì)界面的熱力學(xué)和動力學(xué)。

35.Proton Hyperpolarization Relay from Nanocrystals to Liquid Water.

從納米晶體到液態(tài)水的質(zhì)子超極化中繼。

36.Stereochemically Active Lone Pairs and Nonlinear Optical Properties of Two-Dimensional Multilayered Tin and Germanium Iodide Perovskites.

二維多層錫和碘化鍺鈣鈦礦的立體化學(xué)活性孤對和非線性光學(xué)性質(zhì)。

37.Fluorogenic Dimers as Bright Switchable Probes for Enhanced Super-Resolution Imaging of Cell Membranes.

熒光二聚體作為用于增強細胞膜超分辨率成像的明亮可切換探針。

38.Hydrogen-Bonded Water-Aminium Assemblies for Synthesis of Zeotypes with Ordered Heteroatoms.

用于合成具有有序雜原子的 Zeotypes 的氫鍵合水-銨組件。

39.Chain-to-Layer Dimensionality Engineering of Chiral Hybrid Perovskites to Realize Passive Highly Circular-Polarization-Sensitive Photodetection.

手性雜化鈣鈦礦的鏈層維度工程實現(xiàn)被動高圓偏振敏感光電檢測。

40.Removal of Stomatin, a Membrane-Associated Cell Division Protein, Results in Specific Cellular Lipid Changes.

去除 Stomatin（一種膜相關(guān)細胞分裂蛋白）會導(dǎo)致特定的細胞脂質(zhì)變化。

41.Treating Superhard Materials as Anomalies.

將超硬材料視為異常。

42.A Counterion/Ligand-Tuned Chemo- and Enantioselective Copper-Catalyzed Intermolecular Radical 1,2-Carboamination of Alkenes.

抗衡離子/配體調(diào)節(jié)的化學(xué)和對映選擇性銅催化的烯烴分子間自由基 1,2-碳胺化。

43.Design of a Flexible, Zn-Selective Protein Scaffold that Displays Anti-Irving–Williams Behavior.

顯示反 Irving-Williams 行為的靈活、Zn 選擇性蛋白質(zhì)支架的設(shè)計。

44.Repurposing Cyanine Photoinstability To Develop Near-Infrared Light-Activatable Nanogels for In Vivo Cargo Delivery.

重新利用花青的光不穩(wěn)定性來開發(fā)用于體內(nèi)貨物輸送的近紅外光可激活納米凝膠。

45.Ligand-Enabled C–H Hydroxylation with Aqueous H2O2 at Room Temperature.

在室溫下用 H2O2 水溶液進行配體使能的 C-H 羥基化。

46.A Toolkit for Engineering Proteins in Living Cells: Peptide with a Tryptophan-Selective Ru-TAP Complex to Regioselectively Photolabel Specific Proteins.

用于在活細胞中設(shè)計蛋白質(zhì)的工具包：具有色氨酸選擇性 Ru-TAP 復(fù)合物的肽以區(qū)域選擇性光標(biāo)記特定蛋白質(zhì)。

47.Control of Hot Carrier Cooling in Lead Halide Perovskites by Point Defects.

通過點缺陷控制鹵化鉛鈣鈦礦中的熱載流子冷卻。

48.A Charge-Neutral Self-Assembled L2Zn2 Helicate as Bench-Stable Receptor for Anion Recognition at Nanomolar Concentration.

電荷中性的自組裝 L2Zn2 螺旋酸鹽作為穩(wěn)定受體用于納摩爾濃度下的陰離子識別。

49.What is the Real Origin of the Activity of Fe–N–C Electrocatalysts in the O2 Reduction Reaction? Critical Roles of Coordinating Pyrrolic N and Axially Adsorbing Species.

Fe-N-C 電催化劑在 O2 還原反應(yīng)中活性的真正來源是什么？協(xié)調(diào)吡咯 N 和軸向吸附物質(zhì)的關(guān)鍵作用。

50.The Progress and Outlook of Metal Single-Atom-Site Catalysis.

金屬單原子中心催化的進展與展望。

51.Matrix-Directed Mineralization for Bulk Structural Materials.

大塊結(jié)構(gòu)材料的基質(zhì)定向礦化。

52.Strategies That Utilize Ion Pairing Interactions to Exert Selectivity Control in the Functionalization of C–H Bonds.

利用離子對相互作用對 C-H 鍵功能化進行選擇性控制的策略。

53.Lipid Expansion Microscopy.

脂質(zhì)膨脹顯微鏡。

54.Multi-Component Synthesis of a Buta-1,3-diene-Linked Covalent Organic Framework.

丁-1,3-二烯連接的共價有機骨架的多組分合成。

55.Ni-Catalyzed Oxygen Transfer from N2O onto sp3-Hybridized Carbons.

Ni 催化的氧從 N2O 轉(zhuǎn)移到 sp3 雜化碳上。

56.Identification of Oxidation State +1 in a Molecular Uranium Complex.

分子鈾絡(luò)合物中 +1 氧化態(tài)的鑒定。

57.Solution Deposition for Chalcogenide Perovskites: A Low-Temperature Route to BaMS3 Materials (M = Ti, Zr, Hf).

硫族化物鈣鈦礦的溶液沉積：BaMS3 材料（M = Ti、Zr、Hf）的低溫途徑。

58.Noncoordinating Flame-Retardant Functional Electrolyte Solvents for Rechargeable Lithium-Ion Batteries.

用于可充電鋰離子電池的非配位阻燃功能性電解質(zhì)溶劑。

59.Enantioselective Selenol-ene Using Rh-Hydride Catalysis.

使用 Rh-氫化物催化的對映選擇性硒醇烯。

60.Chemistry of Ketene Transformation to Gasoline Catalyzed by H-SAPO-11.

H-SAPO-11 催化乙烯酮轉(zhuǎn)化為汽油的化學(xué)。

61.Tunable Optical Molecular Thermometers Based on Metallacrowns.

基于金屬冠的可調(diào)諧光學(xué)分子溫度計。

62.Spontaneous Seed Formation during Electrodeposition Drives Epitaxial Growth of Metastable Bismuth Selenide Microcrystals.

電沉積過程中自發(fā)晶種的形成驅(qū)動亞穩(wěn)態(tài)硒化鉍微晶的外延生長。

63.Tailoring Morphology and Elemental Distribution of Cu-In Nanocrystals via Galvanic Replacement.

通過電流置換調(diào)整 Cu-In 納米晶體的形態(tài)和元素分布。

64.Reaction of Thiosulfate Dehydrogenase with a Substrate Mimic Induces Dissociation of the Cysteine Heme Ligand Giving Insights into the Mechanism of Oxidative Catalysis.

硫代硫酸鹽脫氫酶與底物模擬物的反應(yīng)誘導(dǎo)半胱氨酸血紅素配體的解離，從而深入了解氧化催化的機制。

65.Sulfide Boosting Near-Unity Photoluminescence Quantum Yield of Silver Nanocluster.

硫化物提高銀納米團簇的近單位光致發(fā)光量子產(chǎn)率。

66.13C ENDOR Characterization of the Central Carbon within the Nitrogenase Catalytic Cofactor Indicates That the CFe6 Core Is a Stabilizing “Heart of Steel”.

固氮酶催化輔助因子中中心碳的 13C ENDOR 表征表明 CFe6 核心是穩(wěn)定的“鋼心”。

67.Chemical Synthesis of Post-Translationally Modified H2AX Reveals Redundancy in Interplay between Histone Phosphorylation, Ubiquitination, and Methylation on the Binding of 53BP1 with Nucleosomes.

翻譯后修飾的 H2AX 的化學(xué)合成揭示了組蛋白磷酸化、泛素化和甲基化對 53BP1 與核小體結(jié)合的相互作用的冗余。

68.Capillary-Assisted Molecular Pendulum Bioanalysis.

毛細管輔助分子擺生物分析。

69.Folding and Duplex Formation in Sequence-Defined Aniline Benzaldehyde Oligoarylacetylenes.

序列確定的苯胺苯甲醛低聚芳基乙炔中的折疊和雙鏈體形成。

70.An Iridium-Stabilized Borenium Intermediate.

一種銥穩(wěn)定的硼中間體。

71.Modulating the Electromechanical Response of Bio-Inspired Amino Acid-Based Architectures through Supramolecular Co-Assembly.

通過超分子共組裝調(diào)節(jié)仿生氨基酸結(jié)構(gòu)的機電響應(yīng)。

72.Mechano-bioconjugation Strategy Empowering Fusion Protein Therapeutics with Aggregation Resistance, Prolonged Circulation, and Enhanced Antitumor Efficacy.

機械-生物共軛策略賦予融合蛋白治療以抗聚集、延長循環(huán)和增強抗腫瘤功效。