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【標(biāo)題速讀】【Angew】【2022年】【5月】

2023-08-17 00:07 作者:Rt_Cola 0人讀過 | 我要投稿

聲明：本專欄主要對(duì)生命科學(xué)領(lǐng)域的一些期刊文章標(biāo)題進(jìn)行翻譯，所有內(nèi)容均由本人手工整理翻譯。由于本人專業(yè)為生物分析相關(guān)，其他領(lǐng)域如果出現(xiàn)翻譯錯(cuò)誤請(qǐng)諒解。

1.Metal alloy superlattices with large volume asymmetry were constructed based on self-sorting assembly of binary giant shape amphiphiles, as reported by Zebin Su, Stephen Z.?D. Cheng et?al. in their Research Article (e202200637). MgZn2, NaZn13, and CaCu5 superlattices were observed in soft matters, and the thermodynamic origin of their formation was quantitatively analyzed.

Zebin Su、Stephen Z. D. Cheng 等人在他們的研究文章（e202200637）中報(bào)道，基于二元巨形兩親物的自排序組裝，構(gòu)建了具有大體積不對(duì)稱性的金屬合金超晶格。在軟物質(zhì)中觀察到 MgZn2、NaZn13 和 CaCu5 超晶格，并定量分析了它們形成的熱力學(xué)起源。

2.A molecular motor setup that allows harnessing the trajectory of directional motor rotation for an active mechanical threading process is presented by Henry Dube and co-workers in their Research Article (e202201882). The motor is embedded into a macrocycle and its indane-based rotor fragment then serves as a “revolving door” in the light-driven rotation. In this way a process akin to macroscopic threading of a needle is miniaturized to the molecular level, offering a first entry point to mechanical molecular knitting or weaving processes.

Henry Dube 及其同事在他們的研究文章 (e202201882) 中提出了一種分子電機(jī)設(shè)置，該設(shè)置允許利用定向電機(jī)旋轉(zhuǎn)軌跡來實(shí)現(xiàn)主動(dòng)機(jī)械穿線過程。電機(jī)嵌入大循環(huán)中，其基于茚滿的轉(zhuǎn)子碎片在光驅(qū)動(dòng)旋轉(zhuǎn)中充當(dāng)“旋轉(zhuǎn)門”。通過這種方式，類似于宏觀穿針的過程被微型化到分子水平，為機(jī)械分子針織或編織過程提供了第一個(gè)切入點(diǎn)。

3.The Ugi four-component reaction (Ugi-4CR) was applied by Andreas Herrmann, Thorben Cordes, and co-workers in their Research Article (e202112959) to synthesize a library of linker molecules (illustrated as the ESA space gateway) to link biological targets (the space shuttle) to commercially available fluorescent dyes (the Orion service modules). The modular design of the Ugi-4CR allows the addition of different functional groups to the linkers, which in turn alter the properties of the fluorophore. Functional groups were introduced that turned a variety of fluorophores into highly stable self-healing dyes or metal-chelating dyes during biolabelling.

Andreas Herrmann、Thorben Cordes 及其同事在他們的研究文章 (e202112959) 中應(yīng)用 Ugi 四組分反應(yīng) (Ugi-4CR) 來合成連接分子庫(kù)（如 ESA 空間網(wǎng)關(guān)所示）以連接生物靶標(biāo)（航天飛機(jī)）到市售熒光染料（獵戶座服務(wù)模塊）。 Ugi-4CR 的模塊化設(shè)計(jì)允許向接頭添加不同的官能團(tuán)，從而改變熒光團(tuán)的特性。引入官能團(tuán)，在生物標(biāo)記過程中將各種熒光團(tuán)轉(zhuǎn)化為高度穩(wěn)定的自修復(fù)染料或金屬螯合染料。

4.A game of two halves Direct ammonia oxidation unlocks a pathway towards affordable and efficient production of nitrous oxide, a highly promising agent for selective oxidation reactions, but necessitates the development of suitable catalysts. In their Research Article (e202200772), Javier Pérez-Ramírez and co-workers demonstrate that the synergistic interaction between Au nanoparticles and CeO2 support results in a material with unprecedented levels of N2O selectivity and productivity, far surpassing state-of-the-art systems.

兩半的游戲直接氨氧化開啟了一條經(jīng)濟(jì)高效生產(chǎn)一氧化二氮的途徑，一氧化二氮是一種非常有前途的選擇性氧化反應(yīng)試劑，但需要開發(fā)合適的催化劑。 Javier Pérez-Ramírez 及其同事在他們的研究文章 (e202200772) 中證明，Au 納米粒子和 CeO2 載體之間的協(xié)同相互作用導(dǎo)致材料具有前所未有的 N2O 選擇性和生產(chǎn)率，遠(yuǎn)遠(yuǎn)超過最先進(jìn)的系統(tǒng)。

5.RNA In their Communication (e202115481), Kevin Pagel et?al. use cryogenic gas-phase infrared spectroscopy to study the key intermediate of RNA autohydrolysis.

RNA。在Kevin Pagel 等人的通訊中 (e202115481)，他們利用低溫氣相紅外光譜研究RNA自水解的關(guān)鍵中間體。

6.Asymmetric Catalysis Tetrasubstituted thiiranes can be synthesized by an asymmetric catalytic (2+1) cycloaddition of thioketones as reported by Xiaohua Liu, Yun-Dong Wu, Xiaoming Feng et?al. in their Research Article (e202201151).

不對(duì)稱催化。四取代硫雜丙環(huán)可以通過硫酮的不對(duì)稱催化(2+1)環(huán)加成反應(yīng)合成，如Xiaohua Liu、Yun-Dong Wu、Xiaoming Feng等人在他們的研究文章（e202201151）中報(bào)道的。

7.From Structural Design to Functional Construction: Amine Molecules in High-Performance Formamidinium-Based Perovskite Solar Cells.

從結(jié)構(gòu)設(shè)計(jì)到功能構(gòu)建：高性能甲脒基鈣鈦礦太陽能電池中的胺分子。

8.Asymmetric Catalytic (2+1) Cycloaddition of Thioketones to Synthesize Tetrasubstituted Thiiranes.

硫酮的不對(duì)稱催化 (2+1) 環(huán)加成合成四取代硫雜丙環(huán)。

9.DREAMTIME NMR Spectroscopy: Targeted Multi-Compound Selection with Improved Detection Limits.

DREAMTIME NMR 光譜：具有改進(jìn)的檢測(cè)限的靶向多化合物選擇。

10.Linker Molecules Convert Commercial Fluorophores into Tailored Functional Probes during Biolabelling.

連接分子在生物標(biāo)記過程中將商業(yè)熒光團(tuán)轉(zhuǎn)化為定制的功能探針。

11.Asymmetrical-Dendronized TADF Emitters for Efficient Non-doped Solution-Processed OLEDs by Eliminating Degenerate Excited States and Creating Solely Thermal Equilibrium Routes.

通過消除簡(jiǎn)并激發(fā)態(tài)和創(chuàng)建單獨(dú)的熱平衡路線，用于高效非摻雜溶液加工 OLED 的不對(duì)稱樹枝化 TADF 發(fā)射器。

12.Construction of an Autocatalytic Hybridization Assembly Circuit for Amplified In Vivo MicroRNA Imaging.

用于放大體內(nèi) MicroRNA 成像的自催化雜交組裝電路的構(gòu)建。

13.Multiple Emission of Phosphonium Fluorophores Harnessed by the Pathways of Photoinduced Counterion Migration.

通過光誘導(dǎo)抗衡離子遷移途徑利用磷熒光團(tuán)的多次發(fā)射。

14.Highly Efficient Conversion of Propargylic Alcohols and Propargylic Amines with CO2 Activated by Noble-Metal-Free Catalyst Cu2O@ZIF-8.

無貴金屬催化劑 Cu2O@ZIF-8 活化 CO2 高效轉(zhuǎn)化丙炔醇和丙炔胺。

15.Ceria-Supported Gold Nanoparticles as a Superior Catalyst for Nitrous Oxide Production via Ammonia Oxidation.

氧化鈰支持的金納米顆粒作為氨氧化生產(chǎn)一氧化二氮的優(yōu)質(zhì)催化劑。

16.Integrated Ring-Chain Design of a New Fluorinated Ether Solvent for High-Voltage Lithium-Metal Batteries.

用于高壓鋰金屬電池的新型氟化醚溶劑的集成環(huán)鏈設(shè)計(jì)。

17.Design of Near-Infrared Nonfullerene Acceptor with Ultralow Nonradiative Voltage Loss for High-Performance Semitransparent Ternary Organic Solar Cells.

用于高性能半透明三元有機(jī)太陽能電池的具有超低非輻射電壓損耗的近紅外非富勒烯受體設(shè)計(jì)。

18.Site-Specific Protein Modification with Reducing Carbohydrates.

通過減少碳水化合物進(jìn)行位點(diǎn)特異性蛋白質(zhì)修飾。

19.Soluble and Perfluorinated Polyelectrolyte for Safe and High-Performance Li?O2 Batteries.

用于安全高性能鋰氧電池的可溶性全氟化聚電解質(zhì)。

20.A Self-Serviced-Track 3D DNA Walker for Ultrasensitive Detection of Tumor Exosomes by Glycoprotein Profiling.

自助跟蹤 3D DNA Walker，用于通過糖蛋白分析對(duì)腫瘤外泌體進(jìn)行超靈敏檢測(cè)。

21.Regio- and Enantioselective γ-Allylic Alkylation of In Situ-Generated Free Dienolates via Scandium/Iridium Dual Catalysis.

通過鈧/銥雙重催化原位生成的游離二烯醇鹽的區(qū)域選擇性和對(duì)映選擇性γ-烯丙基烷基化。

22.Reversibly Photoswitching Upconversion Nanoparticles for Super-Sensitive Photoacoustic Molecular Imaging.

用于超靈敏光聲分子成像的可逆光開關(guān)上轉(zhuǎn)換納米粒子。

23.A Two-Phase Approach to Fusicoccane Synthesis To Uncover a Compound That Reduces Tumourigenesis in Pancreatic Cancer Cells.

一種兩階段合成 Fusicoccane 的方法，以發(fā)現(xiàn)一種可減少胰腺癌細(xì)胞腫瘤發(fā)生的化合物。

24.Metal–Organic Cages with {SiW9Ni4} Polyoxotungstate Nodes.

具有 {SiW9Ni4} 多鎢酸鹽節(jié)點(diǎn)的金屬有機(jī)保持架。

25.A Rational Biphasic Tailoring Strategy Enabling High-Performance Layered Cathodes for Sodium-Ion Batteries.

合理的雙相定制策略可實(shí)現(xiàn)鈉離子電池的高性能層狀陰極。

26.Predicting the Solubility of Inorganic Ion Pairs in Water.

預(yù)測(cè)無機(jī)離子對(duì)在水中的溶解度。

27.A pH-Responsive Nanoparticle Library with Precise pH Tunability by Co-Polymerization with Non-Ionizable Monomers.

通過與不可電離單體共聚合而具有精確 pH 可調(diào)性的 pH 響應(yīng)納米顆粒庫(kù)。

28.Characterization of Multifunctional and Non-stereoselective Oxidoreductase RubE7/IstO, Expanding the Functional Diversity of the Flavoenzyme Superfamily.

多功能和非立體選擇性氧化還原酶 RubE7/IstO 的表征，擴(kuò)展黃酶超家族的功能多樣性。

29.Tailoring a Nanochaperone to Regulate α-Synuclein Assembly.

定制納米伴侶來調(diào)節(jié) α-突觸核蛋白組裝。

30.Selective Electrooxidation of Biomass-Derived Alcohols to Aldehydes in a Neutral Medium: Promoted Water Dissociation over a Nickel-Oxide-Supported Ruthenium Single-Atom Catalyst.

在中性介質(zhì)中將生物質(zhì)衍生的醇選擇性電氧化為醛：在氧化鎳負(fù)載的釕單原子催化劑上促進(jìn)水解離。

31.Molecularly Engineered Covalent Organic Frameworks for Hydrogen Peroxide Photosynthesis.

用于過氧化氫光合作用的分子工程共價(jià)有機(jī)框架。

32.Reconfiguration and Reorganization of Bottlebrush Polymer Surfactants.

洗瓶刷聚合物表面活性劑的重新配置和重組。

33.Soft Alloys Constructed with Distinct Mesoatoms via Self-Sorting Assembly of Giant Shape Amphiphiles.

通過巨型兩親物的自排序組裝，用不同的介原子構(gòu)建軟合金。

34.Emissive Platinum(II) Macrocycles as Tunable Cascade Energy Transfer Scaffolds.

發(fā)射性鉑 (II) 大環(huán)化合物作為可調(diào)級(jí)聯(lián)能量轉(zhuǎn)移支架。

35.A Pair of Atypical KAS III Homologues with Initiation and Elongation Functions Program the Polyketide Biosynthesis in Asukamycin.

一對(duì)具有起始和延伸功能的非典型 KAS III 同系物編程明日香霉素中的聚酮化合物生物合成。

36.Cystine Knot Peptides with Tuneable Activity and Mechanism.

具有可調(diào)節(jié)活性和機(jī)制的胱氨酸結(jié)肽。

37.Insights into Dynamic Surface Bromide Sites in Bi4O5Br2 for Sustainable N2 Photofixation.

深入了解 Bi4O5Br2 中用于可持續(xù) N2 光固定的動(dòng)態(tài)表面溴化物位點(diǎn)。

38.Theoretical Optimization of Compositions of High-Entropy Oxides for the Oxygen Evolution Reaction.

用于析氧反應(yīng)的高熵氧化物成分的理論優(yōu)化。

39.Fluorination and Betaine Modification Augment the Blood–Brain Barrier-Crossing Ability of Cylindrical Polymer Brushes.

氟化和甜菜堿改性增強(qiáng)了圓柱形聚合物刷的血腦屏障穿越能力。

40.Stereoselective Synthesis of Atropisomeric Acridinium Salts by the Catalyst-Controlled Cyclization of ortho-Quinone Methide Iminiums.

通過鄰醌甲基亞胺的催化劑控制環(huán)化立體選擇性合成阻轉(zhuǎn)異構(gòu)吖啶鎓鹽。

41.NIRII-HDs: A Versatile Platform for Developing Activatable NIR-II Fluorogenic Probes for Reliable In Vivo Analyte Sensing.

NIRII-HD：用于開發(fā)可激活 NIR-II 熒光探針以實(shí)現(xiàn)可靠的體內(nèi)分析物傳感的多功能平臺(tái)。

42.Active Mechanical Threading by a Molecular Motor.

分子馬達(dá)主動(dòng)機(jī)械螺紋。

43.Superhydrophilic 2D Covalent Organic Frameworks as Broadband Absorbers for Efficient Solar Steam Generation.

超親水二維共價(jià)有機(jī)框架作為寬帶吸收劑，用于高效太陽能蒸汽產(chǎn)生。

44.Environmentally Benign Biosynthesis of Hierarchical MOF/Bacterial Cellulose Composite Sponge for Nerve Agent Protection.

用于神經(jīng)毒劑保護(hù)的多級(jí) MOF/細(xì)菌纖維素復(fù)合海綿的環(huán)境良性生物合成。

45.Characterization of a Nitrogenase Iron Protein Substituted with a Synthetic [Fe4Se4] Cluster.

用合成 [Fe4Se4] 簇取代的固氮酶鐵蛋白的表征。

46.A Crystalline Partially Fluorinated Triazine Covalent Organic Framework for Efficient Photosynthesis of Hydrogen Peroxide.

用于過氧化氫高效光合作用的結(jié)晶部分氟化三嗪共價(jià)有機(jī)框架。

47.Pillararene-Induced Intramolecular Through-Space Charge Transfer and Single-Molecule White-Light Emission.

柱芳烯誘導(dǎo)的分子內(nèi)空間電荷轉(zhuǎn)移和單分子白光發(fā)射。

48.Structurally Disordered RuO2 Nanosheets with Rich Oxygen Vacancies for Enhanced Nitrate Electroreduction to Ammonia.

具有豐富氧空位的結(jié)構(gòu)無序 RuO2 納米片，用于增強(qiáng)硝酸鹽電還原至氨。

49.Studying the Key Intermediate of RNA Autohydrolysis by Cryogenic Gas-Phase Infrared Spectroscopy.

利用低溫氣相紅外光譜研究RNA自水解的關(guān)鍵中間體。

50.MOF Synthesis Prediction Enabled by Automatic Data Mining and Machine Learning.

自動(dòng)數(shù)據(jù)挖掘和機(jī)器學(xué)習(xí)支持 MOF 合成預(yù)測(cè)。

51.Estimating Phosphorescent Emission Energies in IrIII Complexes Using Large-Scale Quantum Computing Simulations.

使用大規(guī)模量子計(jì)算模擬估算 IrIII 配合物中的磷光發(fā)射能量。

52.Organoplatinum Compounds as Anion-Tuneable Uphill Hydroxide Transporters.

有機(jī)鉑化合物作為陰離子可調(diào)的上坡氫氧化物轉(zhuǎn)運(yùn)蛋白。

53.Designing a Network of Crystalline Polymers for a Scalable, Nonfluorinated, Healable and Amphiphobic Solid Slippery Interface.

設(shè)計(jì)用于可擴(kuò)展、非氟化、可修復(fù)和雙疏固體光滑界面的結(jié)晶聚合物網(wǎng)絡(luò)。

54.Zinc-Promoted ZnMe/ZnPh Exchange in Eight-Coordinate [Ru(PPh3)2(ZnMe)4H2].

鋅促進(jìn)八配位 ZnMe/ZnPh 交換 [Ru(PPh3)2(ZnMe)4H2]。

55.Bioinspired Total Synthesis of Erectones A and B, and the Revised Structure of Hyperelodione D.

Electones A 和 B 的仿生全合成，以及 Hyperelodione D 的改進(jìn)結(jié)構(gòu)。

56.Reductant-Free Cross-Electrophile Synthesis of Di(hetero)arylmethanes by Palladium-Catalyzed Desulfinative C?C Coupling.

鈀催化脫硫 C?C 偶聯(lián)無還原劑交叉電試劑合成二（雜）芳基甲烷。

57.ATP-Induced Emergent Circularly Polarized Luminescence and Encryption.

ATP 誘導(dǎo)的緊急圓偏振發(fā)光和加密。

58.Chiral Symmetry Breaking of Monoacylated Anhydroerythritols and meso-1,2-Diols through Crystallization-Induced Deracemization.

通過結(jié)晶誘導(dǎo)的去消旋作用打破單?；撍嗵\糖醇和內(nèi)消旋 1,2-二醇。

59.Iridium-Catalyzed Enantioselective C(sp3)?H Borylation of Aminocyclopropanes.

銥催化氨基環(huán)丙烷的對(duì)映選擇性 C(sp3)?H 硼化。

60.Self-Regulating Colloidal Co-Assemblies That Accelerate Their Own Destruction via Chemo-Structural Feedback.

通過化學(xué)結(jié)構(gòu)反饋加速自身破壞的自我調(diào)節(jié)膠體聯(lián)合組件。

61.Catalytic Enantioselective Pictet–Spengler Reaction of α-Ketoamides Catalyzed by a Single H-Bond Donor Organocatalyst.

單一氫鍵供體有機(jī)催化劑催化 α-酮酰胺的催化對(duì)映選擇性 Pictet-Spengler 反應(yīng)。

62.Discovery of Two Polymorphs of TiP4N8 Synthesized from Binary Nitrides.

由二元氮化物合成的 TiP4N8 的兩種多晶型物的發(fā)現(xiàn)。

63.A series of sulfur species prodrugs (reactive sulfur species in a capsule) that can release pure hydrogen sulfide (H2S) and hydrogen persulfide (H2S2) was used by Bowen Ke et?al. in their Communication (e202201668) to compare the pharmacological differences between sulfide and persulfide. The H2S2 prodrug exhibits increased activities and reduced toxicity as compared to the H2S prodrug in vivo, indicating persulfide might represent a better therapeutic paradigm than H2S.

Bowen Ke等人使用了一系列能夠釋放純硫化氫（H2S）和過硫化氫（H2S2）的硫物質(zhì)前藥（膠囊中的活性硫物質(zhì)）。在他們的通訊（e202201668）中比較了硫化物和過硫化物之間的藥理學(xué)差異。與H2S前藥相比，H2S2前藥在體內(nèi)表現(xiàn)出增加的活性和降低的毒性，表明過硫化物可能代表比H2S更好的治療范例。

64.A visible-light-promoted iterative synthesis of 2-deoxyoligosaccharides is reported by De-Cai Xiong, Xin-Shan Ye, and co-workers in their Research Article (e202114726). The rapid constructions of oligosaccharides, 20-mer deoxyglycan, and digoxin are facilitated by a bromide-based hydrogen species through an electron transfer process.

De-Cai Xiong、Xin-Shan Ye 及其同事在他們的研究文章 (e202114726) 中報(bào)道了可見光促進(jìn)的 2-脫氧寡糖的迭代合成。溴化物氫物質(zhì)通過電子轉(zhuǎn)移過程促進(jìn)寡糖、20 聚體脫氧聚糖和地高辛的快速構(gòu)建。

65.Mechanical properties of nanogels influence their cellular fate. Inspired by the natural ability of the cells to sense stiffness, Smriti Singh et?al. in their Research Article (e202116653) developed highly hydrophilic soft nanogels and show that the passive engulfment of the soft nanogels by the immune cells was drastically reduced compared to the stiffer counterpart. The delayed uptake resulted in an enhanced circulation time of the nanogels, an important criterion for drug delivery applications.

納米凝膠的機(jī)械特性影響其細(xì)胞命運(yùn)。受到細(xì)胞感知?jiǎng)偠鹊淖匀荒芰Φ膯l(fā)，Smriti Singh 等人。在他們的研究文章（e202116653）中開發(fā)了高度親水性的軟納米凝膠，并表明與較硬的對(duì)應(yīng)物相比，免疫細(xì)胞對(duì)軟納米凝膠的被動(dòng)吞噬大大減少。延遲吸收導(dǎo)致納米凝膠的循環(huán)時(shí)間延長(zhǎng)，這是藥物輸送應(yīng)用的一個(gè)重要標(biāo)準(zhǔn)。

66.Sugar nucleotides are essential glycosylation donors in carbohydrate metabolism. In their Research Article (e202115696), Liuqing Wen and co-workers developed a general strategy for the efficient preparation of rare sugar nucleotides. Complex de?novo biosynthesis of rare sugar nucleotides was recognized as cascade reactions. The cascade reactions were driven toward the formation of the target sugar nucleotides through a cofactor regeneration system (CRS), thus resulting in clean conversion.

糖核苷酸是碳水化合物代謝中必需的糖基化供體。在他們的研究文章（e202115696）中，劉慶文及其同事制定了有效制備稀有糖核苷酸的總體策略。稀有糖核苷酸的復(fù)雜從頭生物合成被認(rèn)為是級(jí)聯(lián)反應(yīng)。通過輔因子再生系統(tǒng)（CRS）驅(qū)動(dòng)級(jí)聯(lián)反應(yīng)形成目標(biāo)糖核苷酸，從而實(shí)現(xiàn)干凈的轉(zhuǎn)化。

67.Photocatalysis In their Communication (e202202079), Masaichi Saito, Stephan Kupfer, Benjamin Dietzek-Ivan?i?, Wolfgang Weigand et?al. utilize a precious metal-free photocatalyst consisting of a [FeFe] hydrogenase mimic for hydrogen generation under visible light.

通信中的光催化 (e202202079)，Masaichi Saito、Stephan Kupfer、Benjamin Dietzek-Ivan?i?、Wolfgang Weigand 等人。利用由 [FeFe] 氫化酶模擬物組成的不含貴金屬的光催化劑在可見光下產(chǎn)生氫氣。

68.Challenges, Prospects, and Emerging Applications of Inkjet-Printed Electronics: A Chemist's Point of View.

噴墨印刷電子產(chǎn)品的挑戰(zhàn)、前景和新興應(yīng)用：化學(xué)家的觀點(diǎn)。

69.Design and Synthesis of Tunable Chiral 2,2′-Bipyridine Ligands: Application to the Enantioselective Nickel-Catalyzed Reductive Arylation of Aldehydes.

可調(diào)手性 2,2'-聯(lián)吡啶配體的設(shè)計(jì)與合成：在對(duì)映選擇性鎳催化醛還原芳基化中的應(yīng)用。

70.Highly Stable and Reactive Platinum Single Atoms on Oxygen Plasma-Functionalized CeO2 Surfaces: Nanostructuring and Peroxo Effects.

氧等離子體功能化 CeO2 表面上高度穩(wěn)定和反應(yīng)活性的鉑單原子：納米結(jié)構(gòu)和過氧化物效應(yīng)。

71.Iterative Synthesis of 2-Deoxyoligosaccharides Enabled by Stereoselective Visible-Light-Promoted Glycosylation.

通過立體選擇性可見光促進(jìn)糖基化迭代合成 2-脫氧寡糖。

72.Cofactor-Driven Cascade Reactions Enable the Efficient Preparation of Sugar Nucleotides.

輔因子驅(qū)動(dòng)的級(jí)聯(lián)反應(yīng)能夠有效制備糖核苷酸。

73.Non-binary Encoded Nucleic Acid Barcodes Directly Readable by a Nanopore.

納米孔可直接讀取的非二進(jìn)制編碼核酸條形碼。

74.Shell-like Xenon Nano-Traps within Angular Anion-Pillared Layered Porous Materials for Boosting Xe/Kr Separation.

角陰離子柱層狀多孔材料中的殼狀氙納米陷阱可促進(jìn) Xe/Kr 分離。

75.Tuning the Elasticity of Nanogels Improves Their Circulation Time by Evading Immune Cells.

調(diào)整納米凝膠的彈性可以通過逃避免疫細(xì)胞來改善其循環(huán)時(shí)間。

76.Spatially Resolved, Error-Robust Multiplexed MicroRNA Profiling in Single Living Cells.

單個(gè)活細(xì)胞中空間分辨、誤差穩(wěn)健的多重 MicroRNA 分析。

77.Reversible Three-Color Fluorescence Switching of an Organic Molecule in the Solid State via “Pump–Trigger” Optical Manipulation.

通過“泵浦觸發(fā)”光學(xué)操作實(shí)現(xiàn)固態(tài)有機(jī)分子的可逆三色熒光切換。

78.A Heterogeneous Palladium Catalyst for the Polymerization of Olefins Prepared by Halide Abstraction Using Surface R3Si+ Species.

使用表面 R3Si+ 物質(zhì)通過鹵化物提取制備烯烴聚合的多相鈀催化劑。

79.Structural Basis for the Prenylation Reaction of Carbazole-Containing Natural Products Catalyzed by Squalene Synthase-Like Enzymes.

角鯊烯合酶類酶催化含咔唑天然產(chǎn)物異戊二烯化反應(yīng)的結(jié)構(gòu)基礎(chǔ)。

80.Conjugated Polyelectrolyte-Based Complex Fluids as Aqueous Exciton Transport Networks.

作為水激子傳輸網(wǎng)絡(luò)的共軛聚電解質(zhì)復(fù)合流體。

81.Widefield SERS for High-Throughput Nanoparticle Screening.

用于高通量納米粒子篩選的寬場(chǎng) SERS。

82.Regio-, Diastereo-, and Enantioselective Decarboxylative Hydroaminoalkylation of Dienol Ethers Enabled by Dual Palladium/Photoredox Catalysis.

雙鈀/光氧化還原催化實(shí)現(xiàn)二烯醇醚的區(qū)域、非對(duì)映和對(duì)映選擇性脫羧氫氨烷基化。

83.Iridium-Catalyzed Asymmetric Allylic Substitution of Methyl Azaarenes.

銥催化甲基氮雜芳烴的不對(duì)稱烯丙基取代。

84.Real-Time Fluorescent Monitoring of Kinetically Controlled Supramolecular Self-Assembly of Atom-Precise Cu8 Nanocluster.

原子精確 Cu8 納米團(tuán)簇動(dòng)力學(xué)控制超分子自組裝的實(shí)時(shí)熒光監(jiān)測(cè)。

85.A New Platform of B/N-Doped Cyclophanes: Access to a π-Conjugated Block-Type B3N3 Macrocycle with Strong Dipole Moment and Unique Optoelectronic Properties.

B/N 摻雜環(huán)烷的新平臺(tái)：獲得具有強(qiáng)偶極矩和獨(dú)特光電特性的 π 共軛嵌段型 B3N3 大環(huán)化合物。

86.Single-Vesicle Electrochemistry Following Repetitive Stimulation Reveals a Mechanism for Plasticity Changes with Iron Deficiency.

重復(fù)刺激后的單囊泡電化學(xué)揭示了缺鐵時(shí)可塑性變化的機(jī)制。

87.Solvent-Controlled Condensation of [Mo2O5(PTC4A)2]6? Metalloligand in Stepwise Assembly of Hexagonal and Rectangular Ag18 Nanoclusters.

六角形和矩形 Ag18 納米團(tuán)簇逐步組裝中 [Mo2O5(PTC4A)2]6? 金屬配體的溶劑控制縮合。

88.Boosted Inner Surface Charge Transfer in Perovskite Nanodots@Mesoporous Titania Frameworks for Efficient and Selective Photocatalytic CO2 Reduction to Methane.

增強(qiáng)鈣鈦礦納米點(diǎn)@介孔二氧化鈦框架的內(nèi)表面電荷轉(zhuǎn)移，實(shí)現(xiàn)高效、選擇性光催化二氧化碳還原為甲烷。

89.Ratiometric and Colorimetric Optical Thermometers Using Emissive Dimeric and Trimeric {[Au(SCN)2]?}n Moieties Generated in d–f Heterometallic Assemblies.

使用 d–f 異金屬組件中生成的發(fā)射二聚和三聚 {[Au(SCN)2]?}n 部分的比率和比色光學(xué)溫度計(jì)。