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【標(biāo)題速讀】【Angew】【2022年】【1月】

2023-08-15 00:28 作者:Rt_Cola 0人讀過(guò) | 我要投稿

聲明：本專(zhuān)欄主要對(duì)生命科學(xué)領(lǐng)域的一些期刊文章標(biāo)題進(jìn)行翻譯，所有內(nèi)容均由本人手工整理翻譯。由于本人專(zhuān)業(yè)為生物分析相關(guān)，其他領(lǐng)域如果出現(xiàn)翻譯錯(cuò)誤請(qǐng)諒解。

1.The blue/orange dual fluorescence properties of tetramesityldiborane(4) are reported by Yoshiaki Shoji, Yasuhiro Ikabata et?al. in their Research Article (e202113549). Theoretical calculations showed that the diborane(4) in the S1 state adopts a twisted or planar geometry, which is responsible for the blue or orange fluorescence, respectively. The relative intensity of the dual fluorescence is sensitive to the viscosity of the medium, highlighting the potential of the diborane(4) as a ratiometric viscosity sensor.

Yoshiaki Shoji、Yasuhiro Ikabata 等人報(bào)道了四均基乙硼烷 (4) 的藍(lán)/橙色雙熒光特性。在他們的研究文章（e202113549）中。理論計(jì)算表明，S1態(tài)的乙硼烷(4)采用扭曲或平面幾何形狀，分別產(chǎn)生藍(lán)色或橙色熒光。雙熒光的相對(duì)強(qiáng)度對(duì)介質(zhì)的粘度敏感，凸顯了乙硼烷 (4) 作為比率粘度傳感器的潛力。

2.Porous aromatic framework (PAF) membranes with modifiable channels were synthesized by Yuyang Tian, Guangshan Zhu, and co-workers in their Research Article (e202113682). The pore size and chemistry of the membranes were readily modified by ion exchange, resulting in suitable membranes for the separation of different gas mixtures. With Br? in the framework, the membrane exhibited a H2/N2 selectivity of 72.7 with a H2 permeance of 51844 gas permeation units (GPU). With BF4?, the membrane showed a CO2 permeance of 23058?GPU, and an optimized CO2/N2 selectivity of 60.0 was achieved.

Yuyang Tian、Guangshan Zhu 及其同事在他們的研究文章 (e202113682) 中合成了具有可修飾通道的多孔芳香骨架 (PAF) 膜。膜的孔徑和化學(xué)性質(zhì)很容易通過(guò)離子交換進(jìn)行改變，從而形成適合分離不同氣體混合物的膜。骨架中含有 Br?，該膜的 H2/N2 選擇性為 72.7，H2 滲透率為 51844 個(gè)氣體滲透單位 (GPU)。使用 BF4?，膜的 CO2 滲透率為 23058 GPU，并且實(shí)現(xiàn)了 60.0 的優(yōu)化 CO2/N2 選擇性。

3.Diamidophosphate enabled phosphorylation chemistry facilitates the synthesis of closely related nucleotides and nucleoside triphosphates that are compatible with abiotic oligomerization, and ribozyme-mediated polymerization and ligation processes. The one-pot protocol spans nucleosides, nucleotides, and oligonucleotides, implying that the progression from prebiotic chemistry to those conducive for emergence of life's biochemistry could be a more continuous process than previously assumed. Details are discussed in the Research Article by Ulrich?F. Müller, Ramanarayanan Krishnamurthy, and co-workers (e202113625).

二氨基磷酸鹽啟用的磷酸化化學(xué)促進(jìn)了與非生物寡聚、核酶介導(dǎo)的聚合和連接過(guò)程相容的密切相關(guān)的核苷酸和核苷三磷酸的合成。一鍋法方案涵蓋核苷、核苷酸和寡核苷酸，這意味著從生命起源前的化學(xué)到有利于生命生物化學(xué)出現(xiàn)的化學(xué)的進(jìn)展可能是一個(gè)比之前假設(shè)的更連續(xù)的過(guò)程。 Ulrich F. Müller、Ramanarayanan Krishnamurthy 及其同事的研究文章 (e202113625) 討論了詳細(xì)信息。

4.Fusion of extracellular vesicles to cells contributes to many critical biological pathways. Inspired by the natural fusion process, Hang Xing and co-workers developed a liposome fusion-based transport strategy, termed LiFT, that enables the incorporation of a variety of functional moieties onto both external and internal cell membrane surfaces with precise orientation control (e202111647). By using LiFT, asymmetric DNA modifications with orthogonal functionalities on each side of the cell membrane were achieved, realizing applications such as heterotypic cell assembly and intracellular metabolite detection.

細(xì)胞外囊泡與細(xì)胞的融合有助于許多關(guān)鍵的生物學(xué)途徑。受自然融合過(guò)程的啟發(fā)，Hang Xing 及其同事開(kāi)發(fā)了一種基于脂質(zhì)體融合的運(yùn)輸策略，稱(chēng)為 LiFT，該策略能夠通過(guò)精確的方向控制將各種功能部分結(jié)合到外部和內(nèi)部細(xì)胞膜表面上 (e202111647) 。通過(guò)使用LiFT，實(shí)現(xiàn)了細(xì)胞膜兩側(cè)具有正交功能的不對(duì)稱(chēng)DNA修飾，實(shí)現(xiàn)了異型細(xì)胞組裝和細(xì)胞內(nèi)代謝物檢測(cè)等應(yīng)用。

5.Proteins In their Communication (e202109961), Martin Blackledge et?al. report the self-assembly of intrinsically disordered tardigrade proteins into fibrous gels in response to environmental stress.

蛋白質(zhì)的通訊 (e202109961)，Martin Blackledge 等人。報(bào)告了本質(zhì)上無(wú)序的緩步動(dòng)物蛋白自組裝成纖維凝膠以響應(yīng)環(huán)境壓力。

6.Foldamers In their Research Article (e202108364), Sunbum Kwon, Hee-Seung Lee et?al. report on the conformational adaptation of β-peptide foldamers for the formation of metal–peptide frameworks.

Foldamers 在 Sunbum Kwon、Hee-Seung Lee 等人的研究文章 (e202108364) 中。關(guān)于β-肽折疊體的構(gòu)象適應(yīng)形成金屬-肽框架的報(bào)告。

7.Principles of Water Electrolysis and Recent Progress in Cobalt-, Nickel-, and Iron-Based Oxides for the Oxygen Evolution Reaction.

水電解原理以及用于析氧反應(yīng)的鈷、鎳和鐵基氧化物的最新進(jìn)展。

8.Heterocycle/Heteroallene Ring-Opening Copolymerization: Selective Catalysis Delivering Alternating Copolymers.

雜環(huán)/雜聯(lián)烯開(kāi)環(huán)共聚：選擇性催化產(chǎn)生交替共聚物。

9.Conformational Adaptation of β-Peptide Foldamers for the Formation of Metal–Peptide Frameworks.

β-肽折疊體的構(gòu)象適應(yīng)形成金屬-肽框架。

10.Selective 1Hα NMR Methods Reveal Functionally Relevant Proline cis/trans Isomers in Intrinsically Disordered Proteins: Characterization of Minor Forms, Effects of Phosphorylation, and Occurrence in Proteome.

選擇性 1Hα NMR 方法揭示本質(zhì)無(wú)序蛋白質(zhì)中功能相關(guān)的脯氨酸順式/反式異構(gòu)體：次要形式的表征、磷酸化的影響以及蛋白質(zhì)組中的出現(xiàn)。

11.Selective Approaches to α- and β-Arylated Vinyl Ethers.

α-和β-芳基化乙烯基醚的選擇性方法。

12.An N-Trifluoromethylation/Cyclization Strategy for Accessing Diverse N-Trifluoromethyl Azoles from Nitriles and 1,3-Dipoles.

從腈和 1,3-偶極子獲取多種 N-三氟甲基唑的 N-三氟甲基化/環(huán)化策略。

13.Enantioselective Synthesis of Silicon-Stereogenic Monohydrosilanes by Rhodium-Catalyzed Intramolecular Hydrosilylation.

通過(guò)銠催化分子內(nèi)氫化硅烷化對(duì)映選擇性合成硅立體單氫硅烷。

14.Metal-Free Phosphorus-Directed Borylation of C(sp2)?H Bonds.

C(sp2)?H 鍵的無(wú)金屬磷定向硼化。

15.Macrocycle Dynamics in a Branched [8]Catenane Controlled by Three Different Stimuli in Three Different Regions.

三個(gè)不同區(qū)域的三種不同刺激控制的支鏈[8]鏈烷中的大循環(huán)動(dòng)力學(xué)。

16.Chemoselective and Diastereoselective Synthesis of C-Aryl Nucleoside Analogues by Nickel-Catalyzed Cross-Coupling of Furanosyl Acetates with Aryl Iodides.

通過(guò)鎳催化乙酸呋喃糖酯與芳基碘化物的交叉偶聯(lián)化學(xué)選擇性和非對(duì)映選擇性合成 C-芳基核苷類(lèi)似物。

17.Divergent and Modular Synthesis of Terpenoid Scaffolds via a AuI Catalyzed One-Pot Cascade.

通過(guò) AuI 催化一鍋級(jí)聯(lián)進(jìn)行萜類(lèi)支架的發(fā)散和模塊化合成。

18.Unlocking the Stereoselectivity and Substrate Acceptance of Enzymes: Proline-Induced Loop Engineering Test.

解鎖酶的立體選擇性和底物接受性：脯氨酸誘導(dǎo)環(huán)工程測(cè)試。

19.Selective Benzylic CH-Borylations by Tandem Cobalt Catalysis.

通過(guò)串聯(lián)鈷催化選擇性芐基 CH-硼基化。

20.Installing a Green Engine To Drive an Enzyme Cascade: A Light-Powered In Vitro Biosystem for Poly(3-hydroxybutyrate) Synthesis.

安裝綠色引擎來(lái)驅(qū)動(dòng)酶級(jí)聯(lián)：用于聚（3-羥基丁酸酯）合成的光動(dòng)力體外生物系統(tǒng)。

21.Structural and Molecular Basis of the Catalytic Mechanism of Geranyl Pyrophosphate C6-Methyltransferase: Creation of an Unprecedented Farnesyl Pyrophosphate C6-Methyltransferase.

香葉基焦磷酸 C6-甲基轉(zhuǎn)移酶催化機(jī)制的結(jié)構(gòu)和分子基礎(chǔ)：創(chuàng)建前所未有的法呢基焦磷酸 C6-甲基轉(zhuǎn)移酶。

22.Energy Band Alignment and Redox-Active Sites in Metalloporphyrin-Spaced Metal-Catechol Frameworks for Enhanced CO2 Photoreduction.

金屬卟啉間隔金屬兒茶酚框架中的能帶排列和氧化還原活性位點(diǎn)，用于增強(qiáng) CO2 光還原。

23.A Biomimetic Approach for Spatially Controlled Cell Membrane Engineering Using Fusogenic Spherical Nucleic Acid.

使用融合球形核酸進(jìn)行空間控制細(xì)胞膜工程的仿生方法。

24.Rhodium-Catalyzed Atroposelective Access to Axially Chiral Olefins via C?H Bond Activation and Directing Group Migration.

銠催化通過(guò) C?H 鍵激活和引導(dǎo)基團(tuán)遷移選擇性地獲得軸向手性烯烴。

25.Enhancing Dye-Triplet-Sensitized Upconversion Emission Through the Heavy-Atom Effect in CsLu2F7:Yb/Er Nanoprobes.

通過(guò) CsLu2F7:Yb/Er 納米探針中的重原子效應(yīng)增強(qiáng)染料三重態(tài)敏化上轉(zhuǎn)換發(fā)射。

26.Density-Dependent Emission Colors from a Conformation-Switching Chromophore in Polyurethanes.

聚氨酯中構(gòu)象轉(zhuǎn)換發(fā)色團(tuán)的密度依賴(lài)性發(fā)射顏色。

27.Mo3S132? Intercalated Layered Double Hydroxide: Highly Selective Removal of Heavy Metals and Simultaneous Reduction of Ag+ Ions to Metallic Ag0 Ribbons.

Mo3S132? 插層層狀雙氫氧化物：高度選擇性去除重金屬并同時(shí)將 Ag+ 離子還原為金屬 Ag0 帶。

28.Photoinitiated anti-Hydropentafluorosulfanylation of Terminal Alkynes.

末端炔烴的光引發(fā)抗氫五氟磺?；?/p>

29.Five-Fold Symmetric Pentaindolo- and Pentakis(benzoindolo)Corannulenes: Unique Structural Dynamics Derived from the Combination of Helical and Bowl Inversions.

五重對(duì)稱(chēng) Pentaindolo 和 Pentakis（苯并吲哚）Corannulenes：源自螺旋和碗反轉(zhuǎn)組合的獨(dú)特結(jié)構(gòu)動(dòng)力學(xué)。

30.Synthesis, Aromaticity, and Application of peri-Pentacenopentacene: Localized Representation of Benzenoid Aromatic Compounds.

近并五苯并五苯的合成、芳香性和應(yīng)用：苯環(huán)芳香族化合物的局部表征。

31.Active Exsolved Metal–Oxide Interfaces in Porous Single-Crystalline Ceria Monoliths for Efficient and Durable CH4/CO2 Reforming.

多孔單晶二氧化鈰整料中的活性溶解金屬-氧化物界面，可實(shí)現(xiàn)高效、持久的 CH4/CO2 重整。

32.The Aryne Phosphate Reaction.

芳炔磷酸反應(yīng)。

33.Tetraaryldiborane(4) Can Emit Dual Fluorescence Responding to the Structural Change around the B–B Bond.

Tetraaryldiborane(4) 可以響應(yīng) B-B 鍵周?chē)慕Y(jié)構(gòu)變化而發(fā)射雙熒光。

34.Macrocyclic Donor–Acceptor Dyads Composed of a Perylene Bisimide Dye Surrounded by Oligothiophene Bridges.

由被低聚噻吩橋包圍的苝雙酰亞胺染料組成的大環(huán)供體-受體二元體。

35.Concurrent Prebiotic Formation of Nucleoside-Amidophosphates and Nucleoside-Triphosphates Potentiates Transition from Abiotic to Biotic Polymerization.

核苷-酰胺磷酸鹽和核苷-三磷酸鹽的同時(shí)益生元形成增強(qiáng)了從非生物聚合到生物聚合的轉(zhuǎn)變。

36.Visible-Light-Induced C4-Selective Functionalization of Pyridinium Salts with Cyclopropanols.

吡啶鎓鹽與環(huán)丙醇的可見(jiàn)光誘導(dǎo) C4 選擇性官能化。

37.Continuous Porous Aromatic Framework Membranes with Modifiable Sites for Optimized Gas Separation.

具有可修飾位點(diǎn)的連續(xù)多孔芳香骨架膜，可優(yōu)化氣體分離。

38.Calix[4]pyrrole-based Crosslinked Polymer Networks for Highly Effective Iodine Adsorption from Water.

Calix[4]吡咯基交聯(lián)聚合物網(wǎng)絡(luò)可高效吸附水中的碘。

39.Maximizing Electroactive Sites in a Three-Dimensional Covalent Organic Framework for Significantly Improved Carbon Dioxide Reduction Electrocatalysis.

最大化三維共價(jià)有機(jī)框架中的電活性位點(diǎn)，顯著改善二氧化碳還原電催化。

40.Druggable Allosteric Sites in β-Propeller Lectins.

β-螺旋槳凝集素中的可藥物變構(gòu)位點(diǎn)。

41.Tumor-Cell-Specific Targeting of Ibrutinib: Introducing Electrostatic Antibody-Inhibitor Conjugates (AiCs).

依魯替尼的腫瘤細(xì)胞特異性靶向：引入靜電抗體抑制劑偶聯(lián)物 (AiC)。

42.Intrinsically Disordered Tardigrade Proteins Self-Assemble into Fibrous Gels in Response to Environmental Stress.

本質(zhì)上無(wú)序的緩步動(dòng)物蛋白質(zhì)自組裝成纖維凝膠以應(yīng)對(duì)環(huán)境壓力。

43.Mediated Inner-Sphere Electron Transfer Induces Homogeneous Reduction of CO2 via Through-Space Electronic Conjugation.

介導(dǎo)的內(nèi)球電子轉(zhuǎn)移通過(guò)空間電子共軛誘導(dǎo)二氧化碳均勻還原。

44.Solar Urea: Towards a Sustainable Fertilizer Industry.

太陽(yáng)能尿素：邁向可持續(xù)化肥工業(yè)。

45.Synthesis of Functionalized Silsesquioxane Nanomaterials by Rhodium-Catalyzed Carbene Insertion into Si?H Bonds.

通過(guò)銠催化卡賓插入 Si?H 鍵合成功能化倍半硅氧烷納米材料。

46.Athermal, Chemically Triggered Release of RNA from Thioester Nucleic Acids.

硫酯核酸的無(wú)熱、化學(xué)觸發(fā) RNA 釋放。

47.Configurational Lability at Tetrahedral Phosphorus: syn/anti-Isomerization of a P-Stereogenic Phosphiranium Cation by Intramolecular Epimerization at Phosphorus.

四面體磷的構(gòu)型不穩(wěn)定性：通過(guò)磷分子內(nèi)差向異構(gòu)化實(shí)現(xiàn) P-立體磷鎓陽(yáng)離子的順式/反異構(gòu)化。

48.Photocatalytic Sulfonylcarbocyclization of Alkynes Using SEt as a Traceless Directing Group: Access to Cyclopentenes and Indenes.

使用 SEt 作為無(wú)痕導(dǎo)向基團(tuán)進(jìn)行炔烴的光催化磺酰碳環(huán)化：獲得環(huán)戊烯和茚。

49.Visible Light Induced Br?nsted Acid Assisted Pd-Catalyzed Alkyl Heck Reaction of Diazo Compounds and N-Tosylhydrazones.

可見(jiàn)光誘導(dǎo)布朗斯臺(tái)德酸輔助鈀催化重氮化合物和 N-甲苯磺酰腙的烷基 Heck 反應(yīng)。

50.Solid-Phase-Supported Chemoenzymatic Synthesis of a Light-Activatable tRNA Derivative.

光激活 tRNA 衍生物的固相支持化學(xué)酶合成。

51.Enantioselective Synthesis of Chiral Carboxylic Acids from Alkynes and Formic Acid by Nickel-Catalyzed Cascade Reactions: Facile Synthesis of Profens.

通過(guò)鎳催化級(jí)聯(lián)反應(yīng)從炔烴和甲酸對(duì)映選擇性合成手性羧酸：Profens 的簡(jiǎn)便合成。

52.Vitamin D Inhibits the Early Aggregation of α-Synuclein and Modulates Exocytosis Revealed by Electrochemical Measurements.

電化學(xué)測(cè)量顯示，維生素 D 抑制 α-突觸核蛋白的早期聚集并調(diào)節(jié)胞吐作用。

53.Connecting Rheological Properties and Molecular Dynamics of Egg-Tempera Paints based on Egg Yolk.

連接基于蛋黃的蛋彩畫(huà)涂料的流變特性和分子動(dòng)力學(xué)。

54.Truly-Biocompatible Gold Catalysis Enables Vivo-Orthogonal Intra-CNS Release of Anxiolytics.

真正生物相容的金催化使抗焦慮藥能夠在體內(nèi)正交中樞神經(jīng)系統(tǒng)內(nèi)釋放。

55.Accessing Unsymmetrically Linked Heterocycles through Stereoselective Palladium-Catalyzed Domino Cyclization.

通過(guò)立體選擇性鈀催化多米諾環(huán)化獲得不對(duì)稱(chēng)連接的雜環(huán)。

56.Multi-Stimuli-Induced Mechanical Bending and Reversible Fluorescence Switching in a Single Organic Crystal.

單一有機(jī)晶體中的多重刺激誘導(dǎo)機(jī)械彎曲和可逆熒光切換。

57.Photocleavable Fluorescent Membrane Tension Probes: Fast Release with Spatiotemporal Control in Inner Leaflets of Plasma Membrane, Nuclear Envelope, and Secretory Pathway.

可光裂解熒光膜張力探針：質(zhì)膜內(nèi)葉、核膜和分泌途徑的時(shí)空控制快速釋放。

58.Quantifying Intracellular Single Vesicular Catecholamine Concentration with Open Carbon Nanopipettes to Unveil the Effect of L-DOPA on Vesicular Structure.

使用開(kāi)放碳納米移液器定量細(xì)胞內(nèi)單囊泡兒茶酚胺濃度，以揭示 L-DOPA 對(duì)囊泡結(jié)構(gòu)的影響。

59.Layered Double Hydroxide-Assisted Fabrication of Prussian Blue Membranes for Precise Molecular Sieving.

用于精確分子篩分的層狀雙氫氧化物輔助普魯士藍(lán)膜的制造。

60.Air-Stable PdI Dimer Enabled Remote Functionalization: Access to Fluorinated 1,1-Diaryl Alkanes with Unprecedented Speed.

空氣穩(wěn)定的 PdI 二聚體實(shí)現(xiàn)遠(yuǎn)程功能化：以前所未有的速度獲取氟化 1,1-二芳基烷烴。

61.Rigid Bridge-Confined Double-Decker Platinum(II) Complexes Towards High-Performance Red and Near-Infrared Electroluminescence.

剛性橋限制雙層鉑 (II) 配合物實(shí)現(xiàn)高性能紅色和近紅外電致發(fā)光。

62.A Defective Nanotube Molecule of C552H496N24 with Pyridinic and Pyrrolic Nitrogen Atoms.

具有吡啶和吡咯氮原子的 C552H496N24 有缺陷的納米管分子。

63.Stacked but not Stuck: Unveiling the Role of π→π* Interactions with the Help of the Benzofuran–Formaldehyde Complex.

堆疊但不卡住：借助苯并呋喃-甲醛復(fù)合物揭示 π→π* 相互作用的作用。

64.Binary mesocrystals demonstrate the combination of nanocrystals from different materials within a highly ordered manner. While nanocubes appear to be simple in their geometry, they can arrange in various ways into a complex entity that not only directs its habitus but also its properties. In their Research Article (e202112461), Helmut C?lfen et?al. report on the formation and structural analysis of micrometer-sized two- and three-dimensional binary particle assemblies, revealing their mesocrystalline nature and highlighting their importance within the growing field of metamaterials.

二元介晶展示了不同材料的納米晶體以高度有序的方式組合。雖然納米立方體的幾何形狀看起來(lái)很簡(jiǎn)單，但它們可以以各種方式排列成一個(gè)復(fù)雜的實(shí)體，不僅指導(dǎo)其慣態(tài)，而且指導(dǎo)其屬性。 Helmut C?lfen 等人在他們的研究文章 (e202112461) 中。關(guān)于微米尺寸的二維和三維二元粒子組件的形成和結(jié)構(gòu)分析的報(bào)告，揭示了它們的介晶性質(zhì)并強(qiáng)調(diào)了它們?cè)诓粩喟l(fā)展的超材料領(lǐng)域的重要性。

65.Depending on the nature of M+ , the hydrides of the H2Cu11 reactant behave differently. In the case of M=Cu or Ag, they act as regular two-electron ligands yielding [CuH2Cu11{S2P(OiPr)2}6(C≡CPh)3]+ (Cu12H2) or [AgH2Cu14{S2P(OiPr)2}6(C≡CPh)6]+ (AgH2Cu14); in the case of M=Au, they behave as electron donors to form [AuCu11{S2P(OiPr)2}6(C≡CPh)3Cl] (AuCu11). Details of the study are presented by Jean-Yves Saillard, Chen-Wei Liu, and co-workers in their Research Article (e202113266).

根據(jù) M+ 的性質(zhì)，H2Cu11 反應(yīng)物的氫化物表現(xiàn)不同。在 M=Cu 或 Ag 的情況下，它們充當(dāng)常規(guī)雙電子配體，產(chǎn)生 [CuH2Cu11{S2P(OiPr)2}6(C≡CPh)3]+ (Cu12H2) 或 [AgH2Cu14{S2P(OiPr)2} 6(C=CPh)6]+ (AgH2Cu14);在M=Au的情況下，它們作為電子供體形成[AuCu11{S2P(OiPr)2}6(C≡CPh)3Cl] (AuCu11)。 Jean-Yves Saillard、Chen-Wei Liu 及其同事在他們的研究文章 (e202113266) 中介紹了該研究的詳細(xì)信息。

66.Photomechanical crystals composed of 9-methylanthracene molecules were investigated by Daichi Kitagawa, Christopher J. Bardeen, Seiya Kobatake, and co-workers in their Research Article (e202114089). The crystals that expand under illumination could potentially be used as photon-powered actuators. Moreover, the quantitative connection between molecular reaction kinetics and mechanical response in well-defined single crystals provides a new benchmark for analyzing these photomechanical materials.

Daichi Kitakawa、Christopher J. Bardeen、Seiya Kobatake 及其同事在他們的研究文章 (e202114089) 中研究了由 9-甲基蒽分子組成的光機(jī)械晶體。在光照下膨脹的晶體有可能用作光子驅(qū)動(dòng)的致動(dòng)器。此外，明確的單晶中分子反應(yīng)動(dòng)力學(xué)和機(jī)械響應(yīng)之間的定量聯(lián)系為分析這些光機(jī)械材料提供了新的基準(zhǔn)。

67.A sequence-controlled ring-opening metathesis polymerization strategy based on macrobicyclic olefins bearing a sacrificial silyloxide bridge was developed by Hong Yang and co-workers as described in their Communication (e202112526). The cover image depicts a “magic” production line of sequence-defined polymers. The monomeric sequence information shown as a colored ball chain is implanted in the macro-ring, while the small ring induces narrow polydispersity and high regio- and stereospecificity.

Hong Yang 及其同事開(kāi)發(fā)了一種基于帶有犧牲硅氧基橋的大雙環(huán)烯烴的序列控制開(kāi)環(huán)易位聚合策略，如他們的通訊 (e202112526) 中所述。封面圖片描繪了一條“神奇”的序列定義聚合物生產(chǎn)線。顯示為彩色球鏈的單體序列信息被植入大環(huán)中，而小環(huán)則產(chǎn)生窄的多分散性和高區(qū)域特異性和立體特異性。

68.Covalent Organic Frameworks Near-equilibrium growth of chemically stable covalent organic framework–graphene oxide hybrid materials for the hydrogen evolution reaction is reported in the Communication by Jianyi Chen, Jichen Dong, Yunqi Liu et?al. (e202113067).

共價(jià)有機(jī)框架用于析氫反應(yīng)的化學(xué)穩(wěn)定的共價(jià)有機(jī)框架-氧化石墨烯雜化材料的近平衡生長(zhǎng)在陳建一、董繼辰、劉云琪等人的通訊中報(bào)道。（e202113067）。

69.Biosensors Molecular sensors for plant polyphenol imaging based on near-infrared fluorescent single wall carbon nanotubes are presented by Sebastian Kruss et?al. in their Research Article (e202108373).

生物傳感器 Sebastian Kruss 等人提出了基于近紅外熒光單壁碳納米管的植物多酚成像分子傳感器。在他們的研究文章（e202108373）中。

70.Photocatalytic Conversion of Methane: Recent Advancements and Prospects.

甲烷的光催化轉(zhuǎn)化：最新進(jìn)展和前景。

71.Crystal Structure Classification of Copper-Based Sulfides as a Tool for the Design of Inorganic Functional Materials.

銅基硫化物的晶體結(jié)構(gòu)分類(lèi)作為無(wú)機(jī)功能材料設(shè)計(jì)的工具。

72.Detection and Imaging of the Plant Pathogen Response by Near-Infrared Fluorescent Polyphenol Sensors.

通過(guò)近紅外熒光多酚傳感器檢測(cè)和成像植物病原體反應(yīng)。

73.3D Binary Mesocrystals from Anisotropic Nanoparticles.

來(lái)自各向異性納米顆粒的 3D 二元介晶。

74.Moderate Surface Segregation Promotes Selective Ethanol Production in CO2 Hydrogenation Reaction over CoCu Catalysts.

適度的表面偏析促進(jìn) CoCu 催化劑上 CO2 加氫反應(yīng)中選擇性乙醇的產(chǎn)生。

75.NIR-II Hydrogen-Bonded Organic Frameworks (HOFs) Used for Target-Specific Amyloid-β Photooxygenation in an Alzheimer's Disease Model.

NIR-II 氫鍵有機(jī)框架 (HOF) 用于阿爾茨海默病模型中目標(biāo)特異性淀粉樣蛋白-β 光氧合。

76.Discovery and Mechanism of Action of Small Molecule Inhibitors of Ceramidases.

神經(jīng)酰胺酶小分子抑制劑的發(fā)現(xiàn)及其作用機(jī)制。

77.An Exceptional Thermally Induced Four-State Nonlinear Optical Switch Arising from Stepwise Molecular Dynamic Changes in a New Hybrid Salt.

由新型混合鹽中的逐步分子動(dòng)態(tài)變化產(chǎn)生的特殊熱致四態(tài)非線性光開(kāi)關(guān)。

78.A Striking Mode of Activation of Carbon Disulfide with a Cooperative Bis(silylene).

協(xié)同雙（亞硅基）活化二硫化碳的驚人模式。

79.Highly Processable Covalent Organic Framework Gel Electrolyte Enabled by Side-Chain Engineering for Lithium-Ion Batteries.

通過(guò)鋰離子電池側(cè)鏈工程實(shí)現(xiàn)高度可加工的共價(jià)有機(jī)框架凝膠電解質(zhì)。

80.C?C Coupling Is Unlikely to Be the Rate-Determining Step in the Formation of C2+ Products in the Copper-Catalyzed Electrochemical Reduction of CO.

C?C 耦合不太可能是銅催化 CO 電化學(xué)還原中 C2+ 產(chǎn)物形成的速率決定步驟。

81.Electrophilic Activation of [1.1.1]Propellane for the Synthesis of Nitrogen-Substituted Bicyclo[1.1.1]pentanes.

[1.1.1]丙烷的親電活化用于合成氮取代的雙環(huán)[1.1.1]戊烷。

82.Highly Ethylene-Selective Electrocatalytic CO2 Reduction Enabled by Isolated Cu?S Motifs in Metal–Organic Framework Based Precatalysts.

基于金屬有機(jī)骨架的預(yù)催化劑中分離的 Cu?S 基序?qū)崿F(xiàn)了高度乙烯選擇性電催化 CO2 還原。

83.Transport of Molecular Cargo by Interaction with Virus-Like Particle RNA.

通過(guò)與病毒樣顆粒 RNA 相互作用進(jìn)行分子貨物運(yùn)輸。

84.Vacancy Modulating Co3Sn2S2 Topological Semimetal for Aqueous Zinc-Ion Batteries.

用于水系鋅離子電池的空位調(diào)制 Co3Sn2S2 拓?fù)浒虢饘佟?/p>

85.A Unified View on Varied Ultrafast Dynamics of the Primary Process in Microbial Rhodopsins.

微生物視紫紅質(zhì)初級(jí)過(guò)程的各種超快動(dòng)力學(xué)的統(tǒng)一觀點(diǎn)。

86.Dynamic Optical Visualization of Proton Transport Pathways at Water–Solid Interfaces.

水-固界面質(zhì)子傳輸路徑的動(dòng)態(tài)光學(xué)可視化。

87.Cascaded Nanozyme System with High Reaction Selectivity by Substrate Screening and Channeling in a Microfluidic Device.

通過(guò)微流體裝置中的底物篩選和通道形成具有高反應(yīng)選擇性的級(jí)聯(lián)納米酶系統(tǒng)。

88.Clippane: A Mechanically Interlocked Molecule (MIM) Based on Molecular Tweezers.

Clippane：一種基于分子鑷子的機(jī)械互鎖分子 (MIM)。

89.Zr(OH)4-Catalyzed Controllable Selective Oxidation of Anilines to Azoxybenzenes, Azobenzenes and Nitrosobenzenes.

Zr(OH)4-催化苯胺可控選擇性氧化為偶氮苯、偶氮苯和亞硝基苯。

90.Labile Photo-Induced Free Radical in α-Ketoglutaric Acid: a Universal Endogenous Polarizing Agent for In?Vivo Hyperpolarized 13C Magnetic Resonance.

α-酮戊二酸中不穩(wěn)定的光誘導(dǎo)自由基：用于體內(nèi)超極化 13C 磁共振的通用內(nèi)源性極化劑。

91.Dual Nanoislands on Ni/C Hybrid Nanosheet Activate Superior Hydrazine Oxidation-Assisted High-Efficiency H2 Production.

Ni/C 混合納米片上的雙納米島可激活卓越的肼氧化輔助高效氫氣生產(chǎn)。

92.Eutectic Crystallization Activates Solid-State Zinc-Ion Conduction.

共晶結(jié)晶激活固態(tài)鋅離子傳導(dǎo)。

93.Sterically Wrapped Multiple Resonance Fluorophors for Suppression of Concentration Quenching and Spectrum Broadening.

空間包裹的多重共振熒光團(tuán)用于抑制濃度淬滅和光譜展寬。

94.Reactivities of Interstitial Hydrides in a Cu11 Template: En Route to Bimetallic Clusters.

Cu11 模板中間隙氫化物的反應(yīng)性：通往雙金屬簇的途中。

95.Two-Dimensional Fluorinated Covalent Organic Frameworks with Tunable Hydrophobicity for Ultrafast Oil–Water Separation.

具有可調(diào)節(jié)疏水性的二維氟化共價(jià)有機(jī)框架，用于超快油水分離。

96.Construction of NH-Unprotected Spiropyrrolidines and Spiroisoindolines by [4+1] Cyclizations of γ-Azidoboronic Acids with Cyclic N-Sulfonylhydrazones.

通過(guò) γ-疊氮硼酸與環(huán)狀 N-磺酰腙的 [4+1] 環(huán)化構(gòu)建 NH-未保護(hù)的螺吡咯烷和螺異吲哚啉。