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【標題速讀】【Angew】【2022年】【10月】

2023-08-18 17:06 作者:Rt_Cola 0人讀過 | 我要投稿

聲明：本專欄主要對生命科學領(lǐng)域的一些期刊文章標題進行翻譯，所有內(nèi)容均由本人手工整理翻譯。由于本人專業(yè)為生物分析相關(guān)，其他領(lǐng)域如果出現(xiàn)翻譯錯誤請諒解。

1.Amorphous calcium carbonate (ACC) is a pivotal precursor in biomineralization, central to geological and industrial calcification. Some small organic molecules have the ability to affect ACC formation, composition, and stability powerfully. In their Research Article (e202208475), Asher Schmidt, Dirk Zahn, Stephan?E. Wolf et?al. decode the underlying molecular mechanisms that regulate both prenucleation cluster and solution composition and proceed outside the established conceptional framework.

無定形碳酸鈣 (ACC) 是生物礦化的關(guān)鍵前體，是地質(zhì)和工業(yè)鈣化的核心。一些有機小分子能夠強烈影響 ACC 的形成、組成和穩(wěn)定性。 Asher Schmidt、Dirk Zahn、Stephan E. Wolf 等人在他們的研究文章 (e202208475) 中解碼調(diào)節(jié)成核前簇和溶液組成的潛在分子機制，并在既定的概念框架之外進行。

2.Grafting N-heterocyclic carbenes (NHCs) on porous materials to realize high activity and recyclability is a challenge. In their Research Article (e202207478), Yuan-Biao Huang, Rong Cao, and co-workers describe the development of a facile method for utilizing NHC sites generated in?situ from CO2-masked precursors anchored on a covalent organic framework (COF) for sustainable catalytic CO2 conversion. The NHC-CO2 moieties can be transformed into NHC sites by heating in a catalytic process, in which the CO2 molecules mask the NHC sites and reversibly form NHC-CO2 after catalysis.

在多孔材料上接枝N-雜環(huán)卡賓（NHC）以實現(xiàn)高活性和可回收性是一個挑戰(zhàn)。Yuan-Biao Huang、Rong Cao 及其同事在他們的研究文章 (e202207478) 中描述了一種簡便方法的開發(fā)，該方法利用錨定在共價有機框架 (COF) 上的 CO2 掩蔽前體原位生成的 NHC 位點來實現(xiàn)可持續(xù)發(fā)展催化二氧化碳轉(zhuǎn)化。 NHC-CO2部分可以通過催化過程中的加熱轉(zhuǎn)化為NHC位點，其中CO2分子掩蓋NHC位點并在催化后可逆地形成NHC-CO2。

3.Enter stereogradient PLA: A tripodal zirconium complex catalyzes the polymerization of L-lactide contaminated with meso-lactide to yield stereogradient poly(lactic acid) (PLA), as described by Moshe Kol and co-workers in their Research Article (e202207652). The stereogradient copolymers exhibit enhanced crystallinities relative to the stereo-random copolymers derived from tin octanoate, and may alleviate the need for L-lactide purification.

輸入立體梯度 PLA：三足鋯絡(luò)合物催化被內(nèi)消旋丙交酯污染的 L-丙交酯聚合，產(chǎn)生立體梯度聚乳酸 (PLA)，如 Moshe Kol 及其同事在其研究文章 (e202207652) 中所述。相對于衍生自辛酸錫的立體無規(guī)共聚物，立體梯度共聚物表現(xiàn)出增強的結(jié)晶度，并且可以減輕對L-丙交酯純化的需要。

4.A palladium single-atom model catalyst was used by Ning Yan and co-workers in their Research Article (e202208237) to shed light on the kinetics and structural evolution of catalysts in hydrogen spillover, as well as the nature of participation of the spilled-over H in hydrogenation.

Ning Yan 及其同事在他們的研究文章 (e202208237) 中使用鈀單原子模型催化劑來闡明氫溢出中催化劑的動力學和結(jié)構(gòu)演化，以及溢出參與的本質(zhì)加氫時為H。

5.Organic Semiconductors. An amine-directed B?N bond formation for the synthesis of BN-fused polycyclic aromatic multiple resonance emitters is reported by Dongdong Zhang, Lian Duan et?al. in their Communication (e202207293).

有機半導(dǎo)體。張東東、段連等人在他們的通訊（e202207293）中報道了一種胺引導(dǎo)的 BN 鍵形成方法，用于合成 BN 稠合多環(huán)芳香族多重共振發(fā)射體。

6.Photocatalysis. The enantioselective three-component photochemical 1,4-bisalkylation of 1,3-butadiene with Pd/Cu catalysis is reported by Qinglong Zhang, Weiwei Zi, and Huimin Yu in their Research Article (e202208411).

光催化。 Qinglong Zhang、Weiwei Zi 和 Huimin Yu 在他們的研究文章 (e202208411) 中報道了 Pd/Cu 催化下 1,3-丁二烯的對映選擇性三組分光化學 1,4-雙烷基化反應(yīng)。

7.Stimuli-Responsive Metal Complexes for Biomedical Applications.

用于生物醫(yī)學應(yīng)用的刺激響應(yīng)金屬配合物。

8.Chemically Driven Rotatory Molecular Machines.

化學驅(qū)動的旋轉(zhuǎn)分子機器。

9.Design and Growth of Branched Organic Crystals: Recent Advances and Future Applications.

支化有機晶體的設(shè)計和生長：最新進展和未來應(yīng)用。

10.Enantioselective Three-Component Photochemical 1,4-Bisalkylation of 1,3-Butadiene with Pd/Cu Catalysis.

Pd/Cu 催化下 1,3-丁二烯的對映選擇性三組分光化學 1,4-雙烷基化。

11.Atomic-Scale View of Protein-PEG Interactions that Redirect the Thermal Unfolding Pathway of PEGylated Human Galectin-3.

重定向 PEG 化人 Galectin-3 熱解折疊途徑的蛋白質(zhì)-PEG 相互作用的原子尺度視圖。

12.Formation of a Strong Heterogeneous Aluminum Lewis Acid on Silica.

在二氧化硅上形成強異質(zhì)鋁路易斯酸。

13.Expedient Synthesis of Ubiquitin-like Protein ISG15 Tools through Chemo-Enzymatic Ligation Catalyzed by a Viral Protease Lbpro.

通過病毒蛋白酶 Lbpro 催化的化學酶連接法便捷合成泛素樣蛋白 ISG15 工具。

14.The Origin of High-Voltage Stability in Single-Crystal Layered Ni-Rich Cathode Materials.

單晶層狀富鎳正極材料高壓穩(wěn)定性的起源。

15.Phen-DC3 Induces Refolding of Human Telomeric DNA into a Chair-Type Antiparallel G-Quadruplex through Ligand Intercalation.

Phen-DC3 通過配體嵌入誘導(dǎo)人端粒 DNA 重折疊成椅型反平行 G-四鏈體。

16.Controlling the Transition of Nanospheres to Superhelices in Aqueous Media by Using a “Smart” Pyrazine Building Block.

使用“智能”吡嗪構(gòu)件控制水介質(zhì)中納米球向超螺旋的轉(zhuǎn)變。

17.Unblocking Ion-occluded Pore Channels in Poly(triazine imide) Framework for Proton Conduction.

疏通質(zhì)子傳導(dǎo)聚（三嗪酰亞胺）框架中離子閉塞的孔通道。

18.Stereogradient Poly(Lactic Acid) from meso-Lactide/L-Lactide Mixtures.

來自內(nèi)消旋丙交酯/L-丙交酯混合物的立體梯度聚（乳酸）。

19.A CO2-Masked Carbene Functionalized Covalent Organic Framework for Highly Efficient Carbon Dioxide Conversion.

用于高效二氧化碳轉(zhuǎn)化的 CO2 掩蔽卡賓功能化共價有機框架。

20.Divergent CO2 Activation by Tuning the Lewis Acid in Iron-Based Bimetallic Systems.

通過調(diào)節(jié)鐵基雙金屬體系中的路易斯酸來實現(xiàn)不同的 CO2 活化。

21.Transmembrane Shuttling of Photosynthetically Produced Electrons to Propel Extracellular Biocatalytic Redox Reactions in a Modular Fashion.

光合作用產(chǎn)生的電子的跨膜穿梭以模塊化方式推動細胞外生物催化氧化還原反應(yīng)。

22.Direct Dry Synthesis of Supported Bimetallic Catalysts: A Study on Comminution and Alloying of Metal Nanoparticles.

負載型雙金屬催化劑的直接干法合成：金屬納米粒子粉碎和合金化的研究。

23.Unshared Pair Electrons of Zincophilic Lewis Base Enable Long-life Zn Anodes under “Three High” Conditions.

親鋅路易斯堿的不共享電子對可在“三高”條件下實現(xiàn)長壽命的鋅陽極。

24.Modular Construction of Heterobiaryl Atropisomers and Axially Chiral Styrenes via All-Carbon Tetrasubstituted VQMs.

通過全碳四取代 VQM 構(gòu)建雜聯(lián)芳阻轉(zhuǎn)異構(gòu)體和軸向手性苯乙烯。

25.Hydrogen Spillover and Its Relation to Hydrogenation: Observations on Structurally Defined Single-Atom Sites.

氫溢出及其與氫化的關(guān)系：對結(jié)構(gòu)定義的單原子位點的觀察。

26.Arene Activation through Iminium Ions: Product Diversity from Intramolecular Photocycloaddition Reactions.

通過亞胺離子活化芳烴：分子內(nèi)光環(huán)加成反應(yīng)的產(chǎn)物多樣性。

27.Highly Strained Bi-MOF on Bismuth Oxyhalide Support with Tailored Intermediate Adsorption/Desorption Capability for Robust CO2 Photoreduction.

鹵氧化鉍支撐上的高應(yīng)變 Bi-MOF 具有定制的中間吸附/解吸能力，可實現(xiàn)穩(wěn)健的 CO2 光還原。

28.Small-Molecular-Weight Additives Modulate Calcification by Interacting with Prenucleation Clusters on the Molecular Level.

小分子量添加劑通過在分子水平上與成核前簇相互作用來調(diào)節(jié)鈣化。

29.Fiber-spinning Asymmetric Assembly for Janus-structured Bifunctional Nanofiber Films towards All-Weather Smart Textile.

用于全天候智能紡織品的 Janus 結(jié)構(gòu)雙功能納米纖維薄膜的纖維紡絲不對稱組裝。

30.Crystalline Porous Organic Salt for Ultrarapid Adsorption/Desorption-Based Atmospheric Water Harvesting by Dual Hydrogen Bond System.

用于通過雙氫鍵系統(tǒng)超快速吸附/解吸收集大氣水的結(jié)晶多孔有機鹽。

31.Aggregation-Induced Emission and Circularly Polarized Luminescence Duality in Tetracationic Binaphthyl-Based Cyclophanes.

四陽離子聯(lián)萘基環(huán)烷中的聚集誘導(dǎo)發(fā)射和圓偏振發(fā)光二象性。

32.Enantioselective para-C(sp2)?H Functionalization of Alkyl Benzene Derivatives via Cooperative Catalysis of Gold/Chiral Br?nsted Acid.

通過金/手性布朗斯臺德酸的協(xié)同催化對烷基苯衍生物進行對映選擇性對-C(sp2)?H 官能化。

33.Atomically Dispersed Indium-Copper Dual-Metal Active Sites Promoting C?C Coupling for CO2 Photoreduction to Ethanol.

原子分散的銦-銅雙金屬活性位點促進 CO2 光還原成乙醇的 C?C 耦合。

34.A Double-Helix Metal-Chain Metal-Organic Framework as a High-Output Triboelectric Nanogenerator Material for Self-Powered Anticorrosion.

雙螺旋金屬鏈金屬有機骨架作為高輸出摩擦納米發(fā)電機材料，用于自供電防腐。

35.Unravelling the Mechanistic Pathway of the Hydrogen Evolution Reaction Driven by a Cobalt Catalyst.

揭示鈷催化劑驅(qū)動的析氫反應(yīng)的機理途徑。

36.Autonomous Chiral Microswimmers with Self-mixing Capabilities for Highly Efficient Enantioselective Synthesis.

具有自混合能力的自主手性微型游泳器，可實現(xiàn)高效對映選擇性合成。

37.Simultaneous Generation of Methyl Esters and CO in Lignin Transformation.

木質(zhì)素轉(zhuǎn)化中同時生成甲酯和 CO。

38.Ribbon-Type Boron-Doped Polycyclic Aromatic Hydrocarbons: Conformations, Dynamic Complexation and Electronic Properties.

帶狀摻硼多環(huán)芳烴：構(gòu)象、動態(tài)絡(luò)合和電子特性。

39.Cobaloxime Photocatalysis for the Synthesis of Phosphorylated Heteroaromatics.

鈷肟光催化合成磷酸化雜芳烴。

40.Identification of a Novel Pseudo-Natural Product Type IV IDO1 Inhibitor Chemotype.

新型偽天然產(chǎn)品 IV 型 IDO1 抑制劑化學型的鑒定。

41.Multidentate Chelation Heals Structural Imperfections for Minimized Recombination Loss in Lead-Free Perovskite Solar Cells.

多齒螯合可以修復(fù)結(jié)構(gòu)缺陷，最大限度地減少無鉛鈣鈦礦太陽能電池的復(fù)合損失。

42.Direct Observation of Li-Ion Transport Heterogeneity Induced by Nanoscale Phase Separation in Li-rich Cathodes of Solid-State Batteries.

直接觀察固態(tài)電池富鋰陰極納米級相分離引起的鋰離子傳輸不均勻性。

43.Alloying at a Subnanoscale Maximizes the Synergistic Effect on the Electrocatalytic Hydrogen Evolution.

亞納米級合金化可最大限度地發(fā)揮電催化析氫的協(xié)同效應(yīng)。

44.Self-Propelled Initiative Collision at Microelectrodes with Vertically Mobile Micromotors.

具有垂直移動微電機的微電極自驅(qū)動主動碰撞。

45.A Single-Atom Cobalt Catalyst for the Fluorination of Acyl Chlorides at Parts-per-Million Catalyst Loading.

用于酰氯氟化的單原子鈷催化劑（百萬分之一催化劑負載量）。

46.An Activatable Near-Infrared Afterglow Theranostic Prodrug with Self-Sustainable Magnification Effect of Immunogenic Cell Death.

一種可激活的近紅外余輝治療診斷前藥，具有免疫原性細胞死亡的自我維持放大效應(yīng)。

47.A Carbon-Carbon Bond Cleavage-Based Prodrug Activation Strategy Applied to β-Lapachone for Cancer-Specific Targeting.

基于碳-碳鍵斷裂的前藥激活策略應(yīng)用于 β-Lapachone，以實現(xiàn)癌癥特異性靶向。

48.Efficient Gene Silencing in Intact Plant Cells Using siRNA Delivered By Functional Graphene Oxide Nanoparticles.

使用功能性氧化石墨烯納米顆粒傳遞的 siRNA 在完整植物細胞中進行高效基因沉默。

49.Deep-Blue Electroluminescence of Perovskites with Reduced Dimensionality Achieved by Manipulating Adsorption-Energy Differences.

通過操縱吸附能差異實現(xiàn)降維鈣鈦礦的深藍色電致發(fā)光。

50.Construction of Perylene-based Amphiphilic Micelle and Its Efficient Adsorption and In Situ Photodegradation of Bisphenol A in Aqueous Solution.

苝基兩親性膠束的構(gòu)建及其對水溶液中雙酚A的高效吸附和原位光降解。

51.P and Cu Dual Sites on Graphitic Carbon Nitride for Photocatalytic CO2 Reduction to Hydrocarbon Fuels with High C2H6 Evolution.

石墨碳氮化物上的 P 和 Cu 雙位點用于光催化 CO2 還原為具有高 C2H6 演化的碳氫化合物燃料。

52.Bismuth-Mediated α-Arylation of Acidic Diketones with ortho-Substituted Boronic Acids.

鉍介導(dǎo)的酸性二酮與鄰位取代的硼酸的 α-芳基化。

53.Nearly-Unity Quantum Yield and 12-Hour Afterglow from a Transparent Perovskite of Cs2NaScCl6:Tb.

Cs2NaScCl6:Tb 透明鈣鈦礦的近乎一致的量子產(chǎn)率和 12 小時余輝。

54.Two-Dimensional-on-Three-Dimensional Metal-Organic Frameworks for Photocatalytic H2 Production.

用于光催化氫氣生產(chǎn)的二維-三維金屬有機框架。

55.Reconstruction of Highly Dense Cu?N4 Active Sites in Electrocatalytic Oxygen Reduction Characterized by Operando Synchrotron Radiation.

以操作同步輻射為特征的電催化氧還原中高密度 Cu?N4 活性位點的重建。

56.High-Strength Plus Reversible Supramolecular Adhesives Achieved by Regulating Intermolecular PtII???PtII Interactions.

通過調(diào)節(jié)分子間 PtII???PtII 相互作用實現(xiàn)高強度可逆超分子粘合劑。

57.Phase Separation of Heterogeneous Nuclear Ribonucleoprotein A1 upon Specific RNA-Binding Observed by Magnetic Resonance.

通過磁共振觀察到特異性 RNA 結(jié)合時異質(zhì)核核糖核蛋白 A1 的相分離。

58.A Porphyrin-Based Organic Network Comprising Sustainable Carbon Dots for Photopolymerization.

包含用于光聚合的可持續(xù)碳點的卟啉基有機網(wǎng)絡(luò)。

59.Reductive Al?B σ-Bond Formation in Alumaboranes: Facile Scission of Polar Multiple Bonds.

Alumaborane 中還原 Al?B σ 鍵的形成：極性多重鍵的輕松斷裂。

60.Exploiting Coordination Effects for the Regioselective Zincation of Diazines Using TMPZnX?LiX (X=Cl, Br).

利用 TMPZnX·LiX (X=Cl, Br) 對二嗪進行區(qū)域選擇性鋅化的配位效應(yīng)。

61.Amine-Directed Formation of B?N Bonds for BN-Fused Polycyclic Aromatic Multiple Resonance Emitters with Narrowband Emission.

具有窄帶發(fā)射的BN稠合多環(huán)芳香族多重共振發(fā)射體的BN鍵的胺引導(dǎo)形成。

62.Transfer Hydrogenation with a Carbon-Nitride-Supported Palladium Single-Atom Photocatalyst and Water as a Proton Source.

用氮化碳支撐的鈀單原子光催化劑和水作為質(zhì)子源進行轉(zhuǎn)移氫化。

63.Highly Efficient Electrocatalytic Oxygen Evolution Over Atomically Dispersed Synergistic Ni/Co Dual Sites.

原子分散協(xié)同鎳/鈷雙位點高效電催化析氧。

64.Electronic Character of α,3-Dehydrotoluene Intermediates Generated from Isolable Allenyne-Containing Substrates.

由可分離的含丙炔底物生成的 α,3-脫氫甲苯中間體的電子特征。

65.pH-Induced Symmetry Conversion of DNA Origami Lattices.

pH 誘導(dǎo)的 DNA 折紙晶格的對稱性轉(zhuǎn)換。

66.Proton Chemistry Induced Long-Cycle Air Self-Charging Aqueous Batteries.

質(zhì)子化學誘導(dǎo)長周期空氣自充電水電池。

67.Integrating Light-Harvesting Ruthenium(II)-based Units into Three-Dimensional Metal Covalent Organic Frameworks for Photocatalytic Hydrogen Evolution.

將光捕獲釕（II）基單元集成到三維金屬共價有機框架中，用于光催化析氫。

68.Direct Arene Trifluoromethylation Enabled by a High-Valent CuIII?CF3 Compound.

高價 CuIII?CF3 化合物實現(xiàn)芳烴直接三氟甲基化。

69.Photocatalytic Direct Decarboxylation of Carboxylic Acids to Derivatize or Degrade Polymers.

羧酸的光催化直接脫羧以衍生或降解聚合物。

70.Stereoselective Three-Step One-Pot Cascade Combining Amino- and Biocatalysis to Access Chiral γ-Nitro Alcohols.

立體選擇性三步一鍋級聯(lián)結(jié)合氨基催化和生物催化獲得手性 γ-硝基醇。

71.Au???H?C Interactions Support a Robust Thermally Activated Delayed Fluorescence (TADF) Gold(I) Complex for OLEDs with Little Efficiency Roll-Off and Good Stability.

Au???H?C 相互作用支持用于 OLED 的魯棒熱激活延遲熒光 (TADF) 金 (I) 絡(luò)合物，且效率滾降小且穩(wěn)定性良好。

72.A Rebuilding-Free Nucleic Acid Detection Strategy Enables Ultrasensitive Genotyping, N-in-1 Logic Screening and Accurate Multiplex Assay of Dangerous Pathogens.

免重建核酸檢測策略可實現(xiàn)超靈敏基因分型、N-in-1 邏輯篩選和危險病原體的準確多重檢測。

73.1?:?1 Ca2+:Cu2+ A-site Order in a Ferrimagnetic Double Double Perovskite.

亞鐵磁性雙雙鈣鈦礦中的 1 : 1 Ca2+:Cu2+ A 位順序。

74.Selective CO2 Electroreduction to Ethanol over a Carbon-Coated CuOx Catalyst.

在碳包覆 CuOx 催化劑上選擇性 CO2 電還原為乙醇。

75.Molecular Electrochemical Reductive Splitting of Dinitrogen with a Molybdenum Complex.

二氮與鉬絡(luò)合物的分子電化學還原裂解。

76.Fano Resonance in Single-Molecule Junctions.

單分子連接中的法諾共振。

77.Space-Confined Donor-Acceptor Strategy Enables Fast Spin-Flip of Multiple Resonance Emitters for Suppressing Efficiency Roll-Off.

空間受限的供體-受體策略可實現(xiàn)多個諧振發(fā)射器的快速自旋翻轉(zhuǎn)，從而抑制效率滾降。

78.Solution-Phase Synthesis and Isolation of An Aza-Triangulene and Its Cation in Crystalline Form.

氮雜三角烯及其結(jié)晶形式的陽離子的溶液相合成和分離。

79.Tuning the Regioselectivity of Topochemical Polymerization through Cocrystallization of the Monomer with an Inert Isostere.

通過單體與惰性等排體的共結(jié)晶來調(diào)節(jié)拓撲化學聚合的區(qū)域選擇性。

80.Bright and Photostable Fluorescent Metal Nanocluster Supraparticles from Invert Emulsions.

來自反相乳液的明亮且光穩(wěn)定的熒光金屬納米簇超粒子。

81.Novel Poxin Stable cGAMP-Derivatives Are Remarkable STING Agonists.

新型 Poxin 穩(wěn)定 cGAMP 衍生物是卓越的 STING 激動劑。

82.Synthesis of α-Aryl Acrylamides via Lewis-Base-Mediated Aryl/Hydrogen Exchange.

通過路易斯堿介導(dǎo)的芳基/氫交換合成 α-芳基丙烯酰胺。

83.Synthesis of Non-Symmetric Azoarenes by Palladium-Catalyzed Cross-Coupling of Silicon-Masked Diazenyl Anions and (Hetero)Aryl Halides.

通過鈀催化硅掩蔽的二氮烯基陰離子和（雜）芳基鹵化物的交叉偶聯(lián)合成非對稱偶氮芳烴。

84.First explorations of binary Ge/Sb Zintl anions indicated a situation between a “matching” one and one that tends to element segregation owing to a mismatch in atom sizes. Extraction of the ternary solid K12Ge3.5Sb6 allowed access to the so far missing P4-like anion (Ge2Sb2)2?, as well as to species that show tendencies for spatial separation of Ge and Sb atoms, “incomplete” (Ge4Sb12)4? and “complete” (Ge4Sb14)4?, as confirmed by DFT calculations and described by Stefanie Dehnen et?al. in their Research Article (e202207232).

對二元 Ge/Sb Zintl 陰離子的首次探索表明，存在一種介于“匹配”陰離子和由于原子尺寸不匹配而傾向于元素偏析的陰離子之間的情況。提取三元固體 K12Ge3.5Sb6 可以獲取迄今為止缺失的 P4 類陰離子 (Ge2Sb2)2?，以及顯示出 Ge 和 Sb 原子空間分離傾向的物質(zhì)，“不完整”(Ge4Sb12)4?和“完整”(Ge4Sb14)4?，經(jīng) DFT 計算證實并由 Stefanie Dehnen 等人在他們的研究文章（e202207232）中描述。

85.A ball-milling approach allows the efficient activation of calcium metal and thus makes the direct generation of calcium-based heavy Grignard reagents feasible without complicated pre-activation processes. By using this operationally simple method, Koji Kubota, Hajime Ito, and co-workers developed a novel cross-electrophile-coupling reaction mediated by arylcalcium nucleophiles in their Research Article (e202207118), which is typically difficult using conventional Grignard reagents.

球磨方法可以有效活化鈣金屬，從而無需復(fù)雜的預(yù)活化過程即可直接生成鈣基重格氏試劑。通過使用這種操作簡單的方法，Koji Kubota、Hajime Ito 和同事在他們的研究文章 (e202207118) 中開發(fā)了一種由芳基鈣親核試劑介導(dǎo)的新型交叉親電子偶聯(lián)反應(yīng)，這通常很難使用傳統(tǒng)的格氏試劑實現(xiàn)。

86.A self-assembled glucose oxidase (GOx) nanoparticle that falls into the sea and dissociates into several enzymes is depicted in the picture illustrating the Research Article by Peng Huang and co-workers (e202208583). After dissociation, GOx regains its catalytic activity and catalyzes the oxidization of glucose into gluconic acid and H2O2. It's like someone pressing the “OFF-to-H2O2” switch that crosses the sea surface.

Peng Huang 及其同事的研究文章 (e202208583) 的圖片中描繪了一種自組裝的葡萄糖氧化酶 (GOx) 納米顆粒，它落入海中并分解成多種酶。解離后，GOx恢復(fù)催化活性，催化葡萄糖氧化成葡萄糖酸和H2O2。這就像有人按下“OFF-to-H2O2”開關(guān)，穿越海面。

87.The fast and the furious: A computational DFT booster to accelerate cysteine bioconjugation: In their Research Article (202205348), Mu-Hyun Baik, Christian P.?R. Hackenberger, and co-workers introduce ethynyl-triazolyl-phosphinates (ETPs) as modular electrophiles for the straightforward incorporation into complex payloads and proteins for modular protein- and antibody-modification strategies (cover picture: Barth van Rossum, FMP).

速度與激情：加速半胱氨酸生物共軛的計算 DFT 助推器：在他們的研究文章 (202205348) 中，Mu-Hyun Baik、Christian P. R. Hackenberger 及其同事介紹了乙炔基三唑基次膦酸鹽 (ETP) 作為模塊化親電子試劑，用于直接融入復(fù)雜的有效負載和蛋白質(zhì)中，以實現(xiàn)模塊化蛋白質(zhì)和抗體修飾策略（封面圖片：Barth van Rossum，F(xiàn)MP）。

88.Heterogeneous Catalysis. In their Communication (e202207777), Patrick Hemberger et?al. employed PEPICO spectroscopy to identify ketene and methylketene intermediates in methyl acetate conversion over the HZSM-5 zeolite.

多相催化。Patrick Hemberger 等人在他們的通訊 (e202207777) 中采用 PEPICO 光譜法鑒定 HZSM-5 沸石上乙酸甲酯轉(zhuǎn)化中的乙烯酮和甲基乙烯酮中間體。

89.Membranes. In their Research Article (e202206152), Jian Xue, Jürgen Caro, Haihui Wang et?al. report a bioinspired Ti3C2Tx MXene-based ionic diode membrane for osmotic energy conversion with extraordinary ionic rectification.

膜。Jian Xu、Jürgen Caro、Haihui Wang 等人在他們的研究文章 (e202206152) 中報告了一種基于 Ti3C2TX MXene 的仿生離子二極管膜，用于通過非凡的離子整流進行滲透能量轉(zhuǎn)換。

90.Small-Molecule Quenchers for F?rster Resonance Energy Transfer: Structure, Mechanism, and Applications.

用于福斯特共振能量轉(zhuǎn)移的小分子猝滅劑：結(jié)構(gòu)、機制和應(yīng)用。

91.Tailoring Bond Microenvironments and Reaction Pathways of Single-Atom Catalysts for Efficient Water Electrolysis.

定制單原子催化劑的鍵微環(huán)境和反應(yīng)途徑以實現(xiàn)高效水電解。

92.Bioinspired Ti3C2Tx MXene-Based Ionic Diode Membrane for High-Efficient Osmotic Energy Conversion.

基于仿生 Ti3C2TX MXene 的離子二極管膜，用于高效滲透能轉(zhuǎn)換。

93.DFT-Guided Discovery of Ethynyl-Triazolyl-Phosphinates as Modular Electrophiles for Chemoselective Cysteine Bioconjugation and Profiling.

DFT 引導(dǎo)發(fā)現(xiàn)乙炔基三唑基次膦酸鹽作為化學選擇性半胱氨酸生物共軛和分析的模塊化親電子試劑。

94.Synergistic Charge Percolation in Conducting Polymers Enables High-Performance In Vivo Sensing of Neurochemical and Neuroelectrical Signals.

導(dǎo)電聚合物中的協(xié)同電荷滲透可實現(xiàn)神經(jīng)化學和神經(jīng)電信號的高性能體內(nèi)傳感。

95.A Long-Circulating Vector for Aptamers Based upon Polyphosphodiester-Backboned Molecular Brushes.

基于多磷酸二酯主鏈分子刷的適配體長循環(huán)載體。

96.Tandem Electrochemical Oxidative Azidation/Heterocyclization of Tryptophan-Containing Peptides under Buffer Conditions.

緩沖條件下含色氨酸肽的串聯(lián)電化學氧化疊氮化/雜環(huán)化。

97.Programming and Dynamic Control of the Circular Polarization of Luminescence from an Achiral Fluorescent Dye in a Liquid Crystal Host by Molecular Motors.

通過分子馬達對液晶主體中非手性熒光染料發(fā)光的圓偏振進行編程和動態(tài)控制。