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【標(biāo)題速讀】【Angew】【2022年】【8月】

2023-08-17 21:56 作者:Rt_Cola 0人讀過 | 我要投稿

聲明：本專欄主要對生命科學(xué)領(lǐng)域的一些期刊文章標(biāo)題進(jìn)行翻譯，所有內(nèi)容均由本人手工整理翻譯。由于本人專業(yè)為生物分析相關(guān)，其他領(lǐng)域如果出現(xiàn)翻譯錯(cuò)誤請諒解。

1.The reaction path of the Lewis acid catalyzed intramolecular aza-Michael addition to form a C3 ammonium enolate is reported by Jan Paradies et?al. in their Communication (e202204378). This transient intermediate rearranges diastereospecifically to the tetrahydroquinoline-4-one scaffold. The central structure in the picture represents the transition state of the diastereospecific sigmatropic [1,5] carbon shift which proceeds with retention of configuration on the migrating carbon center.

Jan Paradies 等人在他們的通訊（e202204378）中報(bào)道了路易斯酸催化分子內(nèi)氮雜邁克爾加成形成 C3 烯醇銨的反應(yīng)路徑。該瞬時(shí)中間體非對映特異性地重排至四氫喹啉-4-酮支架。圖中的中心結(jié)構(gòu)代表非對映特異性同向性[1,5]碳轉(zhuǎn)移的過渡態(tài)，該轉(zhuǎn)移隨著遷移碳中心構(gòu)型的保留而進(jìn)行。

2.Porous organic salts (POSs) are porous organic materials, in which various aromatic sulfonic acids and amines are regularly self-assembled by charge-assisted hydrogen bonding. Norimitsu Tohnai and co-workers demonstrate in their Research Article (e202202597) the advantages of diverse porous organic salts, such as all-organic, extremely facile preparation methods, diverse void structures and environments, and excellent CO2 adsorption properties.

多孔有機(jī)鹽（POS）是多孔有機(jī)材料，其中各種芳香族磺酸和胺通過電荷輔助氫鍵有規(guī)律地自組裝。 Norimitsu Tohnai 及其同事在他們的研究文章 (e202202597) 中展示了多種多孔有機(jī)鹽的優(yōu)點(diǎn)，例如全有機(jī)、極其簡便的制備方法、多樣化的孔隙結(jié)構(gòu)和環(huán)境以及優(yōu)異的 CO2 吸附性能。

3.Rapid and reagent-free pathogen tests are urgently needed. In their Research Article (e202204252), Leyla Soleymani, Yingfu Li and co-workers developed a dual-electrode electrochemical chip (DEE-Chip) and a barcode-releasing electroactive aptamer for rapid on-farm detection of porcine epidemic diarrhea viruses (PEDv). In contrast to current biosecurity surveillance with turnaround times of 2–4 days, this technology identifies infection with PEDv in pig saliva in one hour with a diagnostic sensitivity of 100?% and specificity of 83?%.

迫切需要快速、無試劑的病原體檢測。在他們的研究文章 (e202204252) 中，Leyla Soleymani、Yingfu Li 及其同事開發(fā)了一種雙電極電化學(xué)芯片 (DEE-Chip) 和一種釋放條形碼的電活性適體，用于在農(nóng)場快速檢測豬流行性腹瀉病毒 (PEDv) 。與目前周轉(zhuǎn)時(shí)間為 2-4 天的生物安全監(jiān)測相比，該技術(shù)可在一小時(shí)內(nèi)識(shí)別出豬唾液中的 PEDv 感染，診斷靈敏度為 100%，特異性為 83%。

4.Tandem catalysis of solid NaPr-CoRu@Al2O3 and molecular [HCo(CO)3PR3] catalysts allows the direct conversion of synthesis gas to alcohols. Walter Leitner, Andreas?J. Vorholt, Gonzalo Prieto et?al. show in their Research Article (e202201004) that the combination of Fischer–Tropsch and hydroformylation catalysts generates alcohols from synthesis gas with exceptional selectivity. While the bimodally porous solid catalyst generates 1-olefins with high efficiency, in situ hydroformylation of olefins to alcohols circumvents secondary hydrogenation and allows to push the alcohol selectivity even further.

固體NaPr-CoRu@Al2O3和分子[HCo(CO)3PR3]催化劑的串聯(lián)催化可以將合成氣直接轉(zhuǎn)化為醇。沃爾特·萊特納 (Walter Leitner)、安德烈亞斯·J·沃霍爾特 (Andreas J. Vorholt)、貢薩洛·普列托 (Gonzalo Prieto) 等人在他們的研究文章 (e202201004) 中表明，費(fèi)托合成和加氫甲酰化催化劑的結(jié)合可以從合成氣中以優(yōu)異的選擇性生成醇。雖然雙峰多孔固體催化劑能夠高效生成 1-烯烴，但烯烴原位加氫甲?；癁榇?，避免了二次加氫，可以進(jìn)一步提高醇的選擇性。

5.Renewable Polymers. In their Communication (e202203353), Mukund?P. Sibi, Dean?C. Webster, Jayaraman Sivaguru et?al. highlight a methodology for the generation of photodegradable and recyclable cross-linked polymers from biomass.

可再生聚合物。在他們的通訊 (e202203353) 中，Mukund P. Sibi、Dean C. Webster、Jayaraman Sivaguru 等人強(qiáng)調(diào)從生物質(zhì)中生成可光降解和可回收的交聯(lián)聚合物的方法。

6.Protein Structures. By collecting matched room-temperature and cryogenic datasets of the biomedical target Hsp90α, Marcus Fischer et?al. identified in their Research Article (e202112919) changes in water networks that impact protein conformations at the ligand binding interface.

蛋白質(zhì)結(jié)構(gòu)。通過收集生物醫(yī)學(xué)目標(biāo) Hsp90α 的匹配室溫和低溫?cái)?shù)據(jù)集，Marcus Fischer 等人在他們的研究文章 (e202112919) 中發(fā)現(xiàn)水網(wǎng)絡(luò)的變化會(huì)影響配體結(jié)合界面的蛋白質(zhì)構(gòu)象。

7.Stepping Out of the Blue: From Visible to Near-IR Triggered Photoswitches.

出人意料：從可見光到近紅外觸發(fā)光電開關(guān)。

8.Water Networks Repopulate Protein–Ligand Interfaces with Temperature.

水網(wǎng)絡(luò)隨溫度重新填充蛋白質(zhì)-配體界面。

9.Ternary Alloy PtWMn as a Mn Nanoreservoir for High-Field MRI Monitoring and Highly Selective Ferroptosis Therapy.

三元合金 PtWMn 作為錳納米儲(chǔ)庫，用于高場 MRI 監(jiān)測和高選擇性鐵死亡治療。

10.Direct Conversion of Syngas to Higher Alcohols via Tandem Integration of Fischer–Tropsch Synthesis and Reductive Hydroformylation.

通過費(fèi)托合成和還原加氫甲?；拇?lián)集成將合成氣直接轉(zhuǎn)化為高級(jí)醇。

11.“Sandwich” Diimine-Copper Catalysts for C?H Functionalization by Carbene Insertion.

通過卡賓插入實(shí)現(xiàn) C?H 功能化的“三明治”二亞胺-銅催化劑。

12.Engineering Aptamers with Selectively Enhanced Biostability in the Tumor Microenvironment.

在腫瘤微環(huán)境中選擇性增強(qiáng)生物穩(wěn)定性的工程適體。

13.S,O-Ligand Promoted meta-C?H Arylation of Anisole Derivatives via Palladium/Norbornene Catalysis.

S,O-配體通過鈀/降冰片烯催化促進(jìn)苯甲醚衍生物的間位C?H芳基化。

14.Chemoenzymatic Cascades for the Enantioselective Synthesis of β-Hydroxysulfides Bearing a Stereocentre at the C?O or C?S Bond by Ketoreductases.

用于通過酮還原酶對映選擇性合成在 C?O 或 C?S 鍵上帶有立構(gòu)中心的 β-羥基硫化物的化學(xué)酶級(jí)聯(lián)。

15.Sustainable Afterglow Room-Temperature Phosphorescence Emission Materials Generated Using Natural Phenolics.

使用天然酚醛樹脂生成的可持續(xù)余輝室溫磷光發(fā)射材料。

16.Porous Organic Salts: Diversifying Void Structures and Environments.

多孔有機(jī)鹽：使空隙結(jié)構(gòu)和環(huán)境多樣化。

17.Concise Synthesis of Tunicamycin?V and Discovery of a Cytostatic DPAGT1 Inhibitor.

衣霉素 V 的簡明合成和細(xì)胞抑制 DPAGT1 抑制劑的發(fā)現(xiàn)。

18.Restoration of the Immunogenicity of Tumor Cells for Enhanced Cancer Therapy via Nanoparticle-Mediated Copper Chaperone Inhibition.

通過納米顆粒介導(dǎo)的銅伴侶抑制恢復(fù)腫瘤細(xì)胞的免疫原性以增強(qiáng)癌癥治療。

19.Polarization-Dependent Ultrasensitive Dynamic Wrinkling on Floating Films Induced by Photo-Orientation of Azopolymer.

偶氮聚合物光取向引起的浮動(dòng)薄膜上的偏振相關(guān)超靈敏動(dòng)態(tài)起皺。

20.From Copper to Basic Copper Carbonate: A Reversible Conversion Cathode in Aqueous Anion Batteries.

從銅到堿式碳酸銅：水性陰離子電池中的可逆轉(zhuǎn)換陰極。

21.Hydrogen Production and Water Desalination with On-demand Electricity Output Enabled by Electrochemical Neutralization Chemistry.

通過電化學(xué)中和化學(xué)實(shí)現(xiàn)氫氣生產(chǎn)和海水淡化以及按需電力輸出。

22.Highly Selective Carbonylation of CH3Cl to Acetic Acid Catalyzed by Pyridine-Treated MOR Zeolite.

吡啶處理的 MOR 沸石催化 CH3Cl 高度選擇性羰基化成乙酸。

23.Fast-Scanning Potential-Gated Organic Electrochemical Transistors for Highly Sensitive Sensing of Dopamine in Living Rat Brain.

快速掃描電位門控有機(jī)電化學(xué)晶體管，用于對活體大鼠大腦中的多巴胺進(jìn)行高靈敏傳感。

24.A DNA Barcode-Based Aptasensor Enables Rapid Testing of Porcine Epidemic Diarrhea Viruses in Swine Saliva Using Electrochemical Readout.

基于 DNA 條形碼的適配體傳感器能夠使用電化學(xué)讀數(shù)快速檢測豬唾液中的豬流行性腹瀉病毒。

25.Ruthenium-Catalyzed Geminal Hydroborative Cyclization of Enynes.

釕催化烯炔的偕硼氫化環(huán)化。

26.“Rim-Differentiated” Pillar[6]arenes.

“邊緣差異化”支柱芳烴[6]。

27.Bipolar Magnetic Molecules for Spin-Polarized Electric Current in Molecular Junctions.

用于分子結(jié)中自旋極化電流的雙極磁性分子。

28.Li?N Interaction Induced Deep Eutectic Gel Polymer Electrolyte for High Performance Lithium-Metal Batteries.

用于高性能鋰金屬電池的Li?N相互作用誘導(dǎo)的深共晶凝膠聚合物電解質(zhì)。

29.Catalytic Atroposelective Electrophilic Amination of Indoles.

吲哚的催化天體選擇性親電胺化。

30.Mild Acidosis-Directed Signal Amplification in Tumor Microenvironment via Spatioselective Recruitment of DNA Amplifiers.

通過 DNA 放大器的空間選擇性募集，在腫瘤微環(huán)境中實(shí)現(xiàn)輕度酸中毒定向信號(hào)放大。

31.Electrostatic-Induced Crystal-Rearrangement of Porous Organic Cage Membrane for CO2 Capture.

用于二氧化碳捕獲的多孔有機(jī)籠膜的靜電誘導(dǎo)晶體重排。

32.Nickel-Catalyzed Switchable Site-Selective Alkene Hydroalkylation by Temperature Regulation.

通過溫度調(diào)節(jié)進(jìn)行鎳催化可切換位點(diǎn)選擇性烯烴加氫烷基化。

33.Straightforward Access to Multifunctional π-Conjugated P-Heterocycles Featuring an Internal Ylidic Bond.

直接獲得具有內(nèi)部Ylidic 鍵的多功能π-共軛P-雜環(huán)。

34.Formation of a Hybrid 1-Bora-3-boratabenzene Heteroarene Anion Derivative.

雜化 1-Bora-3-borata 苯雜芳烴陰離子衍生物的形成。

35.Ultrafast Triplet–Singlet Exciton Interconversion in Narrowband Blue Organoboron Emitters Doped with Heavy Chalcogens.

摻雜重硫?qū)僭氐恼瓗{(lán)色有機(jī)硼發(fā)射體中的超快三線態(tài)-單線態(tài)激子相互轉(zhuǎn)換。

36.Precision Synthesis of Various Low-Bandgap Donor–Acceptor Alternating Conjugated Polymers via Living Suzuki–Miyaura Catalyst-Transfer Polymerization.

通過活性鈴木-宮浦催化劑轉(zhuǎn)移聚合精確合成各種低帶隙供體-受體交替共軛聚合物。

37.Stabilization of Cu+ via Strong Electronic Interaction for Selective and Stable CO2 Electroreduction.

通過強(qiáng)電子相互作用穩(wěn)定 Cu+，實(shí)現(xiàn)選擇性和穩(wěn)定的 CO2 電還原。

38.Highly Active and Stable Li2S?Cu Nanocomposite Cathodes Enabled by Kinetically Favored Displacement Interconversion between Cu2S and Li2S.

通過動(dòng)力學(xué)上有利的 Cu2S 和 Li2S 之間的位移相互轉(zhuǎn)化實(shí)現(xiàn)高活性和穩(wěn)定的 Li2S?Cu 納米復(fù)合材料陰極。

39.Activating Lattice Oxygen in Layered Lithium Oxides through Cation Vacancies for Enhanced Urea Electrolysis.

通過陽離子空位激活層狀氧化鋰中的晶格氧以增強(qiáng)尿素電解。

40.PIII-Directed Late-Stage Ligation and Macrocyclization of Peptides with Olefins by Rhodium Catalysis.

通過銠催化進(jìn)行 PIII 指導(dǎo)的肽與烯烴的后期連接和大環(huán)化。

41.Bioinspired Metalation of the Metal-Organic Framework MIL-125-NH2 for Photocatalytic NADH Regeneration and Gas-Liquid-Solid Three-Phase Enzymatic CO2 Reduction.

用于光催化 NADH 再生和氣-液-固三相酶促 CO2 還原的金屬有機(jī)框架 MIL-125-NH2 的仿生金屬化。

42.Atroposelective Construction of Nine-Membered Carbonate-Bridged Biaryls.

九元碳酸酯橋聯(lián)芳基的天體選擇性構(gòu)建。

43.Eutectic Electrolyte with Unique Solvation Structure for High-Performance Zinc-Ion Batteries.

用于高性能鋅離子電池的具有獨(dú)特溶劑化結(jié)構(gòu)的共晶電解質(zhì)。

44.An Ultrastable 155-Nuclei Silver Nanocluster Protected by Thiacalix[4]arene and Cyclohexanethiol for Photothermal Conversion.

由 Thiacalix[4] 芳烴和環(huán)己烷硫醇保護(hù)的超穩(wěn)定 155 核銀納米團(tuán)簇用于光熱轉(zhuǎn)換。

45.Embedding Multiphoton Active Units within Metal–Organic Frameworks for Turning on High-Order Multiphoton Excited Fluorescence for Bioimaging.

將多光子活性單元嵌入金屬有機(jī)框架中，以開啟高階多光子激發(fā)熒光以進(jìn)行生物成像。

46.Site-Selective Functionalization of Sila-Adamantane and Its Ensuing Optical Effects.

Sila-金剛烷的位點(diǎn)選擇性功能化及其隨之而來的光學(xué)效應(yīng)。

47.Tailored Multivalent Targeting of Siglecs with Photosensitizing Liposome Nanocarriers.

使用光敏脂質(zhì)體納米載體定制 Siglecs 多價(jià)靶向。

48.The Chemistry of Cu3N and Cu3PdN Nanocrystals.

Cu3N 和 Cu3PdN 納米晶體的化學(xué)性質(zhì)。

49.Mesoporous Polyimide-Linked Covalent Organic Framework with Multiple Redox-Active Sites for High-Performance Cathodic Li Storage.

具有多個(gè)氧化還原活性位點(diǎn)的介孔聚酰亞胺連接的共價(jià)有機(jī)框架，用于高性能陰極鋰存儲(chǔ)。

50.Asymmetrically Doping a Platinum Atom into a Au38 Nanocluster for Changing the Electron Configuration and Reactivity in Electrocatalysis.

將鉑原子不對稱摻雜到 Au38 納米團(tuán)簇中，以改變電催化中的電子構(gòu)型和反應(yīng)性。

51.Spatiotemporal Mapping of Efficient Chiral Induction by Helicene-Type Additives in Copolymer Thin Films.

共聚物薄膜中螺旋烯型添加劑的高效手性感應(yīng)的時(shí)空映射。

52.A Deep Eutectic Solvent Thermomorphic Multiphasic System for Biocatalytic Applications.

用于生物催化應(yīng)用的深共晶溶劑熱成型多相系統(tǒng)。

53.Towards Upcycling Biomass-Derived Crosslinked Polymers with Light.

利用光升級(jí)改造生物質(zhì)衍生的交聯(lián)聚合物。

54.Total Synthesis of (+)-Cochlearol?B by an Approach Based on a Catellani Reaction and Visible-Light-Enabled [2+2] Cycloaddition.

基于 Catellani 反應(yīng)和可見光 [2+2] 環(huán)加成的方法全合成 (+)-Cochlearol B。

55.Native Ambient Mass Spectrometry of an Intact Membrane Protein Assembly and Soluble Protein Assemblies Directly from Lens Tissue.

對直接來自晶狀體組織的完整膜蛋白組件和可溶性蛋白組件進(jìn)行天然環(huán)境質(zhì)譜分析。

56.A Novel AgI-DNA Rod Comprising a One-Dimensional Array of 11 Silver Ions within a Double Helical Structure.

一種新型 AgI-DNA 棒，由雙螺旋結(jié)構(gòu)內(nèi)的 11 個(gè)銀離子一維陣列組成。

57.Total Synthesis of Complex Peptidyl Nucleoside Antibiotics: Asymmetric De Novo Syntheses of Miharamycin?B and Its Biosynthetic Precursor.

復(fù)雜肽基核苷抗生素的全合成：米哈霉素 B 及其生物合成前體的不對稱從頭合成。

58.Synthesis of Si-Stereogenic Silanols by Catalytic Asymmetric Hydrolytic Oxidation.

催化不對稱水解氧化合成硅立體硅烷醇。

59.Alkyl/Glycosyl Sulfoxides as Radical Precursors and Their Use in the Synthesis of Pyridine Derivatives.

烷基/糖基亞砜作為自由基前體及其在吡啶衍生物合成中的應(yīng)用。

60.A Modular Approach for Diversity-Oriented Synthesis of 1,3-trans-Disubstituted Tetrahydroisoquinolines: Seven-Step Asymmetric Synthesis of Michellamines?B and C.

1,3-反式二取代四氫異喹啉的多樣性導(dǎo)向合成的模塊化方法：米開胺 B 和 C 的七步不對稱合成。

61.Sirtuin-Derived Covalent Binder for the Selective Recognition of Protein Crotonylation.

Sirtuin 衍生的共價(jià)結(jié)合劑，用于選擇性識(shí)別蛋白質(zhì)巴豆?；?。

62.Enhanced Photocatalytic CO2 Reduction through Hydrophobic Microenvironment and Binuclear Cobalt Synergistic Effect in Metallogels.

通過金屬凝膠中的疏水性微環(huán)境和雙核鈷協(xié)同效應(yīng)增強(qiáng)光催化二氧化碳還原。

63.Synthesis of an N-Heterocylic Boryl-Stabilized Disilyne and Its Application to the Activation of Dihydrogen and C?H Bonds.

N-雜環(huán)硼基穩(wěn)定二硅炔的合成及其在二氫鍵和 C?H 鍵活化中的應(yīng)用。

64.Exploring Equilibria between Aluminium(I) and Aluminium(III): The Formation of Dihydroalanes, Masked Dialumenes and Aluminium(I) Species.

探索鋁 (I) 和鋁 (III) 之間的平衡：二氫丙烷、掩蔽二鋁烯和鋁 (I) 物質(zhì)的形成。

65.Fluorescence or Phosphorescence? The Metallic Composition of the Nanocluster Kernel Does Matter.

熒光還是磷光？納米團(tuán)簇內(nèi)核的金屬成分很重要。

66.Green-Light-Driven Reductive Elimination of Chlorine from a Carbene-Xanthylium Gold(III) Complex.

綠光驅(qū)動(dòng)從卡賓-蒼耳金 (III) 絡(luò)合物中還原消除氯。

67.Formal β-C?H Arylation of Aldehydes and Ketones by Cooperative Nickel and Photoredox Catalysis.

通過鎳和光氧化還原協(xié)同催化對醛和酮進(jìn)行正式 β-C?H 芳基化。

68.Enantioselective Hydrocarbamoylation of Alkenes.

烯烴的對映選擇性加氫甲?；?。

69.Intramolecular Energy and Solvent-Dependent Chirality Transfer within a BINOL-Perylene Hetero-Cyclophane.

BINOL-苝雜環(huán)芳內(nèi)的分子內(nèi)能量和溶劑依賴性手性轉(zhuǎn)移。

70.Facile Synthesis of a Fluorinated-Squaramide Covalent Organic Framework for the Highly Efficient and Broad-Spectrum Removal of Per- and Polyfluoroalkyl Pollutants.

輕松合成氟化方酰胺共價(jià)有機(jī)框架，用于高效、廣譜去除全氟烷基和多氟烷基污染物。

71.Accelerated Degradation of Microplastics at the Liquid Interface of Ice Crystals in Frozen Aqueous Solutions.

冷凍水溶液中冰晶液體界面處微塑料的加速降解。

72.Umpolung AlaB Reagents for the Synthesis of Non-Proteogenic Amino Acids, Peptides and Proteins.

用于合成非蛋白氨基酸、肽和蛋白質(zhì)的 Umpolung AlaB 試劑。

73.Reductive Carbon–Carbon Coupling on Metal Sites Regulates Photocatalytic CO2 Reduction in Water Using ZnSe Quantum Dots.

金屬位點(diǎn)上的還原性碳-碳耦合利用 ZnSe 量子點(diǎn)調(diào)節(jié)水中 CO2 的光催化還原。

74.Sigmatropic [1,5] Carbon Shift of Transient C3 Ammonium Enolates.

瞬態(tài) C3 烯醇銨的 Sigmatropic [1,5] 碳轉(zhuǎn)移。

75.Metathesis Reactions of a NHC-Stabilized Phosphaborene.

NHC 穩(wěn)定的磷硼烯的復(fù)分解反應(yīng)。

76.Preparation of Functionalized Amides Using Dicarbamoylzincs.

使用二氨基甲酰鋅制備官能化酰胺。

77.A Planar Five-Membered Aromatic Ring Stabilized by Only Two π-Electrons.

僅由兩個(gè) π 電子穩(wěn)定的平面五元芳環(huán)。

78.A unique anion exchangeable hybrid composite aerogel material was fabricated by Sujit?K. Ghosh and co-workers in their Research Article (e202203385) by strategically implanting a stable cationic metal–organic polyhedron in a hierarchically porous metal–organic gel material. The composite scavenger efficiently and selectively sequestrates various metal-based toxic oxoanions from natural and simulated industrial wastewater samples in both batch and dynamic column exchange sorption experiments.

Sujit K. Ghosh 及其同事在其研究文章 (e202203385) 中通過在分層多孔金屬有機(jī)凝膠材料中策略性地植入穩(wěn)定的陽離子金屬有機(jī)多面體，制備了一種獨(dú)特的陰離子可交換雜化復(fù)合氣凝膠材料。在批量和動(dòng)態(tài)柱交換吸附實(shí)驗(yàn)中，復(fù)合清除劑可有效、選擇性地從天然和模擬工業(yè)廢水樣品中隔離各種金屬基有毒含氧陰離子。

79.Frustration under control: In their Communication (e202202727), Clémence Corminboeuf and co-workers developed a general approach to map the active site geometry of immobilized frustrated Lewis pair catalysts to their activity for CO2 hydrogenation and demonstrated that a manyfold increase in their performance is attainable through judicious spatial control of the acid and base components.

受阻可控：在他們的通訊 (e202202727) 中，Clémence Corminboeuf 和同事開發(fā)了一種通用方法，將固定受阻路易斯對催化劑的活性位點(diǎn)幾何結(jié)構(gòu)映射到其 CO2 加氫活性，并證明其性能可以實(shí)現(xiàn)數(shù)倍提高通過對酸和堿成分的明智的空間控制。

80.A small-molecule analogue of the formin FH2 domain inhibitor SMIFH2 was developed that selectively inhibits interferon-induced JAK-STAT signalling. Details of the study are reported by Cédric?M. Blouin, Christophe Lamaze, Rapha?l Rodriguez et?al. in their Communication (e202205231).

開發(fā)了福爾馬林 FH2 結(jié)構(gòu)域抑制劑 SMIFH2 的小分子類似物，可選擇性抑制干擾素誘導(dǎo)的 JAK-STAT 信號(hào)傳導(dǎo)。 Cédric M. Blouin、Christophe Lamaze、Rapha?l Rodriguez 等人在他們的通訊（e202205231）中報(bào)道了該研究的詳細(xì)信息。

81.Nucleic acid detection plays a critical role in medical diagnostics, environmental monitoring, and food safety. In their Research Article (e202203826), Xue Gao, Yi Zhang and co-workers developed a new biosensor for amplification-free nucleic acid detection via harnessing the trans-cleavage mechanism of Cas13a and ultrasensitive graphene field-effect transistors (gFETs). The illustration shows the Cas13a-mediated RNA trans-cleavage on a gFET surface for sensor signal transduction.

核酸檢測在醫(yī)療診斷、環(huán)境監(jiān)測和食品安全中發(fā)揮著至關(guān)重要的作用。在他們的研究文章 (e202203826) 中，Xue Gau、YiZhang 及其同事通過利用 Cas13a 的反式切割機(jī)制和超靈敏石墨烯場效應(yīng)晶體管 (gFET) 開發(fā)了一種用于無擴(kuò)增核酸檢測的新型生物傳感器。插圖顯示了 gFET 表面 Cas13a 介導(dǎo)的 RNA 反式切割，用于傳感器信號(hào)轉(zhuǎn)導(dǎo)。

82.Radical Ions The synthesis and characterization of stable iron pentacarbonyl radical cation salts is reported by Ingo Krossing et?al. in their Communication (e202204080).

自由基離子 Ingo Krossing 等人報(bào)道了穩(wěn)定的五羰基鐵自由基陽離子鹽的合成和表征。在他們的通訊（e202204080）中。

83.Carboranes The aromatic nucleophilic amination of 1,2-diaryl- o-carboranes with (R2N)2Mg for the synthesis of 4-R2N-o-carboranes and 2-R2N-m-carboranes is reported by Zuowei Xie and Jie Zhang in their Research Article (e202202675).

碳硼烷Zuowei Xie 和 Jie Zhu 在他們的研究中報(bào)道了 1,2-二芳基-鄰碳硼烷與 (R2N)2Mg 的芳香族親核胺化反應(yīng)合成了 4-R2N-o-碳硼烷和 2-R2N-m-碳硼烷文章（e202202675）。

84.Ultra-High Temperature Molten Oxide Electrochemistry.

超高溫熔融氧化物電化學(xué)。

85.N-Ligand-Enabled Aromatic Nucleophilic Amination of 1,2-Diaryl-o-Carboranes with (R2N)2Mg for Selective Synthesis of 4-R2N-o-Carboranes and 2-R2N-m-Carboranes.

N-配體使 1,2-二芳基-鄰碳硼烷與 (R2N)2Mg 發(fā)生芳香族親核胺化，用于選擇性合成 4-R2N-鄰碳硼烷和 2-R2N-間碳硼烷。

86.Fast Magic-Angle-Spinning NMR Reveals the Evasive Hepatitis?B Virus Capsid C-Terminal Domain.

快速魔角旋轉(zhuǎn) NMR 揭示了隱匿性乙型肝炎病毒衣殼 C 端結(jié)構(gòu)域。

87.Sb3+–Er3+-Codoped Cs2NaInCl6 for Emitting Blue and Short-Wave Infrared Radiation.

Sb3+–Er3+-共摻雜 Cs2NaInCl6 用于發(fā)射藍(lán)色和短波紅外輻射。

88.Sodium Borates: Expanding the Electrolyte Selection for Sodium-Ion Batteries.

硼酸鈉：擴(kuò)大鈉離子電池電解質(zhì)的選擇。

89.Hydrogen Isotope Separation Using a Metal–Organic Cage Built from Macrocycles.

使用由大環(huán)化合物構(gòu)建的金屬有機(jī)籠分離氫同位素。

90.Convergent Synthesis and Anti-Pancreatic Cancer Cell Growth Activity of a Highly Branched Heptadecasaccharide from Carthamus tinctorius.

紅花高度支化十七糖的聚合合成及其抗胰腺癌細(xì)胞生長活性。

91.Four-in-One Stimulus-Responsive Long-Lived Luminescent Systems Based on Pyrene-Doped Amorphous Polymers.

基于芘摻雜非晶聚合物的四合一刺激響應(yīng)長壽命發(fā)光系統(tǒng)。

92.Trap Inlaid Cationic Hybrid Composite Material for Efficient Segregation of Toxic Chemicals from Water.

用于有效分離水中有毒化學(xué)品的陷阱鑲嵌陽離子雜化復(fù)合材料。

93.Methylamine Lithium Borohydride as Electrolyte for All-Solid-State Batteries.

甲胺硼氫化鋰作為全固態(tài)電池的電解質(zhì)。

94.Back-Gated van der Waals Heterojunction Manipulates Local Charges toward Fine-Tuning Hydrogen Evolution.

背門范德華異質(zhì)結(jié)操縱局部電荷以微調(diào)氫的析出。

95.Intrinsic Nonflammable Ether Electrolytes for Ultrahigh-Voltage Lithium Metal Batteries Enabled by Chlorine Functionality.

用于超高壓鋰金屬電池的固有不可燃醚電解質(zhì)，由氯官能團(tuán)實(shí)現(xiàn)。

96.Amplification-Free Detection of SARS-CoV-2 and Respiratory Syncytial Virus Using CRISPR Cas13a and Graphene Field-Effect Transistors.

使用 CRISPR Cas13a 和石墨烯場效應(yīng)晶體管對 SARS-CoV-2 和呼吸道合胞病毒進(jìn)行無擴(kuò)增檢測。

97.Homochiral Multiferroic Cyanido-Bridged Dimetallic Complexes Assembled by C?F???K Interactions.

通過 C?F???K 相互作用組裝的同手性多鐵氰基橋雙金屬配合物。

98.Relaxation of the Plant Cell Wall Barrier via Zwitterionic Liquid Pretreatment for Micelle-Complex-Mediated DNA Delivery to Specific Plant Organelles.

通過兩性離子液體預(yù)處理松弛植物細(xì)胞壁屏障，以實(shí)現(xiàn)膠束復(fù)合物介導(dǎo)的 DNA 遞送至特定植物細(xì)胞器。