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【標題速讀】【JACS】【2022年】【12月】

2023-06-14 16:41 作者:Rt_Cola 0人讀過 | 我要投稿

聲明：本專欄主要對生命科學領域的一些期刊文章標題進行翻譯，所有內(nèi)容均由本人手工整理翻譯。由于本人專業(yè)為生物分析相關，其他領域如果出現(xiàn)翻譯錯誤請諒解。

Cocaine is a time-honored local anesthetic. We report its near-complete biosynthesis and clarify the unexpected intermediate ecgonone for constructing the tropane skeleton in cocaine, which illustrates the beauty of Robison's biomimetic tropinone synthesis. The de novo biosynthesis of cocaine in tobacco is then realized, entailing significant implications for pharmaceutical production.

可卡因是一種歷史悠久的局部麻醉劑。我們報告了其接近完成的生物合成，并闡明了意想不到的中間體芽子酮，用于構建可卡因中的托品酮骨架，這說明了羅賓遜仿生托品酮合成的美妙之處。然后實現(xiàn)了煙草中可卡因的從頭生物合成，這對藥物生產(chǎn)具有重要意義。

Design and synthesis of bench-stable 1,5-diiodobicyclo[3.1.1]heptane opens up facile access to a largely unexplored chemical species, [3.1.1]propellane. Uncovering its reactivity in turn enables convenient synthesis of various bicyclo[3.1.1]heptanes that are attracting attention in the field of drug discovery as potent bioisosteres of meta-substituted benzenes.

實驗室穩(wěn)定的 1,5-二碘雙環(huán) [3.1.1] 庚烷的設計和合成開辟了對很大程度上未開發(fā)的化學物種 [3.1.1] 丙烷的便捷途徑。揭示其反應性反過來又可以方便地合成各種雙環(huán) [3.1.1] 庚烷，這些雙環(huán) [3.1.1] 庚烷作為間位取代苯的有效生物電子等排物在藥物發(fā)現(xiàn)領域引起了人們的關注。

Liquid-ordered (Lo)/liquid-disordered (Ld) phase-coexisting vesicles were transferred to the solid support with microcavities for reconstructing pore-spanning lipid membranes. Accompanied by simulation, suppressed water permeation across the Lo domain was experimentally verified via spatiotemporal tracking of the fluorescent molecules under microcavities passivated by lipid membranes.

液體有序 (Lo)/液體無序 (Ld) 相共存囊泡被轉移到具有微腔的固體支持物上，用于重建跨孔脂質膜。伴隨著模擬，通過在脂質膜鈍化的微腔下熒光分子的時空跟蹤，實驗驗證了 Lo 域的水滲透受到抑制。

Platinum nanoclusters on a graphene catalytic condenser are programmed in their electron density via external voltage to modulate the binding energy and reactivity of molecules on the platinum surface.

石墨烯催化冷凝器上的鉑納米團簇通過外部電壓對其電子密度進行編程，以調(diào)節(jié)鉑表面分子的結合能和反應性。

We introduce a conditional and cell-selective genome editing system, termed enzyme-inducible CRISPR (eiCRISPR). eiCRISPR comprises Cas9 protein, a self-blocked inactive single-guide RNA (bsgRNA), and a chemically caged deoxyribozyme (DNAzyme) that activates bsgRNA and eiCRISPR in response to disease-associated enzyme for cancer cell-selective genome editing in vitro and in vivo.

我們介紹了一種條件和細胞選擇性基因組編輯系統(tǒng)，稱為酶誘導 CRISPR (eiCRISPR)。 eiCRISPR 包含 Cas9 蛋白、一種自我阻斷的無活性單向導 RNA (bsgRNA) 和一種化學籠狀脫氧核酶 (DNAzyme)，可激活 bsgRNA 和 eiCRISPR 以響應疾病相關酶，從而在體外和體內(nèi)對癌細胞進行選擇性基因組編輯。

Generation and collection of reproducible, quantitative surface-enhanced Raman scattering (SERS) signals have been major challenges for the widespread and practical use of Raman spectra. Here, we provide the multiscale perspectives on plasmonic nanoparticle systems that range from atomic to assembled nanostructure scales as well as emerging statistical and artificial intelligence approaches for analyzing SERS signals to realize quantitative SERS.

生成和收集可重現(xiàn)的定量表面增強拉曼散射 (SERS) 信號一直是拉曼光譜廣泛和實際使用的主要挑戰(zhàn)。在這里，我們提供了從原子到組裝納米結構尺度的等離子體納米粒子系統(tǒng)的多尺度視角，以及用于分析 SERS 信號以實現(xiàn)定量 SERS 的新興統(tǒng)計和人工智能方法。

Zhang and co-authors report the development of a selective activity-based probe for the secreted protease Kallikrein-related peptidase 6 (KLK6) by modular design. Probe IMP-2352 shows that selective inhibition of KLK6 reduces the invasiveness of pancreatic cancer cells and allows for the identification of potential KLK6 substrates.

Zhang 和合著者報告了一種基于選擇性活性的探針的開發(fā)，該探針通過模塊化設計用于分泌的蛋白酶激肽釋放酶相關肽酶 6 (KLK6)。探針 IMP-2352 表明，選擇性抑制 KLK6 可降低胰腺癌細胞的侵襲性，并允許識別潛在的 KLK6 底物。

A facile and universal strategy for the one-step synthesis of α-MoC1?x established by introducing a trace amount of Rh. Key factors and the structural evolution during carburization in a “black box” are unlocked by plenty of in situ characterizations from different aspects, shedding light on regulating the phase transformation of carbides View the article.

通過引入痕量 Rh 建立了一種簡單且通用的一步合成 α-MoC1-x 的策略。 “黑匣子”中滲碳過程中的關鍵因素和結構演化通過大量不同方面的原位表征得以解開，揭示了調(diào)節(jié)碳化物相變的方法查看文章。

We design a series of linear polymers with different side groups for further coordination-driven self-assembly. Such a design introduces a main-chain confinement, which effectively slows down the assembly process of metallotriangle side groups, thus allowing us to monitor the real-time evolution of non-equilibrium lychee-like nanostructures.

我們設計了一系列具有不同側基的線性聚合物，用于進一步協(xié)調(diào)驅動的自組裝。這種設計引入了主鏈限制，有效地減緩了金屬三角形側基的組裝過程，從而使我們能夠監(jiān)測非平衡荔枝狀納米結構的實時演變。

A new precoordination confinement strategy has been developed to install isolated metal single atoms (M-SAs; M = Pt, Ir, Au, Ru) in the pore-confined nanospaces of the amino group grafted porphyrinic metal–organic framework (MOF) Pd-PCN-222-NH2. The resultant MOF composites M-SAs@Pd-PCN-222-NH2 display high efficiency in the photocatalytic hydrogen evolution reaction, giving a turnover number up to 21713 based on M-SAs under visible light irradiation (λ ≥ 420 nm).

開發(fā)了一種新的預配位限制策略，將孤立的金屬單原子（M-SAs；M = Pt、Ir、Au、Ru）安裝在氨基接枝卟啉金屬有機骨架（MOF）Pd- PCN-222-NH2。由此產(chǎn)生的 MOF 復合材料 M-SAs@Pd-PCN-222-NH2 在光催化析氫反應中表現(xiàn)出高效率，在可見光照射下（λ≥420 nm），基于 M-SAs 的轉換數(shù)高達 21713。

Phosphorus (P), an essential element, mainly adopts a +5 oxidation state in biomolecules on oxygen-rich Earth, while the form of biosignature PH3 gas appears in the exoplanet atmosphere. Here, we bridge the large gap between oxygen-sensitive phosphine (+3) ligands and metalloprotein chemistry based on E. coli.

磷（P）是一種必需元素，在富氧地球上的生物分子主要以+5氧化態(tài)存在，而在系外行星大氣中則以生物特征PH3氣體的形式出現(xiàn)。在這里，我們彌合了氧敏感膦 (+3) 配體和基于大腸桿菌的金屬蛋白化學之間的巨大差距。

The QCaRA/AFIR method of a 52-atom natural product, endiandric acid C methyl ester, which was synthesized in a single step by Nicolaou in 1982, successfully traces the reaction back to the corresponding starting polyene only using the power of quantum chemical calculations.

Nicolaou 于 1982 年一步合成的 52 原子天然產(chǎn)物二苯二酸 C 甲酯的 QCaRA/AFIR 方法僅利用量子化學計算的力量成功地將反應追溯到相應的起始多烯。

Polarization-controlled coherent Raman microscopy can map 3D molecular orientations with sub-micrometer resolution. Imaging the 3D orientation of polymer chains allows for addressing the lamellar twisting mechanism in polyethylene spherulites.

偏振控制的相干拉曼顯微鏡可以繪制具有亞微米分辨率的 3D 分子方向。對聚合物鏈的 3D 方向進行成像可以解決聚乙烯球晶中的層狀扭曲機制。

Sabatier principle defines the essential criteria for being an ideal catalyst in heterogeneous catalysis, while approaching the Sabatier optimal is a major pursuit in catalyst design. The ferromagnetic catalysts are able to be the Sabatier optimal of the Haber-Bosch process via a second-order ferromagnetic–paramagnetic phase transition.

Sabatier 原理定義了在多相催化中成為理想催化劑的基本標準，而接近 Sabatier 最優(yōu)是催化劑設計的主要追求。鐵磁催化劑能夠通過二階鐵磁-順磁相變成為 Haber-Bosch 過程的 Sabatier 最優(yōu)。

A new class of discrete, chiral polymer–insulin conjugates is reported. These conjugates display composition and chirality-dependent blood glucose lowering effects in diabetic mice, suggesting that these molecular features of synthetic polymers can be tailored to optimize future polymer–protein conjugates.

報道了一類新的離散手性聚合物-胰島素偶聯(lián)物。這些結合物在糖尿病小鼠中顯示出成分和手性依賴性血糖降低作用，表明可以定制合成聚合物的這些分子特征以優(yōu)化未來的聚合物-蛋白質結合物。

Anion-binding catalytic system combining tripodal trithiourea with sodium thiophenolate enables the fast and selective anionic ring-opening polymerization of N-Carboxyanhydrides, leading to the precision construction of various polypeptides with living polymerization behavior. The high selectivity for propagation over deleterious side reactions correlates with enhanced stabilization of propagating carbamate anion.

結合三足三硫脲和苯硫酚鈉的陰離子結合催化體系使 N-羧酸氫化物的快速和選擇性陰離子開環(huán)聚合成為可能，從而精確構建具有活性聚合行為的各種多肽。對有害副反應的傳播的高選擇性與傳播的氨基甲酸酯陰離子的穩(wěn)定性增強相關。

This study exhibits a pathway for jet fuel production from renewable lignocellulose biomass derivatives. An anodic electrocatalysis route was employed to produce jet fuel precursors from biomass platform chemicals on Ni-based electrocatalysts in an aqueous electrolyte at room temperature and atmospheric pressure.

本研究展示了從可再生木質纖維素生物質衍生物生產(chǎn)噴氣燃料的途徑。在室溫和大氣壓力下，采用陽極電催化途徑在水性電解質中通過鎳基電催化劑從生物質平臺化學品生產(chǎn)噴氣燃料前體。

A new class of BF2 formazanate dyes that can cross the blood–brain barrier has been developed for the NIR-II imaging of deep brain areas through the intact scalp and skull. These new NIR-II dyes will provide a new scaffold for the design of probes for brain imaging and therapy.

已經(jīng)開發(fā)出一類可以穿過血腦屏障的新型 BF2 甲酸染料，用于通過完整的頭皮和顱骨對深部腦區(qū)域進行 NIR-II 成像。這些新的 NIR-II 染料將為腦成像和治療探針的設計提供新的支架。

The chiral seed, corannulene, and the chiral wall, pillar[5]arene, are docked and their chirality is fixed. All the subcomponents tilt in the same direction, generating the twisted cavitand with five-fold symmetry as a pair of enantiomers.

手性種子、環(huán)烯和手性壁、柱 [5] 芳烴對接，它們的手性是固定的。所有的子組分都向同一方向傾斜，從而產(chǎn)生具有五重對稱性的扭曲空穴作為一對對映體。

1.Could the Quantum Internet Be Comprised of Molecular Spins with Tunable Optical Interfaces?.

量子互聯(lián)網(wǎng)能否由具有可調(diào)光學界面的分子自旋組成？

2.Native Top-Down Mass Spectrometry with Collisionally Activated Dissociation Yields Higher-Order Structure Information for Protein Complexes.

具有碰撞激活解離的天然自上而下質譜法產(chǎn)生蛋白質復合物的高階結構信息。

3.Bifunctional Compounds as Molecular Degraders for Integrin-Facilitated Targeted Protein Degradation.

雙功能化合物作為整合素促進靶向蛋白質降解的分子降解劑。

4.From Biomass to Functional Crystalline Diamond Nanothread: Pressure-Induced Polymerization of 2,5-Furandicarboxylic Acid.

從生物質到功能性結晶金剛石納米線：2,5-呋喃二甲酸的壓力誘導聚合。

5.Pentosinane, a Post-Translational Modification of Human Proteins with Underappreciated Stability.

Pentosinane，一種穩(wěn)定性被低估的人類蛋白質的翻譯后修飾。

6.Practical and Facile Access to Bicyclo[3.1.1]heptanes: Potent Bioisosteres of meta-Substituted Benzenes.

雙環(huán) [3.1.1] 庚烷的實用和簡便獲?。洪g位取代苯的有效生物電子等排體。

7.Diazophosphane HPN2.

重氮磷 HPN2。

8.Iron-Catalyzed Intermolecular Amination of Benzylic C(sp3)–H Bonds.

鐵催化的芐基 C(sp3)–H 鍵的分子間胺化。

9.Chemical Emulation of the Biosynthetic Route to Anthrasteroids: Synthesis of Asperfloketal A.

蒽甾類生物合成途徑的化學模擬：Asperfloketal A 的合成。

10.Stabilizing Doubly Deprotonated Diazomethane: Isolable Complexes with CN22– and CN2– Radical Ligands.

穩(wěn)定雙重去質子化的重氮甲烷：具有 CN22– 和 CN2– 自由基配體的可分離復合物。

11.Photochemical Ring-Opening Reaction of 1,3-Cyclohexadiene: Identifying the True Reactive State.

1,3-環(huán)己二烯的光化學開環(huán)反應：識別真實的反應狀態(tài)。

12.In Vitro Membrane Platform for the Visualization of Water Impermeability across the Liquid-Ordered Phase under Hypertonic Conditions.

用于在高滲條件下通過液體有序相可視化水滲透性的體外膜平臺。

13.Conformer Ring Flip Enhances Mechanochromic Performance of ansa-Donor–Acceptor–Donor Mechanochromic Torsional Springs.

Conformer Ring Flip 增強了 ansa-Donor-Acceptor-Donor 機械變色扭轉彈簧的機械變色性能。

14.Au Atoms Anchored on Amorphous C3N4 for Single-Site Raman Enhancement.

錨定在無定形 C3N4 上的 Au 原子用于單點拉曼增強。

15.AIB3IIC3IIIQ8VI: A New Family for the Design of Infrared Nonlinear Optical Materials by Coupling Octahedra and Tetrahedra Units.

AIB3IIC3IIIQ8VI：通過耦合八面體和四面體單元設計紅外非線性光學材料的新系列。

16.Controlling the Size of Au Nanoparticles on Reducible Oxides with the Electrochemical Potential.

用電化學勢控制可還原氧化物上 Au 納米粒子的尺寸。

17.Regulating DNA-Hybridization Using a Chemically Fueled Reaction Cycle.

使用化學燃料反應循環(huán)調(diào)節(jié) DNA 雜交。

18.Molecular Design Principles to Elongate the Metal-to-Ligand Charge Transfer Excited-State Lifetimes of Square-Planar Nickel(II) Complexes.

延長方形平面鎳 (II) 配合物的金屬到配體電荷轉移激發(fā)態(tài)壽命的分子設計原則。

19.Clarifying the Relationship between the Lithium Deposition Coverage and Microstructure in Lithium Metal Batteries.

闡明鋰金屬電池中鋰沉積覆蓋率與微觀結構之間的關系。

20.Study of an RNA-Focused DNA-Encoded Library Informs Design of a Degrader of a r(CUG) Repeat Expansion.

以 RNA 為中心的 DNA 編碼文庫的研究為r(CUG) 重復擴增降解劑的設計提供了信息。

21.Partially Oxidized Purely Organic Zwitterionic Neutral Radical Conductor: Multi-step Phase Transitions and Crossover Caused by Intra- and Intermolecular Electronic Interactions.

部分氧化的純有機兩性離子中性自由基導體：由分子內(nèi)和分子間電子相互作用引起的多步相變和交叉。

22.Long-Wavelength Photoconvertible Dimeric BODIPYs for Super-Resolution Single-Molecule Localization Imaging in Near-Infrared Emission.

用于近紅外發(fā)射超分辨率單分子定位成像的長波長光轉換二聚體 BODIPY。

23.Discovery and Engineering of the Cocaine Biosynthetic Pathway.

可卡因生物合成途徑的發(fā)現(xiàn)和工程。

24.Surface-Clean Au25 Nanoclusters in Modulated Microenvironment Enabled by Metal–Organic Frameworks for Enhanced Catalysis.

表面清潔的 Au25 納米團簇在調(diào)制微環(huán)境中由金屬有機框架啟用以增強催化作用。

25.Surface Anion Promotes Pt Electrocatalysts with High CO Tolerance in Fuel-Cell Performance.

表面陰離子促進 Pt 電催化劑在燃料電池性能中具有高 CO 耐受性。

26.Photochemically Mediated Polymerization of Molecular Furan and Pyridine: Synthesis of Nanothreads at Reduced Pressures.

分子呋喃和吡啶的光化學介導聚合：在減壓下合成納米線。

27.Functional Water Networks in Fully Hydrated Photosystem II.

完全水化光系統(tǒng) II 中的功能性水網(wǎng)絡。

28.Photomechanical Motions in Organoboron-Based Phosphorescent Molecular Crystals Driven by a Crystal-State [2 + 2] Cycloaddition Reaction.

晶態(tài) [2 + 2] 環(huán)加成反應驅動的有機硼基磷光分子晶體中的光機械運動。

29.Mesoscale Polymer Surfactants: Photolithographic Production and Localization at Droplet Interfaces.

中尺度聚合物表面活性劑：液滴界面的光刻生產(chǎn)和定位。

30.Discovery, Structure, and Mechanism of a Class II Sesquiterpene Cyclase.

II 類倍半萜環(huán)化酶的發(fā)現(xiàn)、結構和機制。

31.Atomically Dispersed Au-Assisted C–C Coupling on Red Phosphorus for CO2 Photoreduction to C2H6.

用于將 CO2 光還原為 C2H6 的紅磷原子分散 Au 輔助 C-C 偶聯(lián)。

32.Ultrafast Two-Dimensional Infrared Spectroscopy Resolved a Structured Lysine 159 on the Cytoplasmic Surface of the Microbial Photoreceptor Bacteriorhodopsin.

超快二維紅外光譜法解析了微生物光感受器細菌視紫紅質細胞質表面上的結構化賴氨酸 159。

33.Bridging Electrochemistry and Photoelectron Spectroscopy in the Context of Birch Reduction: Detachment Energies and Redox Potentials of Electron, Dielectron, and Benzene Radical Anion in Liquid Ammonia.

中電子、雙電子和苯自由基陰離子的分離能和氧化還原電位。

34.Role of Serine Coordination in the Structural and Functional Protection of the Nitrogenase P-Cluster.

絲氨酸協(xié)調(diào)在固氮酶 P 簇的結構和功能保護中的作用。

35.Platinum Graphene Catalytic Condenser for Millisecond Programmable Metal Surfaces.

用于毫秒級可編程金屬表面的鉑金石墨烯催化冷凝器。

36.Gas-Phase Unfolding of Protein Complexes Distinguishes Conformational Isomers.

蛋白質復合物的氣相展開區(qū)分構象異構體。

37.Enantioselective Radical Addition to Ketones through Lewis Acid-Enabled Photoredox Catalysis.

通過路易斯酸啟用的光氧化還原催化對酮的對映選擇性自由基加成。

38.Uncovering the Electrolyte-Dependent Transport Mechanism of LiO2 in Lithium-Oxygen Batteries.

揭示鋰氧電池中 LiO2 依賴于電解質的傳輸機制。

39.Rhodium-Catalyzed Diastereo- and Enantioselective Divergent Annulations between Cyclobutanones and 1,5-Enynes: Rapid Construction of Complex C(sp3)-Rich Scaffolds.

銠催化的環(huán)丁酮和 1,5-烯炔之間的非對映和對映選擇性發(fā)散環(huán)化：快速構建復雜的 C(sp3)-富支架。

40.Reticular Chemistry with Art: A Case Study of Olympic Rings-Inspired Metal–Organic Frameworks.

網(wǎng)狀化學與藝術：以奧林匹克五環(huán)為靈感的金屬有機骨架案例研究。

41.Control of Ionic Conductivity by Lithium Distribution in Cubic Oxide Argyrodites Li6+xP1–xSixO5Cl.

通過鋰在立方氧化物亞銀石 Li6+xP1–xSixO5Cl 中的分布控制離子電導率。

42.Divalent Lanthanide Metallocene Complexes with a Linear Coordination Geometry and Pronounced 6s–5d Orbital Mixing.

具有線性配位幾何結構和顯著 6s–5d 軌道混合的二價鑭系茂金屬配合物。

43.Correlating CO Coverage and CO Electroreduction on Cu via High-Pressure in Situ Spectroscopic and Reactivity Investigations.

通過高壓原位光譜和反應性研究關聯(lián)銅上的 CO 覆蓋率和 CO 電還原。

44.Mn2+ Bispidine Complex Combining Exceptional Stability, Inertness, and MRI Efficiency.

Mn2+ Bispidine 絡合物兼具出色的穩(wěn)定性、惰性和 MRI 效率。

45.Synthesis of Carborane-Backbone Metallacycles for Highly Selective Capture of n-Pentane.

用于高選擇性捕獲正戊烷的碳硼烷骨架金屬環(huán)的合成。

46.Molecular Mechanisms of Mercury-Sensitive Aquaporins.

汞敏感性水通道蛋白的分子機制。

47.Revealing the Intrinsic Chiroptical Activity in Chiral Metal-Halide Semiconductors.

揭示手性金屬鹵化物半導體的固有手性光學活性。

48.Ambimodal Bispericyclic [6 + 4]/[4 + 6] Transition State Competes with Diradical Pathways in the Cycloheptatriene Dimerization: Dynamics and Experimental Characterization of Thermal Dimers.

雙峰雙周環(huán) [6 + 4]/[4 + 6] 過渡態(tài)與環(huán)庚三烯二聚化中的雙自由基途徑競爭：熱二聚體的動力學和實驗表征。

49.Designing Glass and Crystalline Phases of Metal–Bis(acetamide) Networks to Promote High Optical Contrast.

設計金屬-雙（乙酰胺）網(wǎng)絡的玻璃相和晶相以促進高光學對比度。

50.Orthogonal Chemical Activation of Enzyme-Inducible CRISPR/Cas9 for Cell-Selective Genome Editing.

用于細胞選擇性基因組編輯的酶誘導型 CRISPR/Cas9 的正交化學激活。

51.Regioselective Aromatic Perfluoro-tert-butylation Using Perfluoro-tert-butyl Phenyl Sulfone and Arynes.

使用全氟叔丁基苯基砜和芳烴的區(qū)域選擇性芳族全氟叔丁基化。

52.β-Lactamases Evolve against Antibiotics by Acquiring Large Active-Site Electric Fields.

β-內(nèi)酰胺酶通過獲得大的活性位點電場來對抗抗生素。

53.Ultrafast and Multicolor Luminescence Switching in a Lanthanide-Based Hydrochromic Perovskite.

基于鑭系元素的水致變色鈣鈦礦中的超快和多色發(fā)光切換。

54.Fast Sulfate Formation Initiated by the Spin-Forbidden Excitation of SO2 at the Air–Water Interface.

空氣-水界面處 SO2 的自旋禁止激發(fā)引發(fā)的快速硫酸鹽形成。

55.Skeletal Editing of Pyrimidines to Pyrazoles by Formal Carbon Deletion.

通過形式碳刪除將嘧啶骨架編輯為吡唑。

56.Electrophilic C–H Borylation of Aza[5]helicenes Leading to Bowl-Shaped Quasi-[7]Circulenes with Switchable Dynamics.

Aza[5]helicenes 的親電 C-H 硼酸化導致具有可切換動力學的碗狀準 [7]Circulenes。

57.Inch-Size Molecular Ferroelectric Crystal with a Large Electromechanical Coupling Factor on Par with Barium Titanate.

具有與鈦酸鋇相當?shù)拇髾C電耦合系數(shù)的英寸尺寸分子鐵電晶體。

58.Correction to “Synthesis and Chiral Resolution of Twisted Carbon Nanobelts”.

對“扭曲碳納米帶的合成和手性拆分”的更正。

59.Toward Quantitative Surface-Enhanced Raman Scattering with Plasmonic Nanoparticles: Multiscale View on Heterogeneities in Particle Morphology, Surface Modification, Interface, and Analytical Protocols.

用等離子體納米粒子進行定量表面增強拉曼散射：粒子形態(tài)學、表面改性、界面和分析協(xié)議中異質性的多尺度視圖。

60.The Protein Unfolded State: One, No One and One Hundred Thousand.

蛋白質展開狀態(tài)：一、沒有一和十萬。

61.Structure–Reactivity–Property Relationships in Covalent Adaptable Networks.

共價適應網(wǎng)絡中的結構-反應-性質關系。

62.Reading Information Stored in Synthetic Macromolecules.

讀取存儲在合成大分子中的信息。

63.Mechanical Force Enables an Anomalous Dual Ring-Opening Reaction of Naphthodipyran.

機械力使萘并雙吡喃發(fā)生異常雙開環(huán)反應。

64.A General Strategy to Install Amidine Functional Groups Along the Peptide Backbone.

沿肽主鏈安裝脒官能團的一般策略。

65.Zwitterions in 3D Perovskites: Organosulfide-Halide Perovskites.

3D 鈣鈦礦中的兩性離子：有機硫化物-鹵化物鈣鈦礦。

66.Overcoming Photochemical Limitations in Metallaphotoredox Catalysis: Red-Light-Driven C–N Cross-Coupling.

克服金屬光氧化還原催化中的光化學限制：紅光驅動的 C-N 交叉偶聯(lián)。

67.Polymer Molecular Weight Determination via Fluorescence Lifetime.

通過熒光壽命測定聚合物分子量。

68.Spinolate Lanthanide Complexes for High Circularly Polarized Luminescence Metrics in the Visible and Near-Infrared.

用于可見光和近紅外高圓偏振發(fā)光指標的多旋酸鑭系配合物。

69.Rhodium(III)-Catalyzed Anti-Markovnikov Hydroamidation of Unactivated Alkenes Using Dioxazolones as Amidating Reagents.

以二惡唑酮作為酰胺化試劑，銠 (III) 催化未活化烯烴的反馬爾可夫尼科夫氫化酰胺化反應。

70.Cobalt-Catalyzed Nitrogen Atom Insertion in Arylcycloalkenes.

芳基環(huán)烯烴中鈷催化的氮原子插入。

71.Plate-like Guanine Biocrystals Form via Templated Nucleation of Crystal Leaflets on Preassembled Scaffolds.

板狀鳥嘌呤生物晶體通過預組裝支架上的晶體小葉的模板化成核形成。

72.Neutral Homoaromatic Diboradisilacyclobutene: Synthesis, Structure, and Reactivity.

中性高芳香族二硼硅雜環(huán)丁烯：合成、結構和反應性。

73.Enantioselective Giese Additions of Prochiral α-Amino Radicals.

前手性 α-氨基自由基的對映選擇性 Giese 加成。

74.Nano-Biohybrid DNA Engager That Reprograms the T-Cell Receptor.

重新編程 T 細胞受體的納米生物雜交 DNA 接合劑。

75.Gas-Phase Formation of 1,3,5,7-Cyclooctatetraene (C8H8) through Ring Expansion via the Aromatic 1,3,5-Cyclooctatrien-7-yl Radical (C8H9?) Transient.

1,3,5,7-環(huán)辛四烯 (C8H8) 通過芳族 1,3,5-環(huán)辛三烯-7-基自由基 (C8H9?) 瞬變環(huán)擴展形成氣相。

76.Impact of Hydrophobic/Hydrophilic Balance on Aggregation Pathways, Morphologies, and Excited-State Dynamics of Amphiphilic Diketopyrrolopyrrole Dyes in Aqueous Media.

疏水/親水平衡對水性介質中兩親性二酮吡咯并吡咯染料的聚集途徑、形態(tài)和激發(fā)態(tài)動力學的影響。