聲明：本專欄主要對生命科學領域的一些期刊文章標題進行翻譯，所有內容均由本人手工整理翻譯。由于本人專業(yè)為生物分析相關，其他領域如果出現(xiàn)翻譯錯誤請諒解。

1.Chimeric antigen receptor (CAR) T?cell therapy suffers from complications including cytokine release syndromes and T?cell exhaustion. To curb these drawbacks, Jianfeng Zhou, Wenshe?Ray Liu et?al. report in their Research Article (e202109550) a chemogenetic switch that can be reversibly turned on and off to control the expression of CAR using a clinically approved small-molecule drug, asunaprevir. This novel technique will potentially enable delicate modulation of CAR-T activation during cancer treatment.

嵌合抗原受體 (CAR) T 細胞療法會出現(xiàn)并發(fā)癥，包括細胞因子釋放綜合征和 T 細胞耗竭。為了遏制這些弊端，Jianfeng Zhou、Wenshe Ray Liu 等人。在他們的研究文章 (e202109550) 中報告了一種化學遺傳學開關，可以使用臨床批準的小分子藥物 asunaprevir 可逆地打開和關閉以控制 CAR 的表達。這項新技術將有可能在癌癥治療過程中對 CAR-T 激活進行精細調節(jié)。

2.Hollow triple-shelled Zn/MFI single crystals were designed by Ning Wang and co-workers in their Research Article (e202114786). They exhibit a rather long lifetime as well as an enhanced shape selectivity for p-xylene.

空心三殼 Zn/MFI 單晶是由 Ning Wang 及其同事在他們的研究文章 (e202114786) 中設計的。它們表現(xiàn)出相當長的壽命以及對二甲苯增強的形狀選擇性。

3.Multi-photon absorption (MPA) is needed for certain applications requiring tight spatial control and long wavelength excitation, but few examples of molecules exhibiting higher-order MPA exist. In their Communication (e202116181), Mark?G. Humphrey and co-workers report that metallodendrimers can exhibit outstanding three- to six-photon absorption with fs-pulsed light, and they disclose the key role of metal-to-oligo(phenyleneethynylene) charge transfer in MPA activity.

某些需要嚴格空間控制和長波長激發(fā)的應用需要多光子吸收 (MPA)，但很少有分子表現(xiàn)出高階 MPA 的例子。在他們的通訊 (e202116181) 中，Mark G. Humphrey 及其同事報告說，金屬樹枝狀大分子可以通過飛秒脈沖光表現(xiàn)出出色的三到六光子吸收，并且他們揭示了金屬到低聚（亞苯基乙炔基）電荷的關鍵作用MPA 活動中的轉移。

4.Reduction-induced hydrogenation of a helical bilayer nanographene (C138H120) with K or Rb in 18-crown-6 is reported by Israel Fernández, Marina?A. Petrukhina, Nazario Martín, and co-workers in their Research Article (e202115747). DFT calculations predict that localization of the first two electrons in the helicene moiety leads to a site-specific hydrogenation at the carbon atoms located on the edge of the central [6]helicene backbone (pink hydrogens). The third electron forms a radical trianion on the HBC leading to a final Rb complex.

Israel Fernández、Marina A. Petrukhina、Nazario Martín 及其同事在他們的研究文章 (e202115747) 中報道了 18-crown-6 中螺旋雙層納米石墨烯 (C138H120) 與 K 或 Rb 的還原誘導氫化。 DFT 計算預測，螺旋烯部分中前兩個電子的定位會導致位于中心 [6] 螺旋烯主鏈邊緣的碳原子（粉紅色氫）發(fā)生位點特異性氫化。第三個電子在 HBC 上形成自由基三陰離子，形成最終的 Rb 絡合物。

5.Electron Transfer In their Communication (e202114423), Bei Ding, Dongping Zhong et?al. investigate the photoinduced proton-coupled electron transfer processes of the OaPAC BLUF domain W mutant.

通信中的電子轉移 (e202114423)，丁北，鐘東平等人。研究 OaPAC BLUF 結構域 W 突變體的光誘導質子耦合電子轉移過程。

6.Batteries A covalent organic framework with highly accessible carbonyl groups for advanced potassium-ion batteries is reported in the Research Article by Xing-Long Wu et?al. (e202117661).

電池 Xing-Long Wu 等人在研究文章中報道了一種具有易于接近的羰基的共價有機框架，用于先進的鉀離子電池。 （e202117661）。

7.Deoxygenative Functionalizations of Aldehydes, Ketones and Carboxylic Acids.

醛、酮和羧酸的脫氧官能化。

8.Covalent Organic Framework with Highly Accessible Carbonyls and π-Cation Effect for Advanced Potassium-Ion Batteries.

用于先進鉀離子電池的具有高度易接近的羰基和 π 陽離子效應的共價有機框架。

9.A Reversible Chemogenetic Switch for Chimeric Antigen Receptor T?Cells.

嵌合抗原受體 T 細胞的可逆化學遺傳學開關。

10.Substrate Profiling of Mitochondrial Caseinolytic Protease P via a Site-Specific Photocrosslinking Approach.

通過位點特異性光交聯(lián)方法對線粒體酪蛋白分解蛋白酶 P 進行底物分析。

11.Direct and Unified Access to Carbon Radicals from Aliphatic Alcohols by Cost-Efficient Titanium-Mediated Homolytic C?OH Bond Cleavage.

通過經濟高效的鈦介導的均質 C?OH 鍵斷裂，從脂肪醇中直接統(tǒng)一獲取碳自由基。

12.Tandem Living Insertion and Controlled Radical Polymerization for Polyolefin–Polyvinyl Block Copolymers.

聚烯烴-聚乙烯嵌段共聚物的串聯(lián)活性插入和受控自由基聚合。

13.Organic Supramolecular Zippers with Ultralong Organic Phosphorescence by a Dexter Energy Transfer Mechanism.

Dexter 能量轉移機制具有超長有機磷光的有機超分子拉鏈。

14.In Situ Self-Assembly of Bispecific Peptide for Cancer Immunotherapy.

用于癌癥免疫治療的雙特異性肽的原位自組裝。

15.Accessing Highly Efficient Photothermal Conversion with Stable Open-Shell Aromatic Nitric Acid Radicals.

利用穩(wěn)定的開殼芳香族硝酸自由基實現(xiàn)高效光熱轉換。

16.Two-Dimensional Polycyclic Photovoltaic Molecule with Low Trap Density for High-Performance Photocatalytic Hydrogen Evolution.

用于高性能光催化析氫的低陷阱密度二維多環(huán)光伏分子。

17.Efficient Long-Range Triplet Exciton Transport by Metal–Metal Interaction at Room Temperature.

室溫下金屬-金屬相互作用的高效長程三重態(tài)激子傳輸。

18.Hetero-Lattice Intergrown and Robust MOF Membranes for Polyol Upgrading.

用于多元醇升級的異質晶格共生且堅固的 MOF 膜。

19.Electropolymerization of Metal Clusters Establishing a Versatile Platform for Enhanced Catalysis Performance.

金屬簇的電聚合建立了增強催化性能的多功能平臺。

20.Photoswitchable Epothilone-Based Microtubule Stabilisers Allow GFP-Imaging-Compatible, Optical Control over the Microtubule Cytoskeleton.

基于埃坡霉素的光開關微管穩(wěn)定劑可以對微管細胞骨架進行 GFP 成像兼容的光學控制。

21.Rational Design of Zinc/Zeolite Catalyst: Selective Formation of p-Xylene from Methanol to Aromatics Reaction.

鋅/沸石催化劑的合理設計：從甲醇到芳烴反應選擇性生成對二甲苯。

22.High-Capacity and Long-Life Zinc Electrodeposition Enabled by a Self-Healable and Desolvation Shield for Aqueous Zinc-Ion Batteries.

通過水性鋅離子電池的自愈和去溶劑化屏蔽實現(xiàn)高容量和長壽命的鋅電沉積。

23.A Chemoenzymatic Cascade Combining a Hydration Catalyst with an Amine Dehydrogenase: Synthesis of Chiral Amines.

結合水合催化劑與胺脫氫酶的化學酶級聯(lián)：手性胺的合成。

24.The Underlying Molecular Mechanism of Fence Engineering to Break the Activity–Stability Trade-Off in Catalysts for the Hydrogen Evolution Reaction.

打破析氫反應催化劑活性與穩(wěn)定性權衡的柵欄工程的基本分子機制。

25.The Assembly and Jamming of Nanoparticle Surfactants at Liquid–Liquid Interfaces.

納米顆粒表面活性劑在液-液界面的組裝和干擾。

26.Chiral Hybrid Copper(I) Halides for High Efficiency Second Harmonic Generation with a Broadband Transparency Window.

用于產生具有寬帶透明窗口的高效二次諧波的手性雜化銅 (I) 鹵化物。

27.Asymmetric Hydroaminoalkylation of Alkenylazaarenes via Cooperative Photoredox and Chiral Hydrogen-Bonding Catalysis.

通過協(xié)同光氧化還原和手性氫鍵催化進行烯基氮雜芳烴的不對稱氫氨基烷基化。

28.Experimental and Computational Studies on the Directing Ability of Chalcogenoethers in Palladium-Catalyzed Atroposelective C?H Olefination and Allylation.

硫屬醚在鈀催化的 Atropeselective C?H 烯化和烯丙基化中的導向能力的實驗和計算研究。

29.Sustainable Superhydrophobic Surface with Tunable Nanoscale Hydrophilicity for Water Harvesting Applications.

用于集水應用的具有可調納米級親水性的可持續(xù)超疏水表面。

30.Dinuclear PtII Complexes with Strong Blue Phosphorescence for Operationally Stable Organic Light-Emitting Diodes with EQE up to 23?% at 1000?cd?m?2.

具有強藍色磷光的雙核 PtII 配合物，可用于運行穩(wěn)定的有機發(fā)光二極管，在 1000 cd m?2 時 EQE 高達 23 %。

31.Exceptional Manganese(II) Stability and Manganese(II)/Zinc(II) Selectivity with Rigid Polydentate Ligands.

剛性多齒配體具有出色的錳 (II) 穩(wěn)定性和錳 (II)/鋅 (II) 選擇性。

32.Ultrasensitive Detection of Aqueous Uranyl Based on Uranyl-Triggered Protein Photocleavage.

基于鈾酰觸發(fā)的蛋白質光裂解對水性鈾酰進行超靈敏檢測。

33.Site-Specific Reduction-Induced Hydrogenation of a Helical Bilayer Nanographene with K and Rb Metals: Electron Multiaddition and Selective Rb+ Complexation.

螺旋雙層納米石墨烯與 K 和 Rb 金屬的位點特異性還原誘導氫化：電子多重加成和選擇性 Rb+ 絡合。

34.Torque-Driven Orientation Motion of Chemotactic Colloidal Motors.

趨化膠體電機的扭矩驅動定向運動。

35.Lessons from an Array: Using an Electrode Surface to Control the Selectivity of a Solution-Phase Chemical Reaction.

陣列的經驗教訓：使用電極表面控制溶液相化學反應的選擇性。

36.Site-Selective N-1 and C-3 Heteroarylation of Indole with Heteroarylnitriles by Organocatalysis under Visible Light.

在可見光下通過有機催化對吲哚與雜芳基腈進行位點選擇性 N-1 和 C-3 雜芳基化。

37.Semiconducting Polymer Nano-regulators with Cascading Activation for Photodynamic Cancer Immunotherapy.

用于光動力癌癥免疫治療的具有級聯(lián)激活功能的半導體聚合物納米調節(jié)劑。

38.High-Performance Sulfate Optical Materials Exhibiting Giant Second Harmonic Generation and Large Birefringence.

具有巨大二次諧波產生和大雙折射的高性能硫酸鹽光學材料。

39.Robust Luminescent Molecules with High-Level Reverse Intersystem Crossing for Efficient Near Ultraviolet Organic Light-Emitting Diodes.

具有高水平反向系間竄越的魯棒發(fā)光分子，可實現(xiàn)高效近紫外有機發(fā)光二極管。

40.Chirality Inversion in Self-Assembled Nanocomposites Directed by Curvature-Mediated Interactions.

由曲率介導的相互作用引導的自組裝納米復合材料的手性反轉。

41.Formation and Reactivity of a Hexahydridosilicate [SiH6]2? Coordinated by a Macrocycle-Supported Strontium Cation.

由大環(huán)支撐的鍶陽離子協(xié)調的六氫硅酸鹽 [SiH6]2? 的形成和反應性。

42.Direct Observation of Ultrafast Proton Rocking in the BLUF Domain.

BLUF 域中超快質子搖擺的直接觀測。

43.A Fluorescent Sensor for Quantitative Super-Resolution Imaging of Amyloid Fibril Assembly.

用于淀粉樣原纖維組裝定量超分辨率成像的熒光傳感器。

44.Dissipative Organization of DNA Oligomers for Transient Catalytic Function.

用于瞬時催化功能的 DNA 寡聚物的耗散組織。

45.Total Synthesis of Isorosthin?L and Isoadenolin?I.

異大豆苷L和異腺苷I的全合成。

46.Highly Regio- and Enantioselective Hydrosilylation of gem-Difluoroalkenes by Nickel Catalysis.

通過鎳催化對偕二氟烯烴進行高度區(qū)域和對映選擇性硅氫加成。

47.Isolation and Properties of the Long Elusive Deep Blue Soluble [K3{(NtBu)3S}2]. Cage Radical.

難以捉摸的深藍可溶物 [K3{(NtBu)3S}2] 的分離和性質。凱奇激進。

48.Synthesis of Cyclopropenols Enabled by Visible-Light-Induced Organocatalyzed [2+1] Cyclization.

通過可見光誘導的有機催化 [2+1] 環(huán)化實現(xiàn)環(huán)丙烯醇的合成。

49.Transformation of Covalent Organic Frameworks from N-Acylhydrazone to Oxadiazole Linkages for Smooth Electron Transfer in Photocatalysis.

共價有機框架從 N-酰腙到惡二唑鍵的轉變，以實現(xiàn)光催化中順利的電子轉移。

50.Na4B8O9F10: A Deep-Ultraviolet Transparent Nonlinear Optical Fluorooxoborate with Unexpected Short Phase-Matching Wavelength Induced by Optimized Chromatic Dispersion.

Na4B8O9F10：一種深紫外透明非線性光學氟硼酸鹽，具有由優(yōu)化色散引起的意想不到的短相位匹配波長。

51.Flash Electrochemical Approach to Carbocations.

碳正離子的快速電化學方法。

52.Topochemical Polymerization of a Diacetylene in a Chalcogen-Bonded (ChB) Assembly.

硫屬鍵合 (ChB) 組裝中丁二炔的拓撲化學聚合。

53.Outstanding Multi-Photon Absorption at π-Delocalizable Metallodendrimers.

π-離域金屬樹枝狀聚合物具有出色的多光子吸收能力。

54.Polyyne [3]Rotaxanes: Synthesis via Dicobalt Carbonyl Complexes and Enhanced Stability.

聚炔[3]輪烷：通過二鈷羰基配合物合成并增強穩(wěn)定性。

55.Catalytic Enantioconvergent Allenylation of Aldehydes with Propargyl Halides.

醛與炔丙基鹵化物的催化對映異構烯酰化。

56.Catalytic Transformation of PET and CO2 into High-Value Chemicals.

PET 和 CO2 催化轉化為高價值化學品。

57.Hydrogen-bonded frameworks self-assembled from metal–nucleobase complexes and hexafluoro anions are reported by Wei Zhou, Zongbi Bao et?al. in their Research Article (e202117609). Amino-rich ligands provide multiple H-bonding sites to stabilize the frameworks. In the confined channels, the electron-rich anions combined with the electron-deficient purine rings generate a micro-electric field to polarize and lock Xe atoms, thus achieving highly efficient Xe/Kr separation under ambient conditions.

Wei Zhou、Zongbi Bao 等人報道了由金屬-核堿基配合物和六氟陰離子自組裝的氫鍵框架。在他們的研究文章（e202117609）中。富含氨基的配體提供多個氫鍵位點以穩(wěn)定框架。在受限通道中，富電子陰離子與缺電子嘌呤環(huán)結合產生微電場，極化并鎖定Xe原子，從而在環(huán)境條件下實現(xiàn)高效的Xe/Kr分離。

58.The iron guanidine catalyst shows extraordinary copolymerization activity towards lactide, glycolide, and ?-caprolactone, as reported by Sonja Herres-Pawlis, Moshe Kol, and co-workers in their Research Article (e202112853). Depending on the reaction temperature and the mode of monomer addition, it either forms up to pentablock copolymers in a highly defined way or promotes transesterifications to such a high degree that random copolymers are produced. Therefore, it is a rare example of a catalyst mastering both microstructures: ordered and chaotic.

Sonja Herres-Pawlis、Moshe Kol 及其同事在他們的研究文章 (e202112853) 中報道，鐵胍催化劑對丙交酯、乙交酯和ε-己內酯表現(xiàn)出非凡的共聚活性。根據(jù)反應溫度和單體添加方式，它要么以高度限定的方式形成五嵌段共聚物，要么促進酯交換反應達到產生無規(guī)共聚物的高度。因此，它是掌握有序和混亂兩種微觀結構的催化劑的罕見例子。

59.Pentabenzopentaaza[10]circulene , the largest hetero[n]circulene, has been synthesized by a fold-in approach, as reported by Takayuki Tanaka and co-workers in their Communication (e202116789). The molecule exhibits a saddle-distorted structure in the solid state, reminiscent of a camel's back. The dynamic behavior was analyzed experimentally and theoretically, revealing a low transition state for the saddle-to-saddle inversion. In contrast, a planar, star-shaped conformer is energetically much higher, like a star in the sky.

正如 Takayuki Tanaka 及其同事在他們的通訊 (e202116789) 中報道的那樣，五苯并五氮雜[10]環(huán)烯是最大的雜[n]環(huán)烯，已通過折疊方法合成。該分子在固態(tài)時表現(xiàn)出鞍形扭曲結構，讓人想起駱駝的背部。通過實驗和理論分析了動態(tài)行為，揭示了鞍座到鞍座反轉的低過渡態(tài)。相比之下，平面星形構象異構體的能量要高得多，就像天空中的星星一樣。

60.Perovskites The π-conjugated ionic compound QAPyBF4 was used as a perovskite modulator in the Research Article by Juin-Jei Liou, Taiho Park, Zong-Xiang Xu, and co-workers (e202117303). Experimental investigations showed that p-type conjugated cations [QAPy]2+ adsorb on the perovskite surface with under-coordinated Pb cations and highly electronegative [BF4]? anions enriched at the SnO2 interface. This spontaneous diffusion effect of cation and anion improves the band alignment at two adjacent perovskite interfaces and reduces recombination losses.

鈣鈦礦 在 Juin-Jei Liou、Taiho Park、Zong-Xiang Xu 及其同事的研究文章 (e202117303) 中，π-共軛離子化合物 QAPyBF4 被用作鈣鈦礦調節(jié)劑。實驗研究表明，p 型共軛陽離子 [QAPy]2+ 吸附在鈣鈦礦表面，配位不足的 Pb 陽離子和富集在 SnO2 界面的高電負性 [BF4]? 陰離子。陽離子和陰離子的這種自發(fā)擴散效應改善了兩個相鄰鈣鈦礦界面處的能帶排列并減少了復合損失。

61.Photopolymerization A photoinduced dual-wavelength approach for 3D printing and self-healing of thermosetting materials is reported in the Communication (e202114111) by Zhiheng Zhang, Nathaniel Corrigan, and Cyrille Boyer.

光聚合 張志恒、Nathaniel Corrigan 和 Cyrille Boyer 在通訊 (e202114111) 中報道了一種用于 3D 打印和熱固性材料自修復的光誘導雙波長方法。

62.Laser Chemistry In their Research Article (e202117227), Yasuyuki Tsuboi et?al. report an optical tweezer technique using nanotextured Si that can efficiently trap polymer chains. The fluorescence color of the perylene-labeled polymer chains can be controlled by changing the laser intensity.

激光化學 在他們的研究文章 (e202117227) 中，Yasuyuki Tsuboi 等人。報告了一種使用納米紋理硅的光鑷技術，可以有效捕獲聚合物鏈。苝標記的聚合物鏈的熒光顏色可以通過改變激光強度來控制。

63.Developing an Effective Glycan-Based Vaccine for Streptococcus Pyogenes.

開發(fā)一種有效的基于聚糖的化膿性鏈球菌疫苗。

64.Fluorescence Colour Control in Perylene-Labeled Polymer Chains Trapped by Nanotextured Silicon.

納米紋理硅捕獲的苝標記聚合物鏈的熒光顏色控制。

65.An Orthogonal Dynamic Covalent Polymer Network with Distinctive Topology Transformations for Shape- and Molecular Architecture Reconfiguration.

具有獨特拓撲變換的正交動態(tài)共價聚合物網絡，用于形狀和分子結構重構。

66.Raman Fiber Photometry for Understanding Mitochondrial Superoxide Burst and Extracellular Calcium Ion Influx upon Acute Hypoxia in the Brain of Freely Moving Animals.

拉曼光纖光度測定法用于了解自由活動動物大腦急性缺氧時線粒體超氧化物爆發(fā)和細胞外鈣離子流入。

67.Steering the Glycerol Electro-Reforming Selectivity via Cation–Intermediate Interactions.

通過陽離子-中間相互作用控制甘油電重整選擇性。

68.Systematic Interrogation of Cellular Signaling in Live Cells Using a Membrane-Anchored DNA Multitasking Processor.

使用膜錨定 DNA 多任務處理器系統(tǒng)詢問活細胞中的細胞信號轉導。

69.DNA Origami-Encoded Integration of Heterostructures.

DNA 折紙編碼的異質結構整合。

70.Synthesis of 20-Membered Macrocyclic Pseudo-Natural Products Yields Inducers of LC3 Lipidation.

20 元大環(huán)假天然產物的合成產生 LC3 脂化誘導劑。

71.Nickel-Mediated Enantioselective Photoredox Allylation of Aldehydes with Visible Light.

可見光下鎳介導的醛對映選擇性光氧化還原烯丙基化。

72.Manipulating Selective Metal-to-Metal Electron Transfer to Achieve Multi-Phase Transitions in an Asymmetric [Fe2Co]-Assembled Mixed-Valence Chain.

操縱選擇性金屬間電子轉移以實現(xiàn)不對稱 [Fe2Co] 組裝混合價鏈中的多相轉變。

73.Deoxygenative Cross-Coupling of Aromatic Amides with Polyfluoroarenes.

芳香酰胺與多氟芳烴的脫氧交叉偶聯(lián)。

74.Sensitive Logic Nanodevices with Strong Response for Weak Inputs.

對弱輸入具有強響應的敏感邏輯納米器件。

75.Symmetrically Tetra-functionalized Pillar[6]arenes Prepared by Fragment Coupling.

通過片段偶聯(lián)制備對稱四官能化柱[6]芳烴。

76.An Efficient Rechargeable Aluminium–Amine Battery Working Under Quaternization Chemistry.

季銨化化學下工作的高效可充電鋁胺電池。

77.Passerini–Smiles Reaction of α-Ketophosphonates: Platform for Phospha-Brook/Smiles Embedded Cascades.

α-酮膦酸鹽的 Passerini–Smiles 反應：Phospha-Brook/Smiles 嵌入式級聯(lián)平臺。

78.Discovery of an Ultra-rapid and Sensitive Lysosomal Fluorescence Lipophagy Process.

超快速、靈敏的溶酶體熒光自噬過程的發(fā)現(xiàn)。

79.Screening Heteroatom Configurations for Reversible Sloping Capacity Promises High-Power Na-Ion Batteries.

篩選可逆傾斜容量的雜原子配置有望實現(xiàn)高功率鈉離子電池。

80.Shape Permanence in Diarylethene-Functionalized Liquid-Crystal Elastomers Facilitated by Thiol-Anhydride Dynamic Chemistry.

硫醇酸酐動態(tài)化學促進二芳基乙烯官能化液晶彈性體的形狀穩(wěn)定性。

81.Modular Halogenation, α-Hydroxylation, and Acylation by a Remarkably Versatile Polyketide Synthase.

通過極其通用的聚酮合酶進行模塊化鹵化、α-羥基化和?；?。

82.Enzymatic C-to-C Protein Ligation.

酶促 C 到 C 蛋白質連接。

83.Surface Modification of Nano-Cu2O for Controlling CO2 Electrochemical Reduction to Ethylene and Syngas.

納米 Cu2O 的表面改性用于控制 CO2 電化學還原為乙烯和合成氣。

84.Highly Efficient Photocatalytic Reduction of CO2 to CO by In Situ Formation of a Hybrid Catalytic System Based on Molecular Iron Quaterpyridine Covalently Linked to Carbon Nitride.

通過原位形成基于與氮化碳共價連接的分子鐵季吡啶的混合催化系統(tǒng)，高效光催化將 CO2 還原為 CO。

85.Ligand Engineering toward the Trade-Off between Stability and Activity in Cluster Catalysis.

團簇催化穩(wěn)定性和活性之間權衡的配體工程。

86.Synergy Effect of a π-Conjugated Ionic Compound: Dual Interfacial Energy Level Regulation and Passivation to Promote Voc and Stability of Planar Perovskite Solar Cells.

π-共軛離子化合物的協(xié)同效應：雙界面能級調節(jié)和鈍化促進平面鈣鈦礦太陽能電池的 Voc 和穩(wěn)定性。

87.Rhodium-Catalyzed Stereoselective Deuteration of Benzylic C–H Bonds via Reversible η6-Coordination.

通過可逆 η6-配位，銠催化苯甲基 C-H 鍵的立體選擇性氘化。

88.Hydrogen-Bonded Metal–Nucleobase Frameworks for Efficient Separation of Xenon and Krypton.

用于有效分離氙和氪的氫鍵金屬-核堿基框架。

89.Novel Quinolizine AIE System: Visualization of Molecular Motion and Elaborate Tailoring for Biological Application.

新型喹嗪 AIE 系統(tǒng)：分子運動的可視化和生物應用的精心定制。

90.Master of Chaos and Order: Opposite Microstructures of PCL-co-PGA-co-PLA Accessible by a Single Catalyst.

混沌與秩序大師：單一催化劑可實現(xiàn)的 PCL-co-PGA-co-PLA 的相反微觀結構。

91.HFIP Mediates a Direct C?C Coupling between Michael Acceptors and Eschenmoser's salt.

HFIP 介導 Michael 受體和 Eschenmoser 鹽之間的直接 C?C 偶聯(lián)。

92.A Br?nsted Acidic Gallium Hydride: Facile Interconversion of NNNN-Macrocycle Supported [GaI]+ and [GaIIIH]2+.

布朗斯臺德酸性氫化鎵：NNNN-大環(huán)支持的 [Gal]+ 和 [GaIIIH]2+ 的輕松相互轉化。

93.Transforming Escherichia coli Proteomembranes into Artificial Chloroplasts Using Molecular Photocatalysis.

利用分子光催化將大腸桿菌蛋白質膜轉化為人造葉綠體。

94.A Photoinduced Dual-Wavelength Approach for 3D Printing and Self-Healing of Thermosetting Materials.

用于 3D 打印和熱固性材料自我修復的光致雙波長方法。

95.A Plausible Prebiotic One-Pot Synthesis of Orotate and Pyruvate Suggestive of Common Protometabolic Pathways.

乳清酸和丙酮酸的一種看似合理的益生元一鍋合成暗示了常見的原代謝途徑。

96.Asymmetric Cyclopropanation and Epoxidation via a Catalytically Formed Chiral Auxiliary.

通過催化形成的手性助劑進行不對稱環(huán)丙烷化和環(huán)氧化。

97.Temperature-Directed Formation of Anisotropic Kettlebell and Tadpole Nanostructures in the Absence of a Swelling-Induced Solvent.

在沒有膨脹誘導溶劑的情況下溫度定向形成各向異性壺鈴和蝌蚪納米結構。

98.Bacteria-Triggered Solar Hydrogen Production via Platinum(II)-Tethered Chalcogenoviologens.

通過鉑 (II) 系留的硫族化合物引發(fā)細菌觸發(fā)太陽能制氫。

99.Metal–Organic Frameworks with Zero and Low-Valent Metal Nodes Connected by Tetratopic Phosphine Ligands.

具有通過四位膦配體連接的零價和低價金屬節(jié)點的金屬有機框架。

100.Inhibition of ACE2-Spike Interaction by an ACE2 Binder Suppresses SARS-CoV-2 Entry.

ACE2 結合劑抑制 ACE2-Spike 相互作用可抑制 SARS-CoV-2 進入。

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