聲明：本專(zhuān)欄主要對(duì)生命科學(xué)領(lǐng)域的一些期刊文章標(biāo)題進(jìn)行翻譯，所有內(nèi)容均由本人手工整理翻譯。由于本人專(zhuān)業(yè)為生物分析相關(guān)，其他領(lǐng)域如果出現(xiàn)翻譯錯(cuò)誤請(qǐng)諒解。

1.Crownphyrins are macrocycles combining the structural features of porphyrin and crown ethers. The molecular architecture renders them an intriguing class of hosts capable of binding neutral and ionic guests. The presence of imine linkages connecting the dipyrrin segment with the ether chain enables the unusual coordination behavior of crownphyrins, as demonstrated by the formation of two classes of strikingly different complexes reported by Bartosz Szyszko and co-workers in their Research Article (e202211671).

冠卟啉是結(jié)合了卟啉和冠醚結(jié)構(gòu)特征的大環(huán)化合物。分子結(jié)構(gòu)使它們成為一類(lèi)有趣的主體，能夠結(jié)合中性和離子客體。連接二吡啉片段與醚鏈的亞胺鍵的存在使得冠菲林具有不尋常的配位行為，Bartosz Szyszko 及其同事在他們的研究文章 (e202211671) 中報(bào)道了兩類(lèi)截然不同的復(fù)合物的形成，證明了這一點(diǎn)。

2.Sequential electron transfer leading to the generation of long-lived charge-separated states in the order of 20?ms is demonstrated in multimodular electron donor–acceptor hybrids by Francis D'Souza and co-workers in their Research Article (e202212474), as a promising functional material for light energy conversion. Strategic positioning of diameter-sorted, single-wall carbon nanotubes, BODIPY, and C60 promoted electron and hole transfer events, slowing down the process of charge recombination, as demonstrated by pump–probe studies covering wide temporal and spatial time scales.

Francis D'Souza 及其同事在其研究文章 (e202212474) 中在多模塊電子供體-受體混合體中證明了順序電子轉(zhuǎn)移可導(dǎo)致產(chǎn)生約 20 ms 的長(zhǎng)壽命電荷分離態(tài)，這是一種很有前途的方法光能轉(zhuǎn)換功能材料。直徑排序的單壁碳納米管、BODIPY 和 C60 的戰(zhàn)略定位促進(jìn)了電子和空穴轉(zhuǎn)移事件，減慢了電荷復(fù)合的過(guò)程，涵蓋廣泛時(shí)空時(shí)間尺度的泵浦探針研究證明了這一點(diǎn)。

3.A sensitive and reversible labeling strategy enabling global mapping of the core-fucosylated glycoproteome on cell surfaces is presented in the Research Article (e202206802) by Hu Zhou, Liuqing Wen, and co-workers. The labeled probe can be further cleaved enzymatically after capture by affinity resin. The on-bead traceless cleavage allowed the global mapping of core-fucosylated glycoproteins and glycosylation sites by mass spectrometry.

Hu Zhou、Liuqing Wen 及其同事在研究文章 (e202206802) 中提出了一種敏感且可逆的標(biāo)記策略，能夠?qū)?xì)胞表面的核心巖藻糖基化糖蛋白組進(jìn)行全局繪圖。標(biāo)記的探針在被親和樹(shù)脂捕獲后可以進(jìn)一步酶切。珠上無(wú)痕切割允許通過(guò)質(zhì)譜法對(duì)核心巖藻糖基化糖蛋白和糖基化位點(diǎn)進(jìn)行全局定位。

4.Glycan heterogeneity and subunit composition of therapeutic glycoprotein complexes are challenging to define. In their Communication (e202213170), Di Wu and Carol?V. Robinson present a native top-down mass spectrometry approach, together with in?silico modelling, to reveal the stabilization effect of interfacial N-glycans on therapeutic cytokine and hormone assemblies.

治療性糖蛋白復(fù)合物的聚糖異質(zhì)性和亞基組成很難定義。Di Wu 和 Carol V. Robinson 在他們的通訊 (e202213170) 中提出了一種天然的自上而下的質(zhì)譜方法以及計(jì)算機(jī)建模，以揭示界面 N-聚糖對(duì)治療性細(xì)胞因子和激素組裝的穩(wěn)定作用。

5.Chemical Approaches to Synthetic Drug Delivery Systems for Systemic Applications.

用于全身應(yīng)用的合成藥物輸送系統(tǒng)的化學(xué)方法。

6.Challenges and Opportunities in Electrocatalytic CO2 Reduction to Chemicals and Fuels.

電催化二氧化碳還原為化學(xué)品和燃料的挑戰(zhàn)和機(jī)遇。

7.Hydrogen-Bond-Modulated Nucleofugality of SeIII Species to Enable Photoredox-Catalytic Semipinacol Manifolds.

SeIII 物質(zhì)的氫鍵調(diào)節(jié)離核性可實(shí)現(xiàn)光氧化還原催化賽米那醇流形。

8.Steering the Ultrafast Opening and Closure Dynamics of a Photochromic Coordination Cage by Guest Molecules.

通過(guò)客體分子控制光致變色配位籠的超快打開(kāi)和關(guān)閉動(dòng)力學(xué)。

9.Chromium/Photoredox Dual Catalyzed Synthesis of α-Benzylic Alcohols, Isochromanones, 1,2-Oxy Alcohols and 1,2-Thio Alcohols.

鉻/光氧化還原雙催化合成 α-芐醇、異色滿(mǎn)酮、1,2-氧基醇和 1,2-硫代醇。

10.Confinement of the Triplet States in π-Conjugated BODIPY Dimers Linked with Ethynylene or Butadiynylene Bridges: A Different View on the Effect of Symmetry.

與乙炔基或丁二炔基橋連接的 π 共軛 BODIPY 二聚體中三重態(tài)的限制：對(duì)稱(chēng)性影響的不同觀點(diǎn)。

11.A Sensitive and Reversible Labeling Strategy Enables Global Mapping of the Core-Fucosylated Glycoproteome on Cell Surfaces.

敏感且可逆的標(biāo)記策略可實(shí)現(xiàn)細(xì)胞表面核心巖藻糖基化糖蛋白組的全局繪圖。

12.Engineering Transport Properties in Interconnected Enargite-Stannite Type Cu2+xMn1?xGeS4 Nanocomposites.

互連 Enargite-Stanite 型 Cu2+xMn1?xGeS4 納米復(fù)合材料的工程輸運(yùn)特性。

13.Photo-Facilitated Detection and Sequencing of 5-Formylcytidine RNA.

5-甲酰胞苷 RNA 的光促進(jìn)檢測(cè)和測(cè)序。

14.Supramolecular Assembly of Organoplatinum(II) Complexes for Subcellular Distribution and Cell Viability Monitoring with Differentiated Imaging.

有機(jī)鉑 (II) 復(fù)合物的超分子組裝，用于通過(guò)差異成像進(jìn)行亞細(xì)胞分布和細(xì)胞活力監(jiān)測(cè)。

15.Microhydrated 3-Methyl-3-oxetanemethanol: Evolution of the Hydrogen-Bonding Network from Chains to Cubes.

微水合 3-甲基-3-氧雜環(huán)丁烷甲醇：氫鍵網(wǎng)絡(luò)從鏈到立方體的演變。

16.Combination Cancer Treatment: Using Engineered DNAzyme Molecular Machines for Dynamic Inter- and Intracellular Regulation.

組合癌癥治療：使用工程 DNAzyme 分子機(jī)器進(jìn)行動(dòng)態(tài)細(xì)胞間和細(xì)胞內(nèi)調(diào)節(jié)。

17.Deracemization through Sequential Photoredox-Neutral and Chiral Br?nsted Acid Catalysis.

通過(guò)順序光氧化還原中性和手性布朗斯臺(tái)德酸催化進(jìn)行去消旋化。

18.Hierarchical Supramolecular Self-Assembly: Fabrication and Visualization of Multiblock Microstructures.

分層超分子自組裝：多塊微結(jié)構(gòu)的制造和可視化。

19.Glycan Modulation of Insulin-like Growth Factor-1 Receptor.

胰島素樣生長(zhǎng)因子-1 受體的聚糖調(diào)節(jié)。

20.Spin Effect to Promote Reaction Kinetics and Overall Performance of Lithium-Sulfur Batteries under External Magnetic Field.

自旋效應(yīng)促進(jìn)外部磁場(chǎng)下鋰硫電池的反應(yīng)動(dòng)力學(xué)和整體性能。

21.Photo-Induced Homologation of Carbonyl Compounds for Iterative Syntheses.

用于迭代合成的羰基化合物的光誘導(dǎo)同系化。

22.Deciphering Ligand Controlled Structural Evolution of Prussian Blue Analogues and Their Electrochemical Activation during Alkaline Water Oxidation.

破譯配體控制的普魯士藍(lán)類(lèi)似物的結(jié)構(gòu)演化及其在堿性水氧化過(guò)程中的電化學(xué)活化。

23.Crownphyrins: Metal-Mediated Transformations of the Porphyrin-Crown Ether Hybrids.

冠卟啉：金屬介導(dǎo)的卟啉-冠醚雜化物的轉(zhuǎn)化。

24.The Excited-State Creutz–Taube Ion.

激發(fā)態(tài)克羅伊茨-陶伯離子。

25.Semisynthetic Viral Inhibitor for Light Control of the MHC I Peptide Loading Complex.

用于光控制 MHC I 肽加載復(fù)合物的半合成病毒抑制劑。

26.N-Heterocyclic Carbenes: Molecular Porters of Surface Mounted Ru-Porphyrins.

N-雜環(huán)卡賓：表面安裝的 Ru-卟啉的分子搬運(yùn)工。

27.Heterogeneous Hollow Multi-Shelled Structures with Amorphous-Crystalline Outer-Shells for Sequential Photoreduction of CO2.

具有非晶態(tài)結(jié)晶外殼的異質(zhì)中空多殼結(jié)構(gòu)，用于 CO2 的連續(xù)光還原。

28.Π–Π Stacking Complex Induces Three-Component Coupling Reactions To Synthesize Functionalized Amines.

Π–Π堆積配合物誘導(dǎo)三組分偶聯(lián)反應(yīng)合成功能化胺。

29.Interfacial Designing of MnO2 Half-Wrapped by Aromatic Polymers for High-Performance Aqueous Zinc-Ion Batteries.

高性能水系鋅離子電池芳香族聚合物半包裹二氧化錳的界面設(shè)計(jì)。

30.The Role of Metal Adatoms in a Surface-Assisted Cyclodehydrogenation Reaction on a Gold Surface.

金屬吸附原子在金表面表面輔助環(huán)脫氫反應(yīng)中的作用。

31.A Carbon Nanotube Binding BODIPY-C60 Nano Tweezer: Charge Stabilization through Sequential Electron Transfer.

碳納米管結(jié)合 BODIPY-C60 納米鑷子：通過(guò)順序電子轉(zhuǎn)移實(shí)現(xiàn)電荷穩(wěn)定。

32.Isotropic Anhydrous Superprotonic Conductivity Cooperated with Installed Imidazolium Molecular Motions in a 3D Hydrogen-Bonded Phosphate Network.

各向同性無(wú)水超質(zhì)子電導(dǎo)率與 3D 氫鍵磷酸鹽網(wǎng)絡(luò)中安裝的咪唑分子運(yùn)動(dòng)相配合。

33.Stereo- and Site-Selective Crotylation of Alcohol Proelectrophiles via Ruthenium-Catalyzed Hydrogen Auto-Transfer Mediated by Methylallene and Butadiene.

通過(guò)甲基丙二烯和丁二烯介導(dǎo)的釕催化氫自動(dòng)轉(zhuǎn)移對(duì)醇親電體進(jìn)行立體和位點(diǎn)選擇性巴?；?/p>

34.Efficient Removal of Perfluorinated Chemicals from Contaminated Water Sources Using Magnetic Fluorinated Polymer Sorbents.

使用磁性氟化聚合物吸附劑有效去除受污染水源中的全氟化化學(xué)品。

35.Acceleration of Cathode Interfacial Kinetics by Liquid Organosulfides in Lithium Metal Batteries.

鋰金屬電池中液態(tài)有機(jī)硫化物加速陰極界面動(dòng)力學(xué)。

36.Building Square Planar Cobalt (II) Complexes via Sodium Mediated Cobaltation of Fluoroarenes.

通過(guò)鈉介導(dǎo)的氟化芳烴鈷化構(gòu)建方形平面鈷 (II) 配合物。

37.High-Efficiency CO2/N2 Separation Enabled by Rotation of Electrostatically Anchored Flexible Ligands in Metal–Organic Framework.

通過(guò)靜電錨定柔性配體在金屬有機(jī)框架中的旋轉(zhuǎn)實(shí)現(xiàn)高效 CO2/N2 分離。

38.Substrate Induced Movement of the Metal Cofactor between Active and Resting State.

底物誘導(dǎo)金屬輔因子在活性狀態(tài)和靜止?fàn)顟B(tài)之間的移動(dòng)。

39.A Deep-Learning Framework for the Automated Recognition of Molecules in Scanning-Probe-Microscopy Images.

用于自動(dòng)識(shí)別掃描探針顯微鏡圖像中的分子的深度學(xué)習(xí)框架。

40.Side-Chain Control of Topochemical Polymer Single Crystals with Tunable Elastic Modulus.

彈性模量可調(diào)的拓?fù)浠瘜W(xué)聚合物單晶的側(cè)鏈控制。

41.Energy-Efficient Iodine Uptake by a Molecular Host?Guest Crystal.

分子主體·客體晶體高效吸收碘。

42.Assembling Phenothiazine into a Porous Coordination Cage to Improve Its Photocatalytic Efficiency for Organic Transformations.

將吩噻嗪組裝到多孔配位籠中以提高其有機(jī)轉(zhuǎn)化的光催化效率。

43.Controlling Intermolecular Interaction and Interphase Chemistry Enabled Sustainable Water-tolerance LiMn2O4||Li4Ti5O12 Batteries.

控制分子間相互作用和相間化學(xué)可實(shí)現(xiàn)可持續(xù)的耐水性 LiMn2O4||Li4Ti5O12 電池。

44.Discerning the Contributions of Gold Species in Butadiene Hydrogenation: From Single Atoms to Nanoparticles.

辨別金物質(zhì)在丁二烯氫化中的貢獻(xiàn)：從單原子到納米顆粒。

45.Spatially Directed Biosynthesis of Quantum Dots via Spidroin Templating in Escherichia coli.

在大腸桿菌中通過(guò)蛛絲蛋白模板進(jìn)行量子點(diǎn)的空間定向生物合成。

46.A Facile Strategy to Obtain Low-Cost and High-Performance Gold-Based Catalysts from Artificial Electronic Waste by [Zr48Ni6] Nano-Cages in MOFs for CO2 Electroreduction to CO.

通過(guò) MOF 中的 [Zr48Ni6] 納米籠從人造電子廢物中獲得低成本和高性能金基催化劑的簡(jiǎn)便策略，用于 CO2 電還原為 CO。

47.Graphene Nanoribbon Hybridization of Zeolitic Imidazolate Framework Membranes for Intrinsic Molecular Separation.

用于本征分子分離的沸石咪唑酯框架膜的石墨烯納米帶雜交。

48.Copper-Catalyzed 1,2-Dicarbonylative Cyclization of Alkenes with Alkyl Bromides via Radical Cascade Process.

通過(guò)自由基級(jí)聯(lián)過(guò)程銅催化烯烴與烷基溴的 1,2-二羰基環(huán)化。

49.Native Top-Down Mass Spectrometry Reveals a Role for Interfacial Glycans on Therapeutic Cytokine and Hormone Assemblies.

天然自上而下質(zhì)譜揭示了界面聚糖在治療性細(xì)胞因子和激素組裝中的作用。

50.Vinylene-Linked 2D Conjugated Covalent Organic Frameworks by Wittig Reactions.

通過(guò) Wittig 反應(yīng)制備亞乙烯基連接的二維共價(jià)有機(jī)框架。

51.Fluorine-18 Labeling of Difluoromethyl and Trifluoromethyl Groups via Monoselective C?F Bond Activation.

通過(guò)單選擇性 C?F 鍵激活對(duì)二氟甲基和三氟甲基進(jìn)行 Fluorine-18 標(biāo)記。

52.Directing Group-Free Formal Suzuki–Miyaura Coupling of Simple Ketones Enabled by Activation of Unstrained C?C Bonds.

通過(guò)激活無(wú)應(yīng)變 C?C 鍵實(shí)現(xiàn)簡(jiǎn)單酮的無(wú)基團(tuán)形式鈴木-宮浦偶聯(lián)。

53.A Triplet Label Extends Two-Dimensional Infrared Spectroscopy from Pico- to Microseconds.

三重標(biāo)簽將二維紅外光譜從皮秒擴(kuò)展到微秒。

54.Total Synthesis of Spiro[cyclohexane-2-indoline] Alkaloids: A Regio- and Diastereoselective Spirocyclization Approach.

螺[環(huán)己烷-2-二氫吲哚]生物堿的全合成：區(qū)域選擇性和非對(duì)映選擇性螺環(huán)化方法。

55.General Access to N?CF3 Secondary Amines and Their Transformation to N?CF3 Sulfonamides.

N?CF3 仲胺的一般獲取及其向 N?CF3 磺酰胺的轉(zhuǎn)化。

56.Electrochemical Palladium-Catalyzed Oxidative Carbonylation-Cyclization of Enallenols.

電化學(xué)鈀催化氧化羰基化-烯烯醇環(huán)化。

57.Rhodium-Catalyzed Divergent Arylation of Alkenylsulfonium Salts with Arylboroxines.

銠催化烯基锍鹽與芳基環(huán)硼氧烷的發(fā)散芳基化。

58.Sequential and Reversible Phase Transformations in Zero-Dimensional Organic-Inorganic Hybrid Sb-based Halides towards Multiple Emissions.

零維有機(jī)-無(wú)機(jī)雜化銻基鹵化物的連續(xù)和可逆相變向多重發(fā)射。

59.Atroposelective Synthesis of N-Arylated Quinoids by Organocatalytic Tandem N-Arylation/Oxidation.

通過(guò)有機(jī)催化串聯(lián) N-芳基化/氧化反應(yīng)選擇性合成 N-芳基化醌類(lèi)化合物。

60.Construction of Ni-Co-Fe Hydr(oxy)oxide@Ni-Co Layered Double Hydroxide Yolk-Shelled Microrods for Enhanced Oxygen Evolution.

用于增強(qiáng)析氧的Ni-Co-Fe羥基氧化物@Ni-Co層狀雙氫氧化物蛋黃殼微棒的構(gòu)建。

61.Low-Toxicity ZnSe/ZnS Quantum Dots as Potent Photoreductants and Triplet Sensitizers for Organic Transformations.

低毒性 ZnSe/ZnS 量子點(diǎn)作為有機(jī)轉(zhuǎn)化的有效光還原劑和三線態(tài)敏化劑。

62.Complexed Semiconductor Cores Activate Hexaniobate Ligands as Nucleophilic Sites for Solar-Light Reduction of CO2 by Water.

復(fù)合半導(dǎo)體核心激活六鈮酸鹽配體作為親核位點(diǎn)，用于通過(guò)水進(jìn)行太陽(yáng)光還原二氧化碳。

63.Biosynthesis of Nodulisporic Acids: A Multifunctional Monooxygenase Delivers a Complex and Highly Branched Array.

球孢酸的生物合成：多功能單加氧酶提供復(fù)雜且高度支化的陣列。

64.Construction of Catalytic Covalent Organic Frameworks with Redox-Active Sites for the Oxygen Reduction and the Oxygen Evolution Reaction.

用于氧還原和析氧反應(yīng)的具有氧化還原活性位點(diǎn)的催化共價(jià)有機(jī)框架的構(gòu)建。

65.A Dislocated Twin-Locking Acceptor-Donor-Acceptor Configuration for Efficient Delayed Fluorescence with Multiple Through-Space Charge Transfer.

一種錯(cuò)位雙鎖受體-供體-受體結(jié)構(gòu)，可實(shí)現(xiàn)高效延遲熒光和多重空間電荷轉(zhuǎn)移。

66.Singlet-Triplet Energy Gap as a Critical Molecular Descriptor for Predicting Organic Photovoltaic Efficiency.

單線態(tài)-三線態(tài)能隙作為預(yù)測(cè)有機(jī)光伏效率的關(guān)鍵分子描述符。

67.Pyrogallate-Based Metal-Organic Framework with a Two-Dimensional Secondary Building Unit.

具有二維二級(jí)建筑單元的焦性沒(méi)食子酸鹽基金屬有機(jī)框架。

68.Engineering of Pyroelectric Crystals Decoupled from Piezoelectricity as Illustrated by Doped α-Glycine.

摻雜 α-甘氨酸所示的與壓電解耦的熱釋電晶體工程。

69.A Cation Concentration Gradient Approach to Tune the Selectivity and Activity of CO2 Electroreduction.

調(diào)節(jié) CO2 電還原選擇性和活性的陽(yáng)離子濃度梯度方法。

70.Modular and Fast Synthesis of Versatile Secondary α,α-Dialkyl Boronates via Deoxygenative Alkylboration of Aldehydes.

通過(guò)醛的脫氧烷基硼化反應(yīng)模塊化快速合成多功能二級(jí) α,α-二烷基硼酸酯。

71.Vibrational circular dichroism (VCD) spectroscopy was used by Boris?J. Nachtsheim, Christian Merten et?al. in their Communication (e202204624) to verify DFT-calculated chiral iodane structures. Based on a chiral triazole-substituted iodoarene catalyst, a yet undescribed cationic chiral iodane was elucidated as the most populated intermediate under oxidative conditions with a significant intermolecular N–I interaction.

Boris J. Nachtsheim、Christian Merten 等人在他們的通訊 (e202204624) 中使用振動(dòng)圓二色性 (VCD) 光譜驗(yàn)證 DFT 計(jì)算的手性碘結(jié)構(gòu)?；谑中匀蛉〈牡夥紵N催化劑，一種尚未描述的陽(yáng)離子手性碘被闡明為氧化條件下最常見(jiàn)的中間體，具有顯著的分子間 N-I 相互作用。

72.An all-solid-state proton rectifier , which was fabricated using a heterogeneous membrane composed of a proton-conducting coordination polymer, Cu2(CuTCPP), and a hydroxide-ion-conducting layered double hydroxide, Mg-Al-LDH(NO3), is presented by Yukihiro Yoshida, Hiroshi Kitagawa, and co-workers in their Research Article (e202213077). The device demonstrated a proton rectification ratio greater than 200, which is the highest among the reported all-solid-state H+–OH? rectifiers.

全固態(tài)質(zhì)子整流器，采用由質(zhì)子傳導(dǎo)配位聚合物 Cu2(CuTCPP) 和氫氧根離子傳導(dǎo)層狀雙氫氧化物 Mg-Al-LDH(NO3) 組成的異質(zhì)膜制成，由 Yukihiro Yoshida、Hiroshi Kitakawa 及其同事在他們的研究文章 (e202213077) 中提出。該裝置的質(zhì)子整流比大于200，是已報(bào)道的全固態(tài)H+–OH?整流器中最高的。

73.A bimodal imaging probe FCy7-NO2 was applied to image nitroreductase overexpressed by lung cancer in?vivo, as reported by Xin Zhou and co-workers in their Research Article (e202213495). Integrating two complementary imaging technologies into FCy7-NO2 enables sensitive detection of nitroreductase over a broad concentration range without tissue-depth limit.

正如 Xin Zhou 及其同事在他們的研究文章 (e202213495) 中報(bào)道的那樣，雙峰成像探針 FCy7-NO2 用于對(duì)肺癌體內(nèi)過(guò)表達(dá)的硝基還原酶進(jìn)行成像。將兩種互補(bǔ)的成像技術(shù)集成到 FCy7-NO2 中，可以在廣泛的濃度范圍內(nèi)靈敏地檢測(cè)硝基還原酶，而不受組織深度限制。

74.Helical molecular springs built from chiral ladder polymers expand and contract without unfolding at room temperature. In their Communication (e202209772), Severin?T. Schneebeli and co-workers show that in solution such helical ladder polymers can act like classical Hookean springs with adjustable spring constants.

由手性梯形聚合物制成的螺旋分子彈簧在室溫下膨脹和收縮而不展開(kāi)。 Severin T. Schneebeli 及其同事在他們的通訊 (e202209772) 中表明，在溶液中，這種螺旋梯聚合物可以像經(jīng)典的胡克彈簧一樣發(fā)揮作用，具有可調(diào)節(jié)的彈簧常數(shù)。

75.Dynamic Bonds: Adaptable Timescales for Responsive Materials.

動(dòng)態(tài)鍵：響應(yīng)材料的適應(yīng)性時(shí)間尺度。

76.Zirconium Carbide Mediates Coke-Resistant Methane Dry Reforming on Nickel-Zirconium Catalysts.

碳化鋯介導(dǎo)鎳鋯催化劑上的抗焦甲烷干重整。

77.In Vivo Nitroreductase Imaging via Fluorescence and Chemical Shift Dependent 19F NMR.

通過(guò)熒光和化學(xué)位移相關(guān)的 19F NMR 進(jìn)行體內(nèi)硝基還原酶成像。

78.Design of a Protein with Improved Thermal Stability by an Evolution-Based Generative Model.

通過(guò)基于進(jìn)化的生成模型設(shè)計(jì)具有改進(jìn)的熱穩(wěn)定性的蛋白質(zhì)。

79.Unusual Scaffold Rearrangement in Polyaromatic Hydrocarbons Driven by Concerted Action of Single Gold Atoms on a Gold Surface.

金表面上單個(gè)金原子的協(xié)同作用驅(qū)動(dòng)多芳烴中不尋常的支架重排。

80.Cu Single Atom Nanozyme Based High-Efficiency Mild Photothermal Therapy through Cellular Metabolic Regulation.

基于銅單原子納米酶的通過(guò)細(xì)胞代謝調(diào)節(jié)的高效溫和光熱療法。

81.Ultrafast Dynamics and Catalytic Mechanism of Fatty Acid Photodecarboxylase.

脂肪酸光脫羧酶的超快動(dòng)力學(xué)和催化機(jī)制。

82.Unveiling the Protonation Kinetics-Dependent Selectivity in Nitrogen Electroreduction: Achieving 75.05?% Selectivity.

揭示氮電還原中質(zhì)子化動(dòng)力學(xué)相關(guān)的選擇性：實(shí)現(xiàn) 75.05% 的選擇性。

83.Cobalt-Catalyzed Deaminative Amino- and Alkoxycarbonylation of Aryl Trialkylammonium Salts Promoted by Visible Light.

可見(jiàn)光促進(jìn)芳基三烷基銨鹽的鈷催化脫氨氨基和烷氧基羰基化。

84.Light-Induced Divergent Cyanation of Alkynes Enabled by Phosphorus Radicals.

磷自由基引起的光誘導(dǎo)炔烴發(fā)散氰化。

85.A Redox-Controlled Substrate Engineering Strategy for Site-Specific Enzymatic Fucosylation.

用于位點(diǎn)特異性酶促巖藻糖基化的氧化還原控制底物工程策略。

86.Rational Design of Carbon Nitride Photoelectrodes with High Activity Toward Organic Oxidations.

具有高有機(jī)氧化活性的氮化碳光電極的合理設(shè)計(jì)。

87.Actinide Pnictinidene Chemistry: A Terminal Thorium Parent-Arsinidene Complex Stabilised by a Super-Bulky Triamidoamine Ligand.

Actinide Pnictinidene 化學(xué)：由超大型三酰氨基胺配體穩(wěn)定的末端釷母體-胂絡(luò)合物。

88.Ruthenium-Based Metal–Organic Nanoradiosensitizers Enhance Radiotherapy by Combining ROS Generation and CO Gas Release.

釕基金屬有機(jī)納米放射增敏劑通過(guò)結(jié)合 ROS 生成和 CO 氣體釋放來(lái)增強(qiáng)放射治療。

89.A Vitamin B2-Photocatalysed Approach to Methionine Analogues.

維生素 B2 光催化制備蛋氨酸類(lèi)似物的方法。

90.Light, Heat and Electricity Integrated Energy Conversion System: Photothermal-Assisted Co-Electrolysis of CO2 and Methanol.

光、熱、電一體化能源轉(zhuǎn)換系統(tǒng)：光熱輔助CO2和甲醇共電解。

91.Bioactive Ion-Based Switchable Supercapacitors.

基于生物活性離子的可切換超級(jí)電容器。

92.Porous Liquids Responsive to Light.

對(duì)光敏感的多孔液體。

93.Facet-specific Active Surface Regulation of BixMOy (M=Mo, V, W) Nanosheets for Boosted Photocatalytic CO2 reduction.

BixMOy (M=Mo、V、W) 納米片的小面特異性活性表面調(diào)節(jié)可增強(qiáng)光催化 CO2 還原。

94.Programmed Iteration Controls the Assembly of the Nonanoic Acid Side Chain of the Antibiotic Mupirocin.

程序化迭代控制抗生素莫匹羅星壬酸側(cè)鏈的組裝。

95.Nanoporous Single-Crystalline Oxide Catalysts for Preferential Oxidation of CO in H2 with an Ultra-wide Temperature Window.

納米多孔單晶氧化物催化劑在超寬溫度窗口下優(yōu)先氧化 H2 中的 CO。

96.Ultra-Tough and Recyclable Ionogels Constructed by Coordinated Supramolecular Solvents.

由協(xié)調(diào)超分子溶劑構(gòu)建的超堅(jiān)韌且可回收的離子凝膠。

97.o-Quinodimethane Atropisomers: Enantioselective Synthesis and Stereospecific Transformation.

鄰醌二甲烷阻轉(zhuǎn)異構(gòu)體：對(duì)映選擇性合成和立體定向轉(zhuǎn)化。

98.Host Spin-Crossover Thermodynamics Indicate Guest Fit.

宿主自旋交叉熱力學(xué)表明客體擬合。

99.A Facile Structural Isomerization-Induced 3D Spatial D-A Interlocked Network for Achieving NIR-II Phototheranostic Agents.

一種簡(jiǎn)單的結(jié)構(gòu)異構(gòu)化誘導(dǎo)的 3D 空間 DA 互鎖網(wǎng)絡(luò)，用于實(shí)現(xiàn) NIR-II 光治療劑。

100.Room-Temperature Ring-Opening Polymerization of δ-Valerolactone and ?-Caprolactone Caused by Uptake into Porous Pillar[5]arene Crystals.

吸收到多孔柱[5]芳烴晶體中引起δ-戊內(nèi)酯和ε-己內(nèi)酯的室溫開(kāi)環(huán)聚合。

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