聲明：本專欄主要對生命科學(xué)領(lǐng)域的一些期刊文章標(biāo)題進(jìn)行翻譯，所有內(nèi)容均由本人手工整理翻譯。由于本人專業(yè)為生物分析相關(guān)，其他領(lǐng)域如果出現(xiàn)翻譯錯(cuò)誤請諒解。

Biodegradable ferrous sulfide-based nanocomposites with hydrogen sulfide gas, carbonic anhydrase inhibitor, and Fenton agents releasing capacity were designed and constructed to cause intratumoral acidosis-induced metabolic symbiosis disruption. Upon laser irradiation, the formed nanocomposites can eliminate tumors through photoacoustic and magnetic resonance imaging-guided specific chemodynamic/photothermal/gas therapy.

設(shè)計(jì)并構(gòu)建了具有硫化氫氣體、碳酸酐酶抑制劑和芬頓劑釋放能力的可生物降解硫化亞鐵基納米復(fù)合材料，以引起腫瘤內(nèi)酸中毒誘導(dǎo)的代謝共生破壞。 在激光照射下，形成的納米復(fù)合材料可以通過光聲和磁共振成像引導(dǎo)的特定化學(xué)動力學(xué)/光熱/氣體療法消除腫瘤。

Live cell Raman imaging is an emerging technique. A tiny alkyne can be introduced into small molecules without the loss of biological activity and is an excellent Raman tag for detection in living cells and tissues. EdU, an alkyne-tagged nucleoside, is incorporated into DNA and accumulated in the nucleus.

活細(xì)胞拉曼成像是一項(xiàng)新興技術(shù)。 微小的炔烴可以被引入小分子而不損失生物活性，是用于活細(xì)胞和組織檢測的極佳拉曼標(biāo)簽。 EdU 是一種帶有炔烴標(biāo)記的核苷，被摻入 DNA 并在細(xì)胞核中積累。

The off/on-type fluorescent probe for the HaloTag, Halo SiR-5, showed a strong fluorescence upon conjugating to HaloTag protein by controlling the twisted intramolecular charge transfer (TICT) process.

HaloTag 的關(guān)/開型熒光探針 Halo SiR-5 在通過控制扭曲分子內(nèi)電荷轉(zhuǎn)移 (TICT) 過程與 HaloTag 蛋白結(jié)合后顯示出強(qiáng)烈的熒光。

Temporal control of DNA strand displacement reactions (SDRs) is achieved using blocker strands and specific enzymes. The blocker binds to the toehold domain of the target DNA and efficiently inhibits SDR. Enzymatic degradation of the blocker strand enables SDR with highly controllable kinetics.

DNA 鏈置換反應(yīng) (SDR) 的時(shí)間控制是使用阻斷鏈和特定酶實(shí)現(xiàn)的。 阻斷劑與目標(biāo) DNA 的立足點(diǎn)域結(jié)合并有效抑制 SDR。 阻斷鏈的酶促降解使 SDR 具有高度可控的動力學(xué)。

This work provides an exemplification of the switchable catalysis concept whereby a single organoboron catalyst is triggered to enter ring-opening polymerization or ring-opening copolymerization cycles through thermodynamically and kinetically preferential ring opening of terminal epoxides or internal epoxides under different atmosphere (CO2 or N2).

這項(xiàng)工作提供了可切換催化概念的示例，即通過在不同氣氛（CO2 或 N2）下末端環(huán)氧化物或內(nèi)部環(huán)氧化物的熱力學(xué)和動力學(xué)優(yōu)先開環(huán)，觸發(fā)單一有機(jī)硼催化劑進(jìn)入開環(huán)聚合或開環(huán)共聚循環(huán) .

A eutectic LiI–LiOH salt with the lowest eutectic point among binary eutectic lithium salt systems was selected to provide a Li-rich molten environment, not only offering excess lithium but benefiting ion diffusion compared to that in the solid environment. Hence, the highly degraded layer cathodes in spent lithium ion batteries are directly regenerated.

選擇二元共晶鋰鹽體系中共晶點(diǎn)最低的共晶 LiI-LiOH 鹽來提供富含鋰的熔融環(huán)境，與固體環(huán)境相比，不僅提供過量的鋰，而且有利于離子擴(kuò)散。 因此，廢舊鋰離子電池中高度退化的正極層被直接再生。

Mucus, a biologically dynamic hydrogel, covers the surface of epithelial cells and presents the human body's first line of defense against foreign particles. The unique biophysical properties and selective biological functions of mucus have inspired scientists to synthesize artificial versions (synthetic mucus) in the laboratory to advance mucus-related research.

粘液是一種生物動態(tài)水凝膠，覆蓋在上皮細(xì)胞表面，是人體抵御外來顆粒的第一道防線。 粘液獨(dú)特的生物物理學(xué)特性和選擇性生物學(xué)功能激發(fā)了科學(xué)家們在實(shí)驗(yàn)室中合成人工版本（合成粘液）以推進(jìn)與粘液相關(guān)的研究。

Small extracellular vesicles (sEVs) from cells of different malignant degrees carry different functional proteins. Nano-FTIR identifies malignancy-related protein heterogeneity at the single sEV level, including an increased amide I/II absorption ratio and a reduced proportion of α-helix + random coil. These spectral signatures provide a noninvasive solution for tumor diagnosis.

來自不同惡性程度的細(xì)胞的小細(xì)胞外囊泡（sEVs）攜帶不同的功能蛋白。 Nano-FTIR 在單個(gè) sEV 水平上識別惡性腫瘤相關(guān)的蛋白質(zhì)異質(zhì)性，包括增加的酰胺 I/II 吸收率和減少的 α-螺旋 + 無規(guī)卷曲比例。 這些光譜特征為腫瘤診斷提供了一種無創(chuàng)解決方案。

Corral[5]arene--a conjugated tubular macrocycle--manifests bright fluorescent emission, dynamic chirality, and induced-fit guest-binding behaviors. Its deep and adaptive cavity allows it to accommodate a wide range of guests with different molecular sizes and shapes.

Corral[5]arene——一種共軛管狀大環(huán)化合物——表現(xiàn)出明亮的熒光發(fā)射、動態(tài)手性和誘導(dǎo)適合的客體結(jié)合行為。 其深而適應(yīng)性強(qiáng)的腔使其能夠容納具有不同分子大小和形狀的各種客人。

The first examples of d0 transition-metal-based deep-UV transparent nonlinear optical crystals, MOF4H2 (M = Zr (ZOF), Hf (HOF)), have been obtained by employing an isoreticular node substitution strategy. The KTiOPO4-like ZOH and HOF exhibit exceptionally short UV absorption edges and strong second-harmonic generation, highlighting the promise of d0 transition-metal oxyfluorides as a new source of deep-UV transparent nonlinear optical material.

d0 過渡金屬基深紫外透明非線性光學(xué)晶體 MOF4H2（M = Zr（ZOF），Hf（HOF））的第一個(gè)例子是通過采用等網(wǎng)狀節(jié)點(diǎn)替換策略獲得的。 類 KTiOPO4 的 ZOH 和 HOF 表現(xiàn)出極短的紫外吸收邊緣和強(qiáng)烈的二次諧波產(chǎn)生，突出了 d0 過渡金屬氟氧化物作為深紫外透明非線性光學(xué)材料新來源的前景。

This cover art illustrates palladium hydride-enabled hydroalkenylation of strained molecules, bicyclo[1.1.0]butanes (BCBs) and cyclopropenes. The in situ generated PdH species adds onto strained molecules in a chemoselective manner. The resulting alkyl Pd(II) complex, upon visible-light-induced homolysis of the Pd–C bond, generates the key reaction intermediates, hybrid Pd(I) cyclobutyl or cyclopropyl radical species.

此封面藝術(shù)展示了鈀氫化物對應(yīng)變分子、雙環(huán)[1.1.0]丁烷 (BCB) 和環(huán)丙烯的加氫烯基化作用。 原位生成的 PdH 物質(zhì)以化學(xué)選擇性方式添加到應(yīng)變分子上。 由此產(chǎn)生的烷基 Pd(II) 絡(luò)合物，在可見光誘導(dǎo)的 Pd-C 鍵均裂后，生成關(guān)鍵的反應(yīng)中間體，雜化 Pd(I) 環(huán)丁基或環(huán)丙基自由基物種。

A sequence-controlled one-pot tandem copolymerization was achieved to produce degradable high-molecular-weight functionalized block poly(ester-b-carbonates) with mechanical properties comparable to those of commodity polyolefins.

實(shí)現(xiàn)了順序控制的一鍋串聯(lián)共聚，以生產(chǎn)可降解的高分子量功能化嵌段聚（酯-b-碳酸酯），其機(jī)械性能可與商品聚烯烴相媲美。

Through energy band engineering, a PNP-type single-molecule junction is constructed, whose properties prove that the opposite intrinsic dipole moments are effective in regulating the charge transport mechanism of single-molecule devices.

通過能帶工程，構(gòu)建了PNP型單分子結(jié)，其性質(zhì)證明相反的本征偶極矩可有效調(diào)節(jié)單分子器件的電荷傳輸機(jī)制。

Superatomic crystal is a class of hierarchical materials composed of atomically precise clusters assembled via van der Waals or covalent-like interactions. Au6Te12Se8, an all-inorganic superatomic superconductor exhibiting superatomic charge-density wave (S-CDW), shows the lowest threshold toward external pressure. Moreover, a second superconducting phase emerges with a 3-fold enhancement of the transition temperature (Tc), which is accompanied by a channel switch of conductivity from the a- to the b-axis.

超原子晶體是一類分層材料，由通過范德華力或類共價(jià)相互作用組裝的原子級精確簇組成。 Au6Te12Se8 是一種全無機(jī)超原子超導(dǎo)體，具有超原子電荷密度波 (S-CDW)，顯示出對外部壓力的最低閾值。 此外，第二個(gè)超導(dǎo)相隨著轉(zhuǎn)變溫度 (Tc) 的 3 倍增強(qiáng)而出現(xiàn)，伴隨著從 a 軸到 b 軸的電導(dǎo)率通道轉(zhuǎn)換。

Vertically aligned sub-10 nm corrugated TiO2 nanowire arrays with controllable concave walls have been synthesized by a unique mono-micelle-directed assembly method. An underlying mechanism of the hole extraction effect for concave walls is clarified, demonstrating the exact role of concave walls as the hole collection centers for efficient water splitting.

通過獨(dú)特的單膠束定向組裝方法合成了具有可控凹壁的垂直排列的亞 10 nm 波紋狀 TiO2 納米線陣列。 闡明了凹壁空穴提取效應(yīng)的潛在機(jī)制，證明了凹壁作為高效水分解的空穴收集中心的確切作用。

This study reveals the facet-dependent trapped state of the photogenerated electrons over anatase TiO2. Controlling the shallow or deep electron trap states via selective exposure of the (101) or (001) facet enables the selective photocatalytic conversion of biopolyols to formic acid or CO under irradiation, respectively.

這項(xiàng)研究揭示了光生電子在銳鈦礦 TiO2 上的小平面依賴捕獲態(tài)。 通過 (101) 或 (001) 面的選擇性曝光來控制淺層或深層電子陷阱狀態(tài)，能夠分別在輻照下將生物多元醇選擇性光催化轉(zhuǎn)化為甲酸或 CO。

Py-2, a molecular platform integrating the rhodamine 6G scaffold and polymethine, can be conveniently developed for various activatable ratiometric NIR-II molecular fluorescent probes, offering a wide range of attractive tools for the reliable detection of specific targets within deep tissue with high resolution.

Py-2 是一個(gè)集成了羅丹明 6G 支架和聚甲炔的分子平臺，可方便地開發(fā)用于各種可激活的比例 NIR-II 分子熒光探針，為以高分辨率可靠檢測深層組織內(nèi)的特定靶標(biāo)提供廣泛的有吸引力的工具 .

A bio-inspired Cu MOF achieves simultaneous hydrolysis of the nerve agent simulant and oxidization of the sulfur mustard simulant. The cooperative catalysis of dual copper sites in the MOF greatly promotes the catalytic performance.

受生物啟發(fā)的 Cu MOF 實(shí)現(xiàn)了神經(jīng)毒劑模擬物的同時(shí)水解和硫芥模擬物的氧化。 MOF中雙銅位的協(xié)同催化極大地提升了催化性能。

Local coordination environment of metal sites essentially determines their catalytic performance. On the surface-defect-enriched CeO2, the lattice-embedded Pt atomic single-layer structure derived from embedded Pt single atoms significantly outperforms the surface-adsorbed Pt atomic single-layer structure derived from adsorbed Pt single atoms on the conventional CeO2 for CO oxidation.

金屬位點(diǎn)的局部配位環(huán)境本質(zhì)上決定了它們的催化性能。 在表面缺陷富集的 CeO2 上，嵌入 Pt 單原子衍生的晶格嵌入 Pt 原子單層結(jié)構(gòu)明顯優(yōu)于傳統(tǒng) CeO2 上吸附 Pt 單原子衍生的表面吸附 Pt 原子單層結(jié)構(gòu)用于 CO 氧化 .

A feasible strategy combining precoking and steaming to directionally construct the active naphthalenic species within the crystal center of the SAPO-34 catalyst has been developed, which can not only promote the lower olefin selectivity to ~89% (ethylene and propylene) but also prolong the catalyst lifetime by ~3.7-fold in the methanol-to-olefin conversion.

開發(fā)了一種可行的預(yù)焦化和汽蒸相結(jié)合的策略，將活性萘物種定向構(gòu)建在 SAPO-34 催化劑的晶心內(nèi)，不僅可以將低烯烴選擇性提高到~89%（乙烯和丙烯），而且可以延長 在甲醇轉(zhuǎn)化為烯烴的過程中，催化劑壽命提高了約 3.7 倍。

This cover illustrates the dynamic process of nitrogen substitution of one carbon atom of a fullerene cage containing a metal atom. The nitrogen atom is from the decomposition of a N2 molecule, which is decomposed by DC-arc discharge (mimicked by strong lightning). The high-energy nitrogen atom then attacks the fullerene cage, resulting in substitution/removal of one carbon atom.

本封面說明了氮取代含有金屬原子的富勒烯籠中一個(gè)碳原子的動態(tài)過程。 氮原子來自 N2 分子的分解，N2 分子被直流電弧放電（模仿強(qiáng)閃電）分解。 然后高能氮原子攻擊富勒烯籠，導(dǎo)致一個(gè)碳原子的取代/去除。

Here we report the ultrathin conjugated metalloporphyrin covalent organic framework epitaxially grown on graphene as a two-dimensional van der Waals heterostructure to achieve high-efficiency electrochemical CO2 to CO conversion. Operando spectroscopic and theoretical studies disclosed that the strong interlayer coupling leads to electron-deficient metal centers and speeds up electrocatalysis.

在這里，我們報(bào)告了在石墨烯上外延生長的超薄共軛金屬卟啉共價(jià)有機(jī)框架作為二維范德瓦爾斯異質(zhì)結(jié)構(gòu)，以實(shí)現(xiàn)高效電化學(xué) CO2 到 CO 的轉(zhuǎn)化。 原位光譜和理論研究表明，強(qiáng)層間耦合導(dǎo)致金屬中心缺電子并加速電催化。

Alkyl-substituted N,S-embedded heterocycloarenes with a planar aromatic configuration were synthesized, and it was found that the charge transport characteristics can be effectively manipulated by the engineering of the molecular geometry and the alkyl chain branching position.

合成了具有平面芳族構(gòu)型的烷基取代的 N,S-嵌入雜環(huán)芳烴，發(fā)現(xiàn)通過分子幾何結(jié)構(gòu)和烷基鏈支化位置的工程可以有效地控制電荷傳輸特性。

Built on 8-connected Zr6/Y6 clusters and a flexible tetracarboxylate, a series of three MOF structures with different topologies are achieved, with different ligand and/or SBU geometries. One of the compounds, HIAM-402, exhibits large porosity and high stability and is capable of one-step purification of propylene from propane/propylene/propyne mixtures.

Porphyrin-based π-electronic ion pairs exhibit solid-state and solution-state stacked assemblies according to the peripheral substituents, resulting in a stacked radical pair with antiferromagnetic spin–spin interactions for the "activated" pair that has electron-withdrawing and electron-donating groups in the constituent cation and anion, respectively.

基于卟啉的 π 電子離子對根據(jù)外圍取代基表現(xiàn)出固態(tài)和溶液態(tài)堆疊組件，導(dǎo)致具有反鐵磁自旋 - 自旋相互作用的堆疊自由基對具有吸電子和電子 - 的“激活”對 分別在組成陽離子和陰離子中的供體基團(tuán)。

1.Raman Spectroscopy for Chemical Biology Research.

用于化學(xué)生物學(xué)研究的拉曼光譜。

2.Evidence for Water Antibonding Orbital Mixing in the Hydrated Electron from Its Oxygen 1s X-ray Absorption Spectrum.

從其氧 1s X 射線吸收光譜中水合電子中水反鍵合軌道混合的證據(jù)。

3.Recycling Upstream Redox Enzymes Expands the Regioselectivity of Cycloaddition in Pseudo-Aspidosperma Alkaloid Biosynthesis.

回收上游氧化還原酶可擴(kuò)大環(huán)加成在擬無子植物生物堿生物合成中的區(qū)域選擇性。

4.Efficient Red-Light-Driven Hydrogen Evolution with an Anthraquinone Organic Dye.

用蒽醌有機(jī)染料進(jìn)行高效的紅光驅(qū)動氫析出。

5.Au as a Surrogate for F: The Case of UAu6 vs UF6.

Au 作為 F 的替代品：UAu6 與 UF6 的案例。

6.Aqueous Amine-Tolerant [2+2] Photocycloadditions of Unactivated Olefins.

未活化烯烴的耐水性 [2+2] 光環(huán)加成。

7.Total Synthesis of Matrine Alkaloids.

苦參堿類生物堿的全合成。

8.Catalysis-Enabled 13-Step Total Synthesis of (?)-Peyssonnoside A.

(?)-Peyssonnoside A 的催化啟用 13 步全合成。

9.Total Synthesis of the Dihydrooxepine-Spiroisoxazoline Natural Product Psammaplysin A.

Dihydrooxepine-Spiroisoxazoline 天然產(chǎn)物 Psammaplysin A 的全合成。

10.Direct C(sp3)–N Bond Formation between Toluene and Amine in Water Microdroplets.

水微滴中甲苯和胺之間的直接 C(sp3)–N 鍵形成。

11.Electrochemically Switchable Circularly Polarized Photoluminescence within Self-Assembled Conducting Polymer Helical Microfibers.

自組裝導(dǎo)電聚合物螺旋微纖維內(nèi)的電化學(xué)可切換圓偏振光致發(fā)光。

12.Migratory Insertion of CO into a Au–C Bond.

CO 遷移插入 Au-C 鍵。

13.Nature of Cations Critically Affects Water at the Negatively Charged Silica Interface.

陽離子的性質(zhì)嚴(yán)重影響帶負(fù)電的二氧化硅界面處的水。

14.Achiral-Core-Metal Change in Isomorphic Enantiomeric Ag12Ag32 and Au12Ag32 Clusters Triggers Circularly Polarized Phosphorescence.

同構(gòu)對映體 Ag12Ag32 和 Au12Ag32 簇中的非手性核心金屬變化觸發(fā)圓偏振磷光。

15.Stimuli-Induced Reversible Transformation between Decanuclear and Pentanuclear Gold(I) Sulfido Complexes.

十核和五核金 (I) 硫化物配合物之間的刺激誘導(dǎo)可逆轉(zhuǎn)變。

16.Two-Dimensional Wedge-Shaped Magnetic EuS: Insight into the Substrate Step-Guided Epitaxial Synthesis on Sapphire.

二維楔形磁性 EuS：深入了解藍(lán)寶石上的襯底步進(jìn)引導(dǎo)外延合成。

17.Bromide-Mediated Photoelectrochemical Epoxidation of Alkenes Using Water as an Oxygen Source with Conversion Efficiency and Selectivity up to 100%.

以水為氧源溴化物介導(dǎo)的烯烴光電化學(xué)環(huán)氧化反應(yīng)，轉(zhuǎn)化效率和選擇性高達(dá)100%。

18.General Design Strategy to Precisely Control the Emission of Fluorophores via a Twisted Intramolecular Charge Transfer (TICT) Process.

通過扭曲分子內(nèi)電荷轉(zhuǎn)移 (TICT) 過程精確控制熒光團(tuán)發(fā)射的一般設(shè)計(jì)策略。

19.Orthogonal Enzyme-Driven Timers for DNA Strand Displacement Reactions.

用于 DNA 鏈置換反應(yīng)的正交酶驅(qū)動計(jì)時(shí)器。

20.Length-Controlled Nanofiber Micelleplexes as Efficient Nucleic Acid Delivery Vehicles.

長度可控的納米纖維膠束復(fù)合物作為高效的核酸運(yùn)載工具。

21.Single-Crystalline Imine-Linked Two-Dimensional Covalent Organic Frameworks Separate Benzene and Cyclohexane Efficiently.

單晶亞胺連接的二維共價(jià)有機(jī)骨架可有效分離苯和環(huán)己烷。

22.Spatially Resolved Janus Patterning of Graphene by Direct Laser Writing.

通過直接激光寫入對石墨烯進(jìn)行空間分辨的 Janus 圖案化。

23.VaporSPOT: Parallel Synthesis of Oligosaccharides on Membranes.

VaporSPOT：寡糖在膜上的平行合成。

24.Unraveling the Nature and Role of Layered Cation Ordering in Cation-Disordered Rock-Salt Cathodes.

揭示陽離子無序巖鹽陰極中層狀陽離子有序的性質(zhì)和作用。

25.Evaluation of the Stability of Diamine-Appended Mg2(dobpdc) Frameworks to Sulfur Dioxide.

二胺附加 Mg2(dobpdc) 框架對二氧化硫的穩(wěn)定性評估。

26.Tilting the Balance: London Dispersion Systematically Enhances Enantioselectivities in Br?nsted Acid Catalyzed Transfer Hydrogenation of Imines.

傾斜天平：倫敦分散體系統(tǒng)地增強(qiáng)了亞胺布朗斯臺德酸催化轉(zhuǎn)移氫化中的對映選擇性。

27.Indirect Band Gap Semiconductors for Thin-Film Photovoltaics: High-Throughput Calculation of Phonon-Assisted Absorption.

用于薄膜光伏的間接帶隙半導(dǎo)體：聲子輔助吸收的高通量計(jì)算。

28.Biodegradable Ferrous Sulfide-Based Nanocomposites for Tumor Theranostics through Specific Intratumoral Acidosis-Induced Metabolic Symbiosis Disruption.

可生物降解的基于硫化亞鐵的納米復(fù)合材料通過特定的腫瘤內(nèi)酸中毒誘導(dǎo)的代謝共生破壞用于腫瘤治療。

29.Sequence-Reversible Construction of Oxygen-Rich Block Copolymers from Epoxide Mixtures by Organoboron Catalysts.

有機(jī)硼催化劑從環(huán)氧化物混合物中順序可逆構(gòu)建富氧嵌段共聚物。

30.Quantitative Kinetics of HO2 Reactions with Aldehydes in the Atmosphere: High-Order Dynamic Correlation, Anharmonicity, and Falloff Effects Are All Important.

HO2 與大氣中醛類反應(yīng)的定量動力學(xué)：高階動態(tài)相關(guān)性、非諧性和衰減效應(yīng)都很重要。

31.Monolayer Fullerene Networks as Photocatalysts for Overall Water Splitting.

單層富勒烯網(wǎng)絡(luò)作為全水分解光催化劑。

32.De Novo Construction of Chiral Aminoindolines by Cu-Catalyzed Asymmetric Cyclization and Subsequent Discovery of an Unexpected Sulfonyl Migration.

通過 Cu 催化的不對稱環(huán)化從頭構(gòu)建手性氨基吲哚并隨后發(fā)現(xiàn)意外的磺?；w移。

33.Photoinduced Ion-Pair Inner-Sphere Electron Transfer-Reversible Addition–Fragmentation Chain Transfer Polymerization.

光致離子對內(nèi)球電子轉(zhuǎn)移-可逆加成-斷裂鏈轉(zhuǎn)移聚合。

34.Total Synthesis of Aflastatin A.

黃曲霉素 A 的全合成。

35.Conductive and Ultrastable Covalent Organic Framework/Carbon Hybrid as an Ideal Electrocatalytic Platform.

作為理想電催化平臺的導(dǎo)電和超穩(wěn)定共價(jià)有機(jī)骨架/碳雜化物。

36.Universal Concept for Bright, Organic, Solid-State Emitters─Doping of Small-Molecule Ionic Isolation Lattices with FRET Acceptors.

明亮、有機(jī)、固態(tài)發(fā)射器的通用概念─用 FRET 受體摻雜小分子離子隔離晶格。

37.Elucidating the Roles of Local and Nonlocal Rate Enhancement Mechanisms in Plasmonic Catalysis.

闡明局部和非局部速率增強(qiáng)機(jī)制在等離子體催化中的作用。

38.A Multi-Objective Active Learning Platform and Web App for Reaction Optimization.

用于反應(yīng)優(yōu)化的多目標(biāo)主動學(xué)習(xí)平臺和 Web 應(yīng)用程序。

39.Isolation and Characterization of Heteroleptic Mononuclear Palladium(I) Complexes.

雜配單核鈀 (I) 配合物的分離和表征。

40.Alternating Isotactic Polyhydroxyalkanoates via Site- and Stereoselective Polymerization of Unsymmetrical Diolides.

通過不對稱二醇的位點(diǎn)選擇性和立體選擇性聚合交替等規(guī)聚羥基鏈烷酸酯。

41.Iridium-Catalyzed Asymmetric Cascade Allylation/Retro-Claisen Reaction.

銥催化的不對稱級聯(lián)烯丙基化/逆克萊森反應(yīng)。

42.High-Throughput Inverse Design for 2D Ferroelectric Rashba Semiconductors.

二維鐵電 Rashba 半導(dǎo)體的高吞吐量逆向設(shè)計(jì)。

43.Defining Stereochemistry in the Polymerization of Lactide by Aluminum Catalysts: Insights into the Dual-Stereocontrol Mechanism.

定義鋁催化劑丙交酯聚合中的立體化學(xué)：對雙立體控制機(jī)制的洞察。

44.Investigating Oxidative Addition Mechanisms of Allylic Electrophiles with Low-Valent Ni/Co Catalysts Using Electroanalytical and Data Science Techniques.

使用電分析和數(shù)據(jù)科學(xué)技術(shù)研究烯丙基親電試劑與低價(jià) Ni/Co 催化劑的氧化加成機(jī)制。

45.Ni/Photoredox-Catalyzed C(sp3)–C(sp3) Coupling between Aziridines and Acetals as Alcohol-Derived Alkyl Radical Precursors.

Ni/Photoredox 催化的 C(sp3)–C(sp3) 偶聯(lián)氮丙啶和縮醛作為醇衍生的烷基自由基前體。

46.Rh-Catalyzed Sequential Asymmetric Hydrogenations of 3-Amino-4-Chromones Via an Unusual Dynamic Kinetic Resolution Process.

Rh 催化的 3-Amino-4-Chromones 通過不尋常的動態(tài)動力學(xué)拆分過程連續(xù)不對稱氫化。

47.A General Stereoselective Synthesis of [4]Dendralenes.

[4]Dendralenes 的一般立體選擇性合成。

48.Reassigning the Pressure-Induced Phase Transitions of Methylammonium Lead Bromide Perovskite.

重新分配甲基銨溴化鉛鈣鈦礦的壓力誘導(dǎo)相變。

49.Asymmetric Photochemical [2 + 2]-Cycloaddition of Acyclic Vinylpyridines through Ternary Complex Formation and an Uncontrolled Sensitization Mechanism.

不對稱光化學(xué) [2 + 2]-無環(huán)乙烯基吡啶通過三元復(fù)合物形成和不受控制的敏化機(jī)制的環(huán)加成。

50.Use of a PCET Mediator Enables a Ni-HER Electrocatalyst to Act as a Hydride Delivery Agent.

使用 PCET 介體可使 Ni-HER 電催化劑充當(dāng)氫化物輸送劑。

51.Probing the Synergistic Effects of Mg2+ on CO2 Reduction Reaction on CoPc by In Situ Electrochemical Scanning Tunneling Microscopy.

通過原位電化學(xué)掃描隧道顯微鏡探討 Mg2+ 對 CoPc CO2 還原反應(yīng)的協(xié)同作用。

52.Mucus-Inspired Dynamic Hydrogels: Synthesis and Future Perspectives.

受粘液啟發(fā)的動態(tài)水凝膠：合成和未來展望。

53.Using Catalysis to Drive Chemistry Away from Equilibrium: Relating Kinetic Asymmetry, Power Strokes, and the Curtin–Hammett Principle in Brownian Ratchets.

使用催化作用使化學(xué)遠(yuǎn)離平衡：將動力學(xué)不對稱性、動力沖程和布朗棘輪中的科廷-哈米特原理聯(lián)系起來。

54.Amplification, Enrichment, and Sequencing of Mutagenic Methylated DNA Adduct through Specifically Pairing with Unnatural Nucleobases.

通過與非天然核堿基特異性配對，對誘變甲基化 DNA 加合物進(jìn)行擴(kuò)增、富集和測序。

55.Chemoproteomic Identification of Blue-Light-Damaged Proteins.

藍(lán)光損傷蛋白質(zhì)的化學(xué)蛋白質(zhì)組學(xué)鑒定。

56.Acetonitrile Ligand Photosubstitution in Ru(II) Complexes Directly from the 3MLCT State.

直接來自 3MLCT狀態(tài)的 Ru(II) 復(fù)合物中的乙腈配體光取代。

57.Plasmon-Generated Solvated Electrons for Chemical Transformations.

用于化學(xué)轉(zhuǎn)化的等離子體產(chǎn)生的溶劑化電子。

58.Enantioselective Synthesis of N-Benzylic Heterocycles by Ni/Photoredox Dual Catalysis.

Ni/Photoredox 雙催化對映選擇性合成 N-芐基雜環(huán)。

59.Total Synthesis of (?)-Principinol C.

(?)-Principinol C 的全合成。

60.Photoelectrochemical Asymmetric Catalysis Enables Direct and Enantioselective Decarboxylative Cyanation.

光電化學(xué)不對稱催化可實(shí)現(xiàn)直接和對映選擇性脫羧氰化。

61.Synthesis of Polysubstituted 2-Oxabicyclo[2.1.1]hexanes via Visible-Light-Induced Energy Transfer.

通過可見光誘導(dǎo)能量轉(zhuǎn)移合成多取代 2-氧雜雙環(huán) [2.1.1] 己烷。

62.Single-Handed Helicene Nanoribbons via Transfer of Chiral Information.

通過手性信息轉(zhuǎn)移的單手螺旋納米帶。

63.Optimization of Pore-Space-Partitioned Metal–Organic Frameworks Using the Bioisosteric Concept.

使用生物等排概念優(yōu)化孔隙空間分隔的金屬-有機(jī)框架。

64.Water Dimer-Driven DNA Base Superstructure with Mismatched Hydrogen Bonding.

具有錯(cuò)配氫鍵的水二聚體驅(qū)動的 DNA 堿基超結(jié)構(gòu)。

65.Asymmetric Total Synthesis of Havellockate.

Havellockate 的不對稱全合成。

66.Perdeuteration of Arenes via Hydrogen Isotope Exchange Catalyzed by the Superbasic Sodium Amide Donor Species NaTMP·PMDETA.

芳烴的全氘化通過氫同位素交換催化的超堿性氨基鈉供體物質(zhì) NaTMP·PMDETA。

67.Two-Site O–H Addition to an Iridium Complex Featuring a Nonspectator Tricoordinate Phosphorus Ligand.

具有非旁觀者三配位磷配體的銥絡(luò)合物的兩點(diǎn) O–H 加成。

68.Nickel-Catalyzed Enantioselective Reductive Conjugate Arylation and Heteroarylation via an Elementary Mechanism of 1,4-Addition.

通過 1,4-加成的基本機(jī)制進(jìn)行鎳催化的對映選擇性還原共軛芳基化和雜芳基化。

69.The Influence of the Electron Density in Acyl Protecting Groups on the Selectivity of Galactose Formation.

?；Ｗo(hù)基團(tuán)中電子密度對半乳糖形成選擇性的影響。

70.Electrochemical Strategy for Proton Relay Installation Enhances the Activity of a Hydrogen Evolution Electrocatalyst.

質(zhì)子繼電器裝置的電化學(xué)策略增強(qiáng)了析氫電催化劑的活性。

71.Single-Vesicle Infrared Nanoscopy for Noninvasive Tumor Malignancy Diagnosis.

用于無創(chuàng)腫瘤惡性診斷的單囊泡紅外納米鏡檢查。

72.Hydroxyl-Rich Hydrophilic Endocytosis-Promoting Peptide with No Positive Charge.

富含羥基的親水性內(nèi)吞作用促進(jìn)肽，不帶正電荷。

73.Local Structure Insight into Hydrogen Evolution Reaction with Bimetal Nanocatalysts.

雙金屬納米催化劑對析氫反應(yīng)的局部結(jié)構(gòu)洞察。

74.Adaptable Eutectic Salt for the Direct Recycling of Highly Degraded Layer Cathodes.

用于直接回收高度退化層陰極的適應(yīng)性共晶鹽。

75.Soft Multiaxial Molecular Ferroelectric Thin Films with Self-Powered Broadband Photodetection.

具有自供電寬帶光電檢測功能的軟多軸分子鐵電薄膜。

76.Spectroscopic and Kinetic Studies of the ClSO Radical from Cl2SO Photolysis.

來自 Cl2SO 光解的 ClSO 自由基的光譜和動力學(xué)研究。

77.De Novo Discovery of Thiopeptide Pseudo-natural Products Acting as Potent and Selective TNIK Kinase Inhibitors.

從頭發(fā)現(xiàn)作為有效和選擇性 TNIK 激酶抑制劑的硫肽偽天然產(chǎn)物。

78.Photocatalytic Overall Water Splitting over PbTiO3 Modulated by Oxygen Vacancy and Ferroelectric Polarization.

氧空位和鐵電極化調(diào)制的 PbTiO3 上的光催化全水分解。

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