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【標(biāo)題速讀】【Angew】【2022年】【2月】

2023-08-15 00:30 作者:Rt_Cola 0人讀過(guò) | 我要投稿

聲明：本專(zhuān)欄主要對(duì)生命科學(xué)領(lǐng)域的一些期刊文章標(biāo)題進(jìn)行翻譯，所有內(nèi)容均由本人手工整理翻譯。由于本人專(zhuān)業(yè)為生物分析相關(guān)，其他領(lǐng)域如果出現(xiàn)翻譯錯(cuò)誤請(qǐng)諒解。

1.SO2 and NO2 are important air pollutants, and understanding the mechanism of capture materials drives the development of new clean-up technologies. In situ synchrotron X-ray crystallographic and spectroscopic experiments were used by Sihai Yang, Wei Shi et?al. in their Research Article (e202115585) to establish a detailed molecular mechanism consisting of reversible coordination of SO2 and NO2 at the six open NiII sites on the unprecedented {Ni12}-wheel of a robust metal–organic framework material (NKU-100) at crystallographic resolution.

SO2 和 NO2 是重要的空氣污染物，了解捕獲材料的機(jī)制推動(dòng)了新清潔技術(shù)的發(fā)展。楊四海、石偉等人采用原位同步加速器X射線晶體學(xué)和光譜實(shí)驗(yàn)。在他們的研究文章 (e202115585) 中，建立了一種詳細(xì)的分子機(jī)制，該機(jī)制由 SO2 和 NO2 在晶體學(xué)上堅(jiān)固的金屬有機(jī)骨架材料 (NKU-100) 的前所未有的 {Ni12} 輪上的六個(gè)開(kāi)放 NiII 位點(diǎn)上的可逆配位組成解決。

2.Dianion and dication of a tetracyclopentatetraphenylene derivative were generated and characterized by spectroscopic methods and X-ray crystallography to reveal that the outer and inner conjugation circuits are significantly decoupled as theoretically predicted. The magnetically induced ring currents of the outer and inner circuits flow clockwise and counterclockwise, respectively, in the same direction as the trains run on the outer and inner loops of Osaka Loop Line, as reported by Ichiro Hisaki, Marina?A. Petrukhina, Tohru Nishinaga, Masayoshi Nakano, Yoshito Tobe, and co-workers in their Research Article (e202115316).

生成了四環(huán)戊四亞苯基衍生物的二價(jià)陰離子和二價(jià)陽(yáng)離子，并通過(guò)光譜方法和 X 射線晶體學(xué)進(jìn)行了表征，揭示了外部和內(nèi)部共軛電路按照理論預(yù)測(cè)顯著解耦。據(jù) Ichiro Hisaki、Marina A. Petrukhina、Tohru Nishinaga 報(bào)道，外環(huán)線和內(nèi)環(huán)線的磁感應(yīng)環(huán)電流分別順時(shí)針和逆時(shí)針流動(dòng)，與大阪環(huán)線外環(huán)線和內(nèi)環(huán)線的列車(chē)運(yùn)行方向相同。、Masayoshi Nakano、Yoshito Tobe 及其同事在他們的研究文章 (e202115316) 中。

3.An atomic bridging structure of nickel–nitrogen–carbon active sites confined in porous carbon was revealed by Jintao Zhang and co-workers in their Research Article (e202113918). Uncovering the fundamental mechanism reveals a high potential for modulating bridging structures to enhance interfacial electrocatalytic reactions beyond carbon dioxide reduction.

Jintao Zhang 及其同事在他們的研究文章 (e202113918) 中揭示了限制在多孔碳中的鎳-氮-碳活性位點(diǎn)的原子橋結(jié)構(gòu)。揭示基本機(jī)制揭示了調(diào)節(jié)橋接結(jié)構(gòu)以增強(qiáng)二氧化碳還原之外的界面電催化反應(yīng)的巨大潛力。

4.Aromatics-permeable membranes made from polydimethylsiloxane with tunable side group mobilities are reported by Gongping Liu and co-workers in their Research Article (e202111810). Phenyl groups were introduced as rigid molecular spacers to endow the methyl groups with high mobility and reconstruct the polymer conformation, creating a highway for the fast transport of aromatic molecules, and thus realizing efficient removal of aromatic compounds from aqueous solution.

Gangping Liu 及其同事在他們的研究文章 (e202111810) 中報(bào)道了由聚二甲基硅氧烷制成的具有可調(diào)側(cè)基遷移率的芳烴滲透膜。引入苯基作為剛性分子間隔基，賦予甲基高流動(dòng)性并重構(gòu)聚合物構(gòu)象，為芳香分子的快速傳輸創(chuàng)造一條高速公路，從而實(shí)現(xiàn)從水溶液中高效去除芳香化合物。

5.Electrochemistry. An electrochemical desaturative α-acylation of cyclic N-aryl amines to access α-substituted enamines is reported in the Communication by Youai Qiu et?al. (e202115178).

電化學(xué)。 Youai Qiu 等人在通訊中報(bào)道了環(huán)狀 N-芳基胺的電化學(xué)去飽和 α-酰化反應(yīng)以得到 α-取代的烯胺。（e202115178）。

6.Microwave Chemistry. In their Research Article (e202114340), Hong Li, Xin Gao et?al. report the detection of microwave-induced hot spots in liquid solutions with a fluorescence thermometer attached on microwave-absorbing carbon particles.

微波化學(xué)。 Hong Li、Xin Gaut 等人在他們的研究文章 (e202114340) 中。報(bào)告用附著在微波吸收碳顆粒上的熒光溫度計(jì)檢測(cè)液體溶液中微波引起的熱點(diǎn)。

7.The Mechanism of Piezocatalysis: Energy Band Theory or Screening Charge Effect?.

壓電催化機(jī)制：能帶理論還是屏蔽電荷效應(yīng)？

8.Quantifying Mechanical Properties of Molecular Crystals: A Critical Overview of Experimental Elastic Tensors.

量化分子晶體的力學(xué)性質(zhì)：實(shí)驗(yàn)彈性張量的重要概述。

9.Watching Microwave-Induced Microscopic Hot Spots via the Thermosensitive Fluorescence of Europium/Terbium Mixed-Metal Organic Complexes.

通過(guò)銪/鋱混合金屬有機(jī)絡(luò)合物的熱敏熒光觀察微波引起的微觀熱點(diǎn)。

10.A Ni0 σ-Borane Complex Bearing a Rigid Bidentate Borane/Phosphine Ligand: Boryl Complex Formation by Oxidative Dehydrochloroborylation and Catalytic Activity for Ethylene Polymerization.

帶有剛性二齒硼烷/膦配體的 Ni0 σ-硼烷配合物：通過(guò)氧化脫氫氯硼化形成硼基配合物以及乙烯聚合的催化活性。

11.PDMS with Tunable Side Group Mobility and Its Highly Permeable Membrane for Removal of Aromatic Compounds.

具有可調(diào)側(cè)基遷移率的 PDMS 及其用于去除芳香族化合物的高滲透膜。

12.Atomic Bridging Structure of Nickel–Nitrogen–Carbon for Highly Efficient Electrocatalytic Reduction of CO2.

用于高效電催化還原二氧化碳的鎳-氮-碳原子橋結(jié)構(gòu)。

13.Low-Symmetry MOF-Based Patchy Colloids and Their Precise Linking via Site-Selective Liquid Bridging to Form Supra-Colloidal and Supra-Framework Architectures.

基于 MOF 的低對(duì)稱(chēng)性片狀膠體及其通過(guò)位點(diǎn)選擇性液體橋接的精確連接，形成超膠體和超框架結(jié)構(gòu)。

14.Tunable Second-Level Room-Temperature Phosphorescence of Solid Supramolecules between Acrylamide–Phenylpyridium Copolymers and Cucurbit[7]uril.

丙烯酰胺-苯基吡啶共聚物和葫蘆[7]脲之間固體超分子的可調(diào)諧二級(jí)室溫磷光。

15.Dianion and Dication of Tetracyclopentatetraphenylene as Decoupled Annulene-within-an-Annulene Models.

四環(huán)戊四亞苯基的雙陰離子和雙陽(yáng)離子作為環(huán)烯內(nèi)解耦的環(huán)烯模型。

16.Metallization-Prompted Robust Porphyrin-Based Hydrogen-Bonded Organic Frameworks for Photocatalytic CO2 Reduction.

金屬化促進(jìn)的穩(wěn)健的基于卟啉的氫鍵有機(jī)框架用于光催化二氧化碳還原。

17.Scalable Molten Salt Synthesis of Platinum Alloys Planted in Metal–Nitrogen–Graphene for Efficient Oxygen Reduction.

金屬-氮-石墨烯中種植的鉑合金的可擴(kuò)展熔鹽合成，用于有效的氧還原。

18.A {Ni12}-Wheel-Based Metal–Organic Framework for Coordinative Binding of Sulphur Dioxide and Nitrogen Dioxide.

用于二氧化硫和二氧化氮配位結(jié)合的{Ni12}-輪基金屬有機(jī)框架。

19.Circular Permutated PQQ-Glucose Dehydrogenase as an Ultrasensitive Electrochemical Biosensor.

圓形排列 PQQ-葡萄糖脫氫酶作為超靈敏電化學(xué)生物傳感器。

20.Assembly of Hexagonal Column Interpenetrated Spheres from Plant Polyphenol/Cationic Surfactants and Their Application as Antimicrobial Molecular Banks.

植物多酚/陽(yáng)離子表面活性劑六角柱互穿球的組裝及其作為抗菌分子庫(kù)的應(yīng)用。

21.Heteroatom-Embedded Approach to Vinylene-Linked Covalent Organic Frameworks with Isoelectronic Structures for Photoredox Catalysis.

用于光氧化還原催化的具有等電子結(jié)構(gòu)的亞乙烯基連接的共價(jià)有機(jī)框架的雜原子嵌入方法。

22.Azaphilones as Activation-Free Primary-Amine-Specific Bioconjugation Reagents for Peptides, Proteins and Lipids.

氮雜菲酮作為肽、蛋白質(zhì)和脂質(zhì)的免活化伯胺特異性生物共軛試劑。

23.Fluorescence Imaging of Mitochondrial DNA Base Excision Repair Reveals Dynamics of Oxidative Stress Responses.

線粒體 DNA 堿基切除修復(fù)的熒光成像揭示了氧化應(yīng)激反應(yīng)的動(dòng)態(tài)。

24.Bioorthogonal Ligation-Activated Fluorogenic FRET Dyads.

生物正交連接激活的熒光 FRET 二元組。

25.Imaging Membrane Order and Dynamic Interactions in Living Cells with a DNA Zipper Probe.

使用 DNA 拉鏈探針對(duì)活細(xì)胞中的膜秩序和動(dòng)態(tài)相互作用進(jìn)行成像。

26.Radiation Chemistry Provides Nanoscopic Insights into the Role of Intermediate Phases in CeO2 Mesocrystal Formation.

輻射化學(xué)為 CeO2 介晶形成中中間相的作用提供了納米視角的見(jiàn)解。

27.Stabilizing Interface pH by N-Modified Graphdiyne for Dendrite-Free and High-Rate Aqueous Zn-Ion Batteries.

通過(guò) N-改性石墨炔穩(wěn)定界面 pH 值，用于無(wú)枝晶和高倍率水性鋅離子電池。

28.Design and Development of a Bioorthogonal, Visualizable and Mitochondria-Targeted Hydrogen Sulfide (H2S) Delivery System.

生物正交、可視化和線粒體靶向的硫化氫 (H2S) 輸送系統(tǒng)的設(shè)計(jì)和開(kāi)發(fā)。

29.Highly Durable and Fully Dispersed Cobalt Diatomic Site Catalysts for CO2 Photoreduction to CH4.

高度耐用且完全分散的鈷雙原子位點(diǎn)催化劑，用于 CO2 光還原生成 CH4。

30.Oriented Two-Dimensional Covalent Organic Framework Membranes with High Ion Flux and Smart Gating Nanofluidic Transport.

具有高離子通量和智能門(mén)控納流體傳輸?shù)亩ㄏ蚨S共價(jià)有機(jī)框架膜。

31.Unraveling the Electrical and Magnetic Properties of Layered Conductive Metal-Organic Framework With Atomic Precision.

以原子精度揭示層狀導(dǎo)電金屬有機(jī)框架的電學(xué)和磁性。

32.A DNA Nanocomplex Containing Cascade DNAzymes and Promoter-Like Zn-Mn-Ferrite for Combined Gene/Chemo-dynamic Therapy.

一種含有級(jí)聯(lián) DNAzymes 和啟動(dòng)子樣 Zn-Mn-Ferrite 的 DNA 納米復(fù)合物，用于基因/化學(xué)動(dòng)力學(xué)聯(lián)合治療。

33.Bimetallic Two-Dimensional Metal–Organic Frameworks for the Chemiresistive Detection of Carbon Monoxide.

用于一氧化碳化學(xué)電阻檢測(cè)的雙金屬二維金屬有機(jī)框架。

34.Synthetic Silica Nano-Organelles for Regulation of Cascade Reactions in Multi-Compartmentalized Systems.

用于調(diào)節(jié)多室系統(tǒng)中級(jí)聯(lián)反應(yīng)的合成二氧化硅納米細(xì)胞器。

35.M?bius ZnII-Hexaphyrins Bearing a Chiral Coordinating Arm: A Chiroptical Switch Featuring P/M Twist Inversion Controlled by Achiral Effectors.

帶有手性協(xié)調(diào)臂的莫比烏斯 ZnII-六菲林：一種手性光學(xué)開(kāi)關(guān)，具有由非手性效應(yīng)器控制的 P/M 扭轉(zhuǎn)反轉(zhuǎn)。

36.Altering Chain Flexibility of Aliphatic Polyesters for Yellow-Green Clusteroluminescence in 38?% Quantum Yield.

改變脂肪族聚酯的鏈柔韌性以實(shí)現(xiàn) 38% 量子產(chǎn)率的黃綠色簇發(fā)光。

37.Titanocene(III)-Catalyzed Precision Deuteration of Epoxides.

二茂鈦 (III) 催化環(huán)氧化物的精密氘化。

38.A Supramolecular Polymer Constituted of Antiaromatic NiII Norcorroles.

一種由抗芳香族 NiII Norcorroles 組成的超分子聚合物。

39.Single-Bonded Cubic AsN from High-Pressure and High-Temperature Chemical Reactivity of Arsenic and Nitrogen.

砷和氮的高壓高溫化學(xué)反應(yīng)生成單鍵立方 AsN。

40.A Phenanthrocarbazole-Based Dopant-Free Hole-Transport Polymer with Noncovalent Conformational Locking for Efficient Perovskite Solar Cells.

一種基于菲咔唑的無(wú)摻雜空穴傳輸聚合物，具有非共價(jià)構(gòu)象鎖定，用于高效鈣鈦礦太陽(yáng)能電池。

41.SnF2-Catalyzed Formation of Polymerized Dioxolane as Solid Electrolyte and its Thermal Decomposition Behavior.

SnF2 催化聚合二氧戊環(huán)固體電解質(zhì)的形成及其熱分解行為。

42.A Hydrogen-Bonded Ravel Assembled by Anion Coordination.

通過(guò)陰離子配位組裝的氫鍵拉維爾。

43.One-Pot Synthesis of Melt-Processable Supramolecular Soft Actuators.

可熔融加工的超分子軟執(zhí)行器的一鍋法合成。

44.Stereoselective O-Glycosylations by Pyrylium Salt Organocatalysis.

通過(guò)吡喃鎓鹽有機(jī)催化進(jìn)行立體選擇性 O-糖基化。

45.Electrochemical Desaturative β-Acylation of Cyclic N-Aryl Amines.

環(huán)狀 N-芳基胺的電化學(xué)去飽和 β-?；?/p>

46.Detection of Bacterial Rhamnolipid Toxin by Redox Liposome Single Impact Electrochemistry.

氧化還原脂質(zhì)體單次沖擊電化學(xué)檢測(cè)細(xì)菌鼠李糖脂毒素。

47.Nickel-Catalyzed Stereo- and Enantioselective Cross-Coupling of gem-Difluoroalkenes with Carbon Electrophiles by C?F Bond Activation.

通過(guò) C?F 鍵活化，鎳催化偕二氟烯烴與碳親電子試劑的立體和對(duì)映選擇性交叉偶聯(lián)。

48.Highly Efficient Light-Emitting Diodes Based on an Organic Antimony(III) Halide Hybrid.

基于有機(jī)鹵化銻 (III) 混合物的高效發(fā)光二極管。

49.Biosynthesis of Gut-Microbiota-Derived Lantibiotics Reveals a Subgroup of S8 Family Proteases for Class III Leader Removal.

腸道微生物群衍生的羊毛硫抗生素的生物合成揭示了用于去除 III 類(lèi)前導(dǎo)序列的 S8 家族蛋白酶亞組。

50.Enantioselective Synthesis of Dithia[5]helicenes and their Postsynthetic Functionalization to Access Dithia[9]helicenes.

Dithia[5]helicenes 的對(duì)映選擇性合成及其合成后官能化以獲取 Dithia[9]helicenes。

51.Catalytic Asymmetric Homologation of 4-Substituted Cyclohexanones with CF3CHN2: Enantioselective Synthesis of α-Trifluoromethyl Cycloheptanones.

4-取代環(huán)己酮與 CF3CHN2 的催化不對(duì)稱(chēng)同系化：α-三氟甲基環(huán)庚酮的對(duì)映選擇性合成。

52.Site-Specific Conjugation of a Selenopolypeptide to Alpha-1-antitrypsin Enhances Oxidation Resistance and Pharmacological Properties.

硒多肽與 Alpha-1-抗胰蛋白酶的位點(diǎn)特異性結(jié)合可增強(qiáng)氧化抗性和藥理學(xué)特性。

53.Expeditious and Efficient ortho-Selective Trifluoromethane-sulfonylation of Arylhydroxylamines.

芳基羥胺的快速高效的鄰位選擇性三氟甲烷磺酰化。

54.A Lanthanum Ammonium Sulfate Double Salt with a Strong SHG Response and Wide Deep-UV Transparency.

具有強(qiáng)烈 SHG 響應(yīng)和寬深紫外透明度的硫酸鑭銨復(fù)鹽。

55.Characterization of Mannosyl Dioxanium Ions in Solution Using Chemical Exchange Saturation Transfer NMR Spectroscopy.

使用化學(xué)交換飽和轉(zhuǎn)移核磁共振波譜表征溶液中的甘露糖基二氧根離子。

56.Indomethacin is an anti-inflammatory drug that has been marketed since 1965. The third polymorph, Form?δ, was discovered by both melt and solution crystallization in 1974. By using a combination of 3D electron diffraction (3D ED or MicroED) and microdroplet melt crystallization, Ming Lu, Hongyi Xu et?al. reveal in their Research Article (e202114985) that Form?δ consists of two plastically bendable crystal forms. This discovery and the correction of a 47-year-old misunderstanding signify that MicroED diffraction has become a powerful tool for polymorphic structural studies.

吲哚美辛是一種抗炎藥，自 1965 年起上市。第三種多晶型物 δ 型于 1974 年通過(guò)熔融結(jié)晶和溶液結(jié)晶發(fā)現(xiàn)。通過(guò)結(jié)合使用 3D 電子衍射（3D ED 或 MicroED）和微滴熔融結(jié)晶，盧明，徐宏毅等。在他們的研究文章 (e202114985) 中揭示，δ 型由兩種可塑性彎曲的晶體形式組成。這一發(fā)現(xiàn)以及對(duì)長(zhǎng)達(dá)47年的誤解的糾正，標(biāo)志著MicroED衍射已成為多晶型結(jié)構(gòu)研究的有力工具。

57.A loop deletion mutant of outer membrane protein?F (OmpF) that facilitates the cellular uptake of decoy molecules into Escherichia coli has been developed. In their Communication (e202111612), Osami Shoji and co-workers report that co-expression of the OmpF mutant with wild-type CYP102A1 enables an E.?coli-based whole-cell biocatalyst to efficiently oxidise benzene, alkyl- and cycloalkylbenzenes with the help of decoy molecules, bringing this system a significant step closer to practical applications.

外膜蛋白 F (OmpF) 的環(huán)缺失突變體可促進(jìn)大腸桿菌將誘餌分子攝取。 Osami Shoji 及其同事在他們的通訊 (e202111612) 中報(bào)告說(shuō)，OmpF 突變體與野生型 CYP102A1 的共表達(dá)使得基于大腸桿菌的全細(xì)胞生物催化劑能夠有效氧化苯、烷基苯和環(huán)烷基苯。誘餌分子，使該系統(tǒng)更接近實(shí)際應(yīng)用。

58.The purple cloud (HasA; a heme acquisition protein) delivers cobalt oxaporphyrinium (orange porphyrin and red oxygen) to Pseudomonas aeruginosa (green). Reconstructed HasA has the ability to combat Pseudomonas aeruginosa. The willow shown in the picture is associated with death, symbolizing growth inhibition of Pseudomonas aeruginosa by reconstructed HasA, as detailed in the Communication by Osami Shoji, Hiroshi Shinokubo, and co-workers (e202112456).

紫色云（HasA；一種血紅素獲取蛋白）將氧卟啉鈷（橙色卟啉和紅色氧）傳遞給銅綠假單胞菌（綠色）。重建的HasA具有對(duì)抗銅綠假單胞菌的能力。圖中顯示的柳樹(shù)與死亡相關(guān)，象征著重建的 HasA 對(duì)銅綠假單胞菌的生長(zhǎng)抑制，如 Osami Shoji、Hiroshi Shinokubo 和同事的通訊 (e202112456) 中詳細(xì)介紹的。

59.The concept of self-expanding lithium-ion transport channels to construct a fast-charging anode is proposed by Guoxing Li, Yuliang Li, and co-workers in their Research Article (e202113313). The self-expanding lithium-ion transport channels can be achieved by a self-reversible conversion of chemical bonds with different bond lengths in the anode driven by the interactions with lithium ions during cycling. They reduce the energy barrier of lithium-ion transport, accelerate lithium-ion solid-state diffusion, and thus enable an excellent fast-charging performance.

李國(guó)興、李玉良等人在他們的研究文章（e202113313）中提出了通過(guò)自擴(kuò)展鋰離子傳輸通道構(gòu)建快速充電陽(yáng)極的概念。自膨脹的鋰離子傳輸通道可以通過(guò)循環(huán)過(guò)程中與鋰離子的相互作用驅(qū)動(dòng)的陽(yáng)極中不同鍵長(zhǎng)的化學(xué)鍵的自可逆轉(zhuǎn)換來(lái)實(shí)現(xiàn)。它們降低了鋰離子傳輸?shù)哪軌?，加速了鋰離子固態(tài)擴(kuò)散，從而實(shí)現(xiàn)了優(yōu)異的快速充電性能。

60.Nanomotors 2D nanobots based on soft nanoarchitectonics powered by an ultralow fuel concentration are reported in the Communication by Motilal Mathesh, Elisha Bhattarai, and Wenrong Yang (e202113801).

Motilal Mathesh、Elisha Bhattarai 和 Wenrong Yang 的通訊 (e202113801) 報(bào)道了基于軟納米結(jié)構(gòu)、由超低燃料濃度驅(qū)動(dòng)的納米電機(jī) 2D 納米機(jī)器人。

61.Li–S Batteries In their Research Article (e202114671), Bo-Quan Li, Qiang Zhang et?al. identify the surface gelation on disulfide electrocatalysts in Li–S batteries for the first time.

鋰硫電池在他們的研究文章 (e202114671) 中，Bo-Quan Li、Qiang Zhu 等人。首次確定鋰硫電池中二硫化物電催化劑的表面凝膠化。

62.Chemical Batteries with CO2.

含有二氧化碳的化學(xué)電池。

63.Transition-Metal-Catalyzed Monofluoroalkylation: Strategies for the Synthesis of Alkyl Fluorides by C?C Bond Formation.

過(guò)渡金屬催化的單氟烷基化：通過(guò) C?C 鍵形成合成烷基氟化物的策略。

64.Surface Gelation on Disulfide Electrocatalysts in Lithium–Sulfur Batteries.

鋰硫電池中二硫化物電催化劑的表面凝膠化。

65.Indomethacin Polymorph δ Revealed To Be Two Plastically Bendable Crystal Forms by 3D Electron Diffraction: Correcting a 47-Year-Old Misunderstanding.

3D 電子衍射顯示吲哚美辛多晶型 δ 是兩種可塑性彎曲的晶型：糾正 47 年的誤解。

66.Manipulation of Multiple Cell–Cell Interactions by Tunable DNA Scaffold Networks.

通過(guò)可調(diào)諧 DNA 支架網(wǎng)絡(luò)操縱多個(gè)細(xì)胞間相互作用。

67.A Universal Boronate-Affinity Crosslinking-Amplified Dynamic Light Scattering Immunoassay for Point-of-Care Glycoprotein Detection.

用于護(hù)理點(diǎn)糖蛋白檢測(cè)的通用硼酸鹽親和交聯(lián)放大動(dòng)態(tài)光散射免疫測(cè)定。

68.An Activatable Hybrid Organic–Inorganic Nanocomposite as Early Evaluation System of Therapy Effect.

一種可激活的雜化有機(jī)-無(wú)機(jī)納米復(fù)合材料作為治療效果的早期評(píng)估系統(tǒng)。

69.Dual-Regulation of Defect Sites and Vertical Conduction by Spiral Domain for Electrocatalytic Hydrogen Evolution.

電催化析氫的螺旋域?qū)θ毕菸稽c(diǎn)和垂直傳導(dǎo)的雙重調(diào)節(jié)。

70.Highly Efficient Synthesis of Poly(silylether)s: Access to Degradable Polymers from Renewable Resources.

聚（甲硅烷基醚）的高效合成：從可再生資源中獲取可降解聚合物。

71.The Crystal Plane is not the Key Factor for CO2-to-Methane Electrosynthesis on Reconstructed Cu2O Microparticles.

晶面并不是重構(gòu) Cu2O 微粒上 CO2 電合成甲烷的關(guān)鍵因素。

72.Branched Poly(Aryl Piperidinium) Membranes for Anion-Exchange Membrane Fuel Cells.

用于陰離子交換膜燃料電池的支化聚（芳基哌啶鎓）膜。

73.Remote Amino Acid Recognition Enables Effective Hydrogen Peroxide Activation at a Manganese Oxidation Catalyst.

遠(yuǎn)程氨基酸識(shí)別能夠在錳氧化催化劑上有效激活過(guò)氧化氫。

74.Reversible Covalent Headpiece Enables Interconversion between Double- and Single-Stranded DNA-Encoded Chemical Libraries.

可逆共價(jià)頭能夠?qū)崿F(xiàn)雙鏈和單鏈 DNA 編碼化學(xué)文庫(kù)之間的相互轉(zhuǎn)換。

75.One-Pot Construction of Sulfur-Rich Thermoplastic Elastomers Enabled by Metal-Free Self-Switchable Catalysis and Air-Assisted Coupling.

通過(guò)無(wú)金屬自切換催化和空氣輔助耦合實(shí)現(xiàn)富硫熱塑性彈性體的一鍋法構(gòu)建。

76.Copper-Catalyzed Asymmetric Diyne Cyclization via [1,2]-Stevens-Type Rearrangement for the Synthesis of Chiral Chromeno[3,4-c]pyrroles.

通過(guò)[1,2]-Stevens型重排的銅催化不對(duì)稱(chēng)二炔環(huán)化合成手性色并[3,4-c]吡咯。

77.Transformation of Crowded Oligoarylene into Perylene-Cored Chiral Nanographene by Sequential Oxidative Cyclization and 1,2-Phenyl Migration.

通過(guò)連續(xù)氧化環(huán)化和 1,2-苯基遷移將擁擠的低聚亞芳基轉(zhuǎn)化為苝核手性納米石墨烯。

78.Regio- and Diastereoselective [3+2] Annulation of Aliphatic Aldimines with Alkenes by Scandium-Catalyzed β-C(sp3)?H Activation.

通過(guò)鈧催化的 β-C(sp3)?H 活化，脂肪族醛亞胺與烯烴的區(qū)域和非對(duì)映選擇性 [3+2] 成環(huán)。

79.WSe2 Flakelets on N-Doped Graphene for Accelerating Polysulfide Redox and Regulating Li Plating.

N摻雜石墨烯上的WSe2薄片用于加速多硫化物氧化還原和調(diào)節(jié)鋰鍍層。

80.A Carbene Strategy for Progressive (Deutero)Hydrodefluorination of Fluoroalkyl Ketones.

氟代烷基酮的漸進(jìn)式（氘代）加氫脫氟的卡賓策略。

81.A General Approach to Design Dual Ratiometric Fluorescent and Photoacoustic Probes for Quantitatively Visualizing Tumor Hypoxia Levels In?Vivo.

設(shè)計(jì)雙比率熒光和光聲探針用于定量可視化體內(nèi)腫瘤缺氧水平的通用方法。

82.Self-Expanding Ion-Transport Channels on Anodes for Fast-Charging Lithium-Ion Batteries.

用于快速充電鋰離子電池的陽(yáng)極上的自擴(kuò)展離子傳輸通道。

83.Unexpected Role of a Short-Chain Dehydrogenase/Reductase Family Protein in Type II Polyketide Biosynthesis.

短鏈脫氫酶/還原酶家族蛋白在 II 型聚酮化合物生物合成中的意外作用。

84.Refining of Particulates at Stimuli-Responsive Interfaces: Label-Free Sorting and Isolation.

刺激響應(yīng)界面處的顆粒精煉：無(wú)標(biāo)記分選和分離。

85.Single-Cell Visualization of Monogenic RNA G-quadruplex and Occupied G-quadruplex Ratio through a Module-Assembled Multifunctional Probes Assay (MAMPA).

通過(guò)模塊組裝多功能探針測(cè)定 (MAMPA) 實(shí)現(xiàn)單基因 RNA G 四鏈體和占用 G 四鏈體比率的單細(xì)胞可視化。

86.Promoting CO2 Electroreduction Kinetics on Atomically Dispersed Monovalent ZnI Sites by Rationally Engineering Proton-Feeding Centers.

通過(guò)合理設(shè)計(jì)質(zhì)子供給中心促進(jìn)原子分散的單價(jià) ZnI 位點(diǎn)上的 CO2 電還原動(dòng)力學(xué)。

87.Rational Design of Axially Chiral Styrene-Based Organocatalysts and Their Application in Catalytic Asymmetric (2+4) Cyclizations.

軸向手性苯乙烯基有機(jī)催化劑的合理設(shè)計(jì)及其在催化不對(duì)稱(chēng)（2+4）環(huán)化中的應(yīng)用。

88.Initiating Electron Transfer in Doubly Curved Nanographene Upon Supramolecular Complexation of C60.

C60 超分子絡(luò)合引發(fā)雙曲納米石墨烯中的電子轉(zhuǎn)移。

89.Lactone Backbone Density in Rigid Electron-Deficient Semiconducting Polymers Enabling High n-type Organic Thermoelectric Performance.

剛性缺電子半導(dǎo)體聚合物中的內(nèi)酯主鏈密度可實(shí)現(xiàn)高 n 型有機(jī)熱電性能。

90.Preparing Two-Dimensional Ordered Li0.33La0.557TiO3 Crystal in Interlayer Channel of Thin Laminar Inorganic Solid-State Electrolyte towards Ultrafast Li+ Transfer.

在薄層狀無(wú)機(jī)固態(tài)電解質(zhì)的層間通道中制備二維有序 Li0.33La0.557TiO3 晶體以實(shí)現(xiàn)超快 Li+ 傳輸。

91.Transformation Pathways in Colloidal CdTeSe Magic-Size Clusters.

膠體 CdTeSe 神奇大小團(tuán)簇的轉(zhuǎn)化途徑。

92.2D Active Nanobots Based on Soft Nanoarchitectonics Powered by an Ultralow Fuel Concentration.

基于軟納米結(jié)構(gòu)的二維主動(dòng)納米機(jī)器人，由超低燃料濃度提供動(dòng)力。

93.Collateral Damage Occurs When Using Photosensitizer Probes to Detect or Modulate Nucleic Acid Modifications.

使用光敏劑探針檢測(cè)或調(diào)節(jié)核酸修飾時(shí)會(huì)發(fā)生附帶損害。

94.A Heme-Acquisition Protein Reconstructed with a Cobalt 5-Oxaporphyrinium Cation and Its Growth-Inhibition Activity Toward Multidrug-Resistant Pseudomonas aeruginosa.

用鈷 5-氧代卟啉鎓陽(yáng)離子重建的血紅素獲取蛋白及其對(duì)多重耐藥銅綠假單胞菌的生長(zhǎng)抑制活性。

95.Identification of Cyclopropane Formation in the Biosyntheses of Hormaomycins and Belactosins: Sequential Nitration and Cyclopropanation by Metalloenzymes.

激素和貝乳糖素生物合成中環(huán)丙烷形成的鑒定：金屬酶的連續(xù)硝化和環(huán)丙烷化。