聲明：本專欄主要對生命科學領域的一些期刊文章標題進行翻譯，所有內容均由本人手工整理翻譯。由于本人專業(yè)為生物分析相關，其他領域如果出現(xiàn)翻譯錯誤請諒解。

1.Operando spectroscopy captures the dynamic behavior of ceria-supported Pd single atoms, clusters, and nanoparticles during CO oxidation. In their Research Article (e202200434), Emiel J.?M. Hensen et?al. elucidate the catalytic role of different Pd species using a combination of in?situ spectroscopy with transient and steady-state kinetic analysis. Highly dispersed Pd–oxo species and interfacial Pd sites catalyze low-temperature CO oxidation, while metallic Pd contributes to the activity at elevated temperature.

Operando 光譜捕獲二氧化鈰支撐的 Pd 單原子、簇和納米顆粒在 CO 氧化過程中的動態(tài)行為。 Emiel J. M. Hensen 等人在他們的研究文章 (e202200434) 中利用原位光譜與瞬態(tài)和穩(wěn)態(tài)動力學分析相結合，闡明了不同 Pd 物種的催化作用。高度分散的 Pd-oxo 物種和界面 Pd 位點催化低溫 CO 氧化，而金屬 Pd 則有助于高溫下的活性。

2.The precursor 4,5,9,10-tetrakis(3-methylnaphthalen-2-yl)pyrene is synthesized in solution, sublimed on an Au(111) substrate under ultrahigh vacuum conditions, and converted into the peri-heptacene molecule by thermal activation via surface-assisted oxidative ring-closure and cyclodehydrogenation reactions. Details of this research can be found in the Communication by José?I. Urgel, Pavel Jelínek, Xinliang Feng, David écija, and co-workers (e202114983).

在溶液中合成前體 4,5,9,10-四(3-甲基萘-2-基)芘，在超高真空條件下在 Au(111) 基底上升華，并通過熱活化轉化為近庚苯分子通過表面輔助的氧化閉環(huán)和環(huán)脫氫反應。有關這項研究的詳細信息，請參閱 José I. Urgel、Pavel Jelínek、Xinliang Feng、David écija 及其同事的通訊 (e202114983)。

3.Breslow intermediates (BIs) are pivotal species in Umpolung catalysis effected by N-heterocyclic carbenes (NHCs). For their formation from aldehydes and NHCs, a long-standing riddle has been the mechanism by which the zwitterionic primary intermediate is converted into the BI, as the C-to-O 1,2-H-shift involved is kinetically highly disfavored. The kinetic study described by Albrecht Berkessel and co-workers in their Research Article (e202117682) shows that under aprotic conditions, the BI itself effects this critical H-shift in an autocatalytic fashion. Cover art: Andrea Bertl.

Breslow 中間體 (BI) 是 N-雜環(huán)卡賓 (NHC) 影響的 Umpolung 催化中的關鍵物質。對于它們從醛和 NHC 的形成，兩性離子主要中間體轉化為 BI 的機制一直是一個長期存在的謎團，因為所涉及的 C-to-O 1,2-H-轉變在動力學上是非常不利的。 Albrecht Berkessel 及其同事在其研究文章 (e202117682) 中描述的動力學研究表明，在非質子條件下，BI 本身以自催化方式影響這一關鍵的 H 轉變。封面藝術：安德里亞·伯特爾。

4.The vortex fluidic device accelerated immunoblot assay (VAIA) is a new method that reduces immunoblot processing time from nearly 2?h to less than 5?min. In their Communication (e202202021), Gregory?A. Weiss and co-workers demonstrate the broad applicability and potential of VAIA. In the picture, the artistic interpretation of VAIA demonstrates how the unique thin film microfluidics of the vortex fluidic device can accelerate immunoblot processing.

渦流流體裝置加速免疫印跡測定 (VAIA) 是一種新方法，可將免疫印跡處理時間從近 2 小時縮短至不到 5 分鐘。 Gregory A. Weiss 和同事在他們的通訊 (e202202021) 中展示了 VAIA 的廣泛適用性和潛力。圖中，VAIA 的藝術詮釋展示了渦流流體裝置獨特的薄膜微流體如何加速免疫印跡處理。

5.Asymmetric Catalysis An enantio- and diastereoselective copper-catalyzed allylboration of alkynes with allylic gem-dichlorides is reported by Martín Fa?anás-Mastral et?al. in their Communication (e202117696).

不對稱催化 Martín Fa?anás-Mastral 等人在他們的通訊（e202117696）中報道了炔烴與烯丙基偕二氯化物的對映和非對映選擇性銅催化烯丙基硼化反應。

6.Polymorphism In their Research Article (e202200954), Kana?M. Sureshan et?al. report a topochemical reaction yielding polymorphs of triazolyl-linked polyinositol.

多態(tài)性。在他們的研究文章 (e202200954) 中，Kana M. Sureshan 等人報道了一種拓撲化學反應，產生了三唑基連接的聚肌醇的多晶型物。

7.Photoinduced Controlled/Living Polymerizations.

光誘導的受控/活性聚合。

8.Topochemical Postulates: Are They Relevant for Topochemical Reactions Occurring at Elevated Temperatures?.

拓撲化學假設：它們與高溫下發(fā)生的拓撲化學反應相關嗎？

9.Operando Spectroscopy Unveils the Catalytic Role of Different Palladium Oxidation States in CO Oxidation on Pd/CeO2 Catalysts.

原位光譜揭示了不同鈀氧化態(tài)在 Pd/CeO2 催化劑上 CO 氧化中的催化作用。

10.Redox-Addressable Single-Molecule Junctions Incorporating a Persistent Organic Radical.

包含持久性有機自由基的氧化還原可尋址單分子結。

11.Realizing Fast Synthesis of High-Silica Zeolite Y with Remarkable Catalytic Performance.

實現(xiàn)催化性能優(yōu)異的高硅Y沸石的快速合成。

12.Hierarchically Nanostructured Solid-State Electrolyte for Flexible Rechargeable Zinc–Air Batteries.

用于柔性可充電鋅空氣電池的分層納米結構固態(tài)電解質。

13.Metal- and Strain-Free Bioorthogonal Cycloaddition of o-Diones with Furan-2(3H)-one as Anionic Cycloaddend.

鄰二酮與呋喃-2(3H)-酮作為陰離子環(huán)加成物的無金屬和無應變生物正交環(huán)加成。

14.Achieving 37.1% Green Electroluminescent Efficiency and 0.09 eV Full Width at Half Maximum Based on a Ternary Boron-Oxygen-Nitrogen Embedded Polycyclic Aromatic System.

基于三元硼-氧-氮嵌入多環(huán)芳香族系統(tǒng)，實現(xiàn) 37.1% 的綠色電致發(fā)光效率和 0.09 eV 半高寬。

15.Controllable Disulfide Exchange Polymerization of Polyguanidine for Effective Biomedical Applications by Thiol-Mediated Uptake.

聚胍的可控二硫鍵交換聚合，通過硫醇介導的攝取實現(xiàn)有效的生物醫(yī)學應用。

16.A Bacteria-Responsive Porphyrin for Adaptable Photodynamic/Photothermal Therapy.

用于適應性光動力/光熱療法的細菌響應性卟啉。

17.Rational Design of Silicon-Based Zinc Ionophores.

硅基鋅離子載體的合理設計。

18.Gold-Catalyzed Desymmetric Lactonization of Alkynylmalonic Acids Enabled by Chiral Bifunctional P,N ligands.

手性雙功能 P,N 配體實現(xiàn)金催化的炔基丙二酸的不對稱內酯化。

19.Efficient and Color-Tunable Dual-Mode Afterglow from Large-Area and Flexible Polymer-Based Transparent Films for Anti-Counterfeiting and Information Encryption.

大面積柔性聚合物透明薄膜的高效且顏色可調的雙模式余輝，用于防偽和信息加密。

20.Oligomeric Acceptor: A “Two-in-One” Strategy to Bridge Small Molecules and Polymers for Stable Solar Devices.

寡聚受體：橋接小分子和聚合物以實現(xiàn)穩(wěn)定太陽能器件的“二合一”策略。

21.Dissipative Control over the Toehold-Mediated DNA Strand Displacement Reaction.

對立足點介導的 DNA 鏈置換反應的耗散控制。

22.Single-Cell Quantification of a Highly Biocompatible Dinuclear Iridium(III) Complex for Photocatalytic Cancer Therapy.

用于光催化癌癥治療的高度生物相容性雙核銥 (III) 復合物的單細胞定量。

23.Self-Reporting Activated Ester-Amine Reaction for Enantioselective Multi-Channel Visual Detection of Chiral Amines.

用于手性胺對映選擇性多通道視覺檢測的自報告活化酯胺反應。

24.In Situ Spectroscopic Characterization and Theoretical Calculations Identify Partially Reduced ZnO1?x/Cu Interfaces for Methanol Synthesis from CO2.

原位光譜表征和理論計算確定了用于從 CO2 合成甲醇的部分還原的 ZnO1?x/Cu 界面。

25.Protein-Mediated Biosynthesis of Semiconductor Nanocrystals for Photocatalytic NAD(P)H Regeneration and Chiral Amine Production.

用于光催化 NAD(P)H 再生和手性胺生產的蛋白質介導的半導體納米晶體生物合成。

26.Enantioselective Synthesis of Axially Chiral Styrene-Carboxylic Esters by Rhodium-Catalyzed Chelation-Controlled [2+2+2] Cycloaddition.

通過銠催化螯合控制的 [2+2+2] 環(huán)加成對映選擇性合成軸向手性苯乙烯-羧酸酯。

27.Efficient Electrochemical Nitrate Reduction to Ammonia with Copper-Supported Rhodium Cluster and Single-Atom Catalysts.

使用銅負載銠簇和單原子催化劑高效電化學將硝酸鹽還原為氨。

28.Slow Synthesis Methodology-Directed Immiscible Octahedral PdxRh1?x Dual-Atom-Site Catalysts for Superior Three-Way Catalytic Activities over Rh.

慢速合成方法指導的不混溶八面體 PdxRh1?x 雙原子位催化劑，具有優(yōu)于 Rh 的三向催化活性。

29.Boosting the Productivity of Electrochemical CO2 Reduction to Multi-Carbon Products by Enhancing CO2 Diffusion through a Porous Organic Cage.

通過多孔有機籠增強二氧化碳擴散，提高電化學二氧化碳還原生產多碳產品的生產率。

30.Beyond a Linker: The Role of Photochemistry of Crosslinkers in the Direct Optical Patterning of Colloidal Nanocrystals.

超越連接劑：交聯(lián)劑光化學在膠體納米晶體直接光學圖案化中的作用。

31.Amplified Circularly Polarized Electroluminescence Behavior Triggered by Helical Nanofibers from Chiral Co-assembly Polymers.

由手性共組裝聚合物的螺旋納米纖維觸發(fā)的放大圓偏振電致發(fā)光行為。

32.Remote Site-Selective Asymmetric Protoboration of Unactivated Alkenes Enabled by Bimetallic Relay Catalysis.

雙金屬中繼催化實現(xiàn)未活化烯烴的遠程位點選擇性不對稱原硼化。

33.Surface Engineering of Palladium Nanocrystals: Decoupling the Activity of Different Surface Sites on Nanocrystal Catalysts.

鈀納米晶體的表面工程：解耦納米晶體催化劑上不同表面位點的活性。

34.Euglenatides, Potent Antiproliferative Cyclic Peptides Isolated from the Freshwater Photosynthetic Microalga Euglena gracilis.

眼蟲素，從淡水光合微藻眼蟲中分離出的有效抗增殖環(huán)肽。

35.Constructing Cu?C Bonds in a Graphdiyne-Regulated Cu Single-Atom Electrocatalyst for CO2 Reduction to CH4.

在石墨炔調控的 Cu 單原子電催化劑中構建 Cu?C 鍵，用于將 CO2 還原為 CH4。

36.Palladium-Catalyzed Regiodivergent Synthesis of 1,3-Dienyl and Allyl Esters from Propargyl Esters.

鈀催化從炔丙酯區(qū)域發(fā)散合成 1,3-二烯酯和烯丙酯。

37.Halogen???Halogen and Halogen???π Interactions Enabled Reversible Photo-oligomerization of Conjugated Dienones: Visible Light Triggered Single-Crystal-to-Single-Crystal Transformation.

鹵素···鹵素和鹵素···π相互作用實現(xiàn)了共軛二烯酮的可逆光齊聚：可見光觸發(fā)單晶到單晶的轉變。

38.Formation of Breslow Intermediates from N-Heterocyclic Carbenes and Aldehydes Involves Autocatalysis by the Breslow Intermediate, and a Hemiacetal.

由 N-雜環(huán)卡賓和醛形成 Breslow 中間體涉及 Breslow 中間體和半縮醛的自催化作用。

39.Enantio- and Diastereoselective Copper-Catalyzed Allylboration of Alkynes with Allylic gem-Dichlorides.

對映體和非對映選擇性銅催化炔烴與烯丙基寶石二氯化物的烯丙基硼化。

40.Small Molecules Modulate Liquid-to-Solid Transitions in Phase-Separated Tau Condensates.

小分子調節(jié)相分離 Tau 凝聚物中的液體到固體的轉變。

41.Synthesis and Characterization of peri-Heptacene on a Metallic Surface.

金屬表面上近庚苯的合成和表征。

42.A Nonenzymatic Analog of Pyrimidine Nucleobase Biosynthesis.

嘧啶核堿基生物合成的非酶類似物。

43.Endo-M Mediated Chemoenzymatic Approach Enables Reversible Glycopeptide Labeling for O-GlcNAcylation Analysis.

Endo-M 介導的化學酶法可實現(xiàn) O-GlcNAc ?；治龅目赡嫣请臉擞?。

44.Circularly Polarized White Organic Light-Emitting Diodes Based on Spiro-Type Thermally Activated Delayed Fluorescence Materials.

基于螺環(huán)型熱激活延遲熒光材料的圓偏振白色有機發(fā)光二極管。

45.Organophotocatalytic Regioselective C?H Alkylation of Electron-Rich Arenes Using Activated and Unactivated Alkenes.

使用活化和未活化的烯烴對富電子芳烴進行有機光催化區(qū)域選擇性 C?H 烷基化。

46.Metal-Free Catalytic Hydrogenolysis of Silyl Triflates and Halides into Hydrosilanes.

三氟甲磺酸硅烷基酯和鹵化物的無金屬催化氫解成氫硅烷。

47.Visualizing Proteins in Mammalian Cells by 19F NMR Spectroscopy.

通過 19F NMR 光譜可視化哺乳動物細胞中的蛋白質。

48.Reducing Energy Disorder for Efficient and Stable Sn?Pb Alloyed Perovskite Solar Cells..

減少能量無序，實現(xiàn)高效穩(wěn)定的錫鉛合金鈣鈦礦太陽能電池。

49.Temperature-Reliable Low-Dimensional Perovskites Passivated Black-Phase CsPbI3 toward Stable and Efficient Photovoltaics.

溫度可靠的低維鈣鈦礦鈍化黑相 CsPbI3，實現(xiàn)穩(wěn)定高效的光伏發(fā)電。

50.A Class of Readily Tunable Planar-Chiral Cyclopentadienyl Rhodium(III) Catalysts for Asymmetric C–H Activation.

一類用于不對稱 C-H 活化的易于調節(jié)的平面手性環(huán)戊二烯基銠 (III) 催化劑。

51.Nitrate-to-Ammonia Conversion at an InSn-Enriched Liquid-Metal Electrode.

富含 InSn 的液態(tài)金屬電極將硝酸鹽轉化為氨。

52.Light-Triggered High-Affinity Binding of Tetramethylammonium over Potassium Ions by [18]crown-6 in a Tetrahedral Anion Cage.

四面體陰離子籠中 [18]crown-6 光觸發(fā)四甲基銨與鉀離子的高親和力結合。

53.Under-5-Minute Immunoblot Assays by Vortex Fluidic Device Acceleration.

通過渦流流體裝置加速進行 5 分鐘內的免疫印跡測定。

54.Enantioselective Seleno-Michael Addition Reactions Catalyzed by a Chiral Bifunctional N-Heterocyclic Carbene with Noncovalent Activation.

手性雙功能 N-雜環(huán)卡賓非共價活化催化的對映選擇性硒-邁克爾加成反應。

55.Palladium-Catalyzed Enantioselective γ-Arylation of β,γ-Unsaturated Butenolides.

鈀催化 β,γ-不飽和丁烯酸內酯的對映選擇性 γ-芳基化。

56.Benzo-Extended Cyclohepta[def]fluorene Derivatives with Very Low-Lying Triplet States.

具有極低位三重態(tài)的苯并擴展環(huán)庚[def]芴衍生物。

57.A High-Throughput Approach to Repurposing Olefin Polymerization Catalysts for Polymer Upcycling.

重新利用烯烴聚合催化劑進行聚合物升級循環(huán)的高通量方法。

58.Isolation of Stable Borepin Radicals and Anions.

穩(wěn)定的 Borepin 自由基和陰離子的分離。

59.Diastereo- and Enantioselective Silver-Catalyzed [3+3] Cycloaddition and Kinetic Resolution of Azomethine Imines with Activated Isocyanides.

非對映和對映選擇性銀催化的 [3+3] 環(huán)加成反應以及活化異氰化物對甲亞胺亞胺的動力學拆分。

60.Efficient Generation of Hydrogen Peroxide and Formate by an Organic Polymer Dots Photocatalyst in Alkaline Conditions.

有機聚合物點光催化劑在堿性條件下有效產生過氧化氫和甲酸鹽。

61.Nickel/Copper-Cocatalyzed Asymmetric Benzylation of Aldimine Esters for the Enantioselective Synthesis of α-Quaternary Amino Acids.

鎳/銅助催化醛亞胺酯的不對稱苯甲基化用于對映選擇性合成 α-季氨基酸。

62.Cobalt-Catalyzed Direct Aminocarbonylation of Ethers: Efficient Access to α-Amide Substituted Ether Derivatives.

鈷催化醚的直接氨基羰基化：有效獲得 α-酰胺取代的醚衍生物。

63.Enhancement of the enzymatic activity of cell-membrane-coated metal–organic framework nanoparticles by depleting membrane cholesterol is demonstrated by Weiwei?Gao, Liangfang Zhang et?al. in their Communication (e202203115). Increased membrane permeability, caused by the reduction in cholesterol level, is likely responsible for the increased enzymatic activity. This discovery broadens the use of these biomimetic nanoparticles in drug delivery and biodetoxification.

Weiwei Gau、Liangfang Zhu 等人在他們的通訊（e202203115）中證明，通過消耗膜膽固醇，可以增強細胞膜包被的金屬有機框架納米顆粒的酶活性。由膽固醇水平降低引起的膜通透性增加可能是酶活性增加的原因。這一發(fā)現(xiàn)拓寬了這些仿生納米粒子在藥物輸送和生物解毒中的用途。

64.Using water as a hydrogen source to perform chemical reactions is fascinating but challenging because of the high H?O bond dissociation energy of water (ca. 5?eV). Tingbin Lim, Ren Su, and co-workers show in their Research Article (e202204256) that surface-hydroxylated graphitic carbon nitride only requires 2.25?eV to activate water for reactions involving a hydrogen atom transfer step, allowing solar-driven eco-friendly synthetic chemistry.

使用水作為氫源進行化學反應是令人著迷的，但也具有挑戰(zhàn)性，因為水的 H?O 鍵解離能很高（約 5 eV）。 Tingbin Lim、Ren Su 和同事在他們的研究文章 (e202204256) 中表明，表面羥基化石墨碳氮化物僅需要 2.25 eV 即可激活水以進行涉及氫原子轉移步驟的反應，從而實現(xiàn)太陽能驅動的環(huán)保合成化學。

65.The global atlas of bacterial aromatic polyketides is reported by Lihan Zhang and co-workers in their Research Article (e202202286). By pan-genomic analysis of the biosynthetic gene clusters of type?II polyketide synthases, the global distribution, abundance, and structural diversity of the aromatic polyketides were assessed. The study also provides insight for the molecular evolution of aromatic polyketides and serves as a compass for future discoveries of this class of natural products.

Lihan Zhang 及其同事在他們的研究文章 (e202202286) 中報道了細菌芳香族聚酮化合物的全球圖譜。通過對 II 型聚酮合酶生物合成基因簇進行泛基因組分析，評估了芳香族聚酮化合物的全球分布、豐度和結構多樣性。該研究還為芳香族聚酮化合物的分子進化提供了見解，并為此類天然產物的未來發(fā)現(xiàn)提供了指南針。

66.Are photoproteins stable enough for operation in real world technologies? The Research Article (e202201148) by Vincent?M. Friebe, Raoul?N. Frese, and co-workers pushes the operation of a biohybrid photoelectrode to new lengths. By stabilizing the pathways crucial for electron transfer, it was possible to prolong electrode operation to the equivalent of a full year of solar insolation in the Netherlands, as well as to maintain output after storage for 2.5?years. These findings will be instrumental for realizing photoprotein-based technologies such as biosensors or biophotovoltaics.

發(fā)光蛋白是否足夠穩(wěn)定，可以在現(xiàn)實世界的技術中運行？ Vincent M. Friebe、Raoul N. Frese 及其同事的研究文章 (e202201148) 將生物混合光電極的操作推向了新的高度。通過穩(wěn)定對電子轉移至關重要的路徑，可以將電極的運行時間延長到相當于荷蘭一整年的日照時間，并在存儲 2.5 年后保持輸出。這些發(fā)現(xiàn)將有助于實現(xiàn)基于發(fā)光蛋白的技術，例如生物傳感器或生物光伏技術。

67.Photocatalytic CO2 Reduction Aqueous CO2 reduction on silicon photocathodes functionalized with cobalt molecular catalysts/carbon nanotubes is reported by Fei Li et?al. in their Communication (e202201086).

光催化 CO2 還原。Fei Li 等人在他們的通訊（e202201086）中報道了在用鈷分子催化劑/碳納米管功能化的硅光電陰極上水相 CO2 還原。

68.Coordination Compounds In their Research Article (e202201884), Lili Zhao, Tiow-Gan Ong et?al. report a bis-(carbone) pincer ligand and its coordinative behavior toward multi-metallic configurations.

配位化合物 在他們的研究文章 (e202201884) 中，Lili Zhu、Tiow-Gan Ong 等人報告雙（碳）鉗配體及其對多金屬構型的配位行為。

69.Metal Halide Perovskite Based Heterojunction Photocatalysts.

基于金屬鹵化物鈣鈦礦的異質結光催化劑。

70.A Bis-(carbone) Pincer Ligand and Its Coordinative Behavior toward Multi-Metallic Configurations.

雙（碳）鉗配體及其對多金屬構型的配位行為。

71.Inorganic Chiral Hybrid Nanostructures for Tailored Chiroptics and Chirality-Dependent Photocatalysis.

用于定制手性光學和手性依賴性光催化的無機手性混合納米結構。

72.Catalytic DNA Polymerization Can Be Expedited by Active Product Release.

活性產品的釋放可以加速催化 DNA 聚合。

73.Digitizing Chemical Synthesis in 3D Printed Reactionware.

3D 打印反應器中的數(shù)字化化學合成。

74.Activatable Persistent Luminescence from Porphyrin Derivatives and Supramolecular Probes with Imaging-Modality Transformable Characteristics for Improved Biological Applications.

卟啉衍生物和超分子探針的可激活持續(xù)發(fā)光，具有成像模態(tài)可轉換特性，可改善生物應用。

75.Catalytic Degradation of Polyethylene Terephthalate Using a Phase-Transitional Zirconium-Based Metal–Organic Framework.

使用相變鋯基金屬有機骨架催化降解聚對苯二甲酸乙二醇酯。

76.Enantio-, Diastereo- and Regioselective Synthesis of Chiral Cyclic and Acyclic gem-Difluoromethylenes by Palladium-Catalyzed [4+2] Cycloaddition.

鈀催化的 [4+2] 環(huán)加成對映體、非對映體和區(qū)域選擇性合成手性環(huán)狀和無環(huán)偕二氟亞甲基。

77.Palladium-Catalyzed Stagewise Strain-Release-Driven C?C Activation of Bicyclo[1.1.1]pentanyl Alcohols.

鈀催化分階段應變釋放驅動的 CC 活化雙環(huán)[1.1.1]戊醇。

78.Ruthenium Olefin Metathesis Catalysts Bearing a Macrocyclic N-Heterocyclic Carbene Ligand: Improved Stability and Activity.

帶有大環(huán) N-雜環(huán)卡賓配體的釕烯烴復分解催化劑：提高穩(wěn)定性和活性。

79.Enantioselective Total Synthesis of [3]-Ladderanol through Late-Stage Organocatalytic Desymmetrization.

通過后期有機催化去對稱對映選擇性全合成[3]-Ladderanol。

80.Sustained Release of a Synthetic Autoinducing Peptide Mimetic Blocks Bacterial Communication and Virulence In Vivo..

合成自誘導肽模擬物的持續(xù)釋放可阻斷體內細菌通訊和毒力。

81.Pyrene-Based Dopant-Free Hole-Transport Polymers with Fluorine-Induced Favorable Molecular Stacking Enable Efficient Perovskite Solar Cells.

芘基無摻雜空穴傳輸聚合物具有氟誘導的有利分子堆積，可實現(xiàn)高效鈣鈦礦太陽能電池。

82.Extended Conjugation Attenuates the Quenching of Aggregation-Induced Emitters by Photocyclization Pathways.

延長的共軛減弱了光環(huán)化途徑對聚集誘導發(fā)射體的猝滅。

83.Tuning an Imine Reductase for the Asymmetric Synthesis of Azacycloalkylamines by Concise Structure-Guided Engineering.

通過簡潔的結構引導工程調整亞胺還原酶用于氮雜環(huán)烷基胺的不對稱合成。

84.Fusion of Multi-Resonance Fragment with Conventional Polycyclic Aromatic Hydrocarbon for Nearly BT.2020 Green Emission.

多共振片段與傳統(tǒng)多環(huán)芳烴的融合，實現(xiàn)近BT.2020綠色排放。

85.Investigation of the Molecular Landscape of Bacterial Aromatic Polyketides by Global Analysis of Type?II Polyketide Synthases.

通過 II 型聚酮化合物合成酶的整體分析研究細菌芳香族聚酮化合物的分子景觀。

86.Palladium-Catalyzed Tandem Cycloisomerization/Cross-Coupling of Carbonyl- and Imine-Tethered Alkylidenecyclopropanes.

鈀催化的羰基和亞胺連接的亞烷基環(huán)丙烷的串聯(lián)環(huán)異構化/交叉偶聯(lián)。

87.Single-Step Expeditious Synthesis of Diblock Copolymers with Different Morphologies by Lewis Pair Polymerization-Induced Self-Assembly.

通過路易斯對聚合誘導自組裝一步快速合成不同形貌的二嵌段共聚物。

88.Selective Extraction of Transition Metals from Spent LiNixCoyMn1?x?yO2 Cathode via Regulation of Coordination Environment.

通過調節(jié)配位環(huán)境從廢 LiNixCoyMn1?x?yO2 陰極中選擇性萃取過渡金屬。

89.Surface-Adaptive Capillarity Enabling Densified 3D Printing for Ultra-High Areal and Volumetric Energy Density Supercapacitors.

表面自適應毛細管現(xiàn)象可實現(xiàn)超高面積和體積能量密度超級電容器的致密 3D 打印。

90.Hydrophobization Engineering of the Air–Cathode Catalyst for Improved Oxygen Diffusion towards Efficient Zinc–Air Batteries.

空氣陰極催化劑的疏水化工程，用于改善高效鋅空氣電池的氧擴散。

91.Electrocatalysis for Continuous Multi-Step Reactions in Quasi-Solid-State Electrolytes Towards High-Energy and Long-Life Aluminum–Sulfur Batteries.

準固態(tài)電解質中連續(xù)多步反應的電催化以實現(xiàn)高能和長壽命的鋁硫電池。

92.Highly Chemoselective Transamidation of Unactivated Tertiary Amides by Electrophilic N?C(O) Activation by Amide-to-Acyl Iodide Re-routing.

通過酰胺到?；庵匦侣酚傻挠H電 N?C(O) 活化對未活化的叔酰胺進行高度化學選擇性的轉酰胺基化。

93.Anionic Cyanine J-Type Aggregate Nanoparticles with Enhanced Photosensitization for Mitochondria-Targeting Tumor Phototherapy.

具有增強光敏性的陰離子花青 J 型聚集納米粒子，用于線粒體靶向腫瘤光療。

94.Surface-Plasmon-Enhanced Transmetalation between Copper and Palladium Nanoparticle Catalyst.

銅和鈀納米粒子催化劑之間的表面等離子體增強金屬轉移。

95.A Strategy Based on Aggregation-Induced Ratiometric Emission to Differentiate Molecular Weight of Supramolecular Polymers.

基于聚集誘導比率發(fā)射來區(qū)分超分子聚合物分子量的策略。

96.Direct Amination of Benzene with Molecular Nitrogen Enabled by Plasma-Liquid Interactions.

通過等離子體-液體相互作用實現(xiàn)苯與分子氮的直接胺化。

97.Tandem Catalysis for Selective Oxidation of Methane to Oxygenates Using Oxygen over PdCu/Zeolite.

使用 PdCu/沸石上的氧氣將甲烷選擇性氧化為氧化物的串聯(lián)催化。

98.Photocatalytic Abstraction of Hydrogen Atoms from Water Using Hydroxylated Graphitic Carbon Nitride for Hydrogenative Coupling Reactions.

使用羥基石墨碳氮化物進行氫偶聯(lián)反應光催化從水中提取氫原子。

99.Unprecedented Mushroom Polyketide Synthases Produce the Universal Anthraquinone Precursor.

前所未有的蘑菇聚酮化合物合成酶可生產通用蒽醌前體。

100.Tailored Pyridoxal Probes Unravel Novel Cofactor-Dependent Targets and Antibiotic Hits in Critical Bacterial Pathogens.

定制的吡哆醛探針揭示了關鍵細菌病原體中新的輔因子依賴性靶點和抗生素命中。

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