web of science--Zn air batteries (topic)--2021--461?articles

1-7(research articles)?

[1] Continuous nitrogen-Doped carbon nanotube matrix for boosting oxygen electrocatalysis in rechargeable?Zn-air?batteries,(9.676),?https://doi.org/10.1016/j.jechem.2020.07.012

本文以鹽為軟模板，包覆，生長ZIF-67，合成氮摻雜碳納米管（NCNTM）（？？鈷去哪了）性能：開路電壓?1.50?V，能量密度 220 mW cm?2,在5?mA?cm?2下循環(huán) ?1600?h穩(wěn)定。

本文亮點：1.柔性鋅空電池制備--凝膠電解液（5?mL of 11.25?M KOH+0.25?M ZnO?with 0.5?g of acrylic acid and 0.075?g?N, N’-methylene-bisacrylamide. The white precipitate was filtered out. Then, 75?μL saturated K2S2O8?as initiator was added into the solution and a portion of the solution was poured into the void of acrylic tape once the solution started to polymerize）

問題：1.為什么在ORR測試時通N2和O2氣體測試？--在氮氣沒有還原峰在氧氣有還原峰，證明出現(xiàn)的峰是ORR的峰。2.活性位點是Co-C/N還是碳納米管基底還是協(xié)同？增加對比摻鈷和不摻鈷的性能。

[2]?Rechargeable Zn–Air Batteries with Outstanding Cycling Stability Enabled by Ultrafine FeNi Nanoparticles-Encapsulated N-Doped Carbon Nanosheets as a Bifunctional Electrocatalyst,(11.189),?10.1021/acs.nanolett.1c00279

性能：穩(wěn)定性測試：在?5.0 mA cm?2下循環(huán)1100 h 。

亮點：FeNi nanoparticles, M?Nx species, and N?C在FeNi/N?LCN，ORR,OER測試中的貢獻對比說明；

[3]?Electrospun N-Doped carbon nanofibers decorated with Fe3C nanoparticles as highly active oxygen reduction electrocatalysts for rechargeable?Zn-air?batteries,(2.328),10.1016/j.cplett.2021.138769

鐵碳和碳基底協(xié)同作用催化OER,ORR反應(yīng)。

性能：在?5.0 mA cm?2下循環(huán)16.7?h (-OH)

[4]?Atomic layer deposited nickel sulfide for bifunctional oxygen evolution/reduction electrocatalysis and zinc-air batteries, (3.874)?,?10.1088/1361-6528/abf26f

性能：在?5.0 mA cm?2下循環(huán)20 h (-OH)

問題：1.NiSX 在堿性溶液中不穩(wěn)定，以Ni(OH)x進行反應(yīng)?。反應(yīng)物不穩(wěn)定測試的意義。

[5]?Trimetallic Zeolitic imidazolite framework-derived Co nanoparticles@CoFe-nitrogen-Doped porous carbon as bifunctional electrocatalysts for?Zn-air?battery,?8.128),10.1016/j.jcis.2020.10.130

性能：在?1.0 mA cm?2下循環(huán)100?h (-OH)

[6]?RuCo alloy trifunctional electrocatalysts with ratio-dependent activity for?Zn-air?batteries?and self-powered water splitting,? (6.22),10.1039/d0cc07565e

性能：在?2.0 mA?cm?2下循環(huán)16.7?h (-OH)(Ru元素有利于水分解)

亮點：調(diào)節(jié)Ru和Co的比例分別適應(yīng)OER(7:3)和ORR(5:5)測試，

問題：1：比例在6:4會在OER和ORR都有活性么？

2：是不同比例的元素對催化活性有影響還是不同比例組成物質(zhì)的缺陷有影響？XPS，HRTEM表征

[7]?Rationally Designed?Zn-Anode and Co3O4-Cathode Nanoelectrocatalysts for an Efficient?Zn-Air?Battery,?(3.605),10.1021/acs.energyfuels.1c01108

鋅負極保護：巰基丙酸修飾(表面成核速度??CH3?< ?NH2?< ?CO2H < bare gold)，Zn-S形成穩(wěn)定的層，沉積的Zn與羧酸通過氫鍵相接觸，促使Zn(101)生長。

性能：在 5.0 mA?cm?2下循環(huán)83?h (-OH)

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