聲明：本專欄主要對生命科學領(lǐng)域的一些期刊文章標題進行翻譯，所有內(nèi)容均由本人手工整理翻譯。由于本人專業(yè)為生物分析相關(guān)，其他領(lǐng)域如果出現(xiàn)翻譯錯誤請諒解。

An electrochemical strategy is reported to upgrade CO2-derived formic acid into high-valued formamide by the co-reduction of CO2 and nitrite pollutants. Low-coordinated Cu exhibits a remarkable economic advantage for formamide electrosynthesis over conventional manufacture.

據(jù)報道，一種電化學策略通過 CO2 和亞硝酸鹽污染物的共同還原將 CO2 衍生的甲酸升級為高價值的甲酰胺。 與傳統(tǒng)制造相比，低配位銅在甲酰胺電合成方面具有顯著的經(jīng)濟優(yōu)勢。

Synthetic biodegradable polyesters, e.g., PBAT, suffer from a slow biodegradability under ambient conditions, tending to be biodegradable only under harsh industrial composting conditions. Here, it is demonstrated how the biodegradability of such polyesters can be enhanced under ambient conditions of soils without sacrificing the desirable rheological and mechanical properties.

合成的可生物降解聚酯，例如 PBAT，在環(huán)境條件下生物降解緩慢，只有在惡劣的工業(yè)堆肥條件下才能生物降解。 在這里，展示了如何在土壤環(huán)境條件下增強此類聚酯的生物降解性，而不犧牲所需的流變學和機械性能。

Biphase catalyst of anatase and rutile TiO2 with optimal phase interface concentration enables efficient and selective photooxidation of methane to formaldehyde under the reaction condition of water solvent, oxygen atmosphere, and full-spectrum light irradiation. More importantly, the feasibility of scale-up production of formaldehyde is demonstrated by inventing the “pause-flowing” reactor.

具有最佳相界面濃度的銳鈦礦和金紅石 TiO2 雙相催化劑能夠在水溶劑、氧氣氣氛和全光譜光照射的反應條件下，將甲烷高效、選擇性地光氧化為甲醛。 更重要的是，通過發(fā)明“暫停流動”反應器證明了擴大甲醛生產(chǎn)的可行性。

An excess electron residing on the diffuse nonvalence orbital of the dipole-bound state (DBS) of para-iodophenoxide plays the resonant “doorway” role into either the autodetachment (right) or the chemical-bond fragmentation (left).

駐留在對碘苯氧化物偶極結(jié)合態(tài) (DBS) 的擴散非價軌道上的過量電子在自動分離（右）或化學鍵斷裂（左）中發(fā)揮共振“門口”作用。

Spontaneous oxidative C–H/N–H cross-coupling can be catalyzed by an ultrahigh electric field on water microdroplets.

水微滴上的超高電場可以催化自發(fā)氧化 C-H/N-H 交叉偶聯(lián)。

Light promotes electrons in certain positions of a three-dimensional covalent organic framework into collective excited states. Cover art by Alfy Benny.

光將三維共價有機框架中某些位置的電子促進到集體激發(fā)態(tài)。 Alfy Benny 的封面藝術(shù)。

Metal–organic frameworks (MOFs) with precisely controlled combinations of metal atoms are synthesized. Molecular complexes are used to lock the desired chemical codes and deliver them to the MOFs upon reaction with organic linkers.

合成了具有精確控制的金屬原子組合的金屬有機骨架 (MOF)。 分子復合物用于鎖定所需的化學代碼，并在與有機接頭反應后將它們傳遞給 MOF。

Liver fibrosis is characterized by accumulation and cross-linking of extracellular matrix components, chiefly fibrillar collagens. Lysine residues on the collagen triple helix can be oxidized to the aldehyde containing allysine residue (highlighted spots) during the cross-linking process. We targeted these allysine aldehydes on collagen by molecular magnetic resonance imaging to detect the disease activity in liver fibrosis.

肝纖維化的特征是細胞外基質(zhì)成分（主要是纖維狀膠原蛋白）的積累和交聯(lián)。 在交聯(lián)過程中，膠原蛋白三螺旋上的賴氨酸殘基可以被氧化成含有醛基的醛基殘基（突出顯示的點）。 我們通過分子磁共振成像將這些 allysine 醛靶向膠原蛋白，以檢測肝纖維化中的疾病活動。

Four types of metallo-macromolecules, including concentric ring, helicoid polymer, ladder polymer, and cross-linked polymer, with different geometries but the same chemical composition have been designed and synthesized from chevron-shaped monomers through stepwise platinum–acetylide polymerization. Microscopic characterization techniques including TEM, AFM, and UHV-LT-STM were employed to image these metallo-macromolecules at the single-molecule level.

以人字形單體為原料，通過逐步鉑-乙炔聚合反應，設計并合成了四種金屬大分子，包括同心環(huán)、螺旋聚合物、梯形聚合物和交聯(lián)聚合物，它們具有不同的幾何形狀但化學成分相同。 采用包括 TEM、AFM 和 UHV-LT-STM 在內(nèi)的顯微表征技術(shù)在單分子水平上對這些金屬大分子進行成像。

Elongated and weakened carbon–carbon bonds achieved via solid-state topochemical polymerization yield fully depolymerizable polyolefin-derived single-crystalline materials. Some of these crystalline polymers exhibit facile processability and excellent mechanical properties, suggesting great promise for practical applications toward a greener and more sustainable future.

通過固態(tài)拓撲化學聚合實現(xiàn)的碳-碳鍵伸長和弱化產(chǎn)生完全可解聚的聚烯烴衍生單晶材料。 其中一些結(jié)晶聚合物表現(xiàn)出易于加工和優(yōu)異的機械性能，表明在實際應用中有望實現(xiàn)更綠色、更可持續(xù)的未來。

Artistic rendering of the geometric confluence of the experimentally inaccessible transition structure of the cyclic water dimer and a cyclooctatetraene-based “molecular balance” that probes this dimer in the form of dimethanol hydrogen-bonding contacts held in place by the unsaturated cycle. The thermodynamic measurement of the balance yields an estimate of the cyclic water dimer binding energy because all quantities that affect this equilibrium are known and can be determined rather accurately. Hence, this manifests an attempt to determine the binding energy of a transition state using an experimental equilibrium measurement approach.

環(huán)狀水二聚體的實驗上難以接近的過渡結(jié)構(gòu)和基于環(huán)辛四烯的“分子平衡”的幾何匯合的藝術(shù)渲染，該“分子平衡”以不飽和循環(huán)保持的二甲醇氫鍵接觸的形式探測該二聚體。 平衡的熱力學測量產(chǎn)生了循環(huán)水二聚體結(jié)合能的估計，因為影響這種平衡的所有量都是已知的并且可以相當準確地確定。 因此，這表明嘗試使用實驗平衡測量方法來確定過渡態(tài)的結(jié)合能。

Protomers of nicotine depending on its immediate environment: (left) 3:2 mixture of pyridine to pyrrolidine protomers in the gas phase, (middle) almost exclusively (9:1 ratio) pyridine protomer NICH+???H2O) for a single water, and (right) exclusively pyrrolidine protomer in aqueous solution.

取決于其直接環(huán)境的尼古丁原體：（左）氣相中吡啶與吡咯烷原體的 3:2 混合物，（中）幾乎完全（9:1 比例）吡啶原體 NICH+???H2O) 對于單一水， 和（右）水溶液中的完全吡咯烷原體。

The dominant catalytic site for oxygen reduction in FeNC catalysts relevant to proton exchange fuel cells features pyrrolic nitrogen donors. We observe a new M?ssbauer signal that emerges under operando conditions as other signals decay and use quantum chemistry to develop a structurally, spectroscopically, and thermodynamically consistent active site model.

與質(zhì)子交換燃料電池相關(guān)的 FeNC 催化劑中氧還原的主要催化位點具有吡咯氮供體。 我們觀察到一個新的穆斯堡爾信號，該信號在操作條件下隨著其他信號衰減而出現(xiàn)，并使用量子化學來開發(fā)結(jié)構(gòu)、光譜和熱力學一致的活性位點模型。

A main-group metal oxide catalyst with atomically dispersed In sites has been exploited, which shows remarkable performance for oxidative dehydrogenation of ethane. This work proposes a new strategy to regulate the activity of an inherently selective catalyst from weakness to strength for highly efficient oxidative dehydrogenation.

已開發(fā)出具有原子分散 In 位點的主族金屬氧化物催化劑，其在乙烷氧化脫氫中顯示出卓越的性能。 這項工作提出了一種新策略來調(diào)節(jié)固有選擇性催化劑的活性從弱到強，以實現(xiàn)高效氧化脫氫。

CdS nanosheets terminated by S2– atomic layers enable oriented migration of photoexcited electrons and holes toward spatially separated reductive and oxidative centers, leading to record-breaking photocatalytic performance for solar-driven CO2-to-CO conversion with selectivity of 99%, a CO formation rate reaching 2.13 mol g–1 h–1, and an effective apparent quantum efficiency of 42.1%.

由 S2- 原子層終止的 CdS 納米片使光激發(fā)電子和空穴能夠定向遷移到空間分離的還原和氧化中心，從而導致太陽能驅(qū)動的 CO2 轉(zhuǎn)化為 CO 的光催化性能破紀錄，選擇性為 99%，CO 形成 速率達到2.13 mol g-1 h-1，有效表觀量子效率為42.1%。

A gold nanoparticle (AuNP)–bridge array was constructed with vertical permeability to maximize mass transfer efficiency. The capability of the AuNP–bridge array to improve DNA hybridization efficiency was verified by surface-enhanced Raman spectroscopy (SERS). The AuNP–bridge array provides new insights into the construction of various biosensor chips.

構(gòu)建了具有垂直滲透性的金納米顆粒 (AuNP)-橋陣列，以最大限度地提高傳質(zhì)效率。 通過表面增強拉曼光譜 (SERS) 驗證了 AuNP 橋陣列提高 DNA 雜交效率的能力。 AuNP 橋陣列為各種生物傳感器芯片的構(gòu)建提供了新的見解。

Abstraction of an optimal control solid-state NMR experiment. A powdered sample is spun inside a solenoidal coil. The coil delivers sophisticated radio-frequency pulses (gold numbers fed into coil wires) to manipulate the magnetization vector. Transferring both vector components between nuclei allows systematic sensitivity gains in multidimensional NMR spectra of solids.

最佳控制固態(tài)核磁共振實驗的抽象。 粉末狀樣品在螺線管線圈內(nèi)旋轉(zhuǎn)。 線圈傳送復雜的射頻脈沖（送入線圈線的金號）來操縱磁化矢量。 在原子核之間轉(zhuǎn)移兩個矢量分量可以在固體的多維核磁共振光譜中獲得系統(tǒng)的靈敏度增益。

Peptide phosphorylation, an archetypal post-translational modification, is detected at the single-molecule level based on electrical measurements. The detection relies on bridging of a nanogap between electrodes by the phosphate group, which gives rise to high electrical conductance.

肽磷酸化是一種典型的翻譯后修飾，可根據(jù)電學測量在單分子水平上檢測到。 檢測依賴于磷酸基團橋接電極之間的納米間隙，從而產(chǎn)生高電導。

We report the feasible and scalable exfoliation to produce free-standing 2D metal-organic framework nanosheets (MONs) with high aspect ratio up to 2000:1 and ultrathin thickness (~1.7 nm) from MOF films obtained by an efficient interfacial polycondensation and polycoordination of three active monomers. The MONs exhibited exceptional catalytic activity and excellent reusability for hydroboration reactions of alkynes, compared to reported homogenous and homogenous catalysts.

我們報告了可行且可擴展的剝離，以通過有效的界面縮聚和多配位獲得的 MOF 薄膜生產(chǎn)具有高達 2000:1 的高縱橫比和超薄厚度（~1.7 nm）的獨立二維金屬有機骨架納米片（MON） 三個活性單體。 與報道的均相和均相催化劑相比，MON 對炔烴的硼氫化反應表現(xiàn)出卓越的催化活性和出色的可重復使用性。

The ATG12–ATG5–ATG16L1 complex formation is essential for targeting the ATG12–ATG5 conjugate to proper membranes and to generate LC3-II for the progression of autophagy. A stapled peptide derived from ATG16L1 exhibits potent binding affinity to ATG5, striking resistance to proteolysis, and significant autophagy inhibition activities in cells.

ATG12–ATG5–ATG16L1 復合物的形成對于將 ATG12–ATG5 結(jié)合物靶向適當?shù)哪げa(chǎn)生 LC3-II 以促進自噬過程至關(guān)重要。 源自 ATG16L1 的釘合肽對 ATG5 表現(xiàn)出強大的結(jié)合親和力，對蛋白水解具有顯著的抵抗力，并且在細胞中具有顯著的自噬抑制活性。

1.Rapid Biodegradable Ionic Aggregates of Polyesters Constructed with Fertilizer Ingredients.

用肥料成分構(gòu)建的快速可生物降解的聚酯離子聚集體。

2.Chemoselective Covalent Modification of K-Ras(G12R) with a Small Molecule Electrophile.

用小分子親電試劑對 K-Ras(G12R) 進行化學選擇性共價修飾。

3.Chalcogen Atoms as Electron Donors in Proton-Coupled Electron Transfer Reactions.

硫族原子作為質(zhì)子耦合電子轉(zhuǎn)移反應中的電子供體。

4.Low-Temperature, Solution-Based Synthesis of Luminescent Chalcogenide Perovskite BaZrS3 Nanoparticles.

低溫、基于溶液的發(fā)光硫族化物鈣鈦礦 BaZrS3 納米粒子的合成。

5.The Chromium Dimer: Closing a Chapter of Quantum Chemistry.

鉻二聚體：結(jié)束量子化學的一章。

6.A Pyridine Dearomatization Approach to the Matrine-Type Lupin Alkaloids.

苦參堿類羽扇豆生物堿的吡啶脫芳構(gòu)化方法。

7.High-Entropy Intermetallics Serve Ultrastable Single-Atom Pt for Propane Dehydrogenation.

高熵金屬間化合物為丙烷脫氫提供超穩(wěn)定的單原子鉑。

8.Enzymatic Control over Reactive Intermediates Enables Direct Oxidation of Alkenes to Carbonyls by a P450 Iron-Oxo Species.

對反應性中間體的酶促控制使 P450 鐵氧物種能夠?qū)⑾N直接氧化為羰基。

9.New Approach to the Detection of Short-Lived Radical Intermediates.

檢測短壽命自由基中間體的新方法。

10.Elevating Photooxidation of Methane to Formaldehyde via TiO2 Crystal Phase Engineering.

通過 TiO2 晶相工程將甲烷光氧化為甲醛。

11.Adaptive Binding of Alkyl Glycosides by Nonpeptidic Helix Bundles in Water: Toward Artificial Glycolipid Binding Proteins.

水中非肽螺旋束對烷基糖苷的適應性結(jié)合：對人工糖脂結(jié)合蛋白的研究。

12.Periodic One-Dimensional Single-Atom Arrays.

周期性一維單原子陣列。

13.Electrochemical Upgrading of Formic Acid to Formamide via Coupling Nitrite Co-Reduction.

通過偶聯(lián)亞硝酸鹽共還原將甲酸電化學升級為甲酰胺。

14.Programmable Fabrication of Monodisperse Graphene Nanoribbons via Deterministic Iterative Synthesis.

通過確定性迭代合成可編程制造單分散石墨烯納米帶。

15.Tailoring the Time-Averaged Structure for Polarization-Sensitive Chiral Perovskites.

定制偏振敏感手性鈣鈦礦的時間平均結(jié)構(gòu)。

16.On-Surface Design of a 2D Cobalt-Organic Network Preserving Large Orbital Magnetic Moment.

保持大軌道磁矩的二維鈷有機網(wǎng)絡的表面設計。

17.Total Syntheses of Calyciphylline A-Type Alkaloids (?)-10-Deoxydaphnipaxianine A, (+)-Daphlongamine E and (+)-Calyciphylline R via Late-Stage Divinyl Carbinol Rearrangements.

Calyciphylline A 型生物堿 (?)-10-Deoxydaphnipaxianine A、(+)-Daphlongamine E 和 (+)-Calyciphylline R 通過后期二乙烯基甲醇重排的全合成。

18.Viscoelastic Covalent Organic Nanotube Fabric via Macroscopic Entanglement.

通過宏觀糾纏的粘彈性共價有機納米管織物。

19.Resolving Isomeric Posttranslational Modifications Using a Biological Nanopore as a Sensor of Molecular Shape.

使用生物納米孔作為分子形狀傳感器解決異構(gòu)翻譯后修飾。

20.Quantitatively Determining Surface–Adsorbate Properties from Vibrational Spectroscopy with Interpretable Machine Learning.

使用可解釋的機器學習從振動光譜定量確定表面吸附性質(zhì)。

21.Experimental Observation of the Resonant Doorways to Anion Chemistry: Dynamic Role of Dipole-Bound Feshbach Resonances in Dissociative Electron Attachment.

陰離子化學共振門道的實驗觀察：偶極束縛 Feshbach 共振在離解電子附著中的動態(tài)作用。

22.Five-Spin Supramolecule for Simulating Quantum Decoherence of Bell States.

用于模擬貝爾態(tài)量子退相干的五自旋超分子。

23.Electroactive Covalent Organic Framework Enabling Photostimulus-Responsive Devices.

電活性共價有機框架使光刺激響應設備成為可能。

24.Characterization of Binding Site Interactions and Selectivity Principles in the α3β4 Nicotinic Acetylcholine Receptor.

α3β4 煙堿型乙酰膽堿受體中結(jié)合位點相互作用和選擇性原理的表征。

25.Mechanistic Basis for the Iridium-Catalyzed Enantioselective Allylation of Alkenyl Boronates.

銥催化的烯基硼酸酯的對映選擇性烯丙基化的機理基礎(chǔ)。

26.Metal-Coordinated Phthalocyanines as Platform Molecules for Understanding Isolated Metal Sites in the Electrochemical Reduction of CO2.

金屬配位酞菁作為平臺分子，用于了解 CO2 電化學還原中的孤立金屬位點。

27.Capture Instead of Release: Defect-Modulated Radionuclide Leaching Kinetics in Metal–Organic Frameworks.

捕獲而不是釋放：金屬有機骨架中的缺陷調(diào)制放射性核素浸出動力學。

28.Selective Unnatural Base Pairing and Recognition of 2-Hydroxy-2′-deoxyadenosine in DNA Using Pseudo-dC Derivatives.

使用偽 dC 衍生物選擇性非自然堿基配對和識別 DNA 中的 2-羥基-2'-脫氧腺苷。

29.Peptidyl Prolyl Isomerase A Modulates the Liquid–Liquid Phase Separation of Proline-Rich IDPs.

肽基脯氨酰異構(gòu)酶 A 調(diào)節(jié)富含脯氨酸的 IDP 的液-液相分離。

30.Molecular Basis for Enzymatic Aziridine Formation via Sulfate Elimination.

通過硫酸鹽消除酶促氮丙啶形成的分子基礎(chǔ)。

31.Ir and NHC Dual Chiral Synergetic Catalysis: Mechanism and Stereoselectivity in γ-Butyrolactone Formation.

Ir 和 NHC 雙手性協(xié)同催化：γ-丁內(nèi)酯形成的機理和立體選擇性。

32.High Electric Field on Water Microdroplets Catalyzes Spontaneous and Ultrafast Oxidative C–H/N–H Cross-Coupling.

水微滴上的高電場催化自發(fā)和超快氧化 C–H/N–H 交叉偶聯(lián)。

33.Water-Soluble Self-Assembled Cage with Triangular Metal–Metal-Bonded Units Enabling the Sequential Selective Separation of Alkanes and Isomeric Molecules.

具有三角形金屬-金屬鍵合單元的水溶性自組裝籠，可實現(xiàn)烷烴和異構(gòu)分子的順序選擇性分離。

34.Stereocontrolled Synthesis of the Fully Glycosylated Monomeric Unit of Lomaiviticin A.

Lomaiviticin A 完全糖基化單體單元的立體控制合成。

35.Catalytic Lewis Base Additive Enables Selective Copper-Catalyzed Borylative α-C–H Allylation of Alicyclic Amines.

催化路易斯堿添加劑可實現(xiàn)選擇性銅催化的脂環(huán)族胺的硼基化 α-C-H 烯丙基化。

36.Photochemistry Journey to Multielectron and Multiproton Chemical Transformation.

多電子和多質(zhì)子化學轉(zhuǎn)化的光化學之旅。

37.Precise Assembly of Proteins and Carbohydrates for Next-Generation Biomaterials.

為下一代生物材料精確組裝蛋白質(zhì)和碳水化合物。

38.The Implications of the Br?nsted Acidic Properties of Crabtree-Type Catalysts in the Asymmetric Hydrogenation of Olefins.

Crabtree 型催化劑的 Br?nsted 酸性在烯烴不對稱加氫中的意義。

39.Heterometallic Molecular Complexes Act as Messenger Building Units to Encode Desired Metal-Atom Combinations to Multivariate Metal–Organic Frameworks.

異金屬分子復合物作為信使構(gòu)建單元將所需的金屬-原子組合編碼為多元金屬-有機框架。

40.Covalent Adsorption of N-Heterocyclic Carbenes on a Copper Oxide Surface.

N-雜環(huán)卡賓在氧化銅表面的共價吸附。

41.High-Spin Orbital Interactions Across van der Waals Gaps Controlling the Interlayer Ferromagnetism in van der Waals Ferromagnets.

跨范德瓦爾斯間隙的高自旋軌道相互作用控制范德瓦爾斯鐵磁體中的層間鐵磁性。

42.Activation of Carbon Dioxide by 9-Carbene-9-borafluorene Monoanion: Carbon Monoxide Releasing Transformation of Trioxaborinanone to Luminescent Dioxaborinanone.

9-Carbene-9-borafluorene 單陰離子對二氧化碳的活化：一氧化碳釋放 Trioxaborinanone 轉(zhuǎn)化為發(fā)光的 Dioxaborinanone。

43.Supramolecular Substructure of C60-Embedded Schwarzite.

C60 包埋黑石英的超分子亞結(jié)構(gòu)。

44.Gigantic C120 Fullertubes: Prediction and Experimental Evidence for Isomerically Purified Metallic [5,5] C120-D5d(1) and Nonmetallic [10,0] C120-D5h(10766).

巨大的 C120 Fullertubes：異構(gòu)純化金屬 [5,5] C120-D5d(1) 和非金屬 [10,0] C120-D5h(10766) 的預測和實驗證據(jù)。

45.Bioinspired Synthesis of Spirochensilide A from Lanosterol.

從羊毛甾醇中仿生合成 Spirochensilide A。

46.Borylated Cyclopropanes as Spring-Loaded Entities: Access to Vicinal Tertiary and Quaternary Carbon Stereocenters in Acyclic Systems.

Borylated Cyclopropanes 作為彈簧加載的實體：在無環(huán)系統(tǒng)中獲得鄰位三級和四級碳立體中心。

47.Copper Hydride-Catalyzed Enantioselective Olefin Hydromethylation.

氫化銅催化的對映選擇性烯烴氫甲基化。

48.Enhancing CRISPR-Cas-Mediated Detection of Nucleic Acid and Non-nucleic Acid Targets Using Enzyme-Labeled Reporters.

使用酶標記報告基因增強 CRISPR-Cas 介導的核酸和非核酸靶標檢測。

49.Hydroamination of Unactivated Alkenes with Aliphatic Azides.

未活化烯烴與脂肪族疊氮化物的加氫胺化。

50.Activation of Ammonia by a Carbene-Stabilized Dithiolene Zwitterion.

卡賓穩(wěn)定的二硫烯兩性離子對氨的活化。

51.Total Synthesis of Resiniferatoxin.

樹脂毒素的全合成。

52.Water Structure in the Electrical Double Layer and the Contributions to the Total Interfacial Potential at Different Surface Charge Densities.

雙電層中的水結(jié)構(gòu)以及在不同表面電荷密度下對總界面電勢的貢獻。

53.Forced Disorder in the Solid Solution Li3P–Li2S: A New Class of Fully Reduced Solid Electrolytes for Lithium Metal Anodes.

Li3P–Li2S 固溶體中的強制紊亂：一類用于鋰金屬陽極的新型完全還原固體電解質(zhì)。

54.Lanthanide-Nucleotide Coordination Nanoparticles for STING Activation.

用于 STING 激活的鑭系元素-核苷酸配位納米粒子。

55.Ordering Transitions of Liquid Crystals Triggered by Metal Oxide-catalyzed Reactions of Sulfur Oxide Species.

由氧化硫物質(zhì)的金屬氧化物催化反應觸發(fā)的液晶有序轉(zhuǎn)變。

56.Versatile Inorganic Subnanometer Nanowire Adhesive.

多功能無機亞納米納米線粘合劑。

57.What Is the Right Level of Activation of a High-Spin {FeNO}7 Complex to Enable Direct N–N Coupling? Mechanistic Insight into Flavodiiron NO Reductases.

高自旋 {FeNO}7 絡合物啟用直接 N-N 耦合的正確激活水平是多少？ Flavodiiron NO 還原酶的機理洞察。

58.Development of a GalNAc-Tyrosine-Specific Monoclonal Antibody and Detection of Tyrosine O-GalNAcylation in Numerous Human Tissues and Cell Lines.

GalNAc-酪氨酸特異性單克隆抗體的開發(fā)和許多人體組織和細胞系中酪氨酸 O-GalNAcylation 的檢測。

59.Exciton Diffusion and Annihilation in an sp2 Carbon-Conjugated Covalent Organic Framework.

sp2 碳共軛共價有機骨架中的激子擴散和湮滅。

60.Selective Photocatalytic Dehydrogenation of Formic Acid by an In Situ-Restructured Copper-Postmetalated Metal–Organic Framework under Visible Light.

可見光下原位重組銅后金屬化金屬有機骨架對甲酸的選擇性光催化脫氫。

61.Bright, Modular, and Switchable Near-Infrared II Emission from Compact Tetrathiafulvalene-Based Diradicaloid Complexes.

緊湊型基于四硫富瓦烯的雙自由基復合物的明亮、模塊化和可切換的近紅外 II 發(fā)射。

62.Dopant-Stabilized Assembly of Poly(3-hexylthiophene).

聚（3-己基噻吩）的摻雜劑穩(wěn)定組裝。

63.Induction of Chiral Hybrid Metal Halides from Achiral Building Blocks.

從非手性構(gòu)件中誘導手性雜化金屬鹵化物。

64.Rapid Screening of Bimetallic Electrocatalysts Using Single Nanoparticle Collision Electrochemistry.

使用單納米粒子碰撞電化學快速篩選雙金屬電催化劑。

65.Asymmetric Intermolecular Iodinative Difunctionalization of Allylic Sulfonamides Enabled by Organosulfide Catalysis: Modular Entry to Iodinated Chiral Molecules.

有機硫化物催化實現(xiàn)的烯丙基磺酰胺的不對稱分子間碘化雙功能化：碘化手性分子的模塊化進入。

66.DNA Strand Displacement Driven by Host–Guest Interactions.

由主客體相互作用驅(qū)動的 DNA 鏈位移。

67.Peptide Sequence Determines Structural Sensitivity to Supramolecular Polymerization Pathways and Bioactivity.

肽序列決定了對超分子聚合途徑和生物活性的結(jié)構(gòu)敏感性。

68.Multilevel Computational Studies Reveal the Importance of Axial Ligand for Oxygen Reduction Reaction on Fe–N–C Materials.

多層次計算研究揭示了軸向配體對 Fe-N-C 材料上氧還原反應的重要性。

69.Radical Activation of N–H and O–H Bonds at Bismuth(II).

鉍 (II) 上 N-H 和 O-H 鍵的自由基活化。

70.Detection of Epidermal Growth Factor Receptor Expression in Breast Cancer Cell Lines Using an Ion-Sensitive Field-Effect Transistor in Combination with Enzymatic Chemical Signal Amplification.

使用離子敏感場效應晶體管結(jié)合酶促化學信號放大檢測乳腺癌細胞系中表皮生長因子受體的表達。

71.Dual Hydrazine-Equipped Turn-On Manganese-Based Probes for Magnetic Resonance Imaging of Liver Fibrogenesis.

肝纖維化磁共振成像的雙聯(lián)氨開啟錳基探針。

72.Precise Synthesis of Concentric Ring, Helicoid, and Ladder Metallo-Polymers with Chevron-Shaped Monomers.

用人字形單體精確合成同心環(huán)、螺旋體和梯形金屬聚合物。

73.Hole-Doping to a Cu(I)-Based Semiconductor with an Isovalent Cation: Utilizing a Complex Defect as a Shallow Acceptor.

具有等價陽離子的 Cu(I) 基半導體的空穴摻雜：利用復雜缺陷作為淺受體。

74.Preparation, Supramolecular Organization, and On-Surface Reactivity of Enantiopure Subphthalocyanines: From Bulk to 2D-Polymerization.

對映純亞酞菁的制備、超分子組織和表面反應性：從本體到二維聚合。

75.Circularly Recyclable Polymers Featuring Topochemically Weakened Carbon–Carbon Bonds.

具有拓撲化學弱化碳-碳鍵的循環(huán)可回收聚合物。

76.Programmable Assembly of Amphiphilic DNA through Controlled Cholesterol Stacking.

通過受控膽固醇堆積的兩親性 DNA 的可編程組裝。

77.Photochemical Identification of Auxiliary Severe Acute Respiratory Syndrome Coronavirus 2 Host Entry Factors Using μMap.

使用 μMap 光化學鑒定輔助嚴重急性呼吸系統(tǒng)綜合癥冠狀病毒 2 宿主進入因子。

78.Robust Radical Cations of Hexabenzoperylene Exhibiting High Conductivity and Enabling an Organic Nonvolatile Optoelectronic Memory.

六苯并苝的穩(wěn)健自由基陽離子表現(xiàn)出高導電性并使有機非易失性光電存儲器成為可能。

79.Probing the Strong Nonadiabatic Interactions in the Triazolyl Radical Using Photodetachment Spectroscopy and Resonant Photoelectron Imaging of Cryogenically Cooled Anions.

使用低溫冷卻陰離子的光分離光譜和共振光電子成像探索三唑基中的強非絕熱相互作用。

80.Preparation of Highly Reactive Lithium Metal Dendrites for the Synthesis of Organolithium Reagents.

用于合成有機鋰試劑的高活性鋰金屬枝晶的制備。

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