聲明：本專欄主要對(duì)生命科學(xué)領(lǐng)域的一些期刊文章標(biāo)題進(jìn)行翻譯，所有內(nèi)容均由本人手工整理翻譯。由于本人專業(yè)為生物分析相關(guān)，其他領(lǐng)域如果出現(xiàn)翻譯錯(cuò)誤請(qǐng)諒解。

1.An NHC-organocatalyzed remote C(sp3)?H acylation of amides is developed based on a 1,5-hydrogen atom transfer strategy. As reported in the Research Article by Jun-Long Li et?al. (e202116629), over 120 functionalized δ-amino ketones and isoquinolinones were synthesized in up to 99?% yield under mild conditions. Mechanistic investigations, including control reactions, KIE experiments, and computational studies, shed light on the organocatalytic radical reaction mechanism.

基于 1,5-氫原子轉(zhuǎn)移策略，開發(fā)了 NHC 有機(jī)催化的酰胺遠(yuǎn)程 C(sp3)?H ?；Ｕ缋羁↓埖热嗽谘芯课恼轮兴鶊?bào)道的那樣。 (e202116629)，在溫和條件下合成了超過(guò) 120 種官能化 δ-氨基酮和異喹啉酮，產(chǎn)率高達(dá) 99%。機(jī)理研究，包括控制反應(yīng)、KIE 實(shí)驗(yàn)和計(jì)算研究，揭示了有機(jī)催化自由基反應(yīng)機(jī)理。

2.Copper and zinc oxide are a dream team in transforming carbon dioxide and carbon monoxide together with hydrogen into the valuable base chemical methanol. Inspired by the cover art of the music masterpiece “Wish you were here” by Pink Floyd, the picture featuring the Research Article (e202200301) by Jeroen?A. van?Bokhoven and co-workers highlights the fundamental collaboration of the copper and zinc oxide phase in methanol catalysts for a sustainable future.

銅和氧化鋅是將二氧化碳和一氧化碳與氫氣一起轉(zhuǎn)化為有價(jià)值的基礎(chǔ)化學(xué)品甲醇的理想組合。受 Pink Floyd 音樂杰作“Wish you were here”封面藝術(shù)的啟發(fā)，Jeroen A. van Bokhoven 及其同事的研究文章 (e202200301) 的圖片強(qiáng)調(diào)了銅和氧化鋅相的基本協(xié)作甲醇催化劑，實(shí)現(xiàn)可持續(xù)的未來(lái)。

3.A naphthalene-embedded conjugated nanobelt is an excellent design for achieving the synthesis of cyclophenacene-type and chiral-type carbon nanobelts. A cationic rhodium complex catalyst is a powerful tool for the (asymmetric) synthesis of these analogues, as reported by Ken Tanaka and co-workers in their Research Article (e202200800). In the picture, the three blue belts in the foreground and the rhodium complex in the back represent the cyclophenylene-naphthylene belts and the key catalyst, respectively.

萘嵌入共軛納米帶是實(shí)現(xiàn)環(huán)菲苯型和手性型碳納米帶合成的優(yōu)異設(shè)計(jì)。 Ken Tanaka 及其同事在他們的研究文章 (e202200800) 中報(bào)道，陽(yáng)離子銠配合物催化劑是這些類似物（不對(duì)稱）合成的有力工具。圖中，前景的三個(gè)藍(lán)色帶和后面的銠絡(luò)合物分別代表環(huán)亞苯基-亞萘基帶和關(guān)鍵催化劑。

4.A facile strategy for the controlled synthesis of discrete diamond-shaped two-dimensional platelets with tunable surface functionality and luminescence by crystallization-driven self-assembly of poly(L-lactides) is described by Anindita Das and Aritra Rajak in their Research Article (e202116572). By two-component co- and living-crystallization techniques, predetermined sequence-controlled supramolecular organization of two functional dyes on the co-platelet and block co-platelet surface, respectively, can be achieved.

Anindita Das 和 Aritra Rajak 在他們的研究文章 (e202116572) 中描述了一種通過(guò)聚（L-丙交酯）結(jié)晶驅(qū)動(dòng)自組裝來(lái)受控合成離散菱形二維片狀體的簡(jiǎn)便策略，該片狀體具有可調(diào)的表面功能和發(fā)光性）。通過(guò)雙組分共結(jié)晶和活結(jié)晶技術(shù)，可以分別實(shí)現(xiàn)兩種功能染料在共血小板和塊共血小板表面上的預(yù)定序列控制的超分子組織。

5.Polymer Micelles Self-assembled fluorescent block copolymer micelles with responsive emission are reported by Birgit Weber et?al. in their Research Article (e202117570).

聚合物膠束 Birgit Weber 等人在他們的研究文章（e202117570）中報(bào)道了具有響應(yīng)發(fā)射能力的自組裝熒光嵌段共聚物膠束。

6.Chemical Synthesis and Semisynthesis of Lipidated Proteins.

脂化蛋白質(zhì)的化學(xué)合成和半合成。

7.Self-Assembled Fluorescent Block Copolymer Micelles with Responsive Emission.

具有響應(yīng)發(fā)射能力的自組裝熒光嵌段共聚物膠束。

8.Towards a Systematic Understanding of the Influence of Temperature on Glycosylation Reactions.

系統(tǒng)地了解溫度對(duì)糖基化反應(yīng)的影響。

9.Drastic Events and Gradual Change Define the Structure of an Active Copper-Zinc-Alumina Catalyst for Methanol Synthesis.

劇烈事件和逐漸變化定義了用于甲醇合成的活性銅-鋅-氧化鋁催化劑的結(jié)構(gòu)。

10.Crystallization-Driven Controlled Two-Dimensional (2D) Assemblies from Chromophore-Appended Poly(L-lactide)s: Highly Efficient Energy Transfer on a 2D Surface.

來(lái)自附加發(fā)色團(tuán)的聚（L-丙交酯）的結(jié)晶驅(qū)動(dòng)受控二維（2D）組件：2D 表面上的高效能量轉(zhuǎn)移。

11.Control of Hot Carrier Relaxation in CsPbBr3 Nanocrystals Using Damping Ligands.

使用阻尼配體控制 CsPbBr3 納米晶體中的熱載流子弛豫。

12.Structural Basis for Chaperone-Independent Ubiquitination of Tau Protein by Its E3 Ligase CHIP.

Tau 蛋白通過(guò)其 E3 連接酶芯片進(jìn)行不依賴分子伴侶的泛素化的結(jié)構(gòu)基礎(chǔ)。

13.Design, Synthesis, and Targeted Delivery of an Immune Stimulant that Selectively Reactivates Exhausted CAR T Cells.

設(shè)計(jì)、合成和靶向遞送可選擇性重新激活耗盡的 CAR T 細(xì)胞的免疫刺激劑。

14.A Nuclear-Targeted AIE Photosensitizer for Enzyme Inhibition and Photosensitization in Cancer Cell Ablation.

一種核靶向 AIE 光敏劑，用于癌細(xì)胞消融中的酶抑制和光敏化。

15.Covalent Organic Framework (COF) Derived Ni-N-C Catalysts for Electrochemical CO2 Reduction: Unraveling Fundamental Kinetic and Structural Parameters of the Active Sites.

用于電化學(xué) CO2 還原的共價(jià)有機(jī)框架 (COF) 衍生 Ni-NC 催化劑：揭示活性位點(diǎn)的基本動(dòng)力學(xué)和結(jié)構(gòu)參數(shù)。

16.Protein Ligation and Labeling Enabled by a C-Terminal Tetracysteine Tag.

C 端四半胱氨酸標(biāo)簽實(shí)現(xiàn)蛋白質(zhì)連接和標(biāo)記。

17.Switchable Polymerization Organocatalysis: From Monomer Mixtures to Block Copolymers.

可切換聚合有機(jī)催化：從單體混合物到嵌段共聚物。

18.A TMEDA–Iron Adduct Reaction Manifold in Iron-Catalyzed C(sp2)?C(sp3) Cross-Coupling Reactions.

鐵催化 C(sp2)?C(sp3) 交叉偶聯(lián)反應(yīng)中的 TMEDA-鐵加合物反應(yīng)流形。

19.Versatile Construction of Biomimetic Nanosensors for Electrochemical Monitoring of Intracellular Glutathione.

用于細(xì)胞內(nèi)谷胱甘肽電化學(xué)監(jiān)測(cè)的仿生納米傳感器的多功能構(gòu)建。

20.Interfacial Manganese-Doping in CsPbBr3 Nanoplatelets by Employing a Molecular Shuttle.

利用分子梭在 CsPbBr3 納米片中進(jìn)行界面錳摻雜。

21.Proton-Promoted Nickel-Catalyzed Asymmetric Hydrogenation of Aliphatic Ketoacids.

質(zhì)子促進(jìn)的鎳催化脂肪族酮酸的不對(duì)稱氫化。

22.N-Doped Carbon Electrocatalyst: Marked ORR Activity in Acidic Media without the Contribution from Metal Sites?.

N-摻雜碳電催化劑：在酸性介質(zhì)中顯著的 ORR 活性，無(wú)需金屬位點(diǎn)的貢獻(xiàn)？

23.Mechanism of Spatial and Temporal Control in Precision Cyclic Vinyl Polymer Synthesis by Lewis Pair Polymerization.

路易斯對(duì)聚合精密環(huán)狀乙烯基聚合物合成中的時(shí)空控制機(jī)制。

24.Remote C(sp3)?H Acylation of Amides and Cascade Cyclization via N-Heterocyclic Carbene Organocatalysis.

通過(guò) N-雜環(huán)卡賓有機(jī)催化進(jìn)行酰胺的遠(yuǎn)程 C(sp3)?H ?；图?jí)聯(lián)環(huán)化。

25.A Metallofullertube of Ce2@C100 with a Carbon Nanotube Segment: Synthesis, Single-Molecule Conductance and Supramolecular Assembly.

具有碳納米管段的 Ce2@C100 金屬富勒管：合成、單分子電導(dǎo)和超分子組裝。

26.Side-Chain-Tuned Molecular Packing Allows Concurrently Boosted Photoacoustic Imaging and NIR-II Fluorescence.

側(cè)鏈調(diào)節(jié)的分子堆積可同時(shí)增強(qiáng)光聲成像和 NIR-II 熒光。

27.One-Step Synthesis of Degradable Vinylic Polymer-Based Latexes via Aqueous Radical Emulsion Polymerization.

通過(guò)水自由基乳液聚合一步合成可降解乙烯基聚合物基乳膠。

28.Advancing the Development of Recyclable Aromatic Polyesters by Functionalization and Stereocomplexation.

通過(guò)官能化和立體絡(luò)合促進(jìn)可回收芳香族聚酯的開發(fā)。

29.Logical Analysis of Multiple Single-Nucleotide-Polymorphisms with Programmable DNA Molecular Computation for Clinical Diagnostics.

利用可編程 DNA 分子計(jì)算對(duì)多個(gè)單核苷酸多態(tài)性進(jìn)行邏輯分析，用于臨床診斷。

30.Three-Dimensional Crystalline Covalent Triazine Frameworks via a Polycondensation Approach.

通過(guò)縮聚方法形成三維結(jié)晶共價(jià)三嗪框架。

31.Encoding Enantiomeric Molecular Chiralities on Graphene Basal Planes.

在石墨烯基底平面上編碼對(duì)映體分子手性。

32.Local Symmetry Breaking Suppresses Thermal Conductivity in Crystalline Solids.

局部對(duì)稱性破缺抑制晶體固體的導(dǎo)熱性。

33.Pure Boric Acid Does Not Show Room-Temperature Phosphorescence (RTP).

純硼酸不顯示室溫磷光 (RTP)。

34.Rhodium-Catalyzed ON-OFF Switchable Hydrogenation Using a Molecular Shuttle Based on a [2]Rotaxane with a Phosphine Ligand.

使用基于帶有膦配體的[2]輪烷的分子梭進(jìn)行銠催化的ON-OFF可切換氫化。

35.Macrocyclic Polyoxometalates: Selective Polyanion Binding and Ultrahigh Proton Conduction.

大環(huán)多金屬氧酸鹽：選擇性聚陰離子結(jié)合和超高質(zhì)子傳導(dǎo)。

36.Multifunctional Wearable Silver Nanowire Decorated Leather Nanocomposites for Joule Heating, Electromagnetic Interference Shielding and Piezoresistive Sensing.

用于焦耳加熱、電磁干擾屏蔽和壓阻傳感的多功能可穿戴銀納米線裝飾皮革納米復(fù)合材料。

37.Synthesis of Cyclophenacene- and Chiral-Type Cyclophenylene-Naphthylene Belts.

環(huán)苯并苯和手性型環(huán)亞苯基-亞萘基帶的合成。

38.Nickel-Based Metal–Organic Frameworks for Coal-Bed Methane Purification with Record CH4/N2 Selectivity.

用于煤層甲烷凈化的鎳基金屬有機(jī)框架，具有創(chuàng)紀(jì)錄的 CH4/N2 選擇性。

39.Light-Powered Ion Pumping in a Cation-Selective Conducting Polymer Membrane.

陽(yáng)離子選擇性導(dǎo)電聚合物膜中的光動(dòng)力離子泵浦。

40.Wavelength-Orthogonal Stiffening of Hydrogel Networks with Visible Light.

可見光下水凝膠網(wǎng)絡(luò)的波長(zhǎng)正交硬化。

41.Simultaneous Counting of Molecules in the Halo and Dense-Core of Nanovesicles by Regulating Dynamics of Vesicle Opening.

通過(guò)調(diào)節(jié)囊泡打開的動(dòng)力學(xué)來(lái)同時(shí)計(jì)數(shù)納米囊泡的光環(huán)和致密核心中的分子。

42.Frustrated Lewis Pair in Zeolite Cages for Alkane Activations.

沸石籠中用于烷烴活化的失意的劉易斯對(duì)。

43.Microscopic Mechanism of the Heat-Induced Blueshift in Phosphors and a Logarithmic Energy Dependence on the Nearest Dopant–Vacancy Distance.

熒光粉中熱致藍(lán)移的微觀機(jī)制以及對(duì)最近摻雜劑-空位距離的對(duì)數(shù)能量依賴性。

44.Enantioselective Synthesis of Tertiary β-Boryl Amides by Conjunctive Cross-Coupling of Alkenyl Boronates and Carbamoyl Chlorides.

通過(guò)鏈烯基硼酸酯和氨基甲酰氯的聯(lián)合交叉偶聯(lián)對(duì)映選擇性合成叔 β-硼酰胺。

45.Crystalline Neutral Diboron Analogues of Cyclopropanes.

環(huán)丙烷的結(jié)晶中性二硼類似物。

46.Reactive Extrusion Printing for Simultaneous Crystallization-Deposition of Metal–Organic Framework Films.

用于同時(shí)結(jié)晶沉積金屬有機(jī)框架薄膜的反應(yīng)擠出印刷。

47.Supported Lanthanum Borohydride Catalyzes CH Borylation Inside Zeolite Micropores.

負(fù)載型硼氫化鑭催化沸石微孔內(nèi)的 CH 硼化。

48.NHC Catalysis for Umpolung Pyridinium Alkylation via Deoxy-Breslow Intermediates.

NHC 通過(guò) Deoxy-Breslow 中間體催化 Umpolung 吡啶烷基化。

49.Enantioselective Recognition of Helicenes by a Tailored Chiral Benzo[ghi]perylene Trisimide π-Scaffold.

通過(guò)定制的手性苯并苝三酰亞胺π-支架對(duì)螺旋烯進(jìn)行對(duì)映選擇性識(shí)別。

50.On-Surface Synthesis of [3]Radialenes via [1+1+1] Cycloaddition.

通過(guò)[1+1+1]環(huán)加成在表面合成[3]Radialenes。

51.A Calix[3]acridan-Based Host–Guest Cocrystal Exhibiting Efficient Thermally Activated Delayed Fluorescence.

基于 Calix[3] 吖啶丹的主客體共晶表現(xiàn)出高效的熱激活延遲熒光。

52.Access to a Labile Monomeric Magnesium Radical by Ball-Milling.

通過(guò)球磨獲得不穩(wěn)定的單體鎂自由基。

53.Photo-Imprinting of the Helical Organization in Liquid-Crystal Networks Using Achiral Monomers and Circularly Polarized Light.

使用非手性單體和圓偏振光對(duì)液晶網(wǎng)絡(luò)中的螺旋組織進(jìn)行光壓印。

54.The DNA damage response , which includes DNA repair and cell cycle checkpoint pathways in cancer cells, has been considered one of the main impediments to traditional chemotherapy. In their Research Article (e202117075), Na Kong, Xingcai Zhang, Wei Tao, Jong?Seung Kim, and co-workers developed a multifunctional construct, M1, to target the DNA damage response of cancer cells. The findings identified a critical role of DNA damage repair pathways during 5-FU/FUDR therapy and underscore the role of inhibition of these pathways in sensitizing cancer cells to chemotherapeutics.

DNA損傷反應(yīng)，包括癌細(xì)胞中的DNA修復(fù)和細(xì)胞周期檢查點(diǎn)途徑，被認(rèn)為是傳統(tǒng)化療的主要障礙之一。在他們的研究文章 (e202117075) 中，Na Kong、Xingcai Zhu、Wei Tao、Jong Seung Kim 及其同事開發(fā)了一種多功能結(jié)構(gòu) M1，以靶向癌細(xì)胞的 DNA 損傷反應(yīng)。研究結(jié)果確定了 DNA 損傷修復(fù)途徑在 5-FU/FUDR 治療過(guò)程中的關(guān)鍵作用，并強(qiáng)調(diào)了抑制這些途徑在使癌細(xì)胞對(duì)化療藥物敏感方面的作用。

55.Chalcogen bonding (ChB) is a type of σ-hole interaction between a Group?16 chalcogen atom bearing electron-withdrawing groups and a Lewis base. In their Research Article (e202116071), Xiang-Yu Chen, Zhi-Xiang Wang, and co-workers show that ChB of alkynyl sulfonium salts enables the generation of alkynyl radicals for the synthesis of a variety of chalcogenoacetylenes with diselenides under blue-light irradiation.

硫族鍵合 (ChB) 是帶有吸電子基團(tuán)的第 16 族硫族原子與路易斯堿之間的一種 σ-空穴相互作用。在他們的研究文章 (e202116071) 中，Xiang-Yu Chen、Zhi-Xiang Wang 及其同事表明，炔基锍鹽的 ChB 能夠在藍(lán)光照射下產(chǎn)生炔基自由基，用于與二硒化物合成各種硫?qū)僖胰病?/p>

56.The enzymatic synthesis of eight luciferin analogues from phenolic derivatives in one-pot reactions is reported by Pimchai Chaiyen and co-workers in their Research Article (e202116908). Two novel D-luciferin analogues with methyl substituents were obtained; these compounds emit red and brighter light than the native D-luciferin. A new detection technology named LUMOS was also developed for in?situ detection of organophosphate pesticides (OPs), including parathion, methyl parathion, EPN, profenofos, and fenitrothion, at parts per trillion (ppt) levels without requiring sample pretreatment.

Pimchai Chaiyen 及其同事在他們的研究文章 (e202116908) 中報(bào)道了在一鍋反應(yīng)中從酚衍生物酶促合成八種熒光素類似物。獲得了兩種新型的帶有甲基取代基的D-熒光素類似物；這些化合物發(fā)出比天然 D-熒光素更亮的紅光。還開發(fā)了一種名為 LUMOS 的新檢測(cè)技術(shù)，用于原位檢測(cè)萬(wàn)億分之一 (ppt) 水平的有機(jī)磷農(nóng)藥 (OP)，包括對(duì)硫磷、甲基對(duì)硫磷、EPN、丙溴磷和殺螟松，無(wú)需樣品預(yù)處理。

57.Defect-free alternating conjugated polymers were produced by exploring palladium-catalyzed Stille polymerization at room temperature. The selected copolymers demonstrated no homocoupling defects and superior charge transport properties, thus paving the road for the development of plastic electronics. Details of this study are reported by Qinqin Shi, Hui Huang, and co-workers in their Research Article (e202115969).

通過(guò)探索室溫下鈀催化的 Stille 聚合反應(yīng)，制備了無(wú)缺陷的交替共軛聚合物。所選共聚物沒有表現(xiàn)出自偶聯(lián)缺陷和優(yōu)異的電荷傳輸性能，從而為塑料電子產(chǎn)品的發(fā)展鋪平了道路。這項(xiàng)研究的詳細(xì)信息由史勤勤、黃輝及其同事在他們的研究文章 (e202115969) 中報(bào)告。

58.Magnetic Materials In their Communication (e202117084), Qun Xu et?al. report on the CO2-induced exposure of the intrinsic magnetic surface of BaTiO3 to give room-temperature ferromagnetism.

通信中的磁性材料 (e202117084)，Qun Xu 等人。關(guān)于 CO2 誘導(dǎo) BaTiO3 固有磁性表面暴露以產(chǎn)生室溫鐵磁性的報(bào)告。

59.Light Harvesting In their Research Article (e202200466), Xu-Man Chen, Hong Yang, Quan Li et?al. report an artificial light-harvesting system with controllable efficiency enabled by an annulene-based anisotropic fluid.

光采集 在他們的研究文章 (e202200466) 中，Xu-Man Chen、Hong Yang、Quan Li 等人。報(bào)告了一種由基于輪烯的各向異性流體實(shí)現(xiàn)的具有可控效率的人工光采集系統(tǒng)。

60.Synthetic Cells: From Simple Bio-Inspired Modules to Sophisticated Integrated Systems.

合成細(xì)胞：從簡(jiǎn)單的仿生模塊到復(fù)雜的集成系統(tǒng)。

61.Unraveling Charge-Separation Mechanisms in Photocatalyst Particles by Spatially Resolved Surface Photovoltage Techniques.

通過(guò)空間分辨表面光電壓技術(shù)揭示光催化劑顆粒中的電荷分離機(jī)制。

62.An Artificial Light-Harvesting System with Controllable Efficiency Enabled by an Annulene-Based Anisotropic Fluid.

由基于輪烯的各向異性流體實(shí)現(xiàn)的具有可控效率的人工光采集系統(tǒng)。

63.Topochemical Synthesis of a Heterochiral Peptide Polymer in Different Polymorphic Forms from Crystals and Aerogels.

從晶體和氣凝膠中拓?fù)浠瘜W(xué)合成不同多晶型的異手性肽聚合物。

64.A Polymeric Nanobeacon for Monitoring the Fluctuation of Hydrogen Polysulfides during Fertilization and Embryonic Development.

用于監(jiān)測(cè)受精和胚胎發(fā)育過(guò)程中多硫化氫波動(dòng)的聚合物納米信標(biāo)。

65.Cation-Tuning Induced d-Band Center Modulation on Co-Based Spinel Oxide for Oxygen Reduction/Evolution Reaction.

陽(yáng)離子調(diào)諧誘導(dǎo)鈷基尖晶石氧化物的 d 帶中心調(diào)制，用于氧還原/放出反應(yīng)。

66.Support-Free PEDOT:PSS Fibers as Multifunctional Microelectrodes for In Vivo Neural Recording and Modulation.

無(wú)支撐 PEDOT:PSS 纖維作為多功能微電極，用于體內(nèi)神經(jīng)記錄和調(diào)制。

67.DNA-Damage-Response-Targeting Mitochondria-Activated Multifunctional Prodrug Strategy for Self-Defensive Tumor Therapy.

用于自我防御腫瘤治療的 DNA 損傷反應(yīng)靶向線粒體激活多功能前藥策略。

68.Biomimetic FeMo(Se, Te) as Joint Electron Pool Promoting Nitrogen Electrofixation.

仿生 FeMo(Se, Te) 作為聯(lián)合電子池促進(jìn)氮電固定。

69.Ferroptosis-Enhanced Cancer Immunity by a Ferrocene-Appended Iridium(III) Diphosphine Complex.

通過(guò)添加二茂鐵的銥 (III) 二膦復(fù)合物來(lái)增強(qiáng)鐵死亡增強(qiáng)的癌癥免疫力。

70.Multicolour Fluorescence Based on Excitation-Dependent Electron Transfer Processes in o-Carborane Dyads.

基于鄰碳硼烷二元組中激發(fā)依賴的電子轉(zhuǎn)移過(guò)程的多色熒光。

71.Tuning Bulk O2 and Nonbonding Oxygen State for Reversible Anionic Redox Chemistry in P2-Layered Cathodes.

調(diào)節(jié) P2 層陰極中的本體 O2 和非鍵合氧狀態(tài)以實(shí)現(xiàn)可逆陰離子氧化還原化學(xué)。

72.Intercalation-Activated Layered MoO3 Nanobelts as Biodegradable Nanozymes for Tumor-Specific Photo-Enhanced Catalytic Therapy.

插層激活的層狀 MoO3 納米帶作為可生物降解的納米酶，用于腫瘤特異性光增強(qiáng)催化治療。

73.Controlled Disassembly of Elemental Sulfur: An Approach to the Precise Synthesis of Polydisulfides.

元素硫的受控分解：聚二硫醚的精確合成方法。

74.Defect-Free Alternating Conjugated Polymers Enabled by Room- Temperature Stille Polymerization.

通過(guò)室溫靜聚合實(shí)現(xiàn)的無(wú)缺陷交替共軛聚合物。

75.Alkynyl Sulfonium Salts Can Be Employed as Chalcogen-Bonding Catalysts and Generate Alkynyl Radicals under Blue-Light Irradiation.

炔基锍鹽可用作硫族鍵合催化劑并在藍(lán)光照射下產(chǎn)生炔基自由基。

76.Phosphorogenic Iridium(III) bis-Tetrazine Complexes for Bioorthogonal Peptide Stapling, Bioimaging, Photocytotoxic Applications, and the Construction of Nanosized Hydrogels.

用于生物正交肽縫合、生物成像、光細(xì)胞毒性應(yīng)用和納米水凝膠構(gòu)建的發(fā)磷銥 (III) 雙四嗪復(fù)合物。

77.Visible-Light-Driven Photocatalytic CO2 Reduction to CO/CH4 Using a Metal–Organic “Soft” Coordination Polymer Gel.

使用金屬有機(jī)“軟”配位聚合物凝膠，可見光驅(qū)動(dòng)光催化 CO2 還原為 CO/CH4。

78.Enantioselective Total Synthesis of Hyperforin and Pyrohyperforin.

金絲桃素和焦金絲桃素的對(duì)映選擇性全合成。

79.Luciferin Synthesis and Pesticide Detection by Luminescence Enzymatic Cascades.

熒光素合成和發(fā)光酶級(jí)聯(lián)檢測(cè)農(nóng)藥。

80.Double Lock Label Based on Thermosensitive Polymer Hydrogels for Information Camouflage and Multilevel Encryption.

基于熱敏聚合物水凝膠的雙鎖標(biāo)簽，用于信息偽裝和多級(jí)加密。

81.Unprecedented and Readily Tunable Photoluminescence from Aliphatic Quaternary Ammonium Salts.

脂肪族季銨鹽產(chǎn)生前所未有的且易于調(diào)節(jié)的光致發(fā)光。

82.Coloration in Supraparticles Assembled from Polyhedral Metal-Organic Framework Particles.

由多面體金屬有機(jī)框架顆粒組裝而成的超顆粒的著色。

83.Unmasking the Critical Role of the Ordering Degree of Bimetallic Nanocatalysts on Oxygen Reduction Reaction by In Situ Raman Spectroscopy.

通過(guò)原位拉曼光譜揭示雙金屬納米催化劑有序度對(duì)氧還原反應(yīng)的關(guān)鍵作用。

84.A “Self-Checking” pH/Viscosity-Activatable NIR-II Molecule for Real-Time Evaluation of Photothermal Therapy Efficacy.

用于實(shí)時(shí)評(píng)估光熱治療功效的“自檢”pH/粘度可激活 NIR-II 分子。

85.Chemical Defect-Driven Response on Graphene-Based Chemiresistors for Sub-ppm Ammonia Detection.

用于亞 ppm 氨檢測(cè)的石墨烯化學(xué)電阻的化學(xué)缺陷驅(qū)動(dòng)響應(yīng)。

86.Chemoselective Transamidation of Thioamides by Transition-Metal-Free N?C(S) Transacylation.

通過(guò)無(wú)過(guò)渡金屬的 N?C(S) 轉(zhuǎn)?；瘜?duì)硫代酰胺進(jìn)行化學(xué)選擇性轉(zhuǎn)酰胺基化。

87.Molecular-Level Insights into the Notorious CO Poisoning of Platinum Catalyst.

對(duì)鉑催化劑臭名昭著的一氧化碳中毒的分子水平洞察。

88.Streamline Sulfur Redox Reactions to Achieve Efficient Room-Temperature Sodium–Sulfur Batteries.

簡(jiǎn)化硫氧化還原反應(yīng)以實(shí)現(xiàn)高效的室溫鈉硫電池。

89.Overturned Loading of Inert CeO2 to Active Co3O4 for Unusually Improved Catalytic Activity in Fenton-Like Reactions.

將惰性 CeO2 翻轉(zhuǎn)到活性 Co3O4 上，以顯著提高類芬頓反應(yīng)中的催化活性。

90.Extraordinary p–d Hybridization Interaction in Heterostructural Pd-PdSe Nanosheets Boosts C?C Bond Cleavage of Ethylene Glycol Electrooxidation.

異質(zhì)結(jié)構(gòu) Pd-PdSe 納米片中非凡的 p-d 雜化相互作用促進(jìn)乙二醇電氧化的 C?C 鍵斷裂。

91.Engineering MoOx/MXene Hole Transfer Layers for Unexpected Boosting of Photoelectrochemical Water Oxidation.

工程化 MoOx/MXene 空穴傳輸層可意外促進(jìn)光電化學(xué)水氧化。

92.Alkylgold(III) Complexes Undergo Unprecedented Photo-Induced β-Hydride Elimination and Reduction for Targeted Cancer Therapy.

烷基金 (III) 配合物經(jīng)歷前所未有的光誘導(dǎo) β-氫化物消除和還原，用于靶向癌癥治療。

93.Rapid and Controlled Polymerization of Bio-sourced δ-Caprolactone toward Fully Recyclable Polyesters and Thermoplastic Elastomers.

生物來(lái)源的 δ-己內(nèi)酯快速、受控聚合成完全可回收的聚酯和熱塑性彈性體。

94.Inverse Vulcanization of Norbornenylsilanes: Soluble Polymers with Controllable Molecular Properties via Siloxane Bonds.

降冰片烯基硅烷的逆硫化：通過(guò)硅氧烷鍵具有可控分子性質(zhì)的可溶性聚合物。

95.Combining a Genetically Engineered Oxidase with Hydrogen-Bonded Organic Frameworks (HOFs) for Highly Efficient Biocomposites.

將基因工程氧化酶與氫鍵有機(jī)框架 (HOF) 相結(jié)合，打造高效生物復(fù)合材料。

96.CO2-Induced Exposure of the Intrinsic Magnetic Surface of BaTiO3 to Give Room-Temperature Ferromagnetism.

CO2 誘導(dǎo) BaTiO3 固有磁性表面的暴露以產(chǎn)生室溫鐵磁性。

97.Exploring Unconventional SAM Analogues To Build Cell-Potent Bisubstrate Inhibitors for Nicotinamide N-Methyltransferase.

探索非常規(guī) SAM 類似物來(lái)構(gòu)建煙酰胺 N-甲基轉(zhuǎn)移酶的細(xì)胞強(qiáng)效雙底物抑制劑。

98.Site-Directed Chemical Modification of Amyloid by Polyoxometalates for Inhibition of Protein Misfolding and Aggregation.

通過(guò)多金屬氧酸鹽對(duì)淀粉樣蛋白進(jìn)行定點(diǎn)化學(xué)修飾，以抑制蛋白質(zhì)錯(cuò)誤折疊和聚集。

99.Oriented Nanoarchitectonics of Bacteriorhodopsin for Enhancing ATP Generation in a FoF1-ATPase-Based Assembly System.

用于增強(qiáng)基于 FoF1-ATPase 的組裝系統(tǒng)中 ATP 生成的細(xì)菌視紫紅質(zhì)定向納米結(jié)構(gòu)。

100.Synthesis of a π-Extended Azacorannulenophane Enabled by Strain-Induced 1,3-Dipolar Cycloaddition.

通過(guò)應(yīng)變誘導(dǎo) 1,3-偶極環(huán)加成合成 π-擴(kuò)展氮雜環(huán)烯芬烷。

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