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【標題速讀】【JACS】【2022年】【7月】

2023-06-09 11:07 作者:Rt_Cola 0人讀過 | 我要投稿

聲明：本專欄主要對生命科學(xué)領(lǐng)域的一些期刊文章標題進行翻譯，所有內(nèi)容均由本人手工整理翻譯。由于本人專業(yè)為生物分析相關(guān)，其他領(lǐng)域如果出現(xiàn)翻譯錯誤請諒解。

A ligand-controlled, switchable skeletal rearrangement has been developed. This method allows site-selective activation and reorganization of C–C bonds (C–Ar bond and C–(C=O)) and has been applied for the divergent synthesis of four medicinally relevant fluorine-containing scaffolds from the same starting material. Experimental and DFT calculation studies prove this rational design.

已開發(fā)出配體控制的可切換骨骼重排。該方法允許 C-C 鍵（C-Ar 鍵和 C-(C=O)）的位點選擇性激活和重組，并已應(yīng)用于從相同的起始材料出發(fā)合成四種具有藥用價值的含氟支架。實驗和 DFT 計算研究證明了這種合理的設(shè)計。

Reach for the stars. As cut-outs from a graphene sheet, nanographenes (NGs) and graphene nanoribbons (GNRs) are promising materials with versatile properties and functions, ranging from stimulated emission to spintronics, and from bioimaging to energy storage. NGs and GNRs are therefore multitalents in present and future materials science.

伸手摘星。作為石墨烯片的切口，納米石墨烯 (NGs) 和石墨烯納米帶 (GNRs) 是具有多種特性和功能的有前途的材料，從受激發(fā)射到自旋電子學(xué)，從生物成像到能量存儲。因此，NG 和 GNR 在現(xiàn)在和未來的材料科學(xué)中都是多面手。

Adsorption of AlCl3, Al(CH3)2Cl, Al(C2H5)3, and Al(CH3)3 on SiO2. Carbon: Black; Hydrogen: White; Chlorine: Orange; Aluminum: Green; Oxygen: Red; Si: Gray.

AlCl3、Al(CH3)2Cl、Al(C2H5)3 和 Al(CH3)3 在 SiO2 上的吸附。碳黑; 氫氣：白色；氯氣：橙色；鋁：綠色；氧氣：紅色； Si：灰色。

A fluorinated amphiphilic cyclophane composed of fluorinated rigid aromatic units connected via flexible hydrophilic octa(ethylene glycol) chains formed a supramolecular mechanosensitive potassium channel in lipid bilayer membranes.

由通過柔性親水八（乙二醇）鏈連接的氟化剛性芳族單元組成的氟化兩親環(huán)芳在脂質(zhì)雙層膜中形成超分子機械敏感鉀通道。

The triple-wavelength laser operating near 1060 nm presents numerous challenges and opportunities in the field of optoelectronics. Using crystals of the high temperature phase of Nd3+-doped LaBSiO5, triple-wavelength lasing has been obtained. The Nd3+ doping not only makes the crystal optically active but also suppresses the phase transition.

工作在 1060 nm 附近的三波長激光器在光電子領(lǐng)域提出了許多挑戰(zhàn)和機遇。使用 Nd3+ 摻雜的 LaBSiO5 的高溫相晶體，獲得了三波長激光。 Nd3+摻雜不僅使晶體具有光學(xué)活性，而且抑制了相變。

Relief of anti-aromaticity drives reductive dehydrogenative cyclizations that transform helicenes into polycyclic anionic graphene subunits. The anionic cyclopentadienyl moiety controls the position of a localized anti-aromatic hot-spot where the cyclization is initiated after an additional negative charge is injected.

反芳香性的解除驅(qū)動還原性脫氫環(huán)化，將螺旋烯轉(zhuǎn)化為多環(huán)陰離子石墨烯亞基。陰離子環(huán)戊二烯基部分控制局部反芳香熱點的位置，在注入額外的負電荷后環(huán)化開始。

Three-dimensionally frustrated magnets generally exist in the magnetic diamond and pyrochlore lattices, in which quantum fluctuations suppress magnetic orders and generate highly entangled ground states. A previously unreported pyrochlore lattice was reported here in LiYbSe2.

三維受抑磁體通常存在于磁性金剛石和燒綠石晶格中，其中量子漲落抑制磁序并產(chǎn)生高度糾纏的基態(tài)。在 LiYbSe2 中報道了以前未報道的燒綠石晶格。

The green rust material, a layered iron hydroxide with inserted sulfate anions in the interlayer regions, can assist electrochemical conversion between ferrous hydroxide (Fe II) and iron oxyhydroxide (Fe III). This finding could help repurpose iron rust wastes and revitalize century-old iron alkaline battery chemistry for modern grid-scale energy storage.

綠銹材料是一種層狀氫氧化鐵，在層間區(qū)域插入了硫酸根陰離子，可以促進氫氧化亞鐵 (Fe II) 和氫氧化鐵 (Fe III) 之間的電化學(xué)轉(zhuǎn)化。這一發(fā)現(xiàn)可能有助于重新利用鐵銹廢物，并重振具有百年歷史的堿性鐵電池化學(xué)，用于現(xiàn)代電網(wǎng)規(guī)模的儲能。

The internal space of the mesoporous MCM-41 support, which is exempt from plasma discharge, can provide “shielding protection” for the formed NH3, thus limiting the reverse reaction (i.e., ammonia decomposition) and shifting the reaction equilibrium to enhance plasma-catalytic NH3 production.

介孔 MCM-41 載體的內(nèi)部空間不受等離子體放電的影響，可以為形成的 NH3 提供“屏蔽保護”，從而限制逆反應(yīng)（即氨分解）并改變反應(yīng)平衡以增強等離子體催化 NH3 的產(chǎn)生。

Our study describes the controlled self-assembly of platinum(II) peptides into NIR-emitting nanofibers within cells and details the systemic level shutdown on metabolic functions, including glycolysis and oxidative phosphorylation. The resulting ATP deprivation led to the disruption of actin assembly and HDAC activity, initiating cell-line-independent apoptotic pathways.

我們的研究描述了鉑 (II) 肽在細胞內(nèi)受控自組裝成 NIR 發(fā)射納米纖維，并詳細介紹了代謝功能的系統(tǒng)水平關(guān)閉，包括糖酵解和氧化磷酸化。由此產(chǎn)生的 ATP 剝奪導(dǎo)致肌動蛋白組裝和 HDAC 活性的破壞，從而啟動細胞系非依賴性凋亡途徑。

A simple universal descriptor (i.e., φ = χM + Σχx + Nd/p) based on the inherent atomic properties (electronegativity (χ), electron type, and number (N)) has been proposed, which can well evaluate the complicated interfacial effects on electrochemical reduction reactions (i.e., CO2, O2, and N2 reduction reactions).

提出了一種基于固有原子性質(zhì)（電負性 (χ)、電子類型和數(shù)量 (N)）的簡單通用描述符（即 φ = χM + Σχx + Nd/p），可以很好地評估復(fù)雜的界面效應(yīng) 關(guān)于電化學(xué)還原反應(yīng)（即 CO2、O2 和 N2 還原反應(yīng)）。

The cover image depicts the catalytic activity of fluorescent nanodiamond (ND), which promotes the decomposition of H2O2 while detecting the generated intermediate radicals by utilizing its quantum property. We demonstrate the first application of fluorescent ND as a sensor for H2O2 with sensitivity at the molecular level and spatial resolution at the nanoscale.

封面圖片描繪了熒光納米金剛石 (ND) 的催化活性，它促進 H2O2 的分解，同時利用其量子特性檢測生成的中間自由基。我們展示了熒光 ND 作為 H2O2 傳感器的首次應(yīng)用，具有分子水平的靈敏度和納米級的空間分辨率。

Oxygen-inserted two atomic-layer Ni shell modified Ni metal core nanoparticle (Ni@Oi-Ni) with optimized OH binding energy was prepared, which shows remarkable alkaline hydrogen oxidation reaction (HOR) performance. This work identifies the key role of OH binding strength in alkaline HOR.

制備了具有優(yōu)化的 OH 結(jié)合能的氧插入兩原子層 Ni 殼改性 Ni 金屬核納米粒子 (Ni@Oi-Ni)，該納米粒子具有顯著的堿性氫氧化反應(yīng) (HOR) 性能。這項工作確定了 OH 結(jié)合強度在堿性 HOR 中的關(guān)鍵作用。

Dihydropyrenes with Au surface anchoring groups were synthesized in a stepwise manner by alkylation of a functionalized dimethylisophthalate, macrocylization, sulfur extrusion, and further modification. Switching capabilities were assessed by light irradiation and electrochemically, and charge transport through single molecules has been studied with the STM break junction technique.

通過官能化間苯二甲酸二甲酯的烷基化、大環(huán)化、硫擠出和進一步改性，逐步合成了具有 Au 表面錨定基團的二氫芘。通過光照射和電化學(xué)評估開關(guān)能力，并使用 STM 斷裂連接技術(shù)研究了通過單分子的電荷傳輸。

On-surface synthesis of one-dimensional porphyrinoid polymers, covalently linked through a [3 + 3] cycloaromatization via isopropyl substituents, reveals an antiferromagnetic coupling between the two closer spins from adjacent porphyrinoid units, highlighting the relevance of the π-conjugation in the correlations between spins.

一維類卟啉聚合物的表面合成，通過異丙基取代基通過 [3 + 3] 環(huán)芳構(gòu)化共價連接，揭示了來自相鄰類卟啉單元的兩個更近的自旋之間的反鐵磁耦合，突出了 π 共軛和自旋之間的相關(guān)性。

Design of a unique nanoruler with a ~7 ? spatial resolution, which is based on a two-dimensional atomic crystal where four layers of MoS2 are a reference layer and the monolayer WS2 is a SERS probe intercalated in different layers in a nanocavity to precisely, quantitatively, and directionally probe the longitudinal plasmonic field strength.

設(shè)計具有約 7 ? 空間分辨率的獨特納米尺，它基于二維原子晶體，其中四層 MoS2 是參考層，單層 WS2 是嵌入納米腔不同層中的 SERS 探針，以精確地，定量地、定向地探測縱向等離子體場強。

Synergistic stimulus of vapor hydration and thermal dehydration introduce a molecular level disturbance from the metal node to the whole framework, which facilitates structural disorders for formation of stable supercooled liquid and quenched glass. The method provides a fundamentally new route to acquire glassy materials from MOFs that cannot be melted without causing decomposition.

蒸汽水合和熱脫水的協(xié)同刺激從金屬節(jié)點到整個框架引入了分子水平的擾動，這促進了結(jié)構(gòu)紊亂以形成穩(wěn)定的過冷液體和淬火玻璃。該方法提供了一種從 MOF 中獲取玻璃狀材料的全新途徑，這種材料在不引起分解的情況下無法熔化。

Targeting the SARS-CoV-2 multispike trimers, an icosahedral DNA framework with 30 precisely positioned neutralizing aptamers has been developed to inhibit viral infection. Leveraging multivalent topologically patterned neutralizing aptamers and framework-introduced steric hindrance, we achieved excellent and broad neutralization against SARS-CoV-2 and its variants.

針對 SARS-CoV-2 多刺三聚體，開發(fā)了具有 30 個精確定位的中和適配體的二十面體 DNA 框架來抑制病毒感染。利用多價拓撲圖案中和適體和框架引入的空間位阻，我們實現(xiàn)了對 SARS-CoV-2 及其變體的出色而廣泛的中和。

Photoactivatable materials for cell anchoring has been developed based on a poly(ethylene glycol) lipids. On the material-coated surface, cells can be selectively anchored onto light-irradiated areas where the nanoscale structures of dual-chain lipids are disassembled through photocleavage of one lipid. This surface has achieved single-cell pair arrays for cell–cell communication analysis.

基于聚乙二醇脂質(zhì)開發(fā)了用于細胞錨定的光活化材料。在材料涂層表面，細胞可以選擇性地錨定在光照射區(qū)域，雙鏈脂質(zhì)的納米級結(jié)構(gòu)通過一種脂質(zhì)的光裂解被分解。該表面已經(jīng)實現(xiàn)了用于細胞間通訊分析的單細胞對陣列。

Coordination of three Yb complexes to a central Ru core affords a heterotetranuclear assembly which, upon excitation into the NIR absorption of Yb, displays upconverted red emission of the central Ru atom, affording the first example of cooperative luminescence upconversion in a d–f complex at the molecular scale in solution.

三個 Yb 配合物與中心 Ru 核的配位提供了異四核組裝，在激發(fā)到 Yb 的 NIR 吸收后，顯示出中心 Ru 原子的上轉(zhuǎn)換紅色發(fā)射，提供了 d-f 復(fù)合物中協(xié)同發(fā)光上轉(zhuǎn)換的第一個例子溶液中的分子尺度。

1.Hydroaminoalkylation for the Catalytic Addition of Amines to Alkenes or Alkynes: Diverse Mechanisms Enable Diverse Substrate Scope.

用于胺催化加成烯烴或炔烴的加氫氨基烷基化：不同的機制使不同的底物范圍成為可能。

2.Landscaping Covalent Organic Framework Nanomorphologies.

美化共價有機骨架納米形態(tài)。

3.Nanographenes and Graphene Nanoribbons as Multitalents of Present and Future Materials Science.

納米石墨烯和石墨烯納米帶作為現(xiàn)在和未來材料科學(xué)的多面手。

4.Continuous-Flow Reactor Synthesis for Homogeneous 1 nm-Sized Extremely Small High-Entropy Alloy Nanoparticles.

均勻 1 nm 尺寸的極小高熵合金納米粒子的連續(xù)流動反應(yīng)器合成。

5.Oxygen Vacancy-Mediated Selective C–N Coupling toward Electrocatalytic Urea Synthesis.

氧空位介導(dǎo)的選擇性 C-N 偶聯(lián)用于電催化尿素合成。

6.Iron-Sensitive Prodrugs That Trigger Active Ferroptosis in Drug-Tolerant Pancreatic Cancer Cells.

在耐藥性胰腺癌細胞中觸發(fā)活性鐵死亡的鐵敏感前藥。

7.Copper-Catalyzed Stereospecific Transformations of Alkylboronic Esters.

銅催化的烷基硼酸酯的立體有擇轉(zhuǎn)化。

8.Inherent Minor Conformer of Bordetella Effector BteA Directs Chaperone-Mediated Unfolding.

博德特氏菌效應(yīng)子 BteA 的固有次要構(gòu)象指導(dǎo)伴侶介導(dǎo)的展開。

9.Conformational Flexibility as a Tool for Enabling Site-Selective Functionalization of Unactivated sp3 C–O Bonds in Cyclic Acetals.

構(gòu)象靈活性作為使環(huán)狀縮醛中未激活的 sp3 C-O 鍵實現(xiàn)位點選擇性功能化的工具。

10.Selective ortho-C–H Activation in Arenes without Functional Groups.

沒有官能團的芳烴中的選擇性鄰位 C-H 激活。

11.Photoswitching Behavior of Flavin–Inhibitor Complex in a Nonphotocatalytic Flavoenzyme.

非光催化黃素酶中黃素抑制劑復(fù)合物的光開關(guān)行為。

12.Biogenesis-Inspired, Divergent Synthesis of Spirochensilide A, Spirochensilide B, and Abifarine B Employing a Radical-Polar Crossover Rearrangement Strategy.

Spirochensilide A、Spirochensilide B 和 Abifarine B 的受生物發(fā)生啟發(fā)的發(fā)散合成，采用自由基-極性交叉重排策略。

13.The Biosynthetic Landscape of Triceptides Reveals Radical SAM Enzymes That Catalyze Cyclophane Formation on Tyr- and His-Containing Motifs.

Triceptides 的生物合成景觀揭示了在含 Tyr 和 His 的基序上催化環(huán)硫醚形成的自由基 SAM 酶。

14.Chromium Nitride Umpolung Tuned by the Locus of Oxidation.

由氧化位點調(diào)整的氮化鉻 Umpolung。

15.Selective Isotope Labeling and LC-Photo-CIDNP Enable NMR Spectroscopy at Low-Nanomolar Concentration.

選擇性同位素標記和 LC-Photo-CIDNP 使核磁共振光譜在低納摩爾濃度下成為可能。

16.Transcriptome-Wide Mapping of Small-Molecule RNA-Binding Sites in Cells Informs an Isoform-Specific Degrader of QSOX1 mRNA.

細胞中小分子 RNA 結(jié)合位點的全轉(zhuǎn)錄組圖譜顯示 QSOX1 mRNA 的異構(gòu)體特異性降解劑。

17.Switchable 1,2-Rearrangement Enables Expedient Synthesis of Structurally Diverse Fluorine-Containing Scaffolds.

可切換的 1,2-重排可以方便地合成結(jié)構(gòu)多樣的含氟支架。

18.Anisotropic Molecular Organization at a Liquid/Vapor Interface Promotes Crystal Nucleation with Polymorph Selection.

液體/蒸汽界面處的各向異性分子組織通過多晶型選擇促進晶體成核。

19.Recycling of Solvent Allows for Multiple Rounds of Reproducible Nanoparticle Synthesis.

溶劑的回收允許多輪可重復(fù)的納米粒子合成。

20.Templating Bicarbonate in the Second Coordination Sphere Enhances Electrochemical CO2 Reduction Catalyzed by Iron Porphyrins.

在第二配位層中模板化碳酸氫鹽可增強鐵卟啉催化的電化學(xué) CO2 還原。

21.Understanding the Impacts of Support–Polymer Interactions on the Dynamics of Poly(ethyleneimine) Confined in Mesoporous SBA-15.

了解支撐-聚合物相互作用對限制在介孔 SBA-15 中的聚（乙烯亞胺）動力學(xué)的影響。

22.An Artificial Metalloenzyme Based on a Copper Heteroscorpionate Enables sp3 C–H Functionalization via Intramolecular Carbene Insertion.

基于異蝎酸銅的人工金屬酶通過分子內(nèi)卡賓插入實現(xiàn) sp3 C-H 功能化。

23.REVEALR-Based Genotyping of SARS-CoV-2 Variants of Concern in Clinical Samples.

基于 REVEALR 的臨床樣本中關(guān)注的 SARS-CoV-2 變異體的基因分型。

24.Rectified and Salt Concentration Dependent Wetting of Hydrophobic Nanopores.

疏水性納米孔的整流和鹽濃度依賴性潤濕。

25.Palladium Mediated Synthesis of Protein–Polyarene Conjugates.

鈀介導(dǎo)的蛋白質(zhì)-聚芳烴偶聯(lián)物的合成。

26.Automated Rational Design of Metal–Organic Polyhedra.

金屬有機多面體的自動化合理設(shè)計。

27.Intrinsically Re-curable Photopolymers Containing Dynamic Thiol-Michael Bonds.

含有動態(tài)硫醇-邁克爾鍵的本征可再固化光聚合物。

28.Reversible Structural Isomerization of Nature’s Water Oxidation Catalyst Prior to O–O Bond Formation.

天然水氧化催化劑在 O-O 鍵形成之前的可逆結(jié)構(gòu)異構(gòu)化。

29.Ultramicroporous Organophosphorus Polymers via Self-Accelerating P–C Coupling Reactions: Kinetic Effects on Crosslinking Environments and Porous Structures.

通過自加速 P-C 偶聯(lián)反應(yīng)制備超微孔有機磷聚合物：對交聯(lián)環(huán)境和多孔結(jié)構(gòu)的動力學(xué)影響。

30.Elucidating the Reaction Mechanism of Atomic Layer Deposition of Al2O3 with a Series of Al(CH3)xCl3–x and Al(CyH2y+1)3 Precursors.

用一系列 Al(CH3)xCl3–x 和 Al(CyH2y+1)3 前體闡明 Al2O3 原子層沉積的反應(yīng)機理。

31.Constructing Unique Mesoporous Carbon Superstructures via Monomicelle Interface Confined Assembly.

通過單膠束界面限制組裝構(gòu)建獨特的介孔碳超結(jié)構(gòu)。

32.Potential Difference-Modulated Synthesis of Self-Standing Covalent Organic Framework Membranes at Liquid/Liquid Interfaces.

液/液界面自支撐共價有機骨架膜的電位差調(diào)制合成。

33.Cascade C–H-Activated Polyannulations toward Ring-Fused Heteroaromatic Polymers for Intracellular pH Mapping and Cancer Cell Killing.

級聯(lián) C–H 激活聚環(huán)化反應(yīng)形成用于細胞內(nèi) pH 分布和癌細胞殺傷的環(huán)稠合雜芳烴聚合物。

34.Supramolecular Mechanosensitive Potassium Channel Formed by Fluorinated Amphiphilic Cyclophane.

由氟化兩親環(huán)芳烴形成的超分子機械敏感鉀通道。

35.Modular Difunctionalization of Unactivated Alkenes through Bio-Inspired Radical Ligand Transfer Catalysis.

通過仿生自由基配體轉(zhuǎn)移催化對未活化烯烴進行模塊化雙功能化。

36.Triple-Wavelength Lasing with a Stabilized β-LaBSiO5:Nd3+ Crystal.

使用穩(wěn)定的 β-LaBSiO5:Nd3+ 晶體的三波長激光。

37.Ultralow-Loading Pt/Zn Hybrid Cluster in Zeolite HZSM-5 for Efficient Dehydroaromatization.

沸石 HZSM-5 中用于高效脫氫芳構(gòu)化的超低載量 Pt/Zn 雜化團簇。

38.Integrated Photocatalytic Reduction and Oxidation of Perfluorooctanoic Acid by Metal–Organic Frameworks: Key Insights into the Degradation Mechanisms.

金屬有機骨架對全氟辛酸的綜合光催化還原和氧化：降解機制的關(guān)鍵見解。

39.Modular Two-Step Route to Sulfondiimidamides.

磺二亞胺的模塊化兩步路線。

40.In Situ Mechanistic Insights for the Oxygen Reduction Reaction in Chemically Modulated Ordered Intermetallic Catalyst Promoting Complete Electron Transfer.

促進完全電子轉(zhuǎn)移的化學(xué)調(diào)制有序金屬間催化劑中氧還原反應(yīng)的原位機理洞察。

41.Selective Axial-to-Equatorial Epimerization of Carbohydrates.

碳水化合物的選擇性軸向到赤道差向異構(gòu)化。

42.Structural Basis of Pyridostatin and Its Derivatives Specifically Binding to G-Quadruplexes.

Pyridostatin 及其衍生物特異性結(jié)合 G-四鏈體的結(jié)構(gòu)基礎(chǔ)。

43.Ketone–Olefin Coupling of Aliphatic and Aromatic Carbonyls Catalyzed by Excited-State Acridine Radicals.

激發(fā)態(tài)吖啶自由基催化的脂肪族和芳香族羰基的酮-烯烴偶聯(lián)。

44.Trident Molecule with Nanobrush–Nanoparticle–Nanofiber Transition Property Spatially Suppresses Tumor Metastasis.

具有納米刷-納米顆粒-納米纖維過渡特性的三叉戟分子在空間上抑制腫瘤轉(zhuǎn)移。

45.ABCs of Faraday Rotation in Organic Materials.

有機材料中法拉第旋轉(zhuǎn)的基礎(chǔ)知識。

46.A Co-conformationally “Topologically” Chiral Catenane.

共構(gòu)象“拓撲”手性鏈烷。

47.LiYbSe2: Frustrated Magnetism in the Pyrochlore Lattice.

LiYbSe2：燒綠石晶格中的受抑磁性。

48.Revitalizing Iron Redox by Anion-Insertion-Assisted Ferro- and Ferri-Hydroxides Conversion at Low Alkalinity.

在低堿度下通過陰離子插入輔助的亞鐵和亞鐵氫氧化物轉(zhuǎn)化來活化鐵氧化還原。

49.Synthesis of the Candidate Topological Compound Ni3Pb2.

候選拓撲化合物Ni3Pb2的合成。

50.Structural Basis for Dityrosine-Mediated Inhibition of α-Synuclein Fibrillization.

二酪氨酸介導(dǎo)的 α-突觸核蛋白纖維化抑制作用的結(jié)構(gòu)基礎(chǔ)。

51.Pd(II)-Catalyzed Synthesis of Bicyclo[3.2.1] Lactones via Tandem Intramolecular β-C(sp3)–H Olefination and Lactonization of Free Carboxylic Acids.

Pd(II)-催化合成雙環(huán)[3.2.1]內(nèi)酯通過串聯(lián)分子內(nèi)β-C(sp3)-H烯化和游離羧酸的內(nèi)酯化。

52.Deoxytrifluoromethylation of Alcohols.

醇的脫氧三氟甲基化。

53.Highly Efficient Proton Conduction in the Metal–Organic Framework Material MFM-300(Cr)·SO4(H3O)2.

金屬有機骨架材料 MFM-300(Cr)·SO4(H3O)2 中的高效質(zhì)子傳導(dǎo)。

54.Relative Kinetics of Solid-State Reactions: The Role of Architecture in Controlling Reactivity.

固態(tài)反應(yīng)的相對動力學(xué)：結(jié)構(gòu)在控制反應(yīng)性中的作用。

55.Cu-Electrocatalytic Diazidation of Alkenes at ppm Catalyst Loading.

Cu-Electrocatalytic Diazidation of Alkenes at ppm 催化劑負載。

56.Ion Depletion in the Interfacial Microenvironment from Cell–Surface Interactions.

細胞表面相互作用引起的界面微環(huán)境中的離子耗盡。

57.Pulsed Multifrequency Electron Paramagnetic Resonance Spectroscopy Reveals Key Branch Points for One- vs Two-Electron Reactivity in Mn/Fe Proteins.

脈沖多頻電子順磁共振光譜揭示了 Mn/Fe 蛋白質(zhì)中單電子與雙電子反應(yīng)性的關(guān)鍵分支點。

58.Role of Nanoscale Inhomogeneities in Co2FeO4 Catalysts during the Oxygen Evolution Reaction.

析氧反應(yīng)過程中 Co2FeO4 催化劑納米級不均勻性的作用。

59.Shielding Protection by Mesoporous Catalysts for Improving Plasma-Catalytic Ambient Ammonia Synthesis.

用于改善等離子催化環(huán)境氨合成的介孔催化劑的屏蔽保護。

60.Dual Ligand Enabled Nondirected C–H Chalcogenation of Arenes and Heteroarenes.

雙配體實現(xiàn)芳烴和雜芳烴的非定向 C-H 硫?qū)倩?/p>

61.Quantitative Agreement between Conformational Substates of Holo Calcium-Loaded Calmodulin Detected by Double Electron–Electron Resonance EPR and Predicted by Molecular Dynamics Simulations.

雙電子-電子共振 EPR 檢測和分子動力學(xué)模擬預(yù)測的全息鈣負載鈣調(diào)蛋白構(gòu)象亞基之間的定量一致性。

62.Visible-Light Copper Nanocluster Catalysis for the C–N Coupling of Aryl Chlorides at Room Temperature.

室溫下可見光銅納米團簇催化芳基氯的 C-N 偶聯(lián)。

63.Potential-Driven Restructuring of Cu Single Atoms to Nanoparticles for Boosting the Electrochemical Reduction of Nitrate to Ammonia.

Cu 單原子向納米粒子的電勢驅(qū)動重組，以促進硝酸鹽向氨的電化學(xué)還原。

64.C–H Bond Activation by a Mononuclear Nickel(IV)-Nitrate Complex.

單核鎳 (IV)-硝酸鹽絡(luò)合物的 C-H 鍵活化。

65.Reactivity Differences of Rieke Zinc Arise Primarily from Salts in the Supernatant, Not in the Solids.

Rieke 鋅的反應(yīng)性差異主要來自上清液中的鹽，而不是固體中的鹽。

66.Mechanistic Investigation of Enhanced Catalytic Selectivity toward Alcohol Oxidation with Ce Oxysulfate Clusters.

用 Ce Oxysulfate 簇增強對醇氧化的催化選擇性的機理研究。

67.Elucidating the Role of Antisolvents on the Surface Chemistry and Optoelectronic Properties of CsPbBrxI3-x Perovskite Nanocrystals.

闡明反溶劑對 CsPbBrxI3-x 鈣鈦礦納米晶體表面化學(xué)和光電特性的作用。

68.Toward Improved Charge Separation through Conformational Control in Copper Coordination Complexes.

通過銅配位配合物中的構(gòu)象控制改善電荷分離。

69.Atomic Insight into the Local Structure and Microenvironment of Isolated Co-Motifs in MFI Zeolite Frameworks for Propane Dehydrogenation.

對用于丙烷脫氫的 MFI 沸石骨架中孤立共基序的局部結(jié)構(gòu)和微環(huán)境的原子洞察。

70.Bioorthogonal, Fluorogenic Targeting of Voltage-Sensitive Fluorophores for Visualizing Membrane Potential Dynamics in Cellular Organelles.

電壓敏感熒光團的生物正交熒光靶向，用于可視化細胞器中的膜電位動力學(xué)。

71.Intrinsically Disordered Protein Condensate-Modified Surface for Mitigation of Biofouling and Foreign Body Response.

用于減輕生物污垢和異物反應(yīng)的本質(zhì)無序蛋白質(zhì)凝聚物改性表面。

72.Hydrogenation of Formate Species Using Atomic Hydrogen on a Cu(111) Model Catalyst.

在 Cu(111) 模型催化劑上使用原子氫氫化甲酸鹽類物質(zhì)。

73.Hard Ferromagnetism Down to the Thinnest Limit of Iron-Intercalated Tantalum Disulfide.

硬鐵磁性下降到鐵夾層二硫化鉭的最薄極限。

74.Inherent Promotion of Ionic Conductivity via Collective Vibrational Strong Coupling of Water with the Vacuum Electromagnetic Field.

通過水與真空電磁場的集體振動強耦合固有促進離子電導(dǎo)率。

75.On-DNA Hydroalkylation to Introduce Diverse Bicyclo[1.1.1]pentanes and Abundant Alkyls via Halogen Atom Transfer.

DNA 加氫烷基化通過鹵素原子轉(zhuǎn)移引入多種雙環(huán) [1.1.1] 戊烷和豐富的烷基。

76.Photocatalytic Biocidal Coatings Featuring Zr6Ti4-Based Metal–Organic Frameworks.

具有基于 Zr6Ti4 的金屬-有機框架的光催化殺菌涂層。

77.Controllable Single and Double Difluoromethylene Insertions into C–Cu Bonds: Copper-Mediated Tetrafluoroethylation and Hexafluoropropylation of Aryl Iodides with TMSCF2H and TMSCF2Br.

C-Cu 鍵中的可控單二氟亞甲基和雙二氟亞甲基插入：銅介導(dǎo)的芳基碘化物與 TMSCF2H 和 TMSCF2Br 的四氟乙基化和六氟丙基化。