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【標題速讀】【JACS】【2022年】【8月】

2023-06-11 18:41 作者:Rt_Cola 0人讀過 | 我要投稿

聲明：本專欄主要對生命科學(xué)領(lǐng)域的一些期刊文章標題進行翻譯，所有內(nèi)容均由本人手工整理翻譯。由于本人專業(yè)為生物分析相關(guān)，其他領(lǐng)域如果出現(xiàn)翻譯錯誤請諒解。

This cover image demonstrates the critical role of the solvent in the ion motion of intrinsically anionic metal–organic framework (MOF)-based quasi-solid-state electrolytes (QSSEs). Using hybrid theoretical and experimental approaches, we have identified solvent-assisted hopping as the dominant pathway for Li+ conduction in such materials, exemplified by MOF-688.

這張封面圖片展示了溶劑在基于陰離子金屬有機骨架 (MOF) 的準固態(tài)電解質(zhì) (QSSE) 的離子運動中的關(guān)鍵作用。使用混合理論和實驗方法，我們已經(jīng)確定溶劑輔助躍遷是此類材料中 Li+ 傳導(dǎo)的主要途徑，以 MOF-688 為例。

The cover depicts the cancer cell membrane-facilitated homotypic targeting analysis of exosomes for molecular subtype classification-based diagnosis of breast cancer.

封面描述了癌細胞膜促進的外泌體同型靶向分析，用于基于分子亞型分類的乳腺癌診斷。

A NIR-II fluorescence probe was developed for the detection of hepatic ischemia-reperfusion injury (HIRI) in mice livers. HIRI lesions of the livers glowed owing to the restricted rotation of the probe in the highly viscous lysosomes of the HIRI hepatocytes. View the article.

開發(fā)了一種 NIR-II 熒光探針，用于檢測小鼠肝臟中的肝缺血再灌注損傷 (HIRI)。由于探針在 HIRI 肝細胞的高粘性溶酶體中的旋轉(zhuǎn)受限，肝臟的 HIRI 病變會發(fā)光。

A heterostructured chiral membrane was designed using supramolecular templated self-assembly and an interfacial super-assembled strategy. This platform with the potential of chiral recognition was confirmed by the chiral transcription mechanism. The chiral membrane with cation selectivity as well as the general enantioseparation will motivate the development of the smart multifunctional membranes.

使用超分子模板化自組裝和界面超組裝策略設(shè)計了異質(zhì)結(jié)構(gòu)手性膜。手性轉(zhuǎn)錄機制證實了該平臺具有手性識別的潛力。具有陽離子選擇性以及一般對映分離的手性膜將推動智能多功能膜的發(fā)展。

An innovative strategy, I– vacancy, for designing stable charged domain walls (CDWs) in molecular ferroelectrics is proposed. A novel molecular ferroelectric, 1-adamantanammonium hydroiodate, with stable CDWs was successfully synthesized through the strategy, and CDWs can be precisely generated by the biased PFM tip. Statics and dynamics of domains were investigated on films.

提出了一種用于在分子鐵電體中設(shè)計穩(wěn)定帶電疇壁 (CDW) 的創(chuàng)新策略 I– 空位。通過該策略成功合成了具有穩(wěn)定 CDW 的新型分子鐵電體 1-金剛烷氫碘酸銨，并且可以通過偏置 PFM 尖端精確地產(chǎn)生 CDW 在薄膜上研究了疇的靜力學(xué)和動力學(xué)。

This cover image demonstrates the real chemistry of the synthesis and reversible transformation of AuCd bimetallic clusters. By subtly manipulating the steric hindrance of the ligands and/or the valence state of precursor (Au25q), the AuCd clusters with different structures and properties can be readily fabricated.

這張封面圖片展示了 AuCd 雙金屬簇的合成和可逆轉(zhuǎn)化的真實化學(xué)過程。通過巧妙地操縱配體的空間位阻和/或前體 (Au25q) 的價態(tài)，可以很容易地制造具有不同結(jié)構(gòu)和性質(zhì)的 AuCd 簇。

Mesoporous OMS-1 nanoparticles with high surface areas were successfully synthesized by the crystallization of precursors prepared in one step from Mg(MnO4)2, Mn(OAc)2, and Mg(OAc)2. Such a high surface area contributes to the catalytic performance for aerobic oxidation of alcohols and sulfides compared with other manganese oxide catalysts.

通過由 Mg(MnO4)2、Mn(OAc)2 和 Mg(OAc)2 一步制備的前體結(jié)晶，成功合成了具有高表面積的介孔 OMS-1 納米粒子。與其他錳氧化物催化劑相比，如此高的表面積有助于醇類和硫化物的有氧氧化催化性能。

Plasma activates CO2 for hydrogenation into alternative fuels, enabling the conversion of renewable electricity to chemical energy. The combined effect of plasma-activated CO2 and a Pd2Ga alloy catalyst breaks the thermodynamic equilibrium limitation. The mechanistic insights improve the efficiency of catalytic CO2 conversion and allow the engineers to design new concept catalysts.

等離子激活 CO2 以氫化為替代燃料，從而使可再生電力轉(zhuǎn)化為化學(xué)能。等離子活化 CO2 和 Pd2Ga 合金催化劑的聯(lián)合作用打破了熱力學(xué)平衡限制。對機理的了解提高了催化 CO2 轉(zhuǎn)化的效率，并使工程師能夠設(shè)計出新概念的催化劑。

In this work, such an emerging hydrogenated silicon nanosheet (H-silicene), which can favorably react with environmental water to generate H2 rapidly and continuously without any external energy input, has been explored as an effective anti-inflammatory agent for the therapeutics of diverse inflammatory diseases.

在這項工作中，這種新興的氫化硅納米片（H-silicene）可以在沒有任何外部能量輸入的情況下與環(huán)境水發(fā)生有利反應(yīng)以快速連續(xù)地產(chǎn)生 H2，已被探索作為一種有效的抗炎劑用于治療多種炎性疾病。

A quasi-three-dimensional pore refinement strategy, which is achieved by the tunability of ring size and number in polycycloalkane–dicarboxylate ligands, has been demonstrated to construct robust MOFs with confined aliphatic pore environment that can realize efficient separation of gases with similar structure, including CH4/C2H6/C3H8 and Xe/Kr.

通過聚環(huán)烷烴-二羧酸配體中環(huán)的大小和數(shù)量的可調(diào)性實現(xiàn)的準三維孔細化策略已被證明可以構(gòu)建具有受限脂肪族孔環(huán)境的穩(wěn)健 MOF，可以實現(xiàn)具有相似結(jié)構(gòu)的氣體的有效分離，包括 CH4/C2H6/C3H8 和 Xe/Kr。

Surface gelation triggered by Lewis acidic?basic interactions among electrocatalysts, solvents, and lithium salts deteriorates the redox kinetics in Li?S chemistry. As visually illustrated in the cover art, a Lewis basic salt lithium iodide is introduced to “clip” the Lewis acidic sites and boost the performances of Li?S pouch cells.

由電催化劑、溶劑和鋰鹽之間的路易斯酸-堿相互作用引發(fā)的表面凝膠化會惡化 Li-S 化學(xué)中的氧化還原動力學(xué)。正如封面藝術(shù)中直觀地說明的那樣，引入路易斯堿性鹽碘化鋰以“夾住”路易斯酸性位點并提高 Li-S 軟包電池的性能。

Existing measurement techniques have limited single-particle observation of chemical reactions to surface-tethered or immobilized systems. Active-feedback 3D single-particle tracking overcomes this barrier by “l(fā)ocking on” to freely diffusing and growing polymer particles to extract the growth rates of individual particles, revealing emergent heterogeneity while particles are still freely diffusing in solution.

現(xiàn)有的測量技術(shù)將化學(xué)反應(yīng)的單粒子觀察限制在表面系留或固定系統(tǒng)上。主動反饋 3D 單粒子跟蹤通過“鎖定”自由擴散和生長的聚合物粒子來提取單個粒子的生長速率，從而克服了這一障礙，揭示了粒子仍在溶液中自由擴散時出現(xiàn)的異質(zhì)性。

A planar molecule with S???O noncovalently intramolecular interactions (using a mortise-and-tenon joint to show the “l(fā)ocked” planar conformation in the cover art) has been developed as a solid additive for organic solar cells (OSCs). Based on this strategy, a record power conversion efficiency of 18.85% was achieved for single-junction binary OSCs.

具有 S???O 非共價分子內(nèi)相互作用的平面分子（使用榫眼接頭顯示封面藝術(shù)中的“鎖定”平面構(gòu)象）已被開發(fā)為有機太陽能電池 (OSC) 的固體添加劑。基于這一策略，單結(jié)二元 OSC 實現(xiàn)了創(chuàng)紀錄的 18.85% 的功率轉(zhuǎn)換效率。

An unusual ruthenium-catalyzed hydroboration of ynones provides efficient and selective access to previously inaccessible vinyl α-hydroxylboronates. This process involves unprecedented 1,4-hydroboration of ynones to form a boryl allenol ether followed by a second selective hydroboration of the allene intermediate.

一種不尋常的釕催化的炔烴硼氫化反應(yīng)提供了高效和選擇性地獲得以前無法獲得的乙烯基 α-羥基硼酸酯。該過程涉及炔酮前所未有的 1,4-硼氫化形成硼基丙二醇醚，然后是丙二烯中間體的第二次選擇性硼氫化。

By means of post-synthetic modification, reversible redox reactions onto an open metal site (Au) are manipulated in an iron(II) metal–organic framework, which results in switchable one-/two-/three-step spin-crossover dynamics. The coupling of spin transition and redox states opens a new perspective for multi-responsive molecular switches.

通過合成后修飾，在鐵 (II) 金屬-有機框架中操縱開放金屬位點 (Au) 上的可逆氧化還原反應(yīng)，從而產(chǎn)生可切換的一步/兩步/三步自旋交叉動力學(xué)。自旋躍遷和氧化還原態(tài)的耦合為多響應(yīng)分子開關(guān)開辟了新的視角。

At the primary structure level, the balance of structural flexibility and rigidity significantly enhances the efficiency of CL without wavelength change. More importantly, manipulation of secondary structures can not only enhance the CL efficiency but also induce the redshift of CL.

在一級結(jié)構(gòu)層面，結(jié)構(gòu)柔性和剛性的平衡顯著提高了 CL 的效率，無需改變波長。更重要的是，二級結(jié)構(gòu)的操縱不僅可以提高發(fā)光效率，還可以誘導(dǎo)發(fā)光的紅移。

In this Perspective, we highlighted the dedication to rigidly conjugated MCIs with multi-size and multi-dimensionality from molecular design evolution to functional landscapes.

在這個觀點中，我們強調(diào)了對從分子設(shè)計演變到功能景觀的多尺寸和多維度的剛性共軛 MCI 的奉獻。

Ruthenate nanosheets are known as good two-dimensional conductors, but details including their atomic arrangements and conductivity mechanism are open to debate. Our study revealed polymorphism in them, where symmetry breakage by forming short Ru–Ru pairs resulted in a band structure similar to that of graphene and induced an excellent semi-metallic conductivity.

釕酸鹽納米片被稱為良好的二維導(dǎo)體，但包括其原子排列和導(dǎo)電機制在內(nèi)的細節(jié)仍有待商榷。我們的研究揭示了它們的多態(tài)性，通過形成短的 Ru-Ru 對導(dǎo)致對稱性破缺，導(dǎo)致類似于石墨烯的能帶結(jié)構(gòu)，并誘導(dǎo)出優(yōu)異的半金屬導(dǎo)電性。

Ga-chabazite zeolites (Ga-CHA) have been found to efficiently catalyze propane dehydrogenation with high propylene selectivity (96%). External Ga2O3 particles are reduced in hydrogen and diffuse into the zeolite pores, displacing Br?nsted acid sites and forming extra-framework Ga+ sites. These isolated Ga+ sites react reversibly with H2 to form gallium hydrides and are the active sites for propane dehydrogenation.

已發(fā)現(xiàn)鎵菱沸石 (Ga-CHA) 可有效催化丙烷脫氫，并具有高丙烯選擇性 (96%)。外部 Ga2O3 顆粒在氫氣中被還原并擴散到沸石孔隙中，取代 Br?nsted 酸位點并形成骨架外的 Ga+ 位點。這些孤立的 Ga+ 位點與 H2 發(fā)生可逆反應(yīng)，形成氫化鎵，是丙烷脫氫的活性位點。

Data carriers using spin waves in spintronic and magnonic logic devices can offer low power consumption and even a Joule-heat-free process. Distinct spin-wave excitations arising from antiferromagnetic exchange in combination with the dipole–dipole interaction were predicted in a series of heterometallic ring-like coordination complexes, namely, {ScnGdn} (n = 4, 6, 8).

在自旋電子和磁子邏輯器件中使用自旋波的數(shù)據(jù)載體可以提供低功耗甚至無焦耳熱工藝。在一系列異金屬環(huán)狀配位化合物，即 {ScnGdn} (n = 4, 6, 8) 中預(yù)測了反鐵磁交換與偶極-偶極相互作用相結(jié)合產(chǎn)生的不同自旋波激發(fā)。

Mechanistic understanding of atom transfer radical polymerization (ATRP) is fundamental to predict and control polymerization outcomes and to guide the next advances in ATRP, which include using Fe catalysts, combining various stimuli, expanding the monomer and functionality scope, running it at larger or smaller scale, and developing controlled depolymerization procedures.

對原子轉(zhuǎn)移自由基聚合 (ATRP) 的機理理解是預(yù)測和控制聚合結(jié)果以及指導(dǎo) ATRP 下一步進展的基礎(chǔ)，包括使用 Fe 催化劑、結(jié)合各種刺激、擴大單體和功能范圍、在更大或更小的條件下運行規(guī)模，并開發(fā)受控的解聚程序。

Through a joint experimental and theoretical study of charge transport through dimer molecules formed from graphene-like monomers, a unique quantum state is found, which enables unprecedented nonclassical room-temperature charge transport controlled by stacking interactions.

通過對由類石墨烯單體形成的二聚體分子進行的電荷傳輸?shù)穆?lián)合實驗和理論研究，發(fā)現(xiàn)了一種獨特的量子態(tài)，這使得通過堆疊相互作用控制的前所未有的非經(jīng)典室溫電荷傳輸成為可能。

A high local hydroxyl concentration is constructed near the Pt clusters on the surface of Ti3C2Tx. The increased hydroxyls promote the oxidation of adsorbed CO and improve the activity and durability of Pt clusters for the methanol oxidation reaction.

在 Ti3C2TX 表面的 Pt 簇附近構(gòu)建了高局部羥基濃度。增加的羥基促進了吸附的 CO 的氧化，提高了 Pt 團簇對甲醇氧化反應(yīng)的活性和耐久性。

The metathesis cascade polymerization of polycyclic enyne monomers can yield two different repeat unit structures corresponding to a complete or interrupted cascade reaction before propagation. In our study, we optimize monomer structures to achieve well-controlled polymerizations with high selectivity for the complete cascade.

多環(huán)烯炔單體的復(fù)分解級聯(lián)聚合可以產(chǎn)生兩種不同的重復(fù)單元結(jié)構(gòu)，對應(yīng)于傳播前的完整或中斷的級聯(lián)反應(yīng)。在我們的研究中，我們優(yōu)化了單體結(jié)構(gòu)，以實現(xiàn)對整個級聯(lián)具有高選擇性的可控聚合。

Through a joint experimental and theoretical study of charge transport through dimer molecules formed from graphene-like monomers, a unique quantum state is found, which enables unprecedented nonclassical room-temperature charge transport controlled by stacking interactions.

通過對由類石墨烯單體形成的二聚體分子進行的電荷傳輸?shù)穆?lián)合實驗和理論研究，發(fā)現(xiàn)了一種獨特的量子態(tài)，這使得通過堆疊相互作用控制的前所未有的非經(jīng)典室溫電荷傳輸成為可能。

1.Ionic Conduction Mechanism and Design of Metal–Organic Framework Based Quasi-Solid-State Electrolytes.

基于金屬有機骨架的準固態(tài)電解質(zhì)的離子傳導(dǎo)機制和設(shè)計。

2.Endocytosis of Coacervates into Liposomes.

凝聚層的內(nèi)吞作用進入脂質(zhì)體。

3.A Borosilicide with Clathrate VIII Structure.

具有籠形 VIII 結(jié)構(gòu)的硼硅化物。

4.Enantioselective Reductive N-Cyclization–Alkylation Reaction of Alkene-Tethered Oxime Esters and Alkyl Iodides by Nickel Catalysis.

鎳催化下烯烴系肟酯和烷基碘化物的對映選擇性還原 N-環(huán)化-烷基化反應(yīng)。

5.Enantioselective Radical Trifluoromethylation of Benzylic C–H Bonds via Cooperative Photoredox and Copper Catalysis.

通過協(xié)同光氧化還原和銅催化對芐基 C-H 鍵進行對映選擇性自由基三氟甲基化。

6.Molecular Characterization of Exosomes for Subtype-Based Diagnosis of Breast Cancer.

外泌體的分子特征用于基于亞型的乳腺癌診斷。

7.Kinetic Diagnostics and Synthetic Design of Platinum Group Metal-Free Electrocatalysts for the Oxygen Reduction Reaction Using Reactivity Maps and Site Utilization Descriptors.

使用反應(yīng)圖和位點利用描述符進行氧還原反應(yīng)的鉑族無金屬電催化劑的動力學(xué)診斷和合成設(shè)計。

8.Amplified Spontaneous Emission from Zwitterionic Excited-State Intramolecular Proton Transfer.

兩性離子激發(fā)態(tài)分子內(nèi)質(zhì)子轉(zhuǎn)移的放大自發(fā)發(fā)射。

9.Molecular and Electronic Structure of Isolated Platinum Sites Enabled by the Expedient Measurement of 195Pt Chemical Shift Anisotropy.

通過 195Pt 化學(xué)位移各向異性的便捷測量實現(xiàn)孤立鉑位點的分子和電子結(jié)構(gòu)。

10.Electrochemical Detection of a Few Copies of Unamplified SARS-CoV-2 Nucleic Acids by a Self-Actuated Molecular System.

通過自驅(qū)動分子系統(tǒng)對少量未擴增的 SARS-CoV-2 核酸進行電化學(xué)檢測。

11.Structural Diversity in Dimension-Controlled Assemblies of Tetrahedral Gold Nanocrystals.

四面體金納米晶體尺寸控制組件的結(jié)構(gòu)多樣性。

12.Iridium-Incorporated Strontium Tungsten Oxynitride Perovskite for Efficient Acidic Hydrogen Evolution.

用于高效酸性析氫的摻銥鍶鎢氮氧化物鈣鈦礦。

13.Free Piperazic Acid as a Precursor to Nonribosomal Peptides.

游離哌嗪酸作為非核糖體肽的前體。

14.Hydrogen-Bond Network Promotes Water Splitting on the TiO2 Surface.

氫鍵網(wǎng)絡(luò)促進 TiO2 表面的水分解。

15.Real-Time Polymer Viscosity–Catalytic Activity Relationships on the Microscale.

微尺度上的實時聚合物粘度-催化活性關(guān)系。

16.Precision Navigation of Hepatic Ischemia–Reperfusion Injury Guided by Lysosomal Viscosity-Activatable NIR-II Fluorescence.

由溶酶體粘度激活的 NIR-II 熒光引導(dǎo)的肝缺血再灌注損傷的精確導(dǎo)航。

17.Polymer Dots as Photoactive Membrane Vesicles for [FeFe]-Hydrogenase Self-Assembly and Solar-Driven Hydrogen Evolution.

聚合物點作為光活性膜囊泡，用于 [FeFe]-氫化酶自組裝和太陽能驅(qū)動的氫演化。

18.Time-Resolved Atomistic Imaging and Statistical Analysis of Daptomycin Oligomers with and without Calcium Ions.

含鈣離子和不含鈣離子的達托霉素低聚物的時間分辨原子成像和統(tǒng)計分析。

19.Universal Kinetic Mechanism Describing CO2 Photoreductive Yield and Selectivity for Semiconducting Nanoparticle Photocatalysts.

描述半導(dǎo)體納米粒子光催化劑的 CO2 光還原產(chǎn)率和選擇性的通用動力學(xué)機制。

20.Thermodynamics-Kinetics-Balanced Metal–Organic Framework for In-Depth Radon Removal under Ambient Conditions.

用于在環(huán)境條件下深度去除氡的熱力學(xué)-動力學(xué)-平衡金屬-有機框架。

21.Enantio- and Regioselective Ni-Catalyzed para-C–H Alkylation of Pyridines with Styrenes via Intermolecular Hydroarylation.

通過分子間氫化芳基化對映和區(qū)域選擇性 Ni 催化吡啶與苯乙烯的對 C-H 烷基化。

22.N-Vinyl Acrylamides: Versatile Heterobifunctional Electrophiles for Thiol–Thiol Bioconjugations.

N-乙烯基丙烯酰胺：用于硫醇-硫醇生物共軛的多功能異雙功能親電試劑。

23.A Single-Component Luminescent Biosensor for the SARS-CoV-2 Spike Protein.

用于 SARS-CoV-2 刺突蛋白的單組分發(fā)光生物傳感器。

24.Zinc Titanium Nitride Semiconductor toward Durable Photoelectrochemical Applications.

面向耐用光電化學(xué)應(yīng)用的鋅鈦氮化物半導(dǎo)體。

25.Thermal Enhancement of Luminescence for Negative Thermal Expansion in Molecular Materials.

分子材料中負熱膨脹的發(fā)光熱增強。

26.Magnetic Interactions in Substitutional Core-Doped Graphene Nanoribbons.

替代核摻雜石墨烯納米帶中的磁相互作用。

27.Exploring Structure–Property Relations of B,S-Doped Polycyclic Aromatic Hydrocarbons through the Trinity of Synthesis, Spectroscopy, and Theory.

通過合成、光譜和理論的三位一體探索 B,S 摻雜多環(huán)芳烴的結(jié)構(gòu)-性質(zhì)關(guān)系。

28.Nanopore Identification of Alditol Epimers and Their Application in Rapid Analysis of Alditol-Containing Drinks and Healthcare Products.

糖醇差向異構(gòu)體的納米孔鑒定及其在含糖醇飲料和保健品快速分析中的應(yīng)用。

29.Densified HKUST-1 Monoliths as a Route to High Volumetric and Gravimetric Hydrogen Storage Capacity.

致密的 HKUST-1 整體結(jié)構(gòu)作為實現(xiàn)高體積和重量儲氫能力的途徑。

30.Probing the Electronic Structure and Bond Dissociation of SO3 and SO3– Using High-Resolution Cryogenic Photoelectron Imaging.

探測 SO3 和 SO3 的電子結(jié)構(gòu)和鍵離解——使用高分辨率低溫光電子成像。

31.Data-Driven Enhancement of ZT in SnSe-Based Thermoelectric Systems.

ZT 在基于 SnSe 的熱電系統(tǒng)中的數(shù)據(jù)驅(qū)動增強。

32.Boosting Osmotic Energy Conversion of Graphene Oxide Membranes via Self-Exfoliation Behavior in Nano-Confinement Spaces.

通過納米限制空間中的自剝離行為促進氧化石墨烯膜的滲透能轉(zhuǎn)換。

33.Transuranium Sulfide via the Boron Chalcogen Mixture Method and Reversible Water Uptake in the NaCuTS3 Family.

通過硼硫?qū)僭鼗旌衔锓ê?NaCuTS3 族中的可逆吸水獲得超鈾硫化物。

34.Gd(OH)F2: A Promising Cryogenic Magnetic Refrigerant.

Gd(OH)F2：一種很有前途的低溫磁性制冷劑。

35.Super-Assembled Chiral Mesostructured Heteromembranes for Smart and Sensitive Couple-Accelerated Enantioseparation.

用于智能和靈敏耦合加速對映分離的超級組裝手性介觀結(jié)構(gòu)異質(zhì)膜。

36.Rational Design of Molecular Ferroelectrics with Negatively Charged Domain Walls.

帶負電疇壁的分子鐵電體的合理設(shè)計。

37.The Role of Tryptophan in π Interactions in Proteins: An Experimental Approach.

色氨酸在蛋白質(zhì) π 相互作用中的作用：一種實驗方法。

38.Combinatorial Synthesis and Screening of Mixed Halide Perovskite Megalibraries.

混合鹵化物鈣鈦礦巨型文庫的組合合成和篩選。

39.Confined Motion: Motility of Active Microparticles in Cell-Sized Lipid Vesicles.

受限運動：活性微粒在細胞大小的脂質(zhì)囊泡中的運動。

40.Surface Re-Engineering of Perovskites with Buckybowls to Boost the Inverted-Type Photovoltaics.

用 Buckybowls 對鈣鈦礦進行表面再工程以促進倒置型光伏發(fā)電。

41.Discovery of a Transferrin Receptor 1-Binding Aptamer and Its Application in Cancer Cell Depletion for Adoptive T-Cell Therapy Manufacturing.

轉(zhuǎn)鐵蛋白受體 1 結(jié)合適體的發(fā)現(xiàn)及其在過繼性 T 細胞療法生產(chǎn)中癌細胞耗竭中的應(yīng)用。

42.Isolation of a Cu–H Monomer Enabled by Remote Steric Substitution of a N-Heterocyclic Carbene Ligand: Stoichiometric Insertion and Catalytic Hydroboration of Internal Alkenes.

通過 N-雜環(huán)卡賓配體的遠程空間取代實現(xiàn) Cu-H 單體的分離：內(nèi)部烯烴的化學(xué)計量插入和催化硼氫化。

43.Interconversion of Atomically Dispersed Platinum Cations and Platinum Clusters in Zeolite ZSM-5 and Formation of Platinum gem-Dicarbonyls.

沸石 ZSM-5 中原子分散的鉑陽離子和鉑簇的相互轉(zhuǎn)化以及鉑寶石-二羰基化合物的形成。

44.2.2 ? Cryo-EM Tetra-Protofilament Structure of the Hamster Prion 108–144 Fibril Reveals an Ordered Water Channel in the Center.

2.2 ? Cryo-EM Tetra-Protofilament 倉鼠朊病毒 108–144 Fibril 的結(jié)構(gòu)顯示中心有一個有序的水通道。

45.Electrophotochemical Ce-Catalyzed Ring-Opening Functionalization of Cycloalkanols under Redox-Neutral Conditions: Scope and Mechanism.

氧化還原中性條件下環(huán)烷醇的電光化學(xué) Ce 催化開環(huán)功能化：范圍和機制。

46.Heteroanionic Control of Exemplary Second-Harmonic Generation and Phase Matchability in 1D LiAsS2–xSex.

1D LiAsS2–xSex 中示例性二次諧波產(chǎn)生和相位匹配性的雜陰離子控制。

47.Iodine–Iodine Cooperation Enables Metal-Free C–N Bond-Forming Electrocatalysis via Isolable Iodanyl Radicals.

碘-碘合作通過可分離的碘自由基實現(xiàn)無金屬 C-N 鍵形成電催化。

48.Template-Free Assembly of Functional RNAs by Loop-Closing Ligation.

通過閉環(huán)連接對功能性 RNA 進行無模板組裝。

49.Decrypting Material Performance by Wide-field Femtosecond Interferometric Imaging of Energy Carrier Evolution.

通過載能子演化的寬視場飛秒干涉成像解密材料性能。

50.Deeper Insight into Photopolymerization: The Synergy of Time-Resolved Nonuniform Sampling and Diffusion NMR.

深入了解光聚合：時間分辨非均勻采樣和擴散 NMR 的協(xié)同作用。

51.Diastereoselective Radical 1,4-Ester Migration: Radical Cyclizations of Acyclic Esters with SmI2.

非對映選擇性自由基 1,4-酯遷移：無環(huán)酯與 SmI2 的自由基環(huán)化。

52.Direct Construction of Isomeric Benzobisoxazole–Vinylene-Linked Covalent Organic Frameworks with Distinct Photocatalytic Properties.

直接構(gòu)建具有獨特光催化性能的異構(gòu)苯并雙惡唑-亞乙烯基連接的共價有機骨架。

53.Ligand-Controlled Cobalt-Catalyzed Regiodivergent Alkyne Hydroalkylation.

配體控制的鈷催化的區(qū)域發(fā)散性炔烴加氫烷基化。

54.Iterative Synthesis of Contorted Macromolecular Ladders for Fast-Charging and Long-Life Lithium Batteries.

用于快速充電和長壽命鋰電池的扭曲大分子階梯的迭代合成。

55.“Flash & Click”: Multifunctionalized Lipid Derivatives as Tools To Study Viral Infections.

“ Flash & Click”：多功能脂質(zhì)衍生物作為研究病毒感染的工具。

56.Portable Models for Entropy Effects on Kinetic Selectivity.

熵對動力學(xué)選擇性影響的便攜式模型。

57.Mechanistic Insights into OC–COH Coupling in CO2 Electroreduction on Fragmented Copper.

碎銅上 CO2 電還原中 OC-COH 耦合的機理洞察。

58.Photooxidation of the Phenolate Anion is Accelerated at the Water/Air Interface.

酚鹽陰離子的光氧化在水/空氣界面處加速。

59.Polymerase η Recruits DHX9 Helicase to Promote Replication across Guanine Quadruplex Structures.

聚合酶 η 招募 DHX9 解旋酶以促進跨鳥嘌呤四鏈體結(jié)構(gòu)的復(fù)制。

60.Enhancing Oxygenic Photosynthesis by Cross-Linked Perylenebisimide “Quantasomes”.

通過交聯(lián)苝雙酰亞胺“量子體”增強產(chǎn)氧光合作用。

61.Total Synthesis of Darobactin A.

Darobactin A 的全合成。

62.Robust Spin-Dependent Anisotropy of Circularly Polarized Light Detection from Achiral Layered Hybrid Perovskite Ferroelectric Crystals.

非手性層狀雜化鈣鈦礦鐵電晶體圓偏振光檢測的穩(wěn)健自旋相關(guān)各向異性。

63.C–C σ-Bond Oxidative Addition and Hydrofunctionalization by a Macrocycle-Supported Diiron Complex.

C-C σ-鍵氧化加成和大環(huán)支持的二鐵配合物的氫化作用。

64.A Concise Synthesis of Pleurotin Enabled by a Nontraditional C–H Epimerization.

通過非傳統(tǒng) C-H 差向異構(gòu)化實現(xiàn)的側(cè)耳素簡明合成。

65.Migrative Carbofluorination of Saturated Amides Enabled by Pd-Based Dyotropic Rearrangement.

基于 Pd 的變色重排實現(xiàn)飽和酰胺的遷移碳氟化。

66.The Energy Gap Law at Work: Emission Yield and Rate Fluctuations of Single NIR Emitters.

工作中的能隙定律：單個 NIR 發(fā)射器的發(fā)射產(chǎn)量和速率波動。

67.Structure and Function of a Dehydrating Condensation Domain in Nonribosomal Peptide Biosynthesis.

非核糖體肽生物合成中脫水縮合結(jié)構(gòu)域的結(jié)構(gòu)和功能。

68.(n-Bu)4NBr-Promoted N2 Splitting to Molybdenum Nitride.

(n-Bu)4NBr-促進 N2 分解為氮化鉬。

69.Optically Induced Long-Lived Chirality Memory in the Color-Tunable Chiral Lead-Free Semiconductor (R)/(S)-CHEA4Bi2BrxI10–x (x = 0–10).

顏色可調(diào)手性無鉛半導(dǎo)體 (R)/(S)-CHEA4Bi2BrxI10–x (x = 0–10) 中的光感應(yīng)長壽命手性記憶。

70.Synthesis and Aerobic Oxidation Catalysis of Mesoporous Todorokite-Type Manganese Oxide Nanoparticles by Crystallization of Precursors.

前驅(qū)體結(jié)晶法合成介孔 Todorokite 型氧化錳納米粒子及其有氧氧化催化。

71.Engineered Amber-Emitting Nano Luciferase and Its Use for Immunobioluminescence Imaging In Vivo.

工程琥珀色發(fā)光納米熒光素酶及其在體內(nèi)免疫生物發(fā)光成像中的應(yīng)用。

72.Intracellular Communication between Synthetic Macromolecules.

合成大分子之間的細胞內(nèi)通訊。

73.Unconventional Charge Transport in MgCr2O4 and Implications for Battery Intercalation Hosts.

MgCr2O4 中的非常規(guī)電荷傳輸及其對電池嵌入主體的影響。

74.Chemical Conformation of the Essential Glutamate Site of the c-Ring within Thermophilic Bacillus FoF1-ATP Synthase Determined by Solid-State NMR Based on its Isolated c-Ring Structure.

嗜熱芽孢桿菌 FoF1-ATP 合酶中 c 環(huán)必需谷氨酸位點的化學(xué)構(gòu)象，通過固態(tài) NMR 基于其分離的 c 環(huán)結(jié)構(gòu)確定。