聲明：本專欄主要對生命科學領域的一些期刊文章標題進行翻譯，所有內容均由本人手工整理翻譯。由于本人專業(yè)為生物分析相關，其他領域如果出現翻譯錯誤請諒解。

Biochemical, spectroscopic, and computational investigation of the isonitrile forming non-heme iron dioxygenase ScoE reveals key intermediates including C5-OH CABA and imine CABA. The cover depicts a wrought iron sculpture of ScoE with the active site, elucidated intermediates, and isonitrile-containing product accented in gold.

異腈形成非血紅素鐵雙加氧酶 ScoE 的生化、光譜和計算研究揭示了關鍵中間體，包括 C5-OH CABA 和亞胺 CABA。 封面描繪了 ScoE 的鍛鐵雕塑，其中包含活性位點、闡明的中間體和含異腈的產品，并以金色點綴。

The multimodal and reversible manipulation of ligand accessibility using magnetic nanoparticle aggregates is demonstrated to dynamically regulate receptor–ligand binding in macrophages. The ligand accessibility of macrophages is magnetically manipulated to regulate their adhesion and pro-regenerative polarization both in vitro and in vivo.

使用磁性納米顆粒聚集體對配體可及性的多模式和可逆操作被證明可以動態(tài)調節(jié)巨噬細胞中的受體-配體結合。 巨噬細胞的配體可及性通過磁性操作來調節(jié)它們在體外和體內的粘附和促再生極化。

A robust strategy combining crystallographic group–subgroup theory and high-throughput ab initio calculations was proposed to discover and explore unknown crystals, as demonstrated in the design of ternary crystalline chalcogenide semiconductors for optoelectronic applications. Twenty-two new compounds were predicted to show excellent stability and high photovoltaic conversion efficiency.

提出了一種結合晶體學群-子群理論和高通量從頭算計算的穩(wěn)健策略來發(fā)現和探索未知晶體，正如用于光電應用的三元晶體硫族化物半導體的設計所證明的那樣。 預計 22 種新化合物表現出優(yōu)異的穩(wěn)定性和高光伏轉換效率。

An orthogonal XNA circuit was achieved. Right-handed L-aTNA and left-handed D-aTNA orthogonally facilitated the hybridization chain reaction, generating long duplex products from hairpin monomers. There was no interaction between L-aTNA and D-aTNA even though they had the same sequence. Detection of the RNA sequence by D-aTNA HCR via SNA interface was also demonstrated.

實現了正交 XNA 電路。 右手 L-aTNA 和左手 D-aTNA 正交促進了雜交鏈反應，從發(fā)夾單體生成長雙工產物。 L-aTNA 和 D-aTNA 之間沒有相互作用，即使它們具有相同的序列。 還展示了通過 SNA 接口通過 D-aTNA HCR 檢測 RNA 序列。

A novel self-assembly method called crystallization-driven in situ nanoparticlization of conjugated polymers (CD-INCP), which forms semiconducting 1D nanoparticles synchronously during polymerization, has been developed. Powerful SCTP enables successful polymerization of an unprecedented highly solubilizing conjugated shell as well as a slow polymerization of the core, leading to growth of micelles via a seeded-growth mechanism.

開發(fā)了一種稱為共軛聚合物結晶驅動原位納米顆?；?(CD-INCP) 的新型自組裝方法，該方法在聚合過程中同步形成半導體一維納米顆粒。 強大的 SCTP 能夠成功聚合前所未有的高度增溶共軛殼以及緩慢聚合核心，從而通過種子生長機制導致膠束生長。

Theoretical calculations for the zeolite model in the virtual world guide the rational synthesis of self-pillared pentasil zeolite nanosheets.

虛擬世界中沸石模型的理論計算指導自柱五元沸石納米片的合理合成。

A peptidomimetic approach toward mimicking wet-adhesive mussel foot proteins in the platform of poly(ethylene glycol)-based peptides (PEGtides) is suggested, revealing the synergistic interplay among catechol and amine, and the diverse hydrogen bonding with polyether backbone resulting in their highly adhesive properties.

提出了一種在基于聚乙二醇的肽 (PEGtides) 平臺中模擬濕粘性貽貝足蛋白的擬肽方法，揭示了兒茶酚和胺之間的協同相互作用，以及與聚醚主鏈的多種氫鍵結合導致它們高度 粘合性能。

Organic molecular microcrystals based on a naphthalene framework are exposed to light, progressing a [2 + 2] photodimerization and exhibiting dramatic photoinduced elongation behavior. When crystals crack as the photochemistry proceeds, aqueous dye solutions can be released from the unique sealed hollow cavities.

基于萘骨架的有機分子微晶暴露在光下，進行 [2 + 2] 光二聚化并表現出顯著的光誘導伸長行為。 當晶體隨著光化學的進行而破裂時，染料水溶液可以從獨特的密封空腔中釋放出來。

Phenol molecules at the air–water interface are seen on aerosols in the atmosphere and undergo photochemical reactions much faster than in the bulk water. This paper elucidated the reaction mechanism characteristic to the water surfaces.

空氣-水界面上的苯酚分子在大氣中的氣溶膠上可見，并且比在大量水中更快地進行光化學反應。 本文闡明了水表面的反應機理特征。

Hydrogen intercalation transforms tungsten oxide into tungsten oxide hydrogen bronze, whose catalytic activity toward protons and electrons is fundamentally different from the starting oxide. Miu and co-workers used theory and experiments to show that electrochemical hydrogen evolution only proceeds at measurable rates after formation of the intercalated bronze.

氫嵌入將氧化鎢轉化為氧化鎢氫青銅，其對質子和電子的催化活性與起始氧化物根本不同。 Miu 及其同事使用理論和實驗表明，電化學析氫僅在夾層青銅形成后才以可測量的速率進行。

We report the synthesis of hyper-cross-linked polymer gels to yield a hierarchically porous network. The gels can be used as a platform to achieve molecular-level hybridization with a two-dimensional polymer during the gel formation, which provides functional gels with the enhancement of porosities and mechanical stiffness for molecular separation.

我們報告了超交聯聚合物凝膠的合成，以產生分層多孔網絡。 該凝膠可用作在凝膠形成過程中與二維聚合物實現分子水平雜交的平臺，從而為功能性凝膠提供具有增強的孔隙率和分子分離機械剛度的功能凝膠。

Going hybrid! The chemistry of ring-contracted porphyrinoids is fascinating but still remains underdeveloped. In this work, a new class of hybridized and core-contracted porphyrinoids, B(III)-submonoazaporphyrins, was reported. A new versatile strategy based on a boron-templated intramolecular SNAr reaction has been developed and permits imaginative design and construction of novel ring-contracted porphyrinoids.

混合動力！ 環(huán)縮型卟啉的化學性質令人著迷，但仍未得到充分開發(fā)。 在這項工作中，報道了一類新的雜交和核心收縮的卟啉類化合物 B(III)-submonoazaporphyrins。 已經開發(fā)出一種基于硼模板化分子內 SNAr 反應的新型多功能策略，并允許富有想象力的設計和構建新型環(huán)收縮類卟啉。

A thermally stable periodic monolayer array of discrete C60 was generated on an atomically flat Au(111) surface with the aid of a template adlayer. The template was a two-dimensional (2D) array of molecular pits prepared on a Au(111) surface through 2D crystallization of shape-persistent macrocycles composed of four carbazole and four salphens/Ni-salphens with a 1 nm hollow.

借助模板吸附層，在原子平坦的 Au(111) 表面上生成了離散 C60 的熱穩(wěn)定周期性單層陣列。 該模板是在 Au(111) 表面上制備的分子凹坑的二維 (2D) 陣列，通過由四個咔唑和四個 salphens/Ni-salphens 組成的具有 1 nm 空心的形狀持久大環(huán)的 2D 結晶。

This report presents the synthesis of core–shell nanoparticles composed of a liquid gallium core and a densely packed reduced graphene oxide (RGO) shell (Ga@RGO) via a one-pot nanoprobe sonication method. With enhanced near-infrared absorption and efficient photothermal conversion, these core–shell Ga@RGO nanoparticles can serve as superior photoacoustic imaging contrast agents.

本報告介紹了通過一鍋納米探針超聲法合成由液態(tài)鎵核和致密堆積的還原氧化石墨烯 (RGO) 殼 (Ga@RGO) 組成的核殼納米粒子。 憑借增強的近紅外吸收和高效的光熱轉換，這些核殼結構的 Ga@RGO 納米粒子可以作為優(yōu)異的光聲成像造影劑。

The combination of a flexible chain-driven molecular motion and resonance-engineered spin-flipping process enables the construction of photoactivated organic ultralong room temperature phosphorescence materials, which demonstrate a controllably regulated photoactivated rate, providing a useful platform to design stimuli-responsive optoelectronic materials for advanced encryption applications.

靈活的鏈驅動分子運動和共振工程自旋翻轉過程的結合使得能夠構建光活化有機超長室溫磷光材料，其表現出可控調節(jié)的光活化速率，為設計刺激響應光電材料提供了一個有用的平臺 高級加密應用程序。

Visible light excitation of a perylenediimide radical anion results in electron injection into a ZrO2 insulator, yielding a potent reducing agent with a remarkable ~microsecond lifetime. The long-lived potent reducing agent provides new opportunities to reduce important reagents and catalysts present in low concentrations.

苝二酰亞胺自由基陰離子的可見光激發(fā)導致電子注入 ZrO2 絕緣體，產生具有顯著~微秒壽命的強效還原劑。 長壽命的強效還原劑為還原低濃度的重要試劑和催化劑提供了新的機會。

The cover art demonstrates the importance of proper computational methodology for predicting the structure of multicomponent solids that may exist as salts or cocrystals. An approach based on classical mechanics (represented by Newton's laws) favors salts, and an approach that includes quantum effects (hydrogen atom delocalization) predicts cocrystals.

封面藝術展示了正確的計算方法對于預測可能以鹽或共晶形式存在的多組分固體結構的重要性。 基于經典力學（以牛頓定律為代表）的方法支持鹽，而包括量子效應（氫原子離域）的方法預測共晶。

Ultrathin chiral covalent organic framework (chirCOF) nanosheets with strong chirality and luminescence have been developed using a facile and scalable chiral-induced strategy. The resulting chirCOF nanosheets exhibit excellent circularly polarized luminescence (CPL) performance, and the CPL can be tuned by modifying carboxyl-containing fluorescent dye molecules.

使用簡便且可擴展的手性誘導策略開發(fā)了具有強手性和發(fā)光的超薄手性共價有機框架（chirCOF）納米片。 所得的 chirCOF 納米片表現出優(yōu)異的圓偏振發(fā)光 (CPL) 性能，并且可以通過修飾含羧基的熒光染料分子來調節(jié) CPL。

Core–shell porous nanophotoreactors are designed for highly stable and recyclable photobiocatalysis in combination with native enzymes under aerobic conditions, while conducting efficient cofactor regeneration and protecting enzymatic materials from photogenerated active oxygen species.

核殼多孔納米光反應器設計用于在有氧條件下與天然酶結合進行高度穩(wěn)定和可回收的光生物催化，同時進行有效的輔因子再生并保護酶材料免受光生活性氧的影響。

A new method for the treatment of drug-resistant cancer using biomolecules to activate certain apoptosis pathways has been proposed, which is achieved through intracellular tyrosinase-catalyzed oxidation of a tripeptide and subsequent in situ self-assembly into nanoparticles that are capable of interfering with tubulin polymerization and ultimately reversing the drug resistance of melanoma.

已經提出了一種使用生物分子激活某些細胞凋亡途徑來治療耐藥性癌癥的新方法，該方法是通過細胞內酪氨酸酶催化三肽氧化并隨后原位自組裝成能夠干擾微管蛋白的納米粒子來實現的 聚合并最終逆轉黑色素瘤的耐藥性。

1.The Atypical Cobalamin-Dependent S-Adenosyl-l-Methionine Nonradical Methylase TsrM and Its Radical Counterparts.

非典型鈷胺素依賴性 S-腺苷-l-甲硫氨酸非自由基甲基化酶 TsrM 及其自由基對應物。

2.Bioinspired Ice-Binding Materials for Tissue and Organ Cryopreservation.

用于組織和器官低溫保存的仿生冰結合材料。

3.Covalently Engineered Protein Minibinders with Enhanced Neutralization Efficacy against Escaping SARS-CoV-2 Variants.

共價工程化的蛋白質微型結合劑，具有增強的中和效果，可抵抗逃逸的 SARS-CoV-2 變體。

4.Dissecting Electronic-Structural Transitions in the Nitrogenase MoFe Protein P-Cluster during Reduction.

在還原過程中剖析固氮酶 MoFe 蛋白 P 簇中的電子結構轉變。

5.Protein-Interaction Affinity Gradient Drives [4Fe–4S] Cluster Insertion in Human Lipoyl Synthase.

蛋白質相互作用親和梯度驅動 [4Fe–4S] 簇插入人硫辛酰合酶。

6.Fluorescence Enhancement by Supramolecular Sequestration of a C54-Nanographene Trisimide by Hexabenzocoronene.

六苯并苯并萘對 C54-納米石墨烯三酰亞胺的超分子螯合增強熒光。

7.PhOxi-Seq: Single-Nucleotide Resolution Sequencing of N2-Methylation at Guanosine in RNA by Photoredox Catalysis.

PhOxi-Seq：通過光氧化還原催化對 RNA 中鳥苷的 N2-甲基化進行單核苷酸分辨率測序。

8.3D Covalent Organic Frameworks with Interpenetrated pcb Topology Based on 8-Connected Cubic Nodes.

具有基于 8 連接立方節(jié)點的互穿 pcb 拓撲結構的 3D 共價有機框架。

9.“Self-Adaptive” Coassembly of Colloidal “Saturn-like” Host–Guest Complexes Enabled by Toroidal Micellar Rubber Bands.

由環(huán)形膠束橡皮筋實現的膠體“類土星”主客體復合物的“自適應”組裝。

10.Catalytic Performance and Near-Surface X-ray Characterization of Titanium Hydride Electrodes for the Electrochemical Nitrate Reduction Reaction.

電化學硝酸鹽還原反應中氫化鈦電極的催化性能和近表面 X 射線表征。

11.Chemical Upcycling of Commercial Polystyrene via Catalyst-Controlled Photooxidation.

通過催化劑控制的光氧化對商業(yè)聚苯乙烯進行化學升級。

12.Concise Enantioselective Total Synthesis of Daphenylline Enabled by an Intramolecular Oxidative Dearomatization.

通過分子內氧化脫芳構化實現 Daphenylline 的簡明對映選擇性全合成。

13.Hypoiodite-Catalyzed Oxidative Umpolung of Indoles for Enantioselective Dearomatization.

用于對映選擇性脫芳構化的次碘酸鹽催化的吲哚氧化反作用。

14.Chemoselective (Hetero)Arene Electroreduction Enabled by Rapid Alternating Polarity.

快速交替極性實現的化學選擇性（雜）芳烴電還原。

15.Manipulating Nanoparticle Aggregates Regulates Receptor–Ligand Binding in Macrophages.

操縱納米粒子聚集體調節(jié)巨噬細胞中的受體-配體結合。

16.Size-Dependent Properties of Solution-Processable Conductive MOF Nanocrystals.

可溶液加工的導電 MOF 納米晶體的尺寸依賴特性。

17.Stacking Faults Assist Lithium-Ion Conduction in a Halide-Based Superionic Conductor.

堆垛層錯有助于鋰離子在鹵化物基超離子導體中的傳導。

18.Noninvasive and Spatiotemporal Control of DNAzyme-Based Imaging of Metal Ions In Vivo Using High-Intensity Focused Ultrasound.

使用高強度聚焦超聲對體內金屬離子基于 DNAzyme 的成像進行無創(chuàng)和時空控制。

19.Programmable Cell-Free Transcriptional Switches for Antibody Detection.

用于抗體檢測的可編程無細胞轉錄開關。

20.A Low-Volatile and Durable Deep Eutectic Electrolyte for High-Performance Lithium–Oxygen Battery.

用于高性能鋰氧電池的低揮發(fā)性和耐用的低共熔電解質。

21.Noncovalent Liquid Phase Functionalization of 2H-WS2 with PDI: An Energy Conversion Platform with Long-Lived Charge Separation.

2H-WS2 與 PDI 的非共價液相功能化：具有長壽命電荷分離的能量轉換平臺。

22.Metal–Metal Bonding as an Electrode Design Principle in the Low-Strain Cluster Compound LiScMo3O8.

金屬-金屬鍵合作為低應變簇化合物 LiScMo3O8 中的電極設計原則。

23.Diverse Catalytic Reactions for the Stereoselective Synthesis of Cyclic Dinucleotide MK-1454.

環(huán)狀二核苷酸 MK-1454 立體選擇性合成的多種催化反應。

24.Stabilization of Lead-Reduced Metal Halide Perovskite Nanocrystals by High-Entropy Alloying.

通過高熵合金穩(wěn)定鉛還原金屬鹵化物鈣鈦礦納米晶體。

25.In Situ Control of Crystallinity of 3D Colloidal Crystals by Tuning the Growth Kinetics of Nanoparticle Building Blocks.

通過調整納米顆粒構建塊的生長動力學原位控制 3D 膠體晶體的結晶度。

26.Robust Design of High-Performance Optoelectronic Chalcogenide Crystals from High-Throughput Computation.

基于高吞吐量計算的高性能光電硫族化物晶體的穩(wěn)健設計。

27.Orthogonal Amplification Circuits Composed of Acyclic Nucleic Acids Enable RNA Detection.

由無環(huán)核酸組成的正交放大電路可實現 RNA 檢測。

28.Probing the Mechanism of Isonitrile Formation by a Non-Heme Iron(II)-Dependent Oxidase/Decarboxylase.

探索非血紅素鐵 (II) 依賴性氧化酶/脫羧酶形成異腈的機制。

29.Photoinduced Arylation of Acridinium Salts: Tunable Photoredox Catalysts for C–O Bond Cleavage.

吖啶鹽的光誘導芳基化：用于 C-O 鍵裂解的可調光氧化還原催化劑。

30.Microscopic Insights into Cation-Coupled Electron Hopping Transport in a Metal–Organic Framework.

金屬有機骨架中陽離子耦合電子跳躍傳輸的微觀觀察。

31.Synchronous Preparation of Length-Controllable 1D Nanoparticles via Crystallization-Driven In Situ Nanoparticlization of Conjugated Polymers.

通過共軛聚合物的結晶驅動原位納米粒子同步制備長度可控的一維納米粒子。

32.Engineering O–O Species in Boron Nitrous Nanotubes Increases Olefins for Propane Oxidative Dehydrogenation.

在硼亞硝基納米管中設計 O-O 物種可增加用于丙烷氧化脫氫的烯烴。

33.2H-Imidazol-2-one O-Oxide: A Criegee Intermediate from a σ0π2 Singlet Ground-State Carbene.

2H-Imidazol-2-one O-Oxide：來自 σ0π2 單線態(tài)基態(tài)卡賓的 Criegee 中間體。

34.Rapid Allylic 1,6 H-Atom Transfer in an Unsaturated Criegee Intermediate.

不飽和 Criegee 中間體中的快速烯丙基 1,6 H 原子轉移。

35.Ruthenium Polypyridyl Complex Bound to a Unimolecular Chair-Form G-Quadruplex.

與單分子椅形 G-四鏈體結合的釕多吡啶復合物。

36.Benzylic Dehydroxylation of Echinocandin Antifungal Drugs Restores Efficacy against Resistance Conferred by Mutated Glucan Synthase.

棘白菌素類抗真菌藥物的芐基脫羥基作用可恢復抗突變葡聚糖合酶產生的耐藥性的功效。

37.Methane Monooxygenase Mimic Asymmetric Oxidation: Self-Assembling μ-Hydroxo, Carboxylate-Bridged Diiron(III)-Catalyzed Enantioselective Dehydrogenation.

甲烷單加氧酶模擬不對稱氧化：自組裝 μ-羥基、羧酸鹽橋聯二鐵 (III) 催化的對映選擇性脫氫。

38.Confronting the Challenging Asymmetric Carbonyl 1,2-Addition Using Vinyl Heteroarene Pronucleophiles: Ligand-Controlled Regiodivergent Processes through a Dearomatized Allyl–Cu Species.

使用乙烯基雜芳烴親核試劑應對具有挑戰(zhàn)性的不對稱羰基 1,2-加成：通過脫芳構化的烯丙基-銅物質進行配體控制的區(qū)域發(fā)散過程。

39.Chemical Inductor.

化學電感。

40.Sequencing-free Analysis of Multiple Methylations on Gene-Specific mRNAs.

基因特異性 mRNA 多重甲基化的無測序分析。

41.Dynamic Control of a Multistate Chiral Supramolecular Polymer in Water.

水中多態(tài)手性超分子聚合物的動態(tài)控制。

42.Hydrogen Spillover-Bridged Volmer/Tafel Processes Enabling Ampere-Level Current Density Alkaline Hydrogen Evolution Reaction under Low Overpotential.

氫溢出橋接 Volmer/Tafel 過程在低過電勢下實現安培級電流密度堿性析氫反應。

43.Catalytic Asymmetric Construction of Axially and Centrally Chiral Heterobiaryls by Minisci Reaction.

通過 Minisci 反應催化不對稱構建軸向和中心手性雜二芳基。

44.Self-Immolative Hydroxybenzylamine Linkers for Traceless Protein Modification.

用于無痕蛋白質修飾的自焚羥基芐胺接頭。

45.High-Spin (S = 1) Blatter-Based Diradical with Robust Stability and Electrical Conductivity.

具有穩(wěn)健穩(wěn)定性和導電性的高自旋 (S = 1) Blatter 基雙自由基。

46.Toward Totally Defined Nanocatalysis: Deep Learning Reveals the Extraordinary Activity of Single Pd/C Particles.

走向完全定義的納米催化：深度學習揭示了單個 Pd/C 粒子的非凡活性。

47.Stability Enhancement of a π-Stacked Helical Structure Using Substituents of an Amino Acid Side Chain: Helix Formation via a Nucleation–Elongation Mechanism.

使用氨基酸側鏈取代基增強 π 堆積螺旋結構的穩(wěn)定性：通過成核-延伸機制形成螺旋。

48.Gradient Hierarchically Porous Structure for Rapid Capillary-Assisted Catalysis.

用于快速毛細管輔助催化的梯度分級多孔結構。

49.Access to Cyclic N-Trifluoromethyl Ureas through Photocatalytic Activation of Carbamoyl Azides.

通過氨基甲酰疊氮化物的光催化活化獲得環(huán)狀 N-三氟甲基脲。

50.Cross-Linked Polyphosphazene Nanospheres Boosting Long-Lived Organic Room-Temperature Phosphorescence.

交聯聚磷腈納米球促進長壽命有機室溫磷光。

51.Correction to “C(sp3)–H Fluorination with a Copper(II)/(III) Redox Couple”.

更正“C(sp3)–H 用銅 (II)/(III) 氧化還原對進行氟化”。

52.Circular Discovery in Small Molecule and Conjugated Polymer Synthetic Methodology.

小分子和共軛聚合物合成方法中的循環(huán)發(fā)現。

53.Solvent Drives Switching between Λ and Δ Metal Center Stereochemistry of M8L6 Cubic Cages.

溶劑驅動 M8L6 立方籠的 Λ 和 Δ 金屬中心立體化學之間的切換。

54.Synthesis and Characterization of Binary, Highly Endothermic, and Extremely Sensitive 2,2′-Azobis(5-azidotetrazole).

二元、高度吸熱且極其敏感的 2,2'-偶氮雙（5-疊氮四唑）的合成與表征。

55.Strong Circularly Polarized Luminescence at 1550 nm from Enantiopure Molecular Erbium Complexes.

對映體純分子鉺配合物在 1550 nm 處的強圓偏振發(fā)光。

56.μMap-Red: Proximity Labeling by Red Light Photocatalysis.

μ Map-Red：通過紅光光催化進行鄰近標記。

57.Decarboxylative Borylation and Cross-Coupling of (Hetero)aryl Acids Enabled by Copper Charge Transfer Catalysis.

銅電荷轉移催化使（雜）芳基酸脫羧硼化和交叉偶聯。

58.Enantioselective Organocopper-Catalyzed Hetero Diels–Alder Reaction through in Situ Oxidation of Ethers into Enol Ethers.

通過將醚原位氧化成烯醇醚的對映選擇性有機銅催化的雜 Diels-Alder 反應。

59.Chirality Gearing in an Achiral Cage through Adaptive Binding.

通過自適應結合在非手性籠中進行手性傳動。

60.Nontraditional Fragment Couplings of Alcohols and Carboxylic Acids: C(sp3)–C(sp3) Cross-Coupling via Radical Sorting.

醇和羧酸的非傳統(tǒng)片段偶聯：通過自由基排序的 C(sp3)–C(sp3) 交叉偶聯。

61.Programmed Polyene Cyclization Enabled by Chromophore Disruption.

由發(fā)色團破壞啟用的程序化多烯環(huán)化。

62.Asymmetric Azide–Alkyne Cycloaddition with Ir(I)/Squaramide Cooperative Catalysis: Atroposelective Synthesis of Axially Chiral Aryltriazoles.

Ir(I)/Squaramide 協同催化的不對稱疊氮化物-炔烴環(huán)加成：軸向手性芳基三唑的阻轉選擇性合成。

63.Caging-Pnictogen-Induced Superconductivity in Skutterudites IrX3 (X = As, P).

方鈷礦 IrX3 (X = As, P) 中的籠養(yǎng)-Pnictogen 誘導的超導性。

64.Mechanism of Tripeptide Trimming of Amyloid β-Peptide 49 by γ-Secretase.

γ-分泌酶對淀粉樣蛋白 β-肽 49 的三肽修飾機制。

65.Donor–Acceptor Pyridinium Salts for Photo-Induced Electron-Transfer-Driven Modification of Tryptophan in Peptides, Proteins, and Proteomes Using Visible Light.

使用可見光對肽、蛋白質和蛋白質組中的色氨酸進行光誘導電子轉移驅動修飾的供體-受體吡啶鹽。

66.Small-Molecule Inhibitors Targeting Lipolysis in Human Adipocytes.

針對人體脂肪細胞脂解作用的小分子抑制劑。

67.Synthetic Mechanisms in the Formation of SnTe Nanocrystals.

SnTe 納米晶體形成的合成機制。

68.Peptidomimetic Wet-Adhesive PEGtides with Synergistic and Multimodal Hydrogen Bonding.

具有協同和多模式氫鍵的擬肽濕粘合劑 PEGtides。

69.Design of a Small Organic Template for the Synthesis of Self-Pillared Pentasil Zeolite Nanosheets.

用于合成自柱 Pentasil 沸石納米片的小型有機模板的設計。

70.Engineering Photomechanical Molecular Crystals to Achieve Extraordinary Expansion Based on Solid-State [2 + 2] Photocycloaddition.

工程光機械分子晶體以實現基于固態(tài) [2 + 2] 光環(huán)加成的非凡膨脹。

71.Stochastic Emergence of Two Distinct Self-Replicators from a Dynamic Combinatorial Library.

動態(tài)組合庫中兩個不同的自我復制器的隨機出現。

72.Synthetic Control of Exciton Dynamics in Bioinspired Cofacial Porphyrin Dimers.

Bioinspired Cofacial 卟啉二聚體中激子動力學的綜合控制。

73.Single-Stranded DNA-Encoded Gold Nanoparticle Clusters as Programmable Enzyme Equivalents.

單鏈 DNA 編碼的金納米粒子簇作為可編程酶等價物。

74.Why the Photochemical Reaction of Phenol Becomes Ultrafast at the Air–Water Interface: The Effect of Surface Hydration.

為什么苯酚的光化學反應在空氣-水界面變得超快：表面水化的影響。

75.Covalent Proximity Scanning of a Distal Cysteine to Target PI3Kα.

遠端半胱氨酸的共價接近掃描以靶向 PI3Kα。

76.Orange-Light-Induced Photochemistry Gated by pH and Confined Environments.

由 pH 值和密閉環(huán)境門控的橙光誘導光化學。

77.Alkyne Metathesis with d2 Re(V) Alkylidyne Complexes Supported by Phosphino-Phenolates: Ligand Effect on Catalytic Activity and Applications in Ring-Closing Alkyne Metathesis.

膦基酚鹽支持的 d2 Re(V) 炔烴配合物的炔復分解：配體對催化活性的影響及其在閉環(huán)炔烴復分解中的應用。

78.Oxidative Damage Induces a Vacancy G-Quadruplex That Binds Guanine Metabolites: Solution Structure of a cGMP Fill-in Vacancy G-Quadruplex in the Oxidized BLM Gene Promoter.

氧化損傷誘導結合鳥嘌呤代謝物的空位 G-四鏈體：氧化 BLM 基因啟動子中 cGMP 填充空位 G-四鏈體的溶液結構。

79.Unexpected Methyllanthionine Stereochemistry in the Morphogenetic Lanthipeptide SapT.

形態(tài)發(fā)生羊毛硫肽 SapT 中意外的甲基羊毛硫氨酸立體化學。

80.Ultra-Efficient Americium/Lanthanide Separation through Oxidation State Control.

通過氧化態(tài)控制實現超高效镅/鑭系元素分離。

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