聲明：本專欄主要對生命科學(xué)領(lǐng)域的一些期刊文章標(biāo)題進(jìn)行翻譯，所有內(nèi)容均由本人手工整理翻譯。由于本人專業(yè)為生物分析相關(guān)，其他領(lǐng)域如果出現(xiàn)翻譯錯誤請諒解。

1.Advancing the construction of circularly polarized luminescence (CPL) materials by molecular design has become an important target in this research area. In their Research Article (e202204358), Yoshio Hisaeda, Toshikazu Ono, and co-workers demonstrate a new bipyrrole-based boron difluoride family exhibiting intense multicolor luminescence with easy synthetic access. Tuning the rotational barrier around the 2,2′-bipyrrole affords CPL, and multicolor CPL can be achieved by controlling the aggregation state.

通過分子設(shè)計推進(jìn)圓偏振發(fā)光（CPL）材料的構(gòu)建已成為該研究領(lǐng)域的重要目標(biāo)。在他們的研究文章 (e202204358) 中，Yoshio Hisaeda、Toshikazu Ono 及其同事展示了一種新的基于聯(lián)吡咯的二氟化硼家族，該家族表現(xiàn)出強烈的多色發(fā)光且易于合成。調(diào)節(jié) 2,2'-聯(lián)吡咯周圍的旋轉(zhuǎn)勢壘可提供 CPL，并且可以通過控制聚集狀態(tài)來實現(xiàn)多色 CPL。

2.Photoacids have been understood, since the pioneering work of Theodor F?rster more than seven decades ago, to show a pronounced increase in acidity when electronically excited, but the underlying microscopic mechanisms have remained elusive. Sebastian Eckert et?al. show in their Research Article (e202200709) how time-resolved nitrogen K-edge spectroscopy along the F?rster cycle of a photoacid provides key insight into the electronic structural factors responsible for the photoacidity phenomenon.

自七十多年前 Theodor F?rster 的開創(chuàng)性工作以來，光酸已被人們理解為在電子激發(fā)時顯示出酸度的顯著增加，但其潛在的微觀機制仍然難以捉摸。塞巴斯蒂安·埃克特等人。在他們的研究文章 (e202200709) 中展示了光酸福斯特循環(huán)的時間分辨氮 K 邊光譜如何提供對導(dǎo)致光酸現(xiàn)象的電子結(jié)構(gòu)因素的關(guān)鍵見解。

3.The morphinan alkaloids , especially codeine and morphine, are derived from the opium poppy and have been used for millennia for pain management. They remain vital medicines today, but climate change and geopolitical uncertainties threaten existing supply chains. In their Communication (e202203186), Martin?G. Banwell, Ping Lan, and co-workers detail by far the shortest synthesis of (?)-codeine reported to date, which involves a total “in-flask” time of less than 24?hours.

嗎啡喃生物堿，尤其是可待因和嗎啡，源自罌粟，數(shù)千年來一直用于治療疼痛。如今，它們?nèi)匀皇侵匾乃幬?，但氣候變化和地緣政治的不確定性威脅著現(xiàn)有的供應(yīng)鏈。在他們的通訊 (e202203186) 中，Martin G. Banwell、Ping Lan 和同事詳細(xì)介紹了迄今為止報告的 (?)-可待因的最短合成，其總“燒瓶內(nèi)”時間不到 24 小時。

4.A chiral Lewis acid accelerated asymmetric Pudovik addition/[1,2]-phospha-Brook rearrangement is described by Shunxi Dong, Qian Peng, Xiaoming Feng, and co-workers in their Research Article (e202203650). Control experiments and theoretical calculations revealed that a synergistic effect of the counterion and water was critical for the regio- and enantioselective protonation after the [1,2]-phospha-Brook rearrangement.

Shunxi Dong、Qian Peng、Xiaoming Feng 及其同事在他們的研究文章 (e202203650) 中描述了手性 Lewis 酸加速不對稱 Pudovik 加成/[1,2]-phospha-Brook 重排。對照實驗和理論計算表明，抗衡離子和水的協(xié)同效應(yīng)對于[1,2]-磷酸-布魯克重排后的區(qū)域和對映選擇性質(zhì)子化至關(guān)重要。

5.Supramolecular Catalysis In their Communication (e202203671), Yao Wang and Xinglong Yuan report the synthesis and characterization of a selenide catalyst for the activation of alkenes through Se–π bonding.

超分子催化。在他們的通訊 (e202203671) 中，Yao Wang 和 Xinglong Yuan 報告了通過 Se-π 鍵活化烯烴的硒化物催化劑的合成和表征。

6.Immunotherapeutics The development of tumor-resident living immunotherapeutics is reported by Jinyao Liu et?al. in their Research Article (e202202409). The strategy is based on decorating bacteria with triple immune nanoactivators via in?situ dopamine polymerization.

免疫治療 Jinyao Liu 等人在他們的研究文章（e202202409）中報道了腫瘤駐留活體免疫治療的發(fā)展。該策略基于通過原位多巴胺聚合用三重免疫納米激活劑裝飾細(xì)菌。

7.Electrochemistry in Magnetic Fields.

磁場中的電化學(xué)。

8.Decorating Bacteria with Triple Immune Nanoactivators Generates Tumor-Resident Living Immunotherapeutics.

用三重免疫納米激活劑修飾細(xì)菌可產(chǎn)生腫瘤駐留活體免疫療法。

9.Strain of Supramolecular Interactions in Single-Stacking Junctions.

單堆疊連接中的超分子相互作用應(yīng)變。

10.Nickel-Based High-Entropy Intermetallic as a Highly Active and Selective Catalyst for Acetylene Semihydrogenation.

鎳基高熵金屬間化合物作為乙炔半加氫的高活性和選擇性催化劑。

11.Theory-Guided Regulation of FeN4 Spin State by Neighboring Cu Atoms for Enhanced Oxygen Reduction Electrocatalysis in Flexible Metal–Air Batteries.

鄰近 Cu 原子對 FeN4 自旋態(tài)的理論引導(dǎo)調(diào)節(jié)，增強柔性金屬空氣電池中的氧還原電催化作用。

12.A Valence-Engineered Self-Cascading Antioxidant Nanozyme for the Therapy of Inflammatory Bowel Disease.

用于治療炎癥性腸病的價態(tài)工程自級聯(lián)抗氧化劑納米酶。

13.Computational Design, Synthesis, and Photochemistry of Cy7-PPG, an Efficient NIR-Activated Photolabile Protecting Group for Therapeutic Applications.

Cy7-PPG 的計算設(shè)計、合成和光化學(xué)，一種用于治療應(yīng)用的高效近紅外激活的光不穩(wěn)定保護基團。

14.Enhanced Blue Afterglow through Molecular Fusion for Bio-applications.

通過分子融合增強藍(lán)色余輝的生物應(yīng)用。

15.Electronically Engineering Water Resistance in Methane Combustion with an Atomically Dispersed Tungsten on PdO Catalyst.

使用 PdO 催化劑上原子分散的鎢對甲烷燃燒中的電子工程耐水性進(jìn)行研究。

16.Programmed Supramolecular Assemblies Using Orthogonal Pairs of Heterodimeric Coiled Coil Peptides.

使用異二聚體卷曲螺旋肽正交對的編程超分子組裝體。

17.Introducing 4s–2p Orbital Hybridization to Stabilize Spinel Oxide Cathodes for Lithium-Ion Batteries.

引入 4s–2p 軌道雜交來穩(wěn)定鋰離子電池的尖晶石氧化物陰極。

18.Photocatalytic Chemical Crosslinking for Profiling RNA–Protein Interactions in Living Cells.

用于分析活細(xì)胞中 RNA-蛋白質(zhì)相互作用的光催化化學(xué)交聯(lián)。

19.Reticular Synthesis of Hydrogen-Bonded Organic Frameworks and Their Derivatives via Mechanochemistry.

通過機械化學(xué)來網(wǎng)狀合成氫鍵有機框架及其衍生物。

20.Modular Nitrogen-Doped Concave Polycyclic Aromatic Hydrocarbons for High-Performance Organic Light-Emitting Diodes with Tunable Emission Mechanisms.

用于具有可調(diào)發(fā)射機制的高性能有機發(fā)光二極管的模塊化氮摻雜凹面多環(huán)芳烴。

21.Efficient Triplet-Triplet Annihilation Upconversion Sensitized by a Chromium(III) Complex via an Underexplored Energy Transfer Mechanism.

通過未充分探索的能量轉(zhuǎn)移機制，由鉻 (III) 絡(luò)合物敏化的高效三重態(tài)-三重態(tài)湮滅上轉(zhuǎn)換。

22.Minimizing the Reorganization Energy of Cobalt Redox Mediators Maximizes Charge Transfer Rates from Quantum Dots.

最小化鈷氧化還原介體的重組能可最大化量子點的電荷轉(zhuǎn)移率。

23.Manganese-Catalysed Deuterium Labelling of Anilines and Electron-Rich (Hetero)Arenes.

錳催化氘標(biāo)記苯胺和富電子（雜）芳烴。

24.Poly(ionic liquid)-Armored MXene Membrane: Interlayer Engineering for Facilitated Water Transport.

聚（離子液體）鎧裝 MXene 膜：促進(jìn)水傳輸?shù)膶娱g工程。

25.Multimodal Imaging-Guided Photothermal Immunotherapy Based on a Versatile NIR-II Aggregation-Induced Emission Luminogen.

基于多功能 NIR-II 聚集誘導(dǎo)發(fā)射發(fā)光原的多模態(tài)成像引導(dǎo)光熱免疫治療。

26.Multicolor Zinc(II)-Coordinated Hydrazone-Based Bistable Photoswitches for Rewritable Transparent Luminescent Labels.

用于可重寫透明發(fā)光標(biāo)簽的多色鋅 (II) 配位腙基雙穩(wěn)態(tài)光電開關(guān)。

27.Amine-Catalyzed Copper-Mediated C?H Sulfonylation of Benzaldehydes via a Transient Imine Directing Group.

通過瞬態(tài)亞胺導(dǎo)向基團，胺催化銅介導(dǎo)苯甲醛的 C?H 磺?；?/p>

28.Lattice-Confined Single-Atom Fe1Sx on Mesoporous TiO2 for Boosting Ambient Electrocatalytic N2 Reduction Reaction.

介孔 TiO2 上的晶格限制單原子 Fe1Sx 用于促進(jìn)環(huán)境電催化 N2 還原反應(yīng)。

29.Highly Selective Photocatalytic CO2 Methanation with Water Vapor on Single-Atom Platinum-Decorated Defective Carbon Nitride.

水蒸氣對單原子鉑修飾的缺陷氮化碳進(jìn)行高選擇性光催化二氧化碳甲烷化。

30.Metallo-Supramolecular Octahedral Cages with Three Types of Chirality towards Spontaneous Resolution.

具有三種手性的金屬超分子八面體籠可實現(xiàn)自發(fā)解析。

31.An Activatable Polymeric Nanoprobe for Fluorescence and Photoacoustic Imaging of Tumor-Associated Neutrophils in Cancer Immunotherapy.

一種可激活的聚合物納米探針，用于癌癥免疫治療中腫瘤相關(guān)中性粒細(xì)胞的熒光和光聲成像。

32.Pushing Lithium–Sulfur Batteries towards Practical Working Conditions through a Cathode–Electrolyte Synergy.

通過陰極-電解質(zhì)協(xié)同作用將鋰硫電池推向?qū)嶋H工作條件。

33.Iridium-Catalyzed Ligand-Controlled Remote para-Selective C?H Activation and Borylation of Twisted Aromatic Amides.

銥催化配體控制的遠(yuǎn)程對位選擇性 C?H 激活和扭曲芳香酰胺的硼化。

34.Interfacial Polymetallic Oxides and Hierarchical Porous Core–Shell Fibres for High Energy-Density Electrochemical Supercapacitors.

用于高能量密度電化學(xué)超級電容器的界面多金屬氧化物和分層多孔核殼纖維。

35.Catalytic Regio- and Enantioselective Protonation for the Synthesis of Chiral Allenes: Synergistic Effect of the Counterion and Water.

用于合成手性丙二烯的催化區(qū)域和對映選擇性質(zhì)子化：抗衡離子和水的協(xié)同效應(yīng)。

36.A Hybrid Supramolecular Polymeric Nanomedicine for Cascade-Amplified Synergetic Cancer Therapy.

用于級聯(lián)放大協(xié)同癌癥治療的混合超分子聚合物納米藥物。

37.Synergy in Au?CuO Janus Structure for Catalytic Isopropanol Oxidative Dehydrogenation to Acetone.

Au?CuO Janus 結(jié)構(gòu)催化異丙醇氧化脫氫制丙酮的協(xié)同作用。

38.A New Strategy to Fight Metallodrug Resistance: Mitochondria-Relevant Treatment through Mitophagy to Inhibit Metabolic Adaptations of Cancer Cells.

對抗金屬耐藥性的新策略：通過線粒體自噬抑制癌細(xì)胞代謝適應(yīng)的線粒體相關(guān)治療。

39.MXene Analogue: A 2D Nitridene Solid Solution for High-Rate Hydrogen Production.

MXene 類似物：用于高速制氫的 2D 氮化物固溶體。

40.Hydrogen-Bonded Supramolecular Polymer Adhesives: Straightforward Synthesis and Strong Substrate Interaction.

氫鍵超分子聚合物粘合劑：直接合成和強基材相互作用。

41.Synthesis and Characterization of Hypercoordinated Silicon Anions: Catching Intermediates of Lewis Base Catalysis.

超配位硅陰離子的合成和表征：捕獲路易斯堿催化中間體。

42.Triarylamine/Bithiophene Copolymer with Enhanced Quinoidal Character as Hole-Transporting Material for Perovskite Solar Cells.

具有增強醌型特性的三芳胺/聯(lián)噻吩共聚物作為鈣鈦礦太陽能電池的空穴傳輸材料。

43.Liquid Na/K Alloy Interfacial Synthesis of Functional Porous Carbon at Ambient Temperature.

室溫下功能性多孔碳的液態(tài)Na/K合金界面合成。

44.Avoiding Structural Collapse to Reduce Lead Leakage in Perovskite Photovoltaics.

避免結(jié)構(gòu)倒塌以減少鈣鈦礦光伏中的鉛泄漏。

45.Highly Fluorescent Bipyrrole-Based Tetra-BF2 Flag-Hinge Chromophores: Achieving Multicolor and Circularly Polarized Luminescence.

基于雙吡咯的高熒光 Tetra-BF2 旗鉸鏈發(fā)色團：實現(xiàn)多色和圓偏振發(fā)光。

46.Fibrous Nanoreactors from Microfluidic Blow Spinning for Mass Production of Highly Stable Ligand-Free Perovskite Quantum Dots.

來自微流控吹紡的纖維納米反應(yīng)器用于大規(guī)模生產(chǎn)高度穩(wěn)定的無配體鈣鈦礦量子點。

47.Thermal Alteration in Adsorption Sites over SAPO-34 Zeolite.

SAPO-34 沸石吸附位點的熱變化。

48.Metal-Free SF6 Activation: A New SF5-Based Reagent Enables Deoxyfluorination and Pentafluorosulfanylation Reactions.

無金屬 SF6 活化：一種新型 SF5 基試劑可實現(xiàn)脫氧氟化和五氟磺?；磻?yīng)。

49.Evolution of the Dearomative Functionalization of Activated Quinolines and Isoquinolines: Expansion of the Electrophile Scope.

活化喹啉和異喹啉的脫芳香功能化的演變：親電子范圍的擴展。

50.Beyond Bioisosteres: Divergent Synthesis of Azabicyclohexanes and Cyclobutenyl Amines from Bicyclobutanes.

超越生物電子等排體：從雙環(huán)丁烷出發(fā)合成氮雜雙環(huán)己烷和環(huán)丁烯基胺。

51.Electronic Structure Changes of an Aromatic Amine Photoacid along the F?rster Cycle.

芳香胺光酸沿福斯特循環(huán)的電子結(jié)構(gòu)變化。

52.A Selenide Catalyst for the Activation of Alkenes through Se???π Bonding.

通過 Se???π 鍵激活烯烴的硒化物催化劑。

53.A New Cation-Ordered Structure Type with Multiple Thermal Redistributions in Co2InSbO6.

Co2InSbO6 中具有多重?zé)嵩俜植嫉男滦完栯x子有序結(jié)構(gòu)類型。

54.Expeditious Access to Morphinans by Chemical Synthesis.

通過化學(xué)合成快速獲得嗎啡喃。

55.A Ruthenium(II) Polypyridyl Complex Disrupts Actin Cytoskeleton Assembly and Blocks Cytokinesis.

釕 (II) 聚吡啶復(fù)合物會破壞肌動蛋白細(xì)胞骨架組裝并阻止細(xì)胞分裂。

56.Amphiphilic Polycarbonate Micellar Rhenium Catalysts for Efficient Photocatalytic CO2 Reduction in Aqueous Media.

用于在水介質(zhì)中高效光催化二氧化碳還原的兩親性聚碳酸酯膠束錸催化劑。

57.anti-Selective Borylstannylation of Alkynes with (o-Phenylenediaminato)borylstannanes by a Radical Mechanism.

通過自由基機制用（鄰苯二胺）硼基錫烷對炔烴進(jìn)行反選擇性硼基錫烷基化。

58.Silver-Templated γ-Keggin Alkyltin-Oxo Cluster: Electronic Structure and Optical Limiting Effect.

銀模板化的 γ-Keggin 烷基錫-氧代簇：電子結(jié)構(gòu)和光學(xué)限制效應(yīng)。

59.Dewar Metallabenzenes from Reactions of Metallacyclobutadienes with Alkynes.

金屬環(huán)丁二烯與炔烴反應(yīng)產(chǎn)生的杜瓦金屬苯。

60.Saving the Energy Loss in Lithium-Mediated Nitrogen Fixation by Using a Highly Reactive Li3N Intermediate for C?N Coupling Reactions.

通過使用高反應(yīng)活性的 Li3N 中間體進(jìn)行 CN 偶聯(lián)反應(yīng)，節(jié)省鋰介導(dǎo)的固氮過程中的能量損失。

61.Tetrahedral Liquid-Crystalline Networks: An A15-Like Frank–Kasper Phase Based on Rod-Packing.

四面體液晶網(wǎng)絡(luò)：基于棒堆積的類 A15 Frank-Kasper 相。

62.Scalable Nitrate Treatment for Constructing Integrated Surface Structures to Mitigate Capacity Fading and Voltage Decay of Li-Rich Layered Oxides.

用于構(gòu)建集成表面結(jié)構(gòu)的可擴展硝酸鹽處理，以減輕富鋰層狀氧化物的容量衰減和電壓衰減。

63.Vacuum-Assisted Thermal Annealing of CsPbI3 for Highly Stable and Efficient Inorganic Perovskite Solar Cells.

用于高度穩(wěn)定和高效無機鈣鈦礦太陽能電池的 CsPbI3 真空輔助熱退火。

64.Hydrophilic Catalysts with High Activity and Stability in the Aqueous Polymerization of Ethylene to High-Molecular-Weight-Polyethylene.

在乙烯水聚合成高分子量聚乙烯過程中具有高活性和穩(wěn)定性的親水催化劑。

65.Chiral Covalent Organic Framework Packed Nanochannel Membrane for Enantioseparation.

用于對映分離的手性共價有機框架填充納米通道膜。

66.Organic Ammonium Ion Battery: A New Strategy for a Nonmetallic Ion Energy Storage System.

有機銨離子電池：非金屬離子儲能系統(tǒng)的新策略。

67.Bonding in a Crystalline Tri-Thorium Cluster: Not σ-Aromatic But Still Unique.

晶體三釷簇中的鍵合：不是 σ-芳香族，但仍然是獨特的。

68.Synthesis of Single-Layer Two-Dimensional Metal–Organic Frameworks M3(HAT)2 (M=Ni, Fe, Co, HAT=1,4,5,8,9,12-hexaazatriphenylene) Using an On-Surface Reaction.

利用表面反應(yīng)合成單層二維金屬有機骨架 M3(HAT)2（M=Ni, Fe, Co, HAT=1,4,5,8,9,12-六氮雜苯并菲）。

69.Binaphthyl-Bridged Pyrenophanes: Intense Circularly Polarized Luminescence Based on a D2 Symmetry Strategy.

聯(lián)萘橋芘芬：基于 D2 對稱策略的強圓偏振發(fā)光。

70.Doubling the Length of the Longest Pyrene-Pyrazinoquinoxaline Molecular Nanoribbons.

將最長的芘-吡嗪并喹喔啉分子納米帶的長度加倍。

71.A Novel Catalytic Route to Polymerizable Bicyclic Cyclic Carbonate Monomers from Carbon Dioxide.

從二氧化碳聚合雙環(huán)環(huán)狀碳酸酯單體的新催化路線。

72.Promising Deep-Ultraviolet Birefringent Materials via Rational Design and Assembly of Planar π-Conjugated [B(OH)3] and [B3O3(OH)3] Functional Species.

通過平面π-共軛[B(OH)3]和[B3O3(OH)3]功能物種的合理設(shè)計和組裝，開發(fā)出有前途的深紫外雙折射材料。

73.Additive-Assisted Hydrophobic Li+-Solvated Structure for Stabilizing Dual Electrode Electrolyte Interphases through Suppressing LiPF6 Hydrolysis.

添加劑輔助的疏水性 Li+ 溶劑化結(jié)構(gòu)通過抑制 LiPF6 水解來穩(wěn)定雙電極電解質(zhì)界面。

74.Scalable Synthesis of Photoluminescent Single-Chain Nanoparticles by Electrostatic-Mediated Intramolecular Crosslinking.

通過靜電介導(dǎo)的分子內(nèi)交聯(lián)大規(guī)模合成光致發(fā)光單鏈納米粒子。

75.Anomalous Redox Features Induced by Strong Covalency in Layered NaTi1?yVyS2 Cathodes for Na-Ion Batteries.

鈉離子電池層狀 NaTi1?yVyS2 陰極中強共價引起的異常氧化還原特征。

76.The photocatalyzed uphill isomerization of drugs using Ru(bpy3)2 is reported by Nicolas Winssinger et?al. in their Research Article (e202203390). This chemistry was shown to locally convert inactive drugs into active ones that alter the tubulin dynamics in cells (green structures in the background of the picture).

Nicolas Winssinger 等人在他們的研究文章（e202203390）中報道了使用 Ru(bpy3)2 進(jìn)行藥物光催化上坡異構(gòu)化。這種化學(xué)反應(yīng)被證明可以將非活性藥物局部轉(zhuǎn)化為活性藥物，從而改變細(xì)胞中的微管蛋白動力學(xué)（圖片背景中的綠色結(jié)構(gòu)）。

77.Self-assembled architectures for the encapsulation and transport of anions and ion pairs are still rare. In their Research Article (e202201831), Max von?Delius and co-workers used the dynamic covalent chemistry of orthoesters in combination with urea-based diols and triethylene glycol not only for the formation of a chloride cryptate, but also for the simultaneous encapsulation of both ions present in cesium chloride.

用于封裝和傳輸陰離子和離子對的自組裝結(jié)構(gòu)仍然很少見。在他們的研究文章 (e202201831) 中，Max von Delius 及其同事使用原酸酯的動態(tài)共價化學(xué)與脲基二醇和三甘醇結(jié)合，不僅可以形成氯化物穴狀化合物，還可以同時封裝兩者氯化銫中存在的離子。

78.A multifunctional nanoplatform that allows for in?situ tracking of the spatial and temporal dynamics of enzymes in response to mitochondria-targeted photodynamic therapy is presented by Lele Li and co-workers in their Communication (e202203238). Activatable translocation of the specific enzyme to mitochondria is monitored during the NIR-light-triggered, spatially selective generation of reactive oxygen species.

Lele Li 及其同事在他們的通訊 (e202203238) 中提出了一種多功能納米平臺，可以原位跟蹤酶的空間和時間動態(tài)，以響應(yīng)線粒體靶向光動力療法。在近紅外光觸發(fā)、空間選擇性產(chǎn)生活性氧的過程中，監(jiān)測特定酶向線粒體的可激活易位。

79.A biomimetic catalyst for CO2 photoreduction was developed through self-assembling porphyrins into a hydrogen-bonded organic framework, as reported by Tian-Fu Liu, Rong Cao, and co-workers in their Research Article (e202203955). The combination of photosensitizers and redox centers in the structure not only allows for adequate photon input and efficient utilization of the photogenerated charge, but also changes the microenvironment surrounding the active sites.

正如 Tian-Fu Liu、Rong Cao 及其同事在他們的研究文章 (e202203955) 中報道的那樣，通過將卟啉自組裝成氫鍵有機框架，開發(fā)了一種用于 CO2 光還原的仿生催化劑。結(jié)構(gòu)中光敏劑和氧化還原中心的結(jié)合不僅可以實現(xiàn)足夠的光子輸入和光生電荷的有效利用，而且還可以改變活性位點周圍的微環(huán)境。

80.Nanomembranes. In their Communication (e202204953), Andrey Turchanin et?al. present two concepts to introduce a photoactive Ru(II) polypyridine complex into carbon nanomembranes. The photoactive units are either directly incorporated into the scaffold or covalently grafted to its surface. Frontispiece art by Ilia Ghiasedin.

納米膜。 Andrey Turchanin 等人在他們的通訊 (e202204953) 中。提出了將光活性 Ru(II) 聚吡啶絡(luò)合物引入碳納米膜的兩個概念。光敏單元要么直接摻入支架中，要么共價接枝到其表面。卷首藝術(shù)由 Ilia Ghiasedin 繪制。

81.Carbenes. In their Research Article (e202202637), Tharangattu N. Narayanan, Carola Schulzke, Cem?B. Yildiz, Anukul Jana et?al. report the in?situ generation of cyclic (alkyl)(amino)carbenes through the thermal 1,1-dehydration of secondary pyrrolidin-2-ol alcohols.

卡賓。 Tharangattu N. Narayanan、Carola Schulzke、Cem B. Yildiz、Anukul Jana 等人在他們的研究文章 (e202202637) 中。報道了通過仲吡咯烷-2-醇的熱1,1-脫水原位生成環(huán)狀(烷基)(氨基)卡賓。

82.The Influence of Nanoconfinement on Electrocatalysis.

納米限制對電催化的影響。

83.Realizing 1,1-Dehydration of Secondary Alcohols to Carbenes: Pyrrolidin-2-ols as a Source of Cyclic (Alkyl)(Amino)Carbenes.

實現(xiàn)仲醇 1,1-脫水生成卡賓：吡咯烷-2-醇作為環(huán)狀（烷基）（氨基）卡賓的來源。

84.Intermolecular Energy Gap-Induced Formation of High-Valent Cobalt Species in CoOOH Surface Layer on Cobalt Sulfides for Efficient Water Oxidation.

分子間能隙誘導(dǎo)硫化鈷 CoOOH 表面層高價鈷物質(zhì)的形成，用于高效水氧化。

85.Hybrid Pyridine–Pyridone Foldamer Channels as M2-Like Artificial Proton Channels.

混合吡啶-吡啶酮折疊體通道作為 M2 類人工質(zhì)子通道。

86.Modulating the Electronic Metal-Support Interactions in Single-Atom Pt1?CuO Catalyst for Boosting Acetone Oxidation.

調(diào)節(jié)單原子 Pt1?CuO 催化劑中的電子金屬-載體相互作用以促進(jìn)丙酮氧化。

87.Protein Flexibility and Dissociation Pathway Differentiation Can Explain Onset of Resistance Mutations in Kinases.

蛋白質(zhì)靈活性和解離途徑分化可以解釋激酶耐藥突變的發(fā)生。

88.Metal-Free C?H Functionalization via Diaryliodonium Salts with a Chemically Robust Dummy Ligand.

通過二芳基碘鹽與化學(xué)穩(wěn)定的虛擬配體進(jìn)行無金屬 C?H 官能化。

89.Hydrogen-Bonded Organic Framework (HOF)-Based Single-Neural Stem Cell Encapsulation and Transplantation to Remodel Impaired Neural Networks.

基于氫鍵有機框架（HOF）的單神經(jīng)干細(xì)胞封裝和移植以重塑受損的神經(jīng)網(wǎng)絡(luò)。

90.Harnessing Natural Products by a Pharmacophore-Oriented Semisynthesis Approach for the Discovery of Potential Anti-SARS-CoV-2 Agents.

通過面向藥效團的半合成方法利用天然產(chǎn)物來發(fā)現(xiàn)潛在的抗 SARS-CoV-2 藥物。

91.Copper-Catalyzed Radical Enantioselective Carbo-Esterification of Styrenes Enabled by a Perfluoroalkylated-PyBox Ligand.

全氟烷基化 PyBox 配體實現(xiàn)銅催化苯乙烯自由基對映選擇性碳酯化。

92.In Operando Identification of In Situ Formed Metalloid Zincδ+ Active Sites for Highly Efficient Electrocatalyzed Carbon Dioxide Reduction.

原位形成的準(zhǔn)金屬鋅δ+活性位點的現(xiàn)場鑒定，用于高效電催化二氧化碳還原。

93.Adatom Bonding Sites in a Nickel-Fe3O4(001) Single-Atom Model Catalyst and O2 Reactivity Unveiled by Surface Action Spectroscopy with Infrared Free-Electron Laser Light.

采用紅外自由電子激光的表面作用光譜揭示了鎳-Fe3O4(001) 單原子模型催化劑中的吸附原子鍵合位點和 O2 反應(yīng)性。

94.Crystalline Porphyrazine-Linked Fused Aromatic Networks with High Proton Conductivity.

具有高質(zhì)子傳導(dǎo)率的結(jié)晶四氮雜卟啉連接的稠合芳香族網(wǎng)絡(luò)。

95.Towards Control and Oversight of SARS-CoV-2 Diagnosis and Monitoring through Multiplexed Quantitative Electroanalytical Immune Response Biosensors.

通過多重定量電分析免疫反應(yīng)生物傳感器控制和監(jiān)督 SARS-CoV-2 診斷和監(jiān)測。

96.Optochemical Control of Therapeutic Agents through Photocatalyzed Isomerization.

通過光催化異構(gòu)化對治療劑進(jìn)行光化學(xué)控制。

97.Confinement-Induced Selectivities in Gold(I) Catalysis—The Benefit of Using Bulky Tri-(ortho-biaryl)phosphine Ligands.

金 (I) 催化中限制誘導(dǎo)的選擇性 - 使用大體積三（鄰聯(lián)芳基）膦配體的好處。

98.Rapid High-Contrast Photoreversible Coloration of Surface-Functionalized N-Doped TiO2 Nanocrystals for Rewritable Light-Printing.

用于可重寫光打印的表面功能化 N 摻雜 TiO2 納米晶體的快速高對比度光可逆著色。

99.Photocaging of Activity-Based Ubiquitin Probes via a C-Terminal Backbone Modification Strategy.

通過 C 端主鏈修飾策略對基于活性的泛素探針進(jìn)行光籠蔽。

100.Programming Receptor Clustering with DNA Probabilistic Circuits for Enhanced Natural Killer Cell Recognition.

使用 DNA 概率電路對受體聚類進(jìn)行編程，以增強自然殺傷細(xì)胞識別。

============================================

由于專欄圖片數(shù)量限制，關(guān)注我的個人公眾號“遠(yuǎn)夢研”查看更多。