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【標題速讀】【Angew】【2022年】【9月】

2023-08-18 17:05 作者:Rt_Cola  | 我要投稿

聲明:本專欄主要對生命科學領域的一些期刊文章標題進行翻譯,所有內容均由本人手工整理翻譯。由于本人專業(yè)為生物分析相關,其他領域如果出現(xiàn)翻譯錯誤請諒解。

1.Electroreduction of CO2 to acetate provides a promising strategy to reduce CO2 emissions and store renewable energy, but acetate is usually a by-product. A covalent organic framework with isolated active sites for the highly selective electroreduction of CO2 to acetate is reported by Pei-Qin Liao and co-workers in their Communication (e202206470). The copper–phthalocyanine active site with high electron density is conducive to the key step of C?C coupling of *CH3 with CO2 to produce acetate, and can avoid the coupling of *CO with *CO or *CHO to produce ethylene and ethanol.

將二氧化碳電還原為乙酸鹽為減少二氧化碳排放和儲存可再生能源提供了一種有前途的策略,但乙酸鹽通常是副產品。 Pei-Qin Liao 及其同事在他們的通訊 (e202206470) 中報道了一種具有隔離活性位點的共價有機框架,用于將 CO2 高選擇性電還原為乙酸鹽。高電子密度的銅酞菁活性位點有利于*CH3與CO2 C?C偶聯(lián)生成乙酸的關鍵步驟,并且可以避免*CO與*CO或*CHO偶聯(lián)生成乙烯和乙醇。

2.Atomically precise doping is a promising approach for functionalizing gold superatoms. In their Research Article (e202207290), Tatsuya Tsukuda and co-workers synthesized a series of M@Au12 superatoms (M=Au, Pd, Pt, Rh, or Ir) and investigated their photophysical and photochemical properties. Doping an M element positioned at the lower left of the periodic table led to a remarkable enhancement of the photoluminescence quantum yield and photocatalytic activities for intramolecular [2+2] cycloaddition of bisenone.

原子精確摻雜是金超原子功能化的一種有前途的方法。Tatsuya Tsukuda 和同事在他們的研究文章 (e202207290) 中合成了一系列 M@Au12 超原子(M=Au、Pd、Pt、Rh 或 Ir),并研究了它們的光物理和光化學性質。摻雜位于元素周期表左下角的M元素可以顯著提高雙烯酮分子內[2+2]環(huán)加成的光致發(fā)光量子產率和光催化活性。

3.Flying elephants and delicate cargo. Electrospray ionization of proteins has been likened to making molecular elephants fly. In their Communication (e202202075), Helen?J. Cooper and co-workers demonstrate mass spectrometry detection and imaging of a non-covalent complex formed in?vivo, comprising an endogenous protein and an exogenously administered drug molecule, directly from liver tissue. These methods will provide greater insight into protein–drug complexes in support of drug research and development.

飛翔的大象和精致的貨物。蛋白質的電噴霧電離被比作使分子象飛翔。Helen J. Cooper 及其同事在他們的通訊 (e202202075) 中演示了直接從肝組織中形成的體內形成的非共價復合物的質譜檢測和成像,該非共價復合物包含內源性蛋白質和外源性給藥的藥物分子。這些方法將提供對蛋白質-藥物復合物的更深入的了解,以支持藥物研究和開發(fā)。

4.An efficient polyelectrolyte hole-transport layer was explored for 2D perovskite solar cells by using a compatible butylamine cation, as reported by Jianyu Yuan and co-workers in their Research Article (e202205111). The tailored polyelectrolyte has an anchoring effect and acts as a passivator for 2D perovskites, which can improve 2D perovskite phase alignment and interfacial charge transfer efficiency, and finally enables high-efficiency and large-area 2D perovskite solar cells.

正如Jianyu Yuan 及其同事在他們的研究文章 (e202205111) 中報道的那樣,通過使用相容的丁胺陽離子,探索了一種用于二維鈣鈦礦太陽能電池的高效聚電解質空穴傳輸層。定制的聚電解質具有錨定效應,作為二維鈣鈦礦的鈍化劑,可以改善二維鈣鈦礦的相排列和界面電荷轉移效率,最終實現(xiàn)高效、大面積的二維鈣鈦礦太陽能電池。

5.Electrochemistry. In their Communication (e202206236), Qinghua Ji et?al. demonstrate an in?operando visualization method for investigating the dynamic electrochemical processes occurring at electrode–solution interfaces.

電化學。Qinghua Ji 等人在他們的通訊(e202206236)中展示一種用于研究電極-溶液界面處發(fā)生的動態(tài)電化學過程的操作可視化方法。

6.Mass Spectrometry. In their Research Article (e202205720), Jana Roithová et?al. introduce a method for determining enantioselectivities by mass spectrometry. This method is based on ion mobility separation of diastereomeric intermediates.

質譜。 Jana Roithová 等人在他們的研究文章 (e202205720) 中介紹一種通過質譜法測定對映選擇性的方法。該方法基于非對映體中間體的離子淌度分離。

7.Spotting Trends in Organocatalyzed and Other Organomediated (De)polymerizations and Polymer Functionalizations.

發(fā)現(xiàn)有機催化和其他有機介導的(解)聚合和聚合物官能化的趨勢。

8.Monitoring Reaction Intermediates to Predict Enantioselectivity Using Mass Spectrometry.

使用質譜法監(jiān)測反應中間體以預測對映選擇性。

9.Nickel-Catalyzed Asymmetric Hydroaryloxy- and Hydroalkoxycarbonylation of Cyclopropenes.

鎳催化環(huán)丙烯的不對稱加氫芳氧基和加氫烷氧基羰基化。

10.BTDAzo: A Photoswitchable TRPC5 Channel Activator.

BTDAzo:光可切換 TRPC5 通道激活劑。

11.A SLC35C2 Transporter-Targeting Fluorescent Probe for the Selective Detection of B Lymphocytes Identified by SLC-CRISPRi and Unbiased Fluorescence Library Screening.

用于選擇性檢測 SLC-CRISPRi 和無偏熒光文庫篩選鑒定的 B 淋巴細胞的 SLC35C2 轉運蛋白靶向熒光探針。

12.Molecularly Precise, Bright, Photostable, and Biocompatible Cyanine Nanodots as Alternatives to Quantum Dots for Biomedical Applications.

分子精確、明亮、光穩(wěn)定且生物相容的花青納米點作為生物醫(yī)學應用中量子點的替代品。

13.DNA-Programmable AgAuS-Primed Conductive Nanowelding Wires-Up Wet Colloids.

DNA 可編程 AgAuS 底漆導電納米焊絲濕膠體。

14.Low-Pt NiNC-Supported PtNi Nanoalloy Oxygen Reduction Reaction Electrocatalysts—In Situ Tracking of the Atomic Alloying Process.

低 Pt NiNC 負載的 PtNi 納米合金氧還原反應電催化劑——原子合金化過程的原位跟蹤。

15.A Traceless Site-Specific Conjugation on Native Antibodies Enables Efficient One-Step Payload Assembly.

天然抗體上的無痕位點特異性綴合可實現(xiàn)高效的一步有效負載組裝。

16.Construction of Benzocyclobutenes Enabled by Visible-Light-Induced Triplet Biradical Atom Transfer of Olefins.

通過可見光誘導烯烴三重態(tài)雙自由基原子轉移構建苯并環(huán)丁烯。

17.Hydrogen Tunneling in Catalytic Hydrolysis and Alcoholysis of Silanes.

硅烷催化水解和醇解中的氫隧道。

18.Biodegradable Ca2+ Nanomodulators Activate Pyroptosis through Mitochondrial Ca2+ Overload for Cancer Immunotherapy.

可生物降解的 Ca2+ 納米調節(jié)劑通過線粒體 Ca2+ 超載激活細胞焦亡,用于癌癥免疫治療。

19.Zirconium-oxo Nodes of MOFs with Tunable Electronic Properties Provide Effective ?OH Species for Enhanced Methane Hydroxylation.

具有可調電子特性的 MOF 的鋯氧節(jié)點為增強甲烷羥基化提供了有效的·OH 物種。

20.Tailoring Phase Alignment and Interfaces via Polyelectrolyte Anchoring Enables Large-Area 2D Perovskite Solar Cells.

通過聚電解質錨定調整相對準和界面可實現(xiàn)大面積二維鈣鈦礦太陽能電池。

21.A Three-Dimensional Inorganic Analogue of 9,10-Diazido-9,10-Diboraanthracene: A Lewis Superacidic Azido Borane with Reactivity and Stability.

9,10-二疊氮基-9,10-二硼蒽的三維無機類似物:具有反應性和穩(wěn)定性的路易斯超酸性疊氮基硼烷。

22.A Chimeric Conjugate of Antibody and Programmable DNA Nanoassembly Smartly Activates T Cells for Precise Cancer Cell Targeting.

抗體和可編程 DNA 納米組件的嵌合綴合物可智能激活 T 細胞,實現(xiàn)精確的癌細胞靶向。

23.An Activity-Based Fluorescent Probe for Imaging Fluctuations of Peroxynitrite (ONOO?) in the Alzheimer's Disease Brain.

一種基于活動的熒光探針,用于對阿爾茨海默病大腦中過氧亞硝酸鹽 (ONOO?) 的波動進行成像。

24.Efficient Production of L-Homophenylalanine by Enzymatic-Chemical Cascade Catalysis.

通過酶化學級聯(lián)催化高效生產 L-高苯丙氨酸。

25.Metal-Free PAZE-NH4X3?H2O Perovskite for Flexible Transparent X-ray Detection and Imaging.

無金屬 PAZE-NH4X3?H2O 鈣鈦礦,用于靈活的透明 X 射線檢測和成像。

26.Structural and Dynamic Analysis of Sulphur Dioxide Adsorption in a Series of Zirconium-Based Metal–Organic Frameworks.

一系列鋯基金屬有機框架中二氧化硫吸附的結構和動態(tài)分析。

27.Doping-Mediated Energy-Level Engineering of M@Au12 Superatoms (M=Pd, Pt, Rh, Ir) for Efficient Photoluminescence and Photocatalysis.

用于高效光致發(fā)光和光催化的 M@Au12 超原子(M=Pd、Pt、Rh、Ir)的摻雜介導能級工程。

28.Sulfur–Phenolate Exchange: SuFEx-Derived Dynamic Covalent Reactions and Degradation of SuFEx Polymers.

硫-酚鹽交換:SuFEx 衍生的動態(tài)共價反應和 SuFEx 聚合物的降解。

29.The Rational Design and Atroposelective Synthesis of Axially Chiral C2-Arylpyrrole-Derived Amino Alcohols.

軸向手性 C2-芳基吡咯衍生氨基醇的合理設計和旋轉選擇性合成。

30.Nickel-Catalyzed Enantioselective Reductive Alkyl-Carbamoylation of Internal Alkenes.

鎳催化內烯烴的對映選擇性還原烷基氨基甲酰化。

31.Design of Three-Dimensional Covalent Organic Framework Membranes for Fast and Robust Organic Solvent Nanofiltration.

用于快速、穩(wěn)健的有機溶劑納濾的三維共價有機框架膜的設計。

32.Lysosome Interference Enabled by Proton-Driven Dynamic Assembly of DNA Nanoframeworks inside Cells.

細胞內質子驅動的 DNA 納米框架動態(tài)組裝實現(xiàn)溶酶體干擾。

33.Creating Frustrated Lewis Pairs in Defective Boron Carbon Nitride for Electrocatalytic Nitrogen Reduction to Ammonia.

在有缺陷的碳氮化硼中產生受阻路易斯對,用于電催化氮還原為氨。

34.Third-Generation Covalent TMP-Tag for Fast Labeling and Multiplexed Imaging of Cellular Proteins.

用于細胞蛋白質快速標記和多重成像的第三代共價 TMP 標簽。

35.para-Selective Radical Trifluoromethylation of Benzamide Derivatives via Iminium Intermediates.

通過亞胺中間體對苯甲酰胺衍生物進行對位選擇性自由基三氟甲基化。

36.Impact of Strain Relaxation on 2D Ruddlesden–Popper Perovskite Solar Cells.

應變弛豫對二維 Ruddlesden-Popper 鈣鈦礦太陽能電池的影響。

37.High-Performance Thermoelectric α-Ag9Ga1?xTe6 Compounds with Ultralow Lattice Thermal Conductivity Originating from Ag9Te2 Motifs.

源自 Ag9Te2 基序的具有超低晶格熱導率的高性能熱電 α-Ag9Ga1?xTe6 化合物。

38.Dual Reactivity of a Geometrically Constrained Phosphenium Cation.

幾何約束磷陽離子的雙重反應性。

39.Trojan Nanobacteria System for Photothermal Programmable Destruction of Deep Tumor Tissues.

用于光熱可編程破壞深部腫瘤組織的特洛伊納米細菌系統(tǒng)。

40.Highly Regioselective Cobalt-Catalyzed Hydroboration of Internal Alkynes.

內炔烴的高度區(qū)域選擇性鈷催化硼氫化反應。

41.Tug-of-War between Two Distinct Catalytic Sites Enables Fast and Selective Ring-Opening Copolymerizations.

兩個不同催化位點之間的拉鋸戰(zhàn)實現(xiàn)了快速、選擇性的開環(huán)共聚。

42.Self-Assembly of Adaptive Chiral [1]Rotaxane for Thermo-Rulable Circularly Polarized Luminescence.

用于熱控圓偏振發(fā)光的自適應手性[1]輪烷的自組裝。

43.Tuning Proapoptotic Activity of a Phosphoric-Acid-Tethered Tetraphenylethene by Visible-Light-Triggered Isomerization and Switchable Protein Interactions for Cancer Therapy.

通過可見光觸發(fā)的異構化和可切換的蛋白質相互作用來調節(jié)磷酸束縛的四苯乙烯的促凋亡活性,用于癌癥治療。

44.Consequences of Noncovalent Interfacial Contacts between Nanoparticles and Giant Vesicles.

納米顆粒和巨型囊泡之間非共價界面接觸的后果。

45.Phenacyl Bromide as a Single-Component Photoinitiator: Photoinduced Step-Growth Polymerization of N-Methylpyrrole and N-Methylindole.

苯甲酰溴作為單組分光引發(fā)劑:N-甲基吡咯和 N-甲基吲哚的光誘導逐步生長聚合。

46.A General and Efficient Solution to Monofluoroalkylation: Divergent Synthesis of Aliphatic Monofluorides with Modular Synthetic Scaffolds.

單氟烷基化的通用且有效的解決方案:使用模塊化合成支架的脂肪族單氟化物的發(fā)散合成。

47.Over 70?% Faradaic Efficiency for CO2 Electroreduction to Ethanol Enabled by Potassium Dopant-Tuned Interaction between Copper Sites and Intermediates.

通過鉀摻雜劑調節(jié)銅位點和中間體之間的相互作用,CO2 電還原為乙醇的法拉第效率超過 70%。

48.Atomically Dispersed Pentacoordinated-Zirconium Catalyst with Axial Oxygen Ligand for Oxygen Reduction Reaction.

用于氧還原反應的具有軸向氧配體的原子分散五配位鋯催化劑。

49.Directed Dehydration as Synthetic Tool for Generation of a New Na4SnS4 Polymorph: Crystal Structure, Na+ Conductivity, and Influence of Sb-Substitution.

定向脫水作為生成新 Na4SnS4 多晶型物的合成工具:晶體結構、Na+ 電導率和 Sb 取代的影響。

50.An Adaptive Rhodium Catalyst to Control the Hydrogenation Network of Nitroarenes.

控制硝基芳烴加氫網絡的自適應銠催化劑。

51.Umpolung in a Pair of Cobalt(III) Terminal Imido/Imidyl Complexes.

一對鈷 (III) 末端亞氨基/亞胺基配合物中的 Umpolung。

52.In Operando Visualization and Dynamic Manipulation of Electrochemical Processes at the Electrode–Solution Interface.

電極-溶液界面電化學過程的操作可視化和動態(tài)操縱。

53.Mass Spectrometry Detection and Imaging of a Non-Covalent Protein–Drug Complex in Tissue from Orally Dosed Rats.

口服給藥大鼠組織中非共價蛋白質-藥物復合物的質譜檢測和成像。

54.Drug Repurposing by Siderophore Conjugation: Synthesis and Biological Evaluation of Siderophore-Methotrexate Conjugates as Antibiotics.

通過鐵載體結合物重新利用藥物:鐵載體-甲氨蝶呤結合物作為抗生素的合成和生物學評價。

55.Topochemical, Single-Crystal-to-Single-Crystal [2+2] Photocycloadditions Driven by Chalcogen-Bonding Interactions.

由硫屬鍵相互作用驅動的拓撲化學、單晶到單晶 [2+2] 光環(huán)加成。

56.A Stable and Conductive Covalent Organic Framework with Isolated Active Sites for Highly Selective Electroreduction of Carbon Dioxide to Acetate.

具有隔離活性位點的穩(wěn)定導電共價有機框架,用于二氧化碳高選擇性電還原為乙酸。

57.Stereodivergent Construction of 1,4-Nonadjacent Stereocenters via Hydroalkylation of Racemic Allylic Alcohols Enabled by Copper/Ruthenium Relay Catalysis.

通過銅/釕中繼催化外消旋烯丙醇的加氫烷基化來立體發(fā)散構建 1,4-不相鄰立體中心。

58.PEG-Functionalized Hollow Multishelled Structures with On-Off Switch and Rate-Regulation for Controllable Antimicrobial Release.

具有開關和速率調節(jié)功能的 PEG 功能化中空多殼結構,可實現(xiàn)可控抗菌劑釋放。

59.H2O2-Responsive NIR-II AIE Nanobomb for Carbon Monoxide Boosting Low-Temperature Photothermal Therapy.

H2O2 響應式 NIR-II AIE 納米炸彈,用于一氧化碳促進低溫光熱療法。

60.Methyl Substitution Destabilizes Alkyl Radicals.

甲基取代會破壞烷基自由基的穩(wěn)定性。

61.High-Performance Lithium–Oxygen Batteries Using a Urea-Based Electrolyte with Kinetically Favorable One-Electron Li2O2 Oxidation Pathways.

使用尿素基電解質的高性能鋰氧電池,具有動力學上有利的單電子 Li2O2 氧化途徑。

62.A Mechanochemical, Catalyst-Free Cascade Synthesis of 1,3-Diols and 1,4-Iodoalcohols Using Styrenes and Hypervalent Iodine Reagents.

使用苯乙烯和高價碘試劑機械化學、無催化劑級聯(lián)合成 1,3-二醇和 1,4-碘醇。

63.Dearomative Ring Expansion of Polycyclic Arenes.

多環(huán)芳烴的脫芳香擴環(huán)。

64.Synergy of Weakly-Solvated Electrolyte and Optimized Interphase Enables Graphite Anode Charge at Low Temperature.

弱溶劑化電解質和優(yōu)化界面的協(xié)同作用使石墨陽極能夠在低溫下充電。

65.Polyzwitterionic Hydrogels for Highly Efficient High Salinity Solar Desalination.

用于高效高鹽度太陽能海水淡化的聚兩性離子水凝膠。

66.Additive-Triggered Polar Polymorph Formation: β-Sc(IO3)3, a Promising Next-Generation Mid-Infrared Nonlinear Optical Material.

加法觸發(fā)極性多晶型物形成:β-Sc(IO3)3,一種有前途的下一代中紅外非線性光學材料。

67.Work-function-induced Interfacial Built-in Electric Fields in Os-OsSe2 Heterostructures for Active Acidic and Alkaline Hydrogen Evolution.

用于活性酸性和堿性析氫的 Os-OsSe2 異質結構中功函數(shù)誘導的界面內置電場。

68.(4+3) Annulation of Donor-Acceptor Cyclopropanes and Azadienes: Highly Stereoselective Synthesis of Azepanones.

供體-受體環(huán)丙烷和氮二烯的(4+3)環(huán)化:氮雜環(huán)庚酮的高度立體選擇性合成。

69.Au20(tBu3P)8: A Highly Symmetric Metalloid Gold Cluster in Oxidation State 0.

Au20(tBu3P)8:氧化態(tài) 0 的高度對稱非金屬金簇。

70.Stable Two-Legged Parent Piano-Stool and Mixed Diborabenzene-E4 (E=P, As) Sandwich Complexes of Group 8.

穩(wěn)定的雙足母琴凳和第 8 族混合二硼苯-E4(E=P,As)夾心配合物。

71.Solvent-Dependent Oxidative Addition and Reductive Elimination of H2 Across a Gallium-Zinc Bond.

鎵鋅鍵上 H2 的溶劑依賴性氧化加成和還原消除。

72.Crystal Structure Based Mutagenesis of Cattleyene Synthase Leads to the Generation of Rearranged Polycyclic Diterpenes.

基于晶體結構的 Cattleyene 合酶誘變導致重排多環(huán)二萜的產生。

73.A linker scissoring strategy to control the shape of metal–organic framework (MOF) nanoparticles from nanoplates to nanorods by surface conformational pairing is reported by Hong-Cai Zhou, Zhi-Yuan Gu et?al. in their Research Article (e202207786). Both structure and shape influence the separation ability of MOF stationary phases in gas chromatography by affecting the thermodynamic and kinetic diffusion factors.

Hong-Cai Zhou、Zhi-Yuan Gu 等人在他們的研究文章(e202207786)中報道了一種通過表面構象配對來控制從納米板到納米棒的金屬有機框架 (MOF) 納米顆粒形狀的連接器剪切策略。結構和形狀都通過影響熱力學和動力學擴散因子來影響氣相色譜中 MOF 固定相的分離能力。

74.Bioremediation. The discovery of MG8, an efficient polyethylene terephthalate (PET) hydrolase enzyme from the human saliva metagenome, is reported by Worawan Bhanthumnavin, Chayasith Uttamapinant et?al. in their Research Article (e202203061). Aside from its plastic degradation capability, MG8 was further engineered via genetic code expansion into a covalent binder of PET plastic and can be used to attach protein payloads to PET and other polyesters.

生物修復。 Worawan Bhanthumnavin、Chayasith Uttamapinant 等人在他們的研究文章(e202203061)中報道了從人類唾液宏基因組中發(fā)現(xiàn)的一種高效聚對苯二甲酸乙二醇酯 (PET) 水解酶 MG8。除了其塑料降解能力外,MG8還通過遺傳密碼擴展進一步設計為PET塑料的共價粘合劑,可用于將蛋白質有效負載附著到PET和其他聚酯上。

75.The site-selective functionalization of carboranes with multiple B?H sites is a long-standing challenge. In their Research Article (e202205672), Deshuang Tu, Changsheng Lu, Hong Yan, and co-workers developed an efficient reaction protocol for the selective alkylation, alkenylation, and heteroarylation of carboranes under mild conditions via boron-vertex-centered carboranyl radicals generated by photo-induced decarboxylation of boron-substituted carborane carboxylic acids.

具有多個 B?H 位點的碳硼烷的位點選擇性官能化是一個長期存在的挑戰(zhàn)。在他們的研究文章(e202205672)中,Deshuang Tu、Changsheng Lu、Hong Yan 及其同事開發(fā)了一種有效的反應方案,通過由以下物質產生的以硼頂點為中心的碳硼烷基自由基,在溫和條件下對碳硼烷進行選擇性烷基化、烯基化和雜芳基化:硼取代的碳硼烷羧酸的光誘導脫羧。

76.A universal dual photoredox catalysis platform based on metal–organic polymers synergistically constructed with triphenylpyrylium-mimicking ligands and reductive metal ions is reported by Yunhe Jin, Chunying Duan, and co-workers in their Research Article (e202204918). This strategy enables the integration of photoinduced electron transfer and ligand-to-metal charge transfer events for enhanced efficiency in photocatalytic organic couplings and molecular oxygen activation.

Yunhe Jin、Chunying Duan 及其同事在他們的研究文章 (e202204918) 中報道了一種基于金屬有機聚合物的通用雙光氧化還原催化平臺,該平臺由模擬三苯基吡喃鎓配體和還原性金屬離子協(xié)同構建。該策略能夠整合光誘導電子轉移和配體到金屬的電荷轉移事件,從而提高光催化有機偶聯(lián)和分子氧活化的效率。

77.Nonlinear Optics. In their Communication (e202208168), Mark?G. Humphrey et?al. report photo-stable materials with three-photon absorption cross-sections based on organometallic donors covalently attached to an s-heptazine acceptor.

非線性光學。在他們的通訊 (e202208168) 中,Mark G. Humphrey 等人。報告了基于共價連接到 s-庚嗪受體的有機金屬供體的具有三光子吸收截面的光穩(wěn)定材料。

78.Desalination Materials. A scalable MoS2-based hydrogel for highly efficient solar desalination through enhanced solar evaporation is reported in the Research Article (e202208587) by Baoling Yuan, Ming-Lai Fu et?al.

海水淡化材料。 Baoling Yuan、Ming-Lai Fu 等人在研究文章 (e202208587) 中報道了一種可擴展的 MoS2 基水凝膠,可通過增強太陽能蒸發(fā)實現(xiàn)高效太陽能海水淡化。

79.Enabling Sustainable Chemistry with Ionic Liquids and Deep Eutectic Solvents: A Fad or the Future?.

使用離子液體和低共熔溶劑實現(xiàn)可持續(xù)化學:時尚還是未來?。

80.Enhanced Solar Evaporation Using a Scalable MoS2-Based Hydrogel for Highly Efficient Solar Desalination.

使用可擴展的 MoS2 水凝膠增強太陽能蒸發(fā),實現(xiàn)高效太陽能海水淡化。

81.Two-Dimensional Organic Supramolecule via Hydrogen Bonding and π–π Stacking for Ultrahigh Capacity and Long-Life Aqueous Zinc–Organic Batteries.

通過氫鍵和π-π堆積形成二維有機超分子,用于超高容量和長壽命水系鋅有機電池。

82.Discovery and Genetic Code Expansion of a Polyethylene Terephthalate (PET) Hydrolase from the Human Saliva Metagenome for the Degradation and Bio-Functionalization of PET.

來自人類唾液宏基因組的聚對苯二甲酸乙二醇酯 (PET) 水解酶的發(fā)現(xiàn)和遺傳密碼擴展,用于 PET 的降解和生物功能化。

83.Single-Atom Molybdenum-N3 Sites for Selective Hydrogenation of CO2 to CO.

用于 CO2 選擇性加氫為 CO 的單原子鉬-N3 位點。

84.Catalytic Enantioselective de novo Construction of Chiral Arenes through Desymmetrizing Oxidative [4+2]-Cycloaddition.

通過去對稱氧化 [4+2]-環(huán)加成催化對映選擇性從頭構建手性芳烴。

85.Chromophore-Inspired Design of Pyridinium-Based Metal–Organic Polymers for Dual Photoredox Catalysis.

用于雙光氧化還原催化的吡啶基金屬有機聚合物的發(fā)色團啟發(fā)設計。

86.Site-Selective Functionalization of Carboranes at the Electron-Rich Boron Vertex: Photocatalytic B?C Coupling via a Carboranyl Cage Radical.

碳硼烷在富電子硼頂點的位點選擇性功能化:通過碳硼烷基籠自由基進行光催化 B?C 耦合。

87.Identification and Structure Analysis of an Unusual Halohydrin Dehalogenase for Highly Chemo-, Regio- and Enantioselective Bio-Nitration of Epoxides.

用于環(huán)氧化物高度化學、區(qū)域和對映選擇性生物硝化的不尋常鹵代醇脫鹵酶的鑒定和結構分析。

88.A Specialized Polythioamide-Binding Protein Confers Antibiotic Self-Resistance in Anaerobic Bacteria.

一種特殊的聚硫酰胺結合蛋白賦予厭氧細菌抗生素自身耐藥性。

89.Constructing Interfacial Boron-Nitrogen Moieties in Turbostratic Carbon for Electrochemical Hydrogen Peroxide Production.

在渦層碳中構建界面硼氮部分用于電化學過氧化氫生產。

90.Gauging Radical Stabilization with Carbenes.

用卡賓測量自由基穩(wěn)定性。

91.A Ce-UiO-66 Metal–Organic Framework-Based Graphene-Embedded Photocatalyst with Controllable Activation for Solar Ammonia Fertilizer Production.

用于太陽能氨肥生產的具有可控活化作用的基于 Ce-UiO-66 金屬有機框架的石墨烯嵌入光催化劑。

92.Polystyrene-based Macromolecular Ammonium Halides for Tuning Color and Exchange Kinetics of Perovskite Nanocrystals.

用于調節(jié)鈣鈦礦納米晶體顏色和交換動力學的聚苯乙烯基大分子鹵化銨。

93.Tuning the Anisotropic Facet of Lead Chromate Photocatalysts to Promote Spatial Charge Separation.

調節(jié)鉻酸鉛光催化劑的各向異性面以促進空間電荷分離。

94.From Ensemble Electrochemistry to Nano-Impact Electrochemistry: Altered Reaction Selectivity.

從整體電化學到納米沖擊電化學:改變反應選擇性。

95.High-Field NMR, Reactivity, and DFT Modeling Reveal the γ-Al2O3 Surface Hydroxyl Network.

高場 NMR、反應性和 DFT 建模揭示了 γ-Al2O3 表面羥基網絡。

96.A Plurizyme with Transaminase and Hydrolase Activity Catalyzes Cascade Reactions.

具有轉氨酶和水解酶活性的多酶催化級聯(lián)反應。

97.Solid–Liquid Interfacial Coordination Chemistry Enables High-Capacity Ammonium Storage in Amorphous Manganese Phosphate.

固液界面配位化學使無定形磷酸錳中高容量銨儲存成為可能。

98.Linker Scissoring Strategy Enables Precise Shaping of Metal–Organic Frameworks for Chromatographic Separation.

連接子剪切策略可實現(xiàn)色譜分離金屬有機框架的精確成型。

99.Cocrystallization Enabled Spatial Self-Confinement Approach to Synthesize Crystalline Porous Metal Oxide Nanosheets for Gas Sensing.

共晶空間自限制方法合成用于氣體傳感的結晶多孔金屬氧化物納米片。

100.Scalable, Chemoselective Nickel Electrocatalytic Sulfinylation of Aryl Halides with SO2.

芳基鹵化物與 SO2 的可擴展化學選擇性鎳電催化亞磺?;?。

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