聲明：本專欄主要對生命科學領域的一些期刊文章標題進行翻譯，所有內(nèi)容均由本人手工整理翻譯。由于本人專業(yè)為生物分析相關，其他領域如果出現(xiàn)翻譯錯誤請諒解。

The cover image shows in schematic form a polyaromatic hydrocarbon expanded porphyrin hybrid system that is able to act as a ligand to complex seven zinc atoms in a post-synthetic fashion.

封面圖片以示意圖形式顯示了一種聚芳烴膨脹卟啉雜化系統(tǒng)，該系統(tǒng)能夠作為配體以合成后方式絡合七個鋅原子。

This cover image emphasizes the crucial roles of surface chemistry in the acquisition, avoidance, and exploitation of protein corona. One can design precision nanomedicine by chemical strategies to realize the full potential of nanomedicine for benefiting human health.

這張封面圖片強調了表面化學在蛋白質冠的獲取、避免和利用中的關鍵作用。 人們可以通過化學策略設計精密納米醫(yī)學，以充分發(fā)揮納米醫(yī)學造福人類健康的潛力。

Monolayer NiIr layered double hydroxide (NiIr-LDH) was prepared despite the large radius difference between 3d and 5d metals. The 3d?5d hybrid NiIr-LDH possesses optimized electronic structures for enhanced OER performance in the seawater splitting.

盡管 3d 和 5d 金屬之間的半徑差異很大，但仍制備了單層 NiIr 層狀雙氫氧化物 (NiIr-LDH)。 3d?5d 雜化 NiIr-LDH 具有優(yōu)化的電子結構，可增強海水分解中的 OER 性能。

A comparative study was made between lattice-doping and surface-adsorbed single atoms, which created distinct interfacial structures to interact with oxygen-evolving intermediates. This work reveals the essence of electronic and steric effects for optimizing the catalytic process.

對晶格摻雜和表面吸附的單原子進行了比較研究，這產(chǎn)生了不同的界面結構以與放氧中間體相互作用。 這項工作揭示了優(yōu)化催化過程的電子和空間效應的本質。

Morphological evolution and dynamic processes of the graphdiyne-based materials are revealed by in situ atomic force microscopy. The classical configuration of graphdiyne and well-defined N-doped graphdiyne with precise N content was fabricated to be utilized as working electrodes.

原位原子力顯微鏡揭示了石墨二炔基材料的形態(tài)演化和動力學過程。 石墨二炔的經(jīng)典構型和具有精確 N 含量的明確定義的 N 摻雜石墨二炔被制造為用作工作電極。

Break by squeezing: activation of a hydrogen molecule in the junction of a scanning tunneling microscope can be induced by the atomic-scale confinement from squeezing the tunneling junction cavity with motion of the STM tip. A large energy barrier exists for dissociation of the hydrogen bond on a copper surface.

擠壓破壞：掃描隧道顯微鏡連接處氫分子的激活可以通過 STM 尖端運動擠壓隧道連接腔的原子級限制來誘導。 銅表面上的氫鍵解離存在很大的能壘。

A platform was designed using biomass-derived muconic acid to tailor Nylon 6,6 and to access materials with custom property enhancements. This platform's potential was demonstrated by synthesizing polyamides with built-in hydrophobicity and flame retardancy. A 70% reduction in water uptake and doubling of char were achieved while largely retaining key properties of the parent Nylon.

使用生物質衍生的粘康酸設計了一個平臺來定制尼龍 6,6 并獲取具有自定義屬性增強功能的材料。 通過合成具有內(nèi)置疏水性和阻燃性的聚酰胺證明了該平臺的潛力。 在很大程度上保留了母體尼龍的關鍵特性的同時，吸水率降低了 70%，炭化量增加了一倍。

Type-II core–shell nanocrystals comprising a chiral low-dimensional perovskite shell and an achiral MAPbBr3 core were developed. Based on the chiral-induced spin selectivity (CISS) effect, the chiral shell works as a spin-filter to produce spin-polarized carriers. A spin light-emitting diode (spin-LED) was achieved under ambient conditions.

開發(fā)了包含手性低維鈣鈦礦殼和非手性 MAPbBr3 核的 II 型核殼納米晶體。 基于手性誘導自旋選擇性 (CISS) 效應，手性殼充當自旋過濾器以產(chǎn)生自旋極化載流子。 在環(huán)境條件下實現(xiàn)了自旋發(fā)光二極管（自旋 LED）。

DNA double strands are woven into a nanofabric structure with an interlacing pattern that is distinctively different from reported DNA nanostructures.

DNA 雙鏈被編織成具有交錯圖案的納米結構，這與報道的 DNA 納米結構截然不同。

Complex de novo biosynthesis of sugar nucleotides from common sugars was reorganized as cascade reactions, which were driven through cofactor regeneration systems. The resultant clean conversions allowed the products to be obtained in high yields, with low preparation cost, and without the need for complicated purification manipulations.

從普通糖類復雜的糖核苷酸從頭生物合成被重組為級聯(lián)反應，通過輔因子再生系統(tǒng)驅動。 由此產(chǎn)生的清潔轉化使產(chǎn)品能夠以高產(chǎn)率、低制備成本獲得，并且不需要復雜的純化操作。

Incorporating a pH-sensitive station and a photoactive recognition site in a [2]rotaxane provides access to a light-powered molecular machine that operates through a closed reaction network. Therein, a catalytic photoinduced proton transfer enables reversible ring shuttling, triggering autonomous dissipative operation.

在 [2] 輪烷中加入 pH 敏感站和光活性識別位點，可以訪問通過封閉反應網(wǎng)絡運行的光動力分子機器。 其中，催化光誘導質子轉移可實現(xiàn)可逆環(huán)穿梭，觸發(fā)自主耗散操作。

Tetranuclear Cu(I)–pyrazolate macrocycles can produce solid-state emissions at yellow, green, or deep-blue wavelengths by virtue of a remote steric effect. The conformational behavior of substituents on the pyrazole ligands can impose a rigidochromic effect on the copper core, whose phosphorescence is mediated primarily through a cluster-centered triplet state.

四核 Cu(I)-pyrazolate 大環(huán)化合物可以憑借遠程空間效應在黃色、綠色或深藍色波長下產(chǎn)生固態(tài)發(fā)射。 吡唑配體上取代基的構象行為可以對銅核施加剛性變色效應，其磷光主要通過以簇為中心的三重態(tài)介導。

An innovative spark discharge plasma-enabled N2 oxidation–electroreduction system is presented for efficient/renewable NH3 synthesis, which achieves a high NH3 yield rate of ~40 nmol s–1 cm–2 over Cu nanoparticles. The plasma-enabled activation and recombination processes of N2 and O2 molecules, as well as the microscopic-level mechanism of NOx– electroreduction, are investigated and decoupled by in situ spectroscopy techniques in detail.

提出了一種創(chuàng)新的火花放電等離子體啟用的 N2 氧化-電還原系統(tǒng)，用于高效/可再生 NH3 合成，在 Cu 納米粒子上實現(xiàn)了約 40 nmol s-1 cm-2 的高 NH3 產(chǎn)率。 通過原位光譜技術詳細研究和解耦了 N2 和 O2 分子的等離子體激活和重組過程，以及 NOx 電還原的微觀機制。

Porous organic cage (i.e., CC3) membranes with hierarchical channels composed of discrete internal cavities and cage-aligned external cavities connected by sub-nanometer-sized windows, showing a high ion permselectivity with a monovalent ion flux of 1.0 mol m?2 h?1 and mono-/divalent ion selectivity (e.g., K+/Mg2+) up to 103.

多孔有機籠（即 CC3）膜具有分層通道，由離散的內(nèi)腔和籠對齊的外腔組成，由亞納米尺寸的窗口連接，顯示出高離子選擇性滲透率，單價離子通量為 1.0 mol m?2 h? 1 和高達 103 的單價/二價離子選擇性（例如 K+/Mg2+）。

The on-surface reaction pathway of terminal alkynes was successfully steered from C–C coupling to C–H activation with high selectivity at different status by introducing O2. The catalytic performance and reaction mechanisms of the oxygen species involved were also clarified in this study.

通過引入 O2，末端炔烴的表面反應途徑成功地從 C-C 偶聯(lián)轉向 C-H 活化，在不同狀態(tài)下具有高選擇性。 本研究還闡明了所涉及的氧物種的催化性能和反應機制。

A novel photoinduced fluorescent cross-link between aromatic side chains in proteins is generated by a single fluorine atom on a side chain indole. The cover portrays the atomic-resolution NMR structure of the Trp-Phe cross-linked CypA protein. This unprecedented finding suggests a controllable approach for exploiting aromatic cross-links in proteins and developing fluorescence probes.

蛋白質中芳香側鏈之間的新型光誘導熒光交聯(lián)是由側鏈吲哚上的單個氟原子產(chǎn)生的。 封面描繪了 Trp-Phe 交聯(lián) CypA 蛋白的原子分辨率 NMR 結構。 這一前所未有的發(fā)現(xiàn)提出了一種可控的方法來利用蛋白質中的芳香族交聯(lián)和開發(fā)熒光探針。

Sterically hindered Lewis acid ("B" center) and Lewis base ("N" center) sites were anchored within the rigid lattice of highly crystalline hexagonal boron nitride (h-BN) scaffolds via precision defect regulation. The as-afforded h-BN scaffolds achieved highly efficient H2/D2 activation and dissociation under ambient pressure via Frustrated Lewis Pair-like behavior.

空間位阻路易斯酸（“B”中心）和路易斯堿（“N”中心）位點通過精確缺陷調節(jié)固定在高結晶六方氮化硼 (h-BN) 支架的剛性晶格內(nèi)。 所提供的 h-BN 支架通過 Frustrated Lewis Pair-like 行為在環(huán)境壓力下實現(xiàn)了高效的 H2/D2 激活和解離。

Aerobic N2-fixing bacteria, Azotobacter vinelandii, produce NH3 using light when colloidal quantum dots are inside the cells. Culturing A. vinelandii in the presence of quantum dots enables the efficient cellular uptake of quantum dots via an energy-dependent pathway.

當膠體量子點位于細胞內(nèi)時，好氧固氮細菌 Azotobacter vinelandii 會利用光產(chǎn)生 NH3。 在存在量子點的情況下培養(yǎng) A. vinelandii 可以通過能量依賴性途徑有效地吸收量子點。

Aggregation-enhanced singlet oxygen generation occurs by the irradiation of nanoparticles containing fuchsonarene chromophores encrypted by a macrocyclic scaffold. These organic nanoparticles have been applied in vitro, leading to effective cellular uptake and photoinduced cell death.

通過輻照含有由大環(huán)支架加密的品紅芳烴發(fā)色團的納米粒子，會產(chǎn)生聚集增強的單線態(tài)氧。 這些有機納米粒子已在體外應用，導致有效的細胞攝取和光誘導細胞死亡。

We revealed a common dimension character of the fibrous structures of both Gerris legs and Argyroneta abdomens, featured as the conical topology and micrometer scaled cylindrical diameter. Following this dimension character, we developed a bioinspired micrometer scaled conical fiber array with robust water repellency in high humidity.

我們揭示了 Gerris 腿和 Argyroneta 腹部纖維結構的共同尺寸特征，以圓錐形拓撲結構和微米級圓柱直徑為特征。 遵循這一維度特征，我們開發(fā)了一種受生物啟發(fā)的微米級錐形纖維陣列，在高濕度下具有強大的防水性。

A combined computational and experimental study reveals that, contrary to previously hypothesized enantioinduction mechanisms, the radical rebound step is enantioselectivity-determining under the Curtin–Hammett conditions, whereas the preceding HAT step is only moderately stereoselective. This study highlights an unusual enantioinduction mechanism in metalloenzyme-catalyzed asymmetric transformations involving radical intermediates.

一項結合計算和實驗的研究表明，與先前假設的對映誘導機制相反，自由基回彈步驟在 Curtin-Hammett 條件下是對映選擇性決定的，而前面的 HAT 步驟僅具有適度的立體選擇性。 這項研究強調了金屬酶催化的涉及自由基中間體的不對稱轉化中不尋常的對映體誘導機制。

Three-dimensional hollow Ru colloidosomes were synthesized via a one-pot gas/liquid interface self-assembly strategy. The Ru colloidosomes as catalyst exhibit remarkable HOR catalytic activity.

通過一鍋氣/液界面自組裝策略合成了三維空心 Ru 膠體。 Ru膠體作為催化劑表現(xiàn)出顯著的HOR催化活性。

The charge transport of p-type organic semiconductors is known to occur via the electronic couplings of HOMO. We demonstrate that the electronic couplings of HOMO, second HOMO, and third HOMO all contribute to the formation of the valence band structures and charge transport of the thienopyrazine-containing R–BNTP π-electron system.

已知 p 型有機半導體的電荷傳輸是通過 HOMO 的電子耦合發(fā)生的。 我們證明了 HOMO、第二 HOMO 和第三 HOMO 的電子耦合都有助于價帶結構的形成和含噻吩并吡嗪的 R-BNTP π 電子系統(tǒng)的電荷傳輸。

A robust anion concentration gradient-assisted solid-electrolyte interphase was constructed using an in situ chemical reaction of sulfonic acid polymer and zinc metal to enable the long-term stable cycling of the zinc electrode and recharged zinc metal batteries, which is visually illustrated in the cover art.

利用磺酸聚合物和鋅金屬的原位化學反應構建了一種穩(wěn)健的陰離子濃度梯度輔助固體電解質界面，使鋅電極和充電鋅金屬電池能夠長期穩(wěn)定循環(huán)，如圖所示 封面藝術。

Rapid, cost-effective, and widely available diagnostics are needed to monitor and mitigate the spread of SARS-CoV-2 and future outbreaks. An engineered antibody–enzyme fusion protein (blue) recognizes human antibodies (red) and catalyzes the conversion of sucrose (pink) to glucose (magenta), allowing quantification of antibodies against disease antigens (yellow) using commercial glucometers.

需要快速、經(jīng)濟高效且廣泛可用的診斷方法來監(jiān)測和減輕 SARS-CoV-2 的傳播和未來的爆發(fā)。 一種工程抗體-酶融合蛋白（藍色）識別人類抗體（紅色）并催化蔗糖（粉色）轉化為葡萄糖（品紅色），從而允許使用商用血糖儀對針對疾病抗原（黃色）的抗體進行定量。

1.Chemical and Biophysical Signatures of the Protein Corona in Nanomedicine.

納米醫(yī)學中蛋白質冠的化學和生物物理特征。

2.Multi-active Site Dynamics on a Molecular Cr/Co/Se Cluster Catalyst.

分子 Cr/Co/Se 團簇催化劑上的多活性位點動力學。

3.Pyrene-Bridged Expanded Carbaporphyrin Nanobelts.

芘橋接擴展碳卟啉納米帶。

4.Crystal Structure and Stability in Aqueous Solutions of Na0.5[NpO2(OH)1.5]·0.5H2O and Na[NpO2(OH)2].

Na0.5[NpO2(OH)1.5]·0.5H2O 和 Na[NpO2(OH)2] 水溶液中的晶體結構和穩(wěn)定性。

5.Catalytic Enantioselective Synthesis of γ-Lactams with β-Quaternary Centers via Merging of C–C Activation and Sulfonyl Radical Migration.

通過合并 C-C 活化和磺?；杂苫w移催化對映選擇性合成具有 β-季中心的 γ-內(nèi)酰胺。

6.Fast Photoswitchable Molecular Prosthetics Control Neuronal Activity in the Cochlea.

快速光開關分子假體控制耳蝸中的神經(jīng)元活動。

7.Insights into the Chemistry of Iodine New Particle Formation: The Role of Iodine Oxides and the Source of Iodic Acid.

洞察碘新粒子形成的化學：碘氧化物的作用和碘酸的來源。

8.Monolayer NiIr-Layered Double Hydroxide as a Long-Lived Efficient Oxygen Evolution Catalyst for Seawater Splitting.

單層 NiIr-層狀雙氫氧化物作為海水分解的長壽命高效析氧催化劑。

9.Aptamer-Induced-Dimerization Strategy Attenuates AβO Toxicity through Modulating the Trophic Activity of PrPC Signaling.

適體誘導二聚化策略通過調節(jié) PrPC 信號轉導的營養(yǎng)活動減弱 AβO 毒性。

10.Tuning the Electronic and Steric Interaction at the Atomic Interface for Enhanced Oxygen Evolution.

調整原子界面處的電子和空間相互作用以增強氧氣釋放。

11.Metal–Organic Framework-Derived Graphene Mesh: a Robust Scaffold for Highly Exposed Fe–N4 Active Sites toward an Excellent Oxygen Reduction Catalyst in Acid Media.

金屬-有機骨架衍生的石墨烯網(wǎng)狀結構：一種堅固的支架，可用于高度暴露的 Fe-N4 活性位點，從而在酸性介質中實現(xiàn)出色的氧還原催化劑。

12.High CO-Tolerant Ru-Based Catalysts by Constructing an Oxide Blocking Layer.

通過構建氧化物阻擋層制備高 CO 耐受性 Ru 基催化劑。

13.Suppressing Immune Responses Using Siglec Ligand-Decorated Anti-receptor Antibodies.

使用 Siglec 配體修飾的抗受體抗體抑制免疫反應。

14.In Situ Self-Sorting Peptide Assemblies in Living Cells for Simultaneous Organelle Targeting.

用于同時細胞器靶向的活細胞中的原位自分類肽組裝。

15.Acid Catalysis over Low-Silica Faujasite Zeolites.

低硅八面沸石上的酸催化。

16.Direct Observation of the Dynamics of Ylide Solvation by Hydrogen-bond Donors Using Time-Resolved Infrared Spectroscopy.

使用時間分辨紅外光譜法直接觀察氫鍵供體對葉立德溶劑化的動力學。

17.“Capture-Backdonation-Recapture” Mechanism for Promoting N2 Reduction by Heteronuclear Metal-Free Double-Atom Catalysts.

“捕獲-反捐贈-再捕獲”機制。

18.Interfacial Evolution of the Solid Electrolyte Interphase and Lithium Deposition in Graphdiyne-Based Lithium-Ion Batteries.

石墨烯基鋰離子電池中固體電解質界面的界面演化和鋰沉積。

19.Sea Urchin Polyketide Synthase SpPks1 Produces the Naphthalene Precursor to Echinoderm Pigments.

海膽聚酮合酶 SpPks1 生產(chǎn)棘皮動物色素的萘前體。

20.Biosynthesis of Guanitoxin Enables Global Environmental Detection in Freshwater Cyanobacteria.

鳥毒素的生物合成使淡水藍細菌的全球環(huán)境檢測成為可能。

21.Helically Chiral Hybrid Cyclodextrin Metal–Organic Framework Exhibiting Circularly Polarized Luminescence.

表現(xiàn)出圓偏振發(fā)光的螺旋手性雜化環(huán)糊精金屬-有機骨架。

22.Connecting Molecular and Supramolecular Shapeshifting by the Ostwald’s Nucleation Stages of a Star Giant Molecule.

通過星巨分子的奧斯特瓦爾德成核階段連接分子和超分子變形。

23.Self-Assembled Liposomes Enhance Electron Transfer for Efficient Photocatalytic CO2 Reduction.

自組裝脂質體增強電子轉移以實現(xiàn)有效的光催化 CO2 還原。

24.Versatile Palladium-Catalyzed Approach to Acyl Fluorides and Carbonylations by Combining Visible Light- and Ligand-Driven Operations.

通過結合可見光和配體驅動的操作，多功能鈀催化?；锖汪驶椒?。

25.Surface and Bulk Chemistry of Mechanochemically Synthesized Tohdite Nanoparticles.

機械化學合成 Tohdite 納米粒子的表面和本體化學。

26.A Pyrene-4,5,9,10-Tetraone-Based Covalent Organic Framework Delivers High Specific Capacity as a Li-Ion Positive Electrode.

一種基于芘-4,5,9,10-四酮的共價有機骨架提供高比容量作為鋰離子正極。

27.Living Cell Nanoporation and Exosomal RNA Analysis Platform for Real-Time Assessment of Cellular Therapies.

用于實時評估細胞療法的活細胞納米孔和外泌體 RNA 分析平臺。

28.A Kinetic Isotope Effect in the Formation of Lanthanide Phosphate Nanocrystals.

鑭系磷酸鹽納米晶體形成中的動力學同位素效應。

29.Radiotherapy Reduces N-Oxides for Prodrug Activation in Tumors.

放療減少腫瘤中前體藥物激活的 N-氧化物。

30.Transient Host–Guest Complexation To Control Catalytic Activity.

控制催化活性的瞬態(tài)主客體絡合。

31.One Porphyrin Per Chain Self-Assembled Helical Ion-Exchange Channels for Ultrahigh Osmotic Energy Conversion.

用于超高滲透能量轉換的每鏈一個卟啉自組裝螺旋離子交換通道。

32.Scaling Up Multi-bit DNA Full Adder Circuits with Minimal Strand Displacement Reactions.

用最小鏈置換反應放大多位 DNA 全加器電路。

33.Phenyl Sulfones: A Route to a Diverse Family of Trisubstituted Cyclohexenes from Three Independent Nucleophilic Additions.

苯基砜：通過三個獨立的親核加成反應形成不同家族的三取代環(huán)己烯的途徑。

34.Ionic Dopant-Free Polymer Alloy Hole Transport Materials for High-Performance Perovskite Solar Cells.

用于高性能鈣鈦礦太陽能電池的無離子摻雜聚合物合金空穴傳輸材料。

35.Diffuse Ions Coordinate Dynamics in a Ribonucleoprotein Assembly.

核糖核蛋白組裝中的擴散離子協(xié)調動力學。

36.Structure and Magnetism of Iron- and Chromium-Intercalated Niobium and Tantalum Disulfides.

鐵和鉻插層鈮和二硫化鉭的結構和磁性。

37.Anticancer Agent with Inexplicable Potency in Extreme Hypoxia: Characterizing a Light-Triggered Ruthenium Ubertoxin.

在極度缺氧條件下具有無法解釋的效力的抗癌劑：表征光觸發(fā)的釕 Ubertoxin。

38.Bioenabled Platform to Access Polyamides with Built-In Target Properties.

用于訪問具有內(nèi)置目標屬性的聚酰胺的生物啟用平臺。

39.Diaryl Ether Formation by a Versatile Thioesterase Domain.

多功能硫酯酶結構域形成二芳基醚。

40.Mimicking DNA Periodic Docking Grooves for Adaptive Identification of l-/d-Tryptophan in a Biological Metal–Organic Framework.

模擬 DNA 周期性對接槽以適應性識別生物金屬-有機框架中的 l-/d-色氨酸。

41.Asymmetric Formal Nucleophilic o-Cresolylation with Morita–Baylis–Hillman Carbonates of 2-Cyclohexenones via Palladium Catalysis.

通過鈀催化與 2-環(huán)己酮的 Morita-Baylis-Hillman 碳酸鹽的不對稱形式親核 o-Cresolylation。

42.Site-Specific and Degree-Controlled Alkyl Deuteration via Cu-Catalyzed Redox-Neutral Deacylation.

通過 Cu 催化的氧化還原中性脫酰作用進行位點特異性和程度可控的烷基氘化。

43.Core–Shell Covalently Linked Graphitic Carbon Nitride–Melamine–Resorcinol–Formaldehyde Microsphere Polymers for Efficient Photocatalytic CO2 Reduction to Methanol.

核-殼共價連接的石墨化碳氮化物-三聚氰胺-間苯二酚-甲醛微球聚合物，用于高效光催化 CO2 還原為甲醇。

44.Mechanistic Studies Yield Improved Protocols for Base-Catalyzed Anti-Markovnikov Alcohol Addition Reactions.

機理研究改進了堿催化的反馬爾可夫尼科夫醇加成反應的方案。

45.Ionic Conductivity of Nanocrystalline and Amorphous Li10GeP2S12: The Detrimental Impact of Local Disorder on Ion Transport.

納米晶和非晶 Li10GeP2S12 的離子電導率：局部紊亂對離子傳輸?shù)牟焕绊憽?/p>

46.Trimer-to-Monomer Disruption Mechanism for a Potent, Protease-Resistant Antagonist of Tumor Necrosis Factor-α Signaling.

腫瘤壞死因子-α 信號轉導的有效、耐蛋白酶拮抗劑的三聚體到單體的破壞機制。

47.Confinement-Induced Catalytic Dissociation of Hydrogen Molecules in a Scanning Tunneling Microscope.

掃描隧道顯微鏡中氫分子的限制誘導催化解離。

48.Asymmetric Hydrophosphonylation of Imines to Construct Highly Stable Covalent Organic Frameworks with Efficient Intrinsic Proton Conductivity.

亞胺的不對稱氫膦?；詷嫿ň哂懈咝П菊髻|子傳導率的高度穩(wěn)定的共價有機骨架。

49.Biosynthesis of Argolaphos Illuminates the Unusual Biochemical Origins of Aminomethylphosphonate and Nε-Hydroxyarginine Containing Natural Products.

Argolaphos 的生物合成闡明了含有氨基甲基膦酸鹽和 Nε-羥基精氨酸的天然產(chǎn)物的不尋常生化起源。

50.Laser-Triggered Bottom-Up Transcription of Chemical Information: Toward Patterned Graphene/MoS2 Heterostructures.

化學信息的激光觸發(fā)自下而上轉錄：走向圖案化石墨烯/MoS2 異質結構。

51.Water-Splitting Artificial Leaf Based on a Triple-Junction Silicon Solar Cell: One-Step Fabrication through Photoinduced Deposition of Catalysts and Electrochemical Operando Monitoring.

基于三結硅太陽能電池的水分解人造葉：通過光誘導沉積催化劑和電化學操作監(jiān)測一步法制造。

52.Quasi-Covalently Coupled Ni–Cu Atomic Pair for Synergistic Electroreduction of CO2.

用于 CO2 協(xié)同電還原的準共價耦合 Ni-Cu 原子對。

53.High Gravimetric and Volumetric Ammonia Capacities in Robust Metal–Organic Frameworks Prepared via Double Postsynthetic Modification.

通過雙重合成后修飾制備的穩(wěn)健金屬有機框架中的高重量和體積氨容量。

54.Water-Assisted Proton Transfer in the Sequential Hydration of Benzonitrile Radical Cation C6H5CN?+(H2O)n: Transition to Hydrated Distonic Cation ?C6H4CNH+(H2O)n with n ≥ 4.

苯腈自由基陽離子 C6H5CN 順序水合中的水輔助質子轉移? +(H2O)n：轉變?yōu)樗袭愘|子陽離子? C6H4CNH+(H2O)n，n ≥ 4。

55.Voltage-Gated Electrocatalysis of Efficient and Selective Methane Oxidation by Tricopper Clusters under Ambient Conditions.

環(huán)境條件下三銅簇高效選擇性甲烷氧化的電壓門控電催化。

56.Core–Shell Three-Dimensional Perovskite Nanocrystals with Chiral-Induced Spin Selectivity for Room-Temperature Spin Light-Emitting Diodes.

用于室溫自旋發(fā)光二極管的具有手性誘導自旋選擇性的核殼三維鈣鈦礦納米晶體。

57.Anaerobic Hydroxyproline Degradation Involving C–N Cleavage by a Glycyl Radical Enzyme.

涉及甘氨酰自由基酶 C-N 裂解的厭氧羥脯氨酸降解。

58.Homeostasis inside Single Activated Phagolysosomes: Quantitative and Selective Measurements of Submillisecond Dynamics of Reactive Oxygen and Nitrogen Species Production with a Nanoelectrochemical Sensor.

單活化吞噬溶酶體內(nèi)的穩(wěn)態(tài)：使用納米電化學傳感器對活性氧和氮物質產(chǎn)生的亞毫秒動力學進行定量和選擇性測量。

59.Rate Controlling in Low-Temperature Standard NH3-SCR: Implications from Operando EPR Spectroscopy and Reaction Kinetics.

低溫標準 NH3-SCR 中的速率控制：Operando EPR 光譜學和反應動力學的啟示。

60.Stress in DNA Gridiron Facilitates the Formation of Two-Dimensional Crystalline Structures.

DNA Gridiron 中的應力促進二維晶體結構的形成。

61.Oxygen Reduction Reaction in Alkaline Media Causes Iron Leaching from Fe–N–C Electrocatalysts.

堿性介質中的氧還原反應導致鐵從 Fe-N-C 電催化劑中浸出。

62.Carbene Complexes of Neptunium.

镎的卡賓絡合物。

63.Chirality-Controlled Supramolecular Donor–Acceptor Copolymerization with Distinct Energy Transfer Efficiency.

具有不同能量轉移效率的手性控制的超分子供體-受體共聚。

64.A Class of Magnetic Topological Material Candidates with Hypervalent Bi Chains.

一類具有超價雙鏈的磁性拓撲材料候選者。

65.Time-Resolved Imaging of Stochastic Cascade Reactions over a Submillisecond to Second Time Range at the Angstrom Level.

在埃級別亞毫秒到秒時間范圍內(nèi)隨機級聯(lián)反應的時間分辨成像。

66.Anion π–π Stacking for Improved Lithium Transport in Polymer Electrolytes.

陰離子 π–π 堆疊以改善聚合物電解質中的鋰傳輸。

67.Ultrafast Visible-Light-Induced ATRP in Aqueous Media with Carbon Quantum Dots as the Catalyst and Its Application for 3D Printing.

以碳量子點為催化劑的水介質中超快可見光誘導 ATRP 及其在 3D 打印中的應用。

68.Covalent Organic Frameworks with Irreversible Linkages via Reductive Cyclization of Imines.

通過亞胺的還原環(huán)化形成具有不可逆連接的共價有機框架。

69.Direct Detection of Lithium Exchange across the Solid Electrolyte Interphase by 7Li Chemical Exchange Saturation Transfer.

通過 7Li 化學交換飽和轉移直接檢測固體電解質界面的鋰交換。

70.Light-Driven Molecular Whirligig.

光驅動分子旋轉。

71.Copper(III) Metallacyclopentadienes via Zirconocene Transfer and Reductive Elimination to an Isolable Phenanthrocyclobutadiene.

銅 (III) 金屬環(huán)戊二烯通過鋯茂轉移和還原消除生成可分離的菲環(huán)丁二烯。

72.Cobalt(III) Carbene Complex with an Electronic Excited-State Structure Similar to Cyclometalated Iridium(III) Compounds.

具有類似于環(huán)金屬化銥 (III) 化合物的電子激發(fā)態(tài)結構的鈷 (III) 卡賓絡合物。

73.Controlling One- or Two-Electron Oxidation for Selective Amine Functionalization by Alternating Current Frequency.

通過交流頻率控制選擇性胺功能化的單電子或雙電子氧化。

74.A Series of Soluble Thieno-Fused Coronene Nanoribbons of Precise Lengths.

一系列精確長度的可溶性噻吩并稠合暈烯納米帶。

===================================

由于專欄圖片數(shù)量限制，更多內(nèi)容關注我的個人公眾號“遠夢研”查看更多。