散文網(wǎng) » 科技 »自然 » 【標題速讀】【Angew】【2022年】【11月】

【標題速讀】【Angew】【2022年】【11月】

2023-08-19 15:47 作者:Rt_Cola 0人讀過 | 我要投稿

聲明：本專欄主要對生命科學領域的一些期刊文章標題進行翻譯，所有內容均由本人手工整理翻譯。由于本人專業(yè)為生物分析相關，其他領域如果出現(xiàn)翻譯錯誤請諒解。

1.A chiral Lewis acid catalysed asymmetric [2+2] cycloaddition reaction of allenyl imide and alkenes was developed by Xiaohua Liu, Xiaoming Feng et?al. in their Research Article (e202211596). This protocol provided a series of axially chiral cyclobutenes in high yields with excellent enantioselectivities. A stepwise mechanism was proposed based on experimental studies and DFT calculations, and π–π stacking interactions were identified as crucial for the enantioselectivity.

劉曉華、馮曉明等人開發(fā)了一種手性路易斯酸催化的丙二烯酰亞胺與烯烴的不對稱[2+2]環(huán)加成反應。在他們的研究文章（e202211596）中。該方案以高產率提供了一系列具有優(yōu)異對映選擇性的軸向手性環(huán)丁烯。基于實驗研究和 DFT 計算提出了逐步機制，并且 π-π 堆積相互作用被認為對于對映選擇性至關重要。

2.Zinc ion batteries (ZIBs) face several challenges, such as unstable Zn anodes and a low Zn ion transference number. A unique anion-trap strategy based on the host–guest interaction between β-CD and anions is proposed by Chunyi Zhi, Wenjie Mai, and co-workers in their Research Article (e202210979) to greatly improve the overall performance in terms of both capacity and stability of ZIBs via promoting the Zn ion transfer ability and assisting the formation of reorientated dominant Zn(002) facets on the Zn anode.

鋅離子電池（ZIB）面臨著一些挑戰(zhàn)，例如不穩(wěn)定的鋅陽極和低鋅離子遷移數(shù)。 Chunyizhi、WenjieMai 及其同事在他們的研究文章 (e202210979) 中提出了一種基于 β-CD 和陰離子之間的主客體相互作用的獨特陰離子捕獲策略，可大大提高兩種容量的整體性能通過促進 Zn 離子轉移能力并協(xié)助在 Zn 陽極上形成重新取向的主要 Zn(002) 面來提高 ZIB 的穩(wěn)定性。

3.The precise co-conformation regulation of topologically chiral [2]catenanes under two different external stimuli led to the construction of a bidirectional circularly polarized luminescence (CPL) switch, as reported by Xiao He, Wei Wang, Hai-Bo Yang, and co-workers in their Research Article (e202210542). The results provide not only an attractive approach towards the construction of multistate CPL switches for practical uses but also a promising platform for the construction of novel chiral materials.

拓撲手性[2]鏈烷在兩種不同的外部刺激下的精確共構象調節(jié)導致了雙向圓偏振發(fā)光（CPL）開關的構建，如肖赫、王偉、楊海波和合作者在他們的研究文章（e202210542）中報道的那樣。這些結果不僅為構建實際用途的多態(tài) CPL 開關提供了一種有吸引力的方法，而且為構建新型手性材料提供了一個有前景的平臺。

4.Electroreduction of CO2 to CO is a promising approach for the cyclic use of CO2, but still suffers from impractical current density and durability. A single-atom nanozyme (Ni?N5?C) that achieves industrial-scale performance for CO2-to-CO conversion is reported by Pei-Qin Liao and co-workers in their Research Article (e202210985). Compared with the planar Ni?N4 site, the square-pyramidal Ni?N5 site has significant differences in the dz2 and dxz/yz orbital energy levels. Thus the Ni?N5 catalytic site has superior properties in activating CO2 molecules and promoting CO desorption.

將 CO2 電還原為 CO 是循環(huán)利用 CO2 的一種有前途的方法，但仍然存在電流密度和耐用性不切實際的問題。 Pei-Qin Liao 及其同事在他們的研究文章 (e202210985) 中報道了一種單原子納米酶 (Ni?N5?C)，可實現(xiàn)工業(yè)規(guī)模的 CO2 至 CO 轉化性能。與平面Ni?N4位點相比，方形錐體Ni?N5位點的dz2和dxz/yz軌道能級存在顯著差異。因此，Ni?N5 催化位點在活化 CO2 分子和促進 CO 解吸方面具有優(yōu)異的性能。

5.Acenes. Azulene-fused acenes are described in the Research Article (e202209286) by Qing Jiang, Chunyan Chi et?al. Their dications display a local aromaticity shift, and one of them exhibits open-shell diradical character.

并苯。 Qing Jiang、Chunyan Chi 等人的研究文章 (e202209286) 中描述了甘菊環(huán)稠合并苯。它們的指示顯示出局部芳香性變化，其中之一表現(xiàn)出開殼雙自由基特征。

6.Big (Bio)Chemical Data Mining Using Chemometric Methods: A Need for Chemists.

使用化學計量方法進行大（生物）化學數(shù)據(jù)挖掘：對化學家的需求。

7.Molecular Engineering of Metal Complexes for Electrocatalytic Carbon Dioxide Reduction: From Adjustment of Intrinsic Activity to Molecular Immobilization.

用于電催化二氧化碳還原的金屬配合物的分子工程：從內在活性的調整到分子固定化。

8.Regioselective Transition-Metal-Free C(sp2)?H Borylation: A Subject of Practical and Ongoing Interest in Synthetic Organic Chemistry.

區(qū)域選擇性無過渡金屬 C(sp2)?H 硼化：合成有機化學中實際和持續(xù)關注的主題。

9.Azulene-Fused Acenes.

甘菊稠合苯。

10.Photo-Excited Nickel-Catalyzed Silyl-Radical-Mediated Direct Activation of Carbamoyl Chlorides To Access (Hetero)aryl Carbamides.

光激發(fā)鎳催化甲硅烷基自由基介導的氨基甲酰氯直接活化以獲得（雜）芳基脲。

11.The Linkage of Sulfonimidoyl Fluorides and Unactivated Alkenes via Hydrosulfonimidoylation.

磺酰亞胺酰氟與未活化烯烴通過氫磺酰亞胺酰化的連接。

12.Oxidative Radical NHC Catalysis: Divergent Difunctionalization of Olefins through Intermolecular Hydrogen Atom Transfer.

氧化自由基 NHC 催化：通過分子間氫原子轉移實現(xiàn)烯烴的發(fā)散雙官能化。

13.sp2 to sp3 Hybridization Transformation in Ionic Crystals under Unprecedentedly Low Pressure.

前所未有的低壓下離子晶體中 sp2 到 sp3 的雜化轉化。

14.A Versatile Strategy for Multi-Stimuli-Responsive Fluorescent Material Based on Cross-Linking-Induced Emission: Applications in Encryption.

基于交聯(lián)誘導發(fā)射的多刺激響應熒光材料的多功能策略：在加密中的應用。

15.Simultaneously Enhanced Hydrophilicity and Stability of a Metal-Organic Framework via Post-Synthetic Modification for Water Vapor Sorption/Desorption.

通過水蒸氣吸附/解吸的合成后改性同時增強金屬有機框架的親水性和穩(wěn)定性。

16.Conferring BiVO4 Nanorods with Oxygen Vacancies to Realize Enhanced Sonodynamic Cancer Therapy.

賦予 BiVO4 納米棒氧空位以實現(xiàn)增強的聲動力癌癥治療。

17.3D Blockage Mapping for Identifying Familial Point Mutations in Single Amyloid-β Peptides with a Nanopore.

使用納米孔識別單個淀粉樣蛋白-β 肽中的家族點突變的 3D 阻斷圖譜。

18.Ultrastable Anti-Acid “Shield” in Layered Silver Coordination Polymers.

層狀銀配位聚合物中的超穩(wěn)定抗酸“盾”。

19.Conservation of Nickel Ion Single-Active Site Character in a Bottom-Up Constructed π-Conjugated Molecular Network.

自下而上構建的 π 共軛分子網(wǎng)絡中鎳離子單活性位點特征的守恒。

20.2,4,6-Trimethylpyridine-Derived Vinylene-Linked Covalent Organic Frameworks for Confined Catalytic Esterification.

用于密閉催化酯化的 2,4,6-三甲基吡啶衍生的亞乙烯基連接的共價有機框架。

21.Temperature-Controlled Mechanochemistry for the Nickel-Catalyzed Suzuki–Miyaura-Type Coupling of Aryl Sulfamates via Ball Milling and Twin-Screw Extrusion..

通過球磨和雙螺桿擠出進行鎳催化芳基氨基磺酸鹽的 Suzuki-Miyaura 型偶聯(lián)的溫控機械化學。

22.Polymerisation-Induced Self-Assembly of Graft Copolymers.

聚合誘導的接枝共聚物的自組裝。

23.Multistate Circularly Polarized Luminescence Switching through Stimuli-Induced Co-Conformation Regulations of Pyrene-Functionalized Topologically Chiral [2]Catenane.

通過芘官能化拓撲手性 [2] 鏈烷的刺激誘導共構象調節(jié)進行多態(tài)圓偏振發(fā)光切換。

24.Intranuclear Nanoribbons for Selective Killing of Osteosarcoma Cells.

用于選擇性殺死骨肉瘤細胞的核內納米帶。

25.Semi-Solid Superprotonic Supramolecular Polymer Electrolytes Based on Deep Eutectic Solvents and Polyoxometalates.

基于低共熔溶劑和多金屬氧酸鹽的半固態(tài)超質子超分子聚合物電解質。

26.Piezo-Photocatalytic Synergy in BiFeO3@COF Z-Scheme Heterostructures for High-Efficiency Overall Water Splitting.

BiFeO3@COF Z 型異質結構中的壓電光催化協(xié)同作用可實現(xiàn)高效整體水分解。

27.Unraveling the Complex Chirality Evolution in DNA-Assembled High-Order, Hybrid Chiroplasmonic Superstructures from Multi-Scale Chirality Mechanisms.

從多尺度手性機制中揭示 DNA 組裝的高階混合手性等離子體超結構中復雜的手性演化。

28.The First Chiro-Inositol Organosilicon Ferroelectric Crystal.

第一個手性肌醇有機硅鐵電晶體。

29.Bottom-Up Preparation of Twisted Graphene Nanoribbons by Cu-Catalyzed Deoxygenative Coupling.

通過銅催化脫氧偶聯(lián)自下而上制備扭曲石墨烯納米帶。

30.Anion-Trap Engineering toward Remarkable Crystallographic Reorientation and Efficient Cation Migration of Zn Ion Batteries.

陰離子陷阱工程可實現(xiàn)鋅離子電池顯著的晶體重新取向和高效的陽離子遷移。

31.Single-Product Faradaic Efficiency for Electrocatalytic of CO2 to CO at Current Density Larger than 1.2?A?cm?2 in Neutral Aqueous Solution by a Single-Atom Nanozyme.

單原子納米酶在中性水溶液中電流密度大于 1.2 A cm?2 時將 CO2 電催化轉化為 CO 的單產物法拉第效率。

32.Ti-doped CeO2 Stabilized Single-Atom Rhodium Catalyst for Selective and Stable CO2 Hydrogenation to Ethanol.

Ti 摻雜 CeO2 穩(wěn)定單原子銠催化劑用于選擇性和穩(wěn)定 CO2 加氫生成乙醇。

33.Unique Double Intramolecular and Intermolecular Exciton Coupling in Ethene-Bridged aza-BODIPY Dimers for High-Efficiency Near-Infrared Photothermal Conversion and Therapy.

乙烯橋氮雜-BODIPY二聚體中獨特的雙分子內和分子間激子耦合，用于高效近紅外光熱轉換和治療。

34.In Vivo Olefin Metathesis in Microalgae Upgrades Lipids to Building Blocks for Polymers and Chemicals.

微藻中的體內烯烴復分解將脂質升級為聚合物和化學品的結構單元。

35.Programmable Assembly of Multivalent DNA-Protein Superstructures for Tumor Imaging and Targeted Therapy.

用于腫瘤成像和靶向治療的多價 DNA-蛋白質超結構的可編程組裝。

36.Activity-based Photoacoustic Probes Reveal Elevated Intestinal MGL and FAAH Activity in a Murine Model of Obesity.

基于活動的光聲探針揭示肥胖小鼠模型中腸道 MGL 和 FAAH 活動升高。

37.Enantioselective [2+2] Cycloaddition of Allenyl Imide with Mono- or Disubstituted Alkenes.

烯酰亞胺與單取代或雙取代烯烴的對映選擇性 [2+2] 環(huán)加成。

38.The Continuum Between Hexagonal Planar and Trigonal Planar Geometries.

六邊形平面和三角形平面幾何形狀之間的連續(xù)體。

39.Dynamic AIE crosslinks in liquid crystal networks: visualizing for actuation-guiding, re-bonding for actuation-altering.

液晶網(wǎng)絡中的動態(tài) AIE 交聯(lián)：可視化用于驅動引導，重新鍵合用于驅動改變。

40.Origins of p-Doping and Nonradiative Recombination in CsSnI3.

CsSnI3 中 p 摻雜和非輻射復合的起源。

41.A Bifunctional CdS/MoO2/MoS2 Catalyst Enhances Photocatalytic H2 Evolution and Pyruvic Acid Synthesis.

雙功能 CdS/MoO2/MoS2 催化劑增強光催化 H2 分解和丙酮酸合成。

42.The Microscopic Origin of Second Harmonic Generation Response: The Spatial Structure of Instantaneous Dipole Moments in Electron Excitation.

二次諧波產生響應的微觀起源：電子激發(fā)中瞬時偶極矩的空間結構。

43.Synergistic Interfacial Bonding in Reduced Graphene Oxide Fiber Cathodes Containing Polypyrrole@sulfur Nanospheres for Flexible Energy Storage.

含有聚吡咯@硫納米球的還原氧化石墨烯纖維陰極中的協(xié)同界面鍵合，用于靈活的能量存儲。

44.Regioselective Access to Vicinal Diamines by Metal-Free Photosensitized Amidylimination of Alkenes with Oxime Esters.

通過用肟酯對烯烴進行無金屬光敏脒基化，區(qū)域選擇性地獲得鄰位二胺。

45.Pseudo-heterolepticity in Low-Symmetry Metal-Organic Cages.

低對稱金屬有機籠中的偽雜配性。

46.Tracking Hepatic Ischemia-Reperfusion Injury in Real Time with a Reversible NIR-IIb Fluorescent Redox Probe.

使用可逆 NIR-IIb 熒光氧化還原探針實時跟蹤肝缺血再灌注損傷。

47.Regulating Surface Reaction Kinetics through Ligand Field Effects for Fast and Reversible Aqueous Zinc Batteries.

通過配體場效應調節(jié)快速可逆水性鋅電池的表面反應動力學。

48.Facile Route to Novel Diazaphosphinine-Based Polycyclic Aromatic Hydrocarbons.

新型二氮雜膦基多環(huán)芳烴的簡便路線。

49.Generation of Tunable Ultrastrong White-Light Emission by Activation of a Solid Supramolecule through Bromonaphthylpyridinium Polymerization.

通過溴萘基吡啶聚合激活固體超分子產生可調諧超強白光發(fā)射。

50.Differential Peptide Multi-Macrocyclizations at the Surface of a Helical Foldamer Template.

螺旋折疊體模板表面的差異肽多大環(huán)化。

51.Fast-Scan Cyclic Voltammetry (FSCV) Reveals Behaviorally Evoked Dopamine Release by Sugar Feeding in the Adult Drosophila Mushroom Body.

快速掃描循環(huán)伏安法 (FSCV) 揭示了成年果蠅蘑菇體內喂糖引起的行為誘發(fā)多巴胺釋放。

52.Rapid and Economical Chemoselective Metabolomics Using Boronate Ester Formation on a Monolithic Substrate.

在整體基質上使用硼酸酯形成的快速且經(jīng)濟的化學選擇性代謝組學。

53.Bi-polaron Transport and Magnetic Field Induced Pauli Spin Blockade in Redox-Active Molecular Junctions.

雙極化子傳輸和磁場誘導氧化還原活性分子結中的泡利自旋封鎖。

54.Dramatically Enhanced Reactivity of Fullerenes and Tetrazine towards the Inverse-Electron-Demand Diels–Alder Reaction inside a Porous Porphyrinic Cage.

富勒烯和四嗪對多孔卟啉籠內逆電子需求狄爾斯-阿爾德反應的反應活性顯著增強。

55.Substrate Tumbling in a Chemisorbed Diastereomeric α-Ketoester/1-(1-Naphthyl)ethylamine Complex.

化學吸附的非對映體 α-酮酯/1-(1-萘基)乙胺復合物中的底物翻滾。

56.Silicon Catalyzed C?O Bond Ring Closing Metathesis of Polyethers.

硅催化聚醚的 C?O 鍵閉環(huán)復分解。

57.Dual-Network Structured Hydrogel Electrolytes Engaged Solid-State Rechargeable Zn-Air/Iodide Hybrid Batteries.

雙網(wǎng)絡結構水凝膠電解質參與固態(tài)可充電鋅空氣/碘化物混合電池。

58.Enantioselective Synthesis of N?N Bisindole Atropisomers.

N?N 雙吲哚阻轉異構體的對映選擇性合成。

59.Photocatalyzed Cascade Reactions of Cyclopropanols and α-Trifluoromethyl-Substituted Olefins for the Synthesis of Fused gem-Difluorooxetanes.

環(huán)丙醇和 α-三氟甲基取代烯烴的光催化級聯(lián)反應用于合成稠合寶石二氟氧雜環(huán)丁烷。

60.Optically Controlled Thermochromic Switching for Multi-Input Molecular Logic.

用于多輸入分子邏輯的光控熱致變色開關。

61.Heteroatoms Induce Localization of the Electric Field and Promote a Wide Potential-Window Selectivity Towards CO in the CO2 Electroreduction.

雜原子誘導電場局域化并促進 CO2 電還原中對 CO 的寬電位窗口選擇性。

62.Redox-Regulated Conformational Change of Disulfide-Rich Assembling Peptides.

氧化還原調節(jié)的富含二硫鍵的組裝肽的構象變化。

63.Scalable Electrosynthesis of Formamide through C?N Coupling at the Industrially Relevant Current Density of 120?mA?cm?2.

在 120 mA cm?2 的工業(yè)相關電流密度下通過 CN 耦合可擴展甲酰胺電合成。

64.An anthracene-based molecular crystal with a unique "slipped herringbone" packing motif was developed by crystal engineering through terminal tert-butylation. Appropriate exciton–exciton coupling/electron–phonon coupling originating from the unique crystal packing induces a remarkably strong solid-state emission and efficient charge transport, as reported by Wenping Hu et?al. in their Research Article (e202206825).

通過末端叔丁基化的晶體工程開發(fā)了一種具有獨特“滑動人字形”堆積圖案的蒽基分子晶體。正如 Wenping Hu 等人在他們的研究文章（e202206825）中報道的那樣，源自獨特晶體堆積的適當?shù)募ぷ?激子耦合/電子-聲子耦合誘導了非常強的固態(tài)發(fā)射和有效的電荷傳輸。

65.A proton conductive hydrogen-bonded organic framework (HOF) was constructed from a C3-symmetric hexatopic carboxylic acid derivative with an 18-crown-6-ether component. Despite the flexibility of the macrocycle, H-bonding modules allow the derivative to yield a hexagonally networked framework with permanent porosity. As reported by Takayoshi Nakamura, Ichiro Hisaki, and co-workers in their Communication (e202211686), the HOF possesses 1D channels with a bottleneck composed of the macrocycles and shows proton conductivity (1.12×10?7 S?cm?1) through the Grotthuss mechanism (Ea=0.27?eV) under 98?%RH.

由具有 18-冠-6-醚組分的 C3 對稱六位羧酸衍生物構建了質子傳導氫鍵有機骨架 (HOF)。盡管大環(huán)具有靈活性，但氫鍵模塊允許衍生物產生具有永久孔隙率的六邊形網(wǎng)絡框架。正如 Takayoshi Nakamura、Ichiro Hisaki 及其同事在他們的 Communication (e202211686) 中所報道的，HOF 擁有由大環(huán)組成的瓶頸的一維通道，并通過 Grotthuss 顯示出質子傳導性 (1.12×10?7 S cm?1) 98%RH 下的機制（Ea=0.27 eV）。

66.The formation of ultrathin nanowires has thermodynamic advantages at low temperature. However, at low temperatures the monomers for nanocrystal growth are difficult to generate through precursor decomposition. In their Research Article (e202212251), Di Qiu, Yaping Du, and co-workers report an efficient growth process based on adding polyoxometalate clusters to the monomers. Fifteen types of rare earth oxide ultrathin nanowires were synthesized, all exhibiting polymer-like behavior due to the extremely high aspect ratio.

超細納米線的形成在低溫下具有熱力學優(yōu)勢。然而，在低溫下，用于納米晶體生長的單體很難通過前體分解產生。在他們的研究文章 (e202212251) 中，Di Qiu、Yaping Du 和同事報告了一種基于向單體添加多金屬氧酸鹽簇的高效生長過程。合成了十五種稀土氧化物超細納米線，由于極高的長徑比，所有這些納米線都表現(xiàn)出類似聚合物的行為。

67.A non-enzymatic circuitry activation strategy can realize an orthogonally controlled catalytic DNA (CCD) circuit through multiple molecular recognition events and progressively accelerated signal amplification, as reported by Fuan Wang and co-workers in their Research Article (e202206529). The on-site activated CCD circuitry system has considerable potential for high-precision in?vivo imaging of low-abundance microRNA.

Fuan Wang 及其同事在他們的研究文章 (e202206529) 中報道，非酶電路激活策略可以通過多個分子識別事件和逐漸加速的信號放大來實現(xiàn)正交控制的催化 DNA (CCD) 電路。現(xiàn)場激活的 CCD 電路系統(tǒng)在低豐度 microRNA 的高精度體內成像方面具有巨大的潛力。

68.The Control of the Coordination Chemistry for the Genesis of Heterogeneous Catalytically Active Sites in Oxidation Reactions.

氧化反應中異質催化活性位點生成的配位化學控制。

69.Antibiotic-Derived Radiotracers for Positron Emission Tomography: Nuclear or “Unclear” Infection Imaging?.

用于正電子發(fā)射斷層掃描的抗生素衍生放射性示蹤劑：核或“不清楚”的感染成像？

70.Rationally Designing Efficient Electrocatalysts for Direct Seawater Splitting: Challenges, Achievements, and Promises.

合理設計用于直接海水分解的高效電催化劑：挑戰(zhàn)、成就和承諾。

71.On-Site Non-enzymatic Orthogonal Activation of a Catalytic DNA Circuit for Self-Reinforced In Vivo MicroRNA Imaging.

用于自我強化體內 MicroRNA 成像的催化 DNA 電路的現(xiàn)場非酶促正交激活。

72.Regulating Crystal Packing by Terminal tert-Butylation for Enhanced Solid-State Emission and Efficacious Charge Transport in an Anthracene-Based Molecular Crystal.

通過末端叔丁基化調節(jié)晶體堆積，以增強蒽基分子晶體中的固態(tài)發(fā)射和有效電荷傳輸。

73.Affinity Bioorthogonal Chemistry (ABC) Tags for Site-Selective Conjugation, On-Resin Protein-Protein Coupling, and Purification of Protein Conjugates.

用于位點選擇性綴合、樹脂上蛋白質-蛋白質偶聯(lián)和蛋白質綴合物純化的親和生物正交化學 (ABC) 標簽。

74.Linker Redox Mediated Control of Morphology and Properties in Semiconducting Iron-Semiquinoid Coordination Polymers.

連接體氧化還原介導的半導體鐵-半醌配位聚合物的形態(tài)和性能控制。

75.Simultaneous Photo-Induced Magnetic and Dielectric Switching in an Iron(II)-Based Spin-Crossover Hofmann-Type Metal-Organic Framework.

鐵（II）基自旋交叉霍夫曼型金屬有機框架中同時光致磁和介電開關。

76.Dual-Gradient Unified Chromatography: A New Paradigm for Versatility in Simultaneous Multicomponent Analysis.

雙梯度統(tǒng)一色譜：同時多組分分析多功能性的新范例。

77.Mechanistic Insights into the Phase Separation Behavior and Pathway-Directed Information Exchange in all-DNA Droplets.

對全 DNA 液滴中相分離行為和通路定向信息交換的機制見解。

78.Uncertainty Quantification of Michaelis–Menten Kinetic Rates and Its Application to the Analysis of CRISPR-Based Diagnostics.

Michaelis-Menten 動力學速率的不確定性量化及其在基于 CRISPR 的診斷分析中的應用。

79.Metal-Free Allylic C?H Amination of Vinylsilanes and Vinylboronates using Silicon or Boron as a Regioselectivity Switch.

使用硅或硼作為區(qū)域選擇性開關對乙烯基硅烷和乙烯基硼酸酯進行無金屬烯丙基 C?H 胺化。

80.Target-Triggered Formation of Artificial Enzymes on Filamentous Phage for Ultrasensitive Direct Detection of Circulating miRNA Biomarkers in Clinical Samples.

絲狀噬菌體上人工酶的靶向觸發(fā)形成，用于臨床樣本中循環(huán) miRNA 生物標志物的超靈敏直接檢測。

81.Salting-Out Aldehyde from the Electrooxidation of Alcohols with 100?% Selectivity.

從醇的電氧化中鹽析出醛，選擇性為 100%。

82.Cascade Cyclopolymerization of 5-Ethynyl-1,8-Nonadiyne Derivatives to Synthesize Low Band Gap Conjugated Polyacetylenes Containing a Fused Bicyclic Structure.

5-乙炔基-1,8-壬二炔衍生物的級聯(lián)環(huán)聚合合成含有稠合雙環(huán)結構的低帶隙共軛聚乙炔。

83.Decarboxylative Selective Phosphorylation of Aliphatic Acids: A Transition-Metal- and Photocatalyst-Free Avenue to Dialkyl and Trialkyl Phosphine Oxides from White Phosphorus.

脂肪酸的脫羧選擇性磷酸化：從白磷制備二烷基和三烷基氧化膦的無過渡金屬和光催化劑的途徑。

84.Enantiomeric NIR-II Emitting Rare-Earth-Doped Ag2Se Nanoparticles with Differentiated In Vivo Imaging Efficiencies.

對映體 NIR-II 發(fā)射稀土摻雜 Ag2Se 納米顆粒，具有差異化的體內成像效率。

85.An Ion-Enhanced Oncolytic Virus-Like Nanoparticle for Tumor Immunotherapy.

用于腫瘤免疫治療的離子增強型溶瘤病毒樣納米顆粒。

86.Aggregation-Dependent Circularly Polarized Luminescence and Thermally Activated Delayed Fluorescence from Chiral Carbene-CuI-Amide Enantiomers.

手性卡賓-CuI-酰胺對映體的聚集依賴性圓偏振發(fā)光和熱激活延遲熒光。

87.Regio- and Diastereoselective Formal [2+2] Cycloaddition of Allenes with Amino-Functionalized Alkenes by Rare-Earth-Catalyzed C(sp2)?H Activation.

通過稀土催化的 C(sp2)?H 活化，艾倫烯與氨基官能化烯烴的區(qū)域和非對映形式 [2+2] 環(huán)加成。

88.Intramolecular Thiol- and Selenol-Assisted Delivery of Hydrogen Sulfide.

分子內硫醇和硒醇輔助的硫化氫傳遞。

89.Vibration-Assisted Charge Transport through Positively Charged Dimer Junctions.

通過帶正電荷的二聚體結進行振動輔助電荷傳輸。

90.Photoredox-Catalyzed Deoxygenation of Hexafluoroacetone Hydrate Enables Hydroxypolyfluoroalkylation of Alkenes.

六氟丙酮水合物的光氧化還原催化脫氧能夠實現(xiàn)烯烴的羥基多氟烷基化。

91.Microbial Fermentation of Polyethylene Terephthalate (PET) Plastic Waste for the Production of Chemicals or Electricity.

用于生產化學品或電力的聚對苯二甲酸乙二醇酯 (PET) 塑料廢物的微生物發(fā)酵。

92.Asymmetric Construction of an Aryl-Alkene Axis by Palladium-Catalyzed Suzuki–Miyaura Coupling Reaction.

鈀催化的 Suzuki-Miyaura 偶聯(lián)反應不對稱構建芳基-烯烴軸。

93.Human Cyclophilin B Nuclease Activity Revealed via Nucleic Acid-Based Electrochemical Sensors.

通過核酸電化學傳感器揭示人親環(huán)蛋白 B 核酸酶活性。

94.Diatomic Pd?Cu Metal-Phosphorus Sites for Complete N≡N Bond Formation in Photoelectrochemical Nitrate Reduction.

雙原子 Pd?Cu 金屬-磷位點在光電化學硝酸鹽還原中形成完整的 N=N 鍵。

95.Discovery of a Unique Structural Motif in Lanthipeptide Synthetases for Substrate Binding and Interdomain Interactions.

發(fā)現(xiàn)蘭硫肽合成酶中用于底物結合和域間相互作用的獨特結構基序。

96.Redesign of Rifamycin Antibiotics to Overcome ADP-Ribosylation-Mediated Resistance.

重新設計利福霉素抗生素以克服 ADP 核糖基化介導的耐藥性。

97.Ag22 Nanoclusters with Thermally Activated Delayed Fluorescence Protected by Ag/Cyanurate/Phosphine Metallamacrocyclic Monolayers through In-Situ Ligand Transesterification.

Ag22 納米團簇通過原位配體酯交換受到 Ag/氰尿酸鹽/膦金屬大環(huán)單層保護，具有熱激活延遲熒光。