聲明：本專欄主要對生命科學(xué)領(lǐng)域的一些期刊文章標(biāo)題進行翻譯，所有內(nèi)容均由本人手工整理翻譯。由于本人專業(yè)為生物分析相關(guān)，其他領(lǐng)域如果出現(xiàn)翻譯錯誤請諒解。

A protection-group-free, metal-free, and atom-economical chemistry combining hydroxyl-yne and thiol-ene click reactions was developed, by which sequence-defined linear and topological oligo(monothioacetal)s for high-density data storage were efficiently prepared.

開發(fā)了一種結(jié)合羥基-炔和硫醇-烯點擊反應(yīng)的無保護基團、無金屬和原子經(jīng)濟化學(xué)，通過這種化學(xué)方法有效地制備了用于高密度數(shù)據(jù)存儲的序列定義的線性和拓撲低聚物（單硫縮醛）.

A label-free nanophotonic biosensor was developed to detect pseudotyped SARS-CoV-2 with single-virus resolution by virtue of elastically scattered light. With DNA aptamers as the biorecognition element, the nanosensor can effectively capture and count individual active viruses in preference to deactivated viruses, providing a novel and versatile strategy for low-cost virus detection.

開發(fā)了一種無標(biāo)記的納米光子生物傳感器，以利用彈性散射光以單病毒分辨率檢測假型 SARS-CoV-2。 以 DNA 適體作為生物識別元件，納米傳感器可以有效地捕獲和計數(shù)單個活性病毒，而不是滅活病毒，為低成本病毒檢測提供了一種新穎、通用的策略。

Monovalent and multivalent cations in the electrolyte influence electrocatalytic water reduction and CO2 reduction, primarily by cation accumulation in the double layer.

電解質(zhì)中的單價和多價陽離子主要通過雙層中的陽離子積累影響電催化水還原和 CO2 還原。

Asymmetric porous hollow carbon nanoparticles are prepared via a kinetics-controlled interfacially super-assembly strategy through the precise regulation of polymerization and assembly rates of two kinds of precursors. The unique structure and unexpected excellent photothermal performance endow these nanoparticles with the ability to serve as smart NIR light-driven nanovehicles.

通過精確調(diào)節(jié)兩種前體的聚合和組裝速率，通過動力學(xué)控制的界面超組裝策略制備不對稱多孔中空碳納米粒子。 獨特的結(jié)構(gòu)和意想不到的優(yōu)異光熱性能賦予這些納米粒子作為智能近紅外光驅(qū)動納米載體的能力。

Novel single-fluorophore-based white-light-emitting polymers, which exhibit excellent color reproducibility via an excited-state intramolecular proton-transfer (ESIPT) process, have been developed through a powerful direct C–H amidation polymerization. Fine tunability of hydrogen bond strength enables white-light generation by controlling relative emission intensities between blue and yellow lights.

通過強大的直接 C-H 酰胺化聚合開發(fā)了新型基于單熒光團的白光發(fā)光聚合物，其通過激發(fā)態(tài)分子內(nèi)質(zhì)子轉(zhuǎn)移 (ESIPT) 過程表現(xiàn)出出色的顏色再現(xiàn)性。 氫鍵強度的微調(diào)性可以通過控制藍光和黃光之間的相對發(fā)射強度來產(chǎn)生白光。

Multiple chemically equivalent reactive sites are selectively and precisely activated by scanning probe microscopy tip-controlled plasmonic resonance at the submolecular scale.

通過掃描探針顯微鏡尖端控制的亞分子尺度等離子體共振，選擇性且精確地激活多個化學(xué)等效的反應(yīng)位點。

Expanding the dynamic chemistry toolbox is key to future smart materials. An emerging class of poly(disulfide)s featuring reversible disulfide-mediated ring-opening polymerization offers many opportunities in designing materials with unique dynamic functions, such as self-healing ability, responsiveness, adaptability, and chemical recyclability.

擴展動態(tài)化學(xué)工具箱是未來智能材料的關(guān)鍵。 一類新興的聚（二硫化物）具有可逆二硫化物介導(dǎo)的開環(huán)聚合，為設(shè)計具有獨特動態(tài)功能的材料提供了許多機會，例如自愈能力、響應(yīng)能力、適應(yīng)性和化學(xué)可回收性。

The image illustrates electrochemical carbon dioxide capture and release with a redox-active amine. Carbon dioxide was captured from the air by reduction potential and released as a pure gas by oxidation potential.

該圖說明了氧化還原活性胺的電化學(xué)二氧化碳捕獲和釋放。 二氧化碳通過還原電位從空氣中捕獲，并通過氧化電位作為純氣體釋放。

Single vacancies in defective graphene can trap atomic Pt to form a specific Pt–C3 configuration, which improves electron capture and lowers the Gibbs free energy difference (ΔG). The unique configuration promotes the reduction of adsorbed H2O and accelerates the H2 desorption, thus exhibiting extraordinary HER activity.

有缺陷的石墨烯中的單個空位可以捕獲原子 Pt 以形成特定的 Pt-C3 構(gòu)型，從而改善電子捕獲并降低吉布斯自由能差 (ΔG)。 獨特的構(gòu)型促進了吸附H2O的還原并加速了H2的解吸，從而表現(xiàn)出非凡的HER活性。

Blue LED irradiation induced a copper-catalyzed highly enantioselective umpolung allylic acylation reaction with acylsilanes as acyl anion equivalents. Copper-to-acyl metal-to-ligand charge transfer (MLCT) photoexcitation of an acylcopper complex with a chiral NHC ligand generates a charge-separated triplet state as a highly reactive ketyl radical-type intermediate.

藍色 LED 照射誘導(dǎo)了銅催化的高對映選擇性 umpolung 烯丙基酰化反應(yīng)，?；柰樽鳛轷；庪x子等價物。 具有手性 NHC 配體的?；~絡(luò)合物的銅-?；饘?配體電荷轉(zhuǎn)移 (MLCT) 光激發(fā)產(chǎn)生電荷分離的三重態(tài)作為高反應(yīng)性的羰基自由基型中間體。

Self-assembled metal–phenolic networks (MPNs) can be formed on the surface of microbes. These coatings were found to protect next-generation microbial biotherapeutics from harsh processing conditions and oxygen exposure. Cover image and design: Felice Frankel

自組裝金屬酚網(wǎng)絡(luò) (MPNs) 可以在微生物表面形成。 這些涂層被發(fā)現(xiàn)可以保護下一代微生物生物治療藥物免受惡劣的加工條件和氧氣暴露。 封面圖片和設(shè)計：Felice Frankel

N2 was efficiently split on a MoII complex, induced by visible light irradiation, forming the MoV terminal nitride. After the N–P coupling and hydrolysis, the N atom from N2 was transferred into iminophosphorane ultimately.

在可見光照射下，N2 在 MoII 絡(luò)合物上有效分裂，形成 MoV 末端氮化物。 N-P偶聯(lián)和水解后，N2中的N原子最終被轉(zhuǎn)移到亞氨基正膦中。

A new class of thiol-containing polymers was synthesized. Dithiocatechol-pendant polymers were synthesized from their precursor polymers using lithium and naphthalene. This work paves the way toward the exploitation of dithiocatechol-containing polymers for engineering functional materials.

合成了一類新的含硫醇聚合物。 二硫代兒茶酚懸垂聚合物是使用鋰和萘從其前體聚合物合成的。 這項工作為開發(fā)含二硫代兒茶酚的聚合物用于工程功能材料鋪平了道路。

Copper K-edge X-ray absorption and valence-to-core X-ray emission spectroscopy of organocopper complexes in +1, +2, and +3 formal oxidation states reveals identifiable trends consistent with increased effective nuclear charge (deeper binding energy) for higher oxidation states.

+1、+2 和 +3 形式氧化態(tài)的有機銅配合物的銅 K 邊 X 射線吸收和價核 X 射線發(fā)射光譜揭示了與有效核電荷增加（更深的結(jié)合能）一致的可識別趨勢更高的氧化態(tài)。

Unprecedented switch between thermally activated fluorescence (TAF) and long persistent luminescence (LPL) is achieved in a unique ESIPT-attributed coordination polymer, manifesting the relevance and balance among reverse intersystem crossing (RISC), intersystem crossing (ISC), and internal conversion (IC).

在一種獨特的 ESIPT 配位聚合物中實現(xiàn)了熱激活熒光 (TAF) 和長余輝發(fā)光 (LPL) 之間前所未有的轉(zhuǎn)換，體現(xiàn)了反向系統(tǒng)間交叉 (RISC)、系統(tǒng)間交叉 (ISC) 和內(nèi)部轉(zhuǎn)換（IC）之間的相關(guān)性和平衡。

In this work, a straightforward synthetic strategy to design a single-component organic long persistent luminescent (OLPL) system with detectable afterglow for at least 12 min under ambient conditions is presented. This work demonstrates a new design principle that can simplify the design and production of new OLPL materials.

在這項工作中，提出了一種直接的合成策略，用于設(shè)計單組分有機長余輝發(fā)光 (OLPL) 系統(tǒng)，該系統(tǒng)在環(huán)境條件下可檢測余輝至少 12 分鐘。 這項工作展示了一種新的設(shè)計原則，可以簡化新 OLPL 材料的設(shè)計和生產(chǎn)。

A critical stage in the SARS-CoV-2 infection is the fusion of host and viral membranes induced by the spike protein. Calcium drives the N-terminal of the spike's fusion domain to fully cross the host membrane, while another region of the domain bridges viral and host membranes, thereby facilitating fusion.

SARS-CoV-2 感染的一個關(guān)鍵階段是由刺突蛋白誘導(dǎo)的宿主和病毒膜的融合。 鈣驅(qū)動刺突融合域的 N 端完全穿過宿主膜，而該域的另一個區(qū)域橋接病毒和宿主膜，從而促進融合。

A porous ionic crystal based on a Keggin-type polyoxometalate and a Cr complex was utilized as an electrocatalyst for oxygen evolution reaction under nonbasic conditions, taking advantage of its designability and well-defined structure. The synergistic catalysis originates from the increased electron density of the polyoxometalate via charge transfer from the Cr complex.

基于 Keggin 型多金屬氧酸鹽和 Cr 絡(luò)合物的多孔離子晶體被用作非堿性條件下析氧反應(yīng)的電催化劑，利用其可設(shè)計性和明確的結(jié)構(gòu)。 協(xié)同催化源于多金屬氧酸鹽通過 Cr 絡(luò)合物的電荷轉(zhuǎn)移增加的電子密度。

Metallosupramolecular cages assembled from diazocine photoswitches are converted between a yellow-colored thermodynamically stable cis-form and its red trans-isomer by irradiation. Only the trans-cage can bind a guest. The host–guest complex is a transient species that falls apart via thermal backswitching unless its population is sustained by continuous irradiation.

由重氮辛光開關(guān)組裝而成的金屬超分子籠通過輻照在黃色熱力學(xué)穩(wěn)定的順式異構(gòu)體與其紅色反式異構(gòu)體之間進行轉(zhuǎn)換。 只有傳送籠才能綁定客體。 主客體復(fù)合體是一種瞬態(tài)物種，除非其種群通過連續(xù)輻射維持，否則會通過熱反向切換而分裂。

The combination of single-molecule electrical detection and kinetic isotope effect provides a powerful tool to determine the rate-determining step and accurately quantify the transition state structure in a reaction, therefore establishing a novel approach for controlling the transition state by an electric field.

單分子電檢測和動力學(xué)同位素效應(yīng)的結(jié)合為確定反應(yīng)中的決速步驟和準(zhǔn)確量化反應(yīng)中的過渡態(tài)結(jié)構(gòu)提供了有力的工具，從而建立了一種通過電場控制過渡態(tài)的新方法。

1.Mechanistic Aspects of Cobalt–Oxo Cubane Clusters in Oxidation Chemistry.

鈷-氧立方體簇在氧化化學(xué)中的機制方面。

2.Aptamers Entirely Built from Therapeutic Nucleoside Analogues for Targeted Cancer Therapy.

完全由治療性核苷類似物構(gòu)建的適配體用于癌癥靶向治療。

3.Label-Free Digital Detection of Intact Virions by Enhanced Scattering Microscopy.

增強型散射顯微鏡下的無標(biāo)簽數(shù)字檢測病毒的方法.

4.Cationic Effects on the Net Hydrogen Atom Bond Dissociation Free Energy of High-Valent Manganese Imido Complexes.

陽離子對高價錳亞氨基化合物凈氫原子鍵解離自由能的影響.

5.Fluorescent Colloidal Ferroelectric Nanocrystals.

熒光膠體鐵電納米晶體.

6.Efficient Pulsed Dynamic Nuclear Polarization with the X-Inverse-X Sequence.

X-Inverse-X 序列的高效脈沖動態(tài)核偏振.

7.Facile Synthesis of the Dicyanophosphide Anion via Electrochemical Activation of White Phosphorus: An Avenue to Organophosphorus Compounds.

通過白磷的電化學(xué)活化方便地合成二氰化磷陰離子： 通往有機磷化合物的道路。

8.Room-Temperature Fast H– Conduction in Oxygen-Substituted Lanthanum Hydride.

氧取代的鑭系氫化物中的室溫快速氫傳導(dǎo)。

9.Total Syntheses of Scabrolide A and Nominal Scabrolide B.

赤蘚內(nèi)酯A和赤蘚內(nèi)酯B的全合成。

10.Organometallic Fe2(μ-SH)2(CO)4(CN)2 Cluster Allows the Biosynthesis of the [FeFe]-Hydrogenase with Only the HydF Maturase.

有機金屬Fe2(μ-SH)2(CO)4(CN)2簇允許只用HydF母體酶進行[FeFe]-氫化酶的生物合成。

11.Entanglement of Square Nets in Covalent Organic Frameworks.

共價有機框架中方網(wǎng)的糾纏。

12.Engineering a Hyperstable Yersinia pestis Outer Membrane Protein Ail Using Thermodynamic Design.

使用熱力學(xué)設(shè)計來設(shè)計超穩(wěn)定的耶爾森氏菌外膜蛋白Ail。

13.Electrochemical Strategy for the Simultaneous Production of Cyclohexanone and Benzoquinone by the Reaction of Phenol and Water.

酚與水反應(yīng)同時生產(chǎn)環(huán)己酮和苯醌的電化學(xué)策略。

14.Color-Changing Fluorescent Barcode Based on Strand Displacement Reaction Enables Simple Multiplexed Labeling.

基于鏈?zhǔn)街脫Q反應(yīng)的變色熒光條形碼實現(xiàn)了簡單的多重標(biāo)記。

15.Ultrasmall Magneto-chiral Cobalt Hydroxide Nanoparticles Enable Dynamic Detection of Reactive Oxygen Species in Vivo.

超小磁手性氫氧化鈷納米粒子可在體內(nèi)動態(tài)檢測活性氧物質(zhì)。

16.The Role of Cation Acidity on the Competition between Hydrogen Evolution and CO2 Reduction on Gold Electrodes.

陽離子酸度在金電極上氫氣進化和二氧化碳還原競爭中的作用。

17.Kinetic Modulation of Amyloid-β (1–42) Aggregation and Toxicity by Structure-Based Rational Design.

基于結(jié)構(gòu)的合理設(shè)計對淀粉樣β（1-42）聚集和毒性的動力學(xué)調(diào)控。

18.Colloidal Platinum–Copper Nanocrystal Alloy Catalysts Surpass Platinum in Low-Temperature Propene Combustion.

膠體鉑-銅納米晶合金催化劑在低溫丙烯燃燒中超過了鉑。

19.Biosynthesis of Tasikamides via Pathway Coupling and Diazonium-Mediated Hydrazone Formation.

Tasikamides的生物合成通過路徑耦合和偶氮化合物介導(dǎo)的腙形成。

20.Kinetics-Controlled Super-Assembly of Asymmetric Porous and Hollow Carbon Nanoparticles as Light-Sensitive Smart Nanovehicles.

不對稱多孔和空心碳納米粒子的動力學(xué)控制的超級組裝作為光敏智能納米粒子。

21.Catalytic Activation of Bioorthogonal Chemistry with Light (CABL) Enables Rapid, Spatiotemporally Controlled Labeling and No-Wash, Subcellular 3D-Patterning in Live Cells Using Long Wavelength Light.

用光催化激活生物正交化學(xué)(CABL)實現(xiàn)了快速、時空可控的標(biāo)記，以及使用長波長的光在活細胞中進行免洗的亞細胞三維圖案制作。

22.Chiral Generation of Hot Carriers for Polarization-Sensitive Plasmonic Photocatalysis.

用于偏振敏感的等離子體光催化的熱載體的手性生成。

23.Combining Hydroxyl-Yne and Thiol-Ene Click Reactions to Facilely Access Sequence-Defined Macromolecules for High-Density Data Storage.

結(jié)合羥基-炔和硫醇-炔點擊反應(yīng)，方便地訪問高密度數(shù)據(jù)存儲的序列定義的大分子。

24.Metal–Organic Framework Based Hydrogen-Bonding Nanotrap for Efficient Acetylene Storage and Separation.

基于金屬有機框架的氫鍵納米捕集器用于高效乙炔儲存和分離.

25.Secondary Amine Pendant β-Peptide Polymers Displaying Potent Antibacterial Activity and Promising Therapeutic Potential in Treating MRSA-Induced Wound Infections and Keratitis.

二級胺掛件β-肽聚合物在治療MRSA誘導(dǎo)的傷口感染和角膜炎中顯示出強大的抗菌活性和良好的治療潛力。

26.Chemical Polishing of Perovskite Surface Enhances Photovoltaic Performances.

過氧化物表面的化學(xué)拋光增強了光伏性能。

27.Multiple Proton-Coupled Electron Transfers at a Tricopper Cluster: Modeling the Reductive Regeneration Process in Multicopper Oxidases.

三銅簇上的多質(zhì)子耦合電子轉(zhuǎn)移： 多銅氧化酶中還原再生過程的建模。

28.Direct Measurement of Interhelical DNA Repulsion and Attraction by Quantitative Cross-Linking.

通過定量交聯(lián)直接測量螺旋間DNA的排斥力和吸引力。

29.Pickering Interfacial Catalysis for Aerobic Alcohol Oxidation in Oil Foams.

Pickering界面催化作用在油泡沫中的有氧酒精氧化。

30.Short-Range Backbone Dihedral Rotations Modulate Internal Friction in Intrinsically Disordered Proteins.

短程骨架二面體旋轉(zhuǎn)調(diào)節(jié)本征無序蛋白質(zhì)的內(nèi)部摩擦力

31.Energy Counterbalance to Harness Photoinduced Structural Planarization of Dibenzo[b,f]azepines toward Thermal Reversibility.

利用光誘導(dǎo)的二苯并[b,f]氮雜卓結(jié)構(gòu)平面化的能量平衡，實現(xiàn)熱可逆性。

32.Synthesis of Silacyclic Dipeptides: Peptide Elongation at Both N- and C-Termini of Dipeptide.

硅環(huán)類二肽的合成： 在二肽的N端和C端都有肽的延伸。

33.Evidence for Entropically Controlled Interfacial Hydration in Mesoporous Organosilicas.

中多孔有機硅中熵控界面水化的證據(jù)。

34.Powerful Direct C–H Amidation Polymerization Affords Single-Fluorophore-Based White-Light-Emitting Polysulfonamides by Fine-Tuning Hydrogen Bonds.

通過微調(diào)氫鍵，強大的直接C-H氨化聚合產(chǎn)生了基于單氟的白光發(fā)光聚磺酰胺。

35.Alkali Metal Ions Dictate the Structure and Reactivity of an Iron(II) Imido Complex.

堿金屬離子決定了鐵(II)亞氨基化合物的結(jié)構(gòu)和反應(yīng)性。

36.Opening Diffusion Pathways through Site Disorder: The Interplay of Local Structure and Ion Dynamics in the Solid Electrolyte Li6+xP1–xGexS5I as Probed by Neutron Diffraction and NMR.

通過位點紊亂打開擴散途徑： 中子衍射和核磁共振探測的固體電解質(zhì)Li6+xP1-xGexS5I的局部結(jié)構(gòu)和離子動力學(xué)的相互作用。

37.Both Charge-Regulation and Charge-Patch Distribution Can Drive Adsorption on the Wrong Side of the Isoelectric Point.

電荷調(diào)控和電荷斑點分布都能促使吸附在等電點的錯誤一側(cè)。

38.Water Sorption Evolution Enabled by Reticular Construction of Zirconium Metal–Organic Frameworks Based on a Unique [2.2]Paracyclophane Scaffold.

基于獨特的[2.2]Paracyclophane支架的鋯金屬有機框架的網(wǎng)狀結(jié)構(gòu)所促成的水吸附進化。

39.The Role of Charge Density Coupled DNA Bending in Transcription Factor Sequence Binding Specificity: A Generic Mechanism for Indirect Readout.

電荷密度耦合的DNA彎曲在轉(zhuǎn)錄因子序列結(jié)合特異性中的作用： 一個間接讀出的通用機制。

40.A Tunable Structural Family with Ultralow Thermal Conductivity: Copper-Deficient Cu1–x□xPb1–xBi1+xS3.

具有超低導(dǎo)熱性的可調(diào)結(jié)構(gòu)系列： 缺銅的Cu1-x□xPb1-xBi1+xS3.

41.Confining and Highly Dispersing Single Polyoxometalate Clusters in Covalent Organic Frameworks by Covalent Linkages for CO2 Photoreduction.

通過共價連接封閉和高度分散共價有機框架中的單個多氧金屬簇，用于二氧化碳光還原。

42.Access to β-Lactams via Iron-Catalyzed Olefin Oxyamidation Enabled by the π-Accepting Phthalocyanine Ligand.

通過鐵催化烯烴氧胺化獲得β-內(nèi)酰胺的π-受體酞菁配體的作用。

43.Mechanistically Guided Workflow for Relating Complex Reactive Site Topologies to Catalyst Performance in C–H Functionalization Reactions.

復(fù)雜反應(yīng)位點拓撲結(jié)構(gòu)與C-H功能化反應(yīng)中催化劑性能相關(guān)的機制指導(dǎo)工作流程。

44.Radical Carbonyl Umpolung Arylation via Dual Nickel Catalysis.

通過雙鎳催化的自由基羰基烏姆波隆芳構(gòu)化。

45.Atomically Resolved Electrically Active Intragrain Interfaces in Perovskite Semiconductors.

過氧化物半導(dǎo)體中原子分辨的電活性粒內(nèi)界面.

46.Highly Dispersed Platinum Chlorine Atoms Anchored on Gold Quantum Dots for a Highly Efficient Electrocatalyst.

錨定在金量子點上的高度分散的鉑氯原子的高效電催化劑。

47.Photoinduced Regioselective Olefination of Arenes at Proximal and Distal Sites.

光誘導(dǎo)的近端和遠端 Arenes 的選擇性烯烴化。

48.Backbone Hydrocarbon-Constrained Nucleic Acids Modulate Hybridization Kinetics for RNA.

主鏈烴限制性核酸調(diào)節(jié) RNA 的雜交動力學(xué)。

49.A Unified and Desymmetric Approach to Chiral Tertiary Alkyl Halides.

手性叔烷基鹵化物的統(tǒng)一和不對稱方法。

50.General Synthesis of N-Trifluoromethyl Compounds with N-Trifluoromethyl Hydroxylamine Reagents.

N-三氟甲基化合物與N-三氟甲基羥胺試劑的一般合成。

51.Dispersion and Steric Effects on Enantio-/Diastereoselectivities in Synergistic Dual Transition-Metal Catalysis.

協(xié)同雙過渡金屬催化中對映體/非對映體選擇性的分散和立體效應(yīng)。

52.Merging Halogen-Atom Transfer (XAT) and Copper Catalysis for the Modular Suzuki–Miyaura-Type Cross-Coupling of Alkyl Iodides and Organoborons.

鹵素原子轉(zhuǎn)移（XAT）和銅催化合并用于烷基碘化物和有機硼的模塊化鈴木-米亞拉型交叉耦合。

53.Modulating the Reactivity of Liquid Ga Nanoparticle Inks by Modifying Their Surface Chemistry.

通過改變表面化學(xué)來調(diào)節(jié)液態(tài)Ga納米粒子油墨的反應(yīng)性。

54.Pathways for Electron Transfer at MgO–Water Interfaces from Ab Initio Molecular Dynamics.

來自Ab Initio分子動力學(xué)的氧化鎂-水界面電子轉(zhuǎn)移的途徑。

55.Progressive Local Accumulation of Self-Assembled Nanoreactors in a Hydrogel Matrix through Repetitive Injections of ATP.

通過重復(fù)注入ATP在水凝膠基質(zhì)中逐步實現(xiàn)自組裝納米反應(yīng)器的局部積累。

56.Correction to “Chemically Stable Carbazole-Based Imine Covalent Organic Frameworks with Acidochromic Response for Humidity Control Applications”.

對 "化學(xué)上穩(wěn)定的基于咔唑的亞胺共價有機框架的濕度控制應(yīng)用 "的更正。

57.Disulfide-Mediated Reversible Polymerization toward Intrinsically Dynamic Smart Materials.

二硫化物介導(dǎo)的可逆聚合走向內(nèi)在動態(tài)智能材料。

58.Carbon Monoxide in Main-Group Chemistry.

主族化學(xué)中的一氧化碳。

59.Controlling Localized Plasmons via an Atomistic Approach: Attainment of Site-Selective Activation inside a Single Molecule.

通過原子學(xué)方法控制局部質(zhì)子： 單一分子內(nèi)實現(xiàn)位點選擇的激活。

60.Synthesis and Characterization of Enantiopure Chiral Bis NHC-Stabilized Edge-Shared Au10 Nanocluster with Unique Prolate Shape.

具有獨特形狀的對映純手性雙NHC穩(wěn)定的邊緣共享Au10納米團簇的合成和特征。

61.Electrochemical Ring-Opening Dicarboxylation of Strained Carbon–Carbon Single Bonds with CO2: Facile Synthesis of Diacids and Derivatization into Polyesters.

緊張的碳-碳單鍵與二氧化碳的電化學(xué)開環(huán)脫羧反應(yīng)： 二元酸的簡易合成及衍生為聚酯的方法.

62.In Vitro Selection of Foldamer-Like Macrocyclic Peptides Containing 2-Aminobenzoic Acid and 3-Aminothiophene-2-Carboxylic Acid.

體外選擇含有2-氨基苯甲酸和3-氨基噻吩-2-羧酸的類似折疊器的大環(huán)肽。

63.Solid-State Pathway Control via Reaction-Directing Heteroatoms: Ordered Pyridazine Nanothreads through Selective Cycloaddition.

通過反應(yīng)導(dǎo)向雜原子的固態(tài)途徑控制： 通過選擇性環(huán)加成的有序噠嗪納米線。

64.Stabilizing Cu2+ Ions by Solid Solutions to Promote CO2 Electroreduction to Methane.

用固體溶液穩(wěn)定Cu2+離子以促進CO2電還原成甲烷.

65.Precise Control of Radial Catenane Synthesis via Clipping and Pumping.

通過剪輯和泵送精確控制徑向卡特蘭的合成。

66.High-Throughput Activity Profiling of RNA-Cleaving DNA Catalysts by Deoxyribozyme Sequencing (DZ-seq).

通過脫氧核糖核酸酶測序（DZ-seq）對RNA切割DNA催化劑進行高通量活性分析。

67.π-Extended Doublet Open-Shell Graphene Fragments Exhibiting One-Dimensional Chain Stacking.

顯示一維鏈堆積的π-擴展雙殼石墨烯片段。

68.Divergent Reactivity of α,α-Disubstituted Alkenyl Hydrazones: Bench Stable Cyclopropylcarbinyl Equivalents.

α,α-二取代的烯基腙的不同反應(yīng)性： 穩(wěn)定的環(huán)丙基羰基等價物。

69.An N-Fluorinated Imide for Practical Catalytic Imidations.

一種用于實際催化酰亞胺的N-氟化酰亞胺。

70.A Fluorogenic ONOO–-Triggered Carbon Monoxide Donor for Mitigating Brain Ischemic Damage.

一種用于減輕腦缺血損傷的氟化ONOO-觸發(fā)的一氧化碳供體。

71.Native Ambient Mass Spectrometry Imaging of Ligand-Bound and Metal-Bound Proteins in Rat Brain.

大鼠腦中配體結(jié)合和金屬結(jié)合的蛋白質(zhì)的本地環(huán)境質(zhì)譜成像。

72.Revealing the Intrinsic Atomic Structure and Chemistry of Amorphous LiO2-Containing Products in Li–O2 Batteries Using Cryogenic Electron Microscopy.

利用低溫電子顯微鏡揭示鋰-O2電池中含無定形二氧化鋰產(chǎn)品的內(nèi)在原子結(jié)構(gòu)和化學(xué)成分。

73.Emulating Membrane Protein Environments─How Much Lipid Is Required for a Native Structure: Influenza S31N M2.

模仿膜蛋白環(huán)境--本地結(jié)構(gòu)需要多少脂質(zhì)： 流感S31N M2.

74.Programmable Macroscopic Self-Assembly of DNA-Decorated Hydrogels.

可編程宏觀自組裝的DNA裝飾水凝膠.

75.Asymmetric Twisting of C-Centered Octahedral Gold(I) Clusters by Chiral N-Heterocyclic Carbene Ligation.

手性N-雜環(huán)碳化物連接的C-中心八面體金（I）簇的不對稱扭曲。

76.Electrochemical Carbon Dioxide Capture and Release with a Redox-Active Amine.

使用氧化還原活性胺的電化學(xué)二氧化碳捕獲和釋放。

77.Single Carbon Vacancy Traps Atomic Platinum for Hydrogen Evolution Catalysis.

單一碳空位捕獲原子鉑的氫氣進化催化作用。

78.Coordination-Assisted Precise Construction of Metal Oxide Nanofilms for High-Performance Solid-State Batteries.

配位法輔助的高性能固態(tài)電池金屬氧化物納米薄膜的精確構(gòu)建.

79.Boosting the Optoelectronic Performance by Regulating Exciton Behaviors in a Porous Semiconductive Metal–Organic Framework.

通過調(diào)節(jié)多孔半導(dǎo)電金屬有機框架中的激子行為提升光電性能.

80.Altering Ligand Fields in Single-Atom Sites through Second-Shell Anion Modulation Boosts the Oxygen Reduction Reaction.

通過第二殼陰離子調(diào)控改變單原子位點的配體場，促進了氧氣還原反應(yīng)。

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